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Full-Text Articles in Physical Sciences and Mathematics
Ultrahigh Energy Storage Properties In (Sr0.7bi0.2)Tio3-Bi(Mg0.5zr0.5)O3 Lead-Free Ceramics And Potential For High-Temperature Capacitors, Xi Kong, Letao Yang, Zhenxiang Cheng, Shujun Zhang
Ultrahigh Energy Storage Properties In (Sr0.7bi0.2)Tio3-Bi(Mg0.5zr0.5)O3 Lead-Free Ceramics And Potential For High-Temperature Capacitors, Xi Kong, Letao Yang, Zhenxiang Cheng, Shujun Zhang
Australian Institute for Innovative Materials - Papers
2020 by the authors. Due to the enhanced demand for numerous electrical energy storage applications, including applications at elevated temperatures, dielectric capacitors with optimized energy storage properties have attracted extensive attention. In this study, a series of lead-free strontium bismuth titanate based relaxor ferroelectric ceramics have been successfully synthesized by high temperature solid-state reaction. The ultrahigh recoverable energy storage density of 4.2 J/cm3 under 380 kV/cm, with the high efficiency of 88%, was obtained in the sample with x = 0.06. Of particular importance is that this ceramic composition exhibits excellent energy storage performance over a wide work temperature up …
Dielectric And Piezoelectric Properties Of Textured Lead-Free Na0.5bi0.5tio3-Based Ceramics, Nannan Dong, Xiaoyi Gao, Fangquan Xia, Hanxing Liu, Hua Hao, Shujun Zhang
Dielectric And Piezoelectric Properties Of Textured Lead-Free Na0.5bi0.5tio3-Based Ceramics, Nannan Dong, Xiaoyi Gao, Fangquan Xia, Hanxing Liu, Hua Hao, Shujun Zhang
Australian Institute for Innovative Materials - Papers
This work provides a comparative study of the dielectric and piezoelectric properties of randomly oriented and textured 0.88Na 0.5 Bi 0.5 TiO 3 -0.08K 0.5 Bi 0.5 TiO 3 -0.04BaTiO 3 (88NBT) ceramics. Textured ceramics were fabricated by template grain growth (TGG) method using NaNbO 3 (NN) for templates. For textured ceramics with 4 wt% NN templates, a Lotgering factor of 96% and piezoelectric coefficient d 33 of 185 pC/N were obtained. Compared to the randomly oriented ceramics, textured ceramics show lower strain hysteresis (H = 7.6%), higher unipolar strain of 0.041% with corresponding large signal piezoelectric coefficient d 33* …
Perovskite R3c Phase Agcuf3: Multiple Dirac Cones, 100% Spin Polarization And Its Thermodynamic Properties, Minquan Kuang, Tingzhou Li, Zhenxiang Cheng, Houari Khachai, Rabah Khenata, Tie Yang, Tingting Lin, Xiaotian Wang
Perovskite R3c Phase Agcuf3: Multiple Dirac Cones, 100% Spin Polarization And Its Thermodynamic Properties, Minquan Kuang, Tingzhou Li, Zhenxiang Cheng, Houari Khachai, Rabah Khenata, Tie Yang, Tingting Lin, Xiaotian Wang
Australian Institute for Innovative Materials - Papers
Very recently, experimentally synthesized R3c phase LaCuO3 was studied by Zhang, Jiao, Kou, Liao & Du [J. Mater. Chem. C (2018), 6, 6132-6137], and they found that this material exhibits multiple Dirac cones in its non-spin-polarized electronic structure. Motivated by this study, the focus here is on a new R3c phase material, AgCuF3, which has a combination of multiple Dirac cones and 100% spin polarization properties. Compared to the non-spin-polarized system LaCuO3, the spin-polarized Dirac behavior in AgCuF3 is intrinsic. The effects of on-site Coulomb interaction, uniform strain and spin-orbit coupling were added to examine the stability of its multiple …
Preparation And Physical Properties Of A Cr3al Filmwith A Do3structure, Weiqi Zhao, Xuefang Dai, X M. Zhang, Z Mo, Xiaotian Wang, G F. Chen, Zhenxiang Cheng, Guodong Liu
Preparation And Physical Properties Of A Cr3al Filmwith A Do3structure, Weiqi Zhao, Xuefang Dai, X M. Zhang, Z Mo, Xiaotian Wang, G F. Chen, Zhenxiang Cheng, Guodong Liu
Australian Institute for Innovative Materials - Papers
A Cr3Al compound with a DO3 structure has previously been predicted to be nearly half metal and a promising spintronics material; however, its synthesis has not been reported. Here, a Cr3Al compound with a DO3 structure is successfully prepared in thin-film form by the magnetron sputtering method. It was found that the substrate temperature is crucial to the atomic ordering, thin-film density and lattice constant. The lattice constant varies with different substrate temperatures and is smaller than the theoretical equilibrium lattice constant. Theoretical investigations on the electronic structures and magnetic properties indicate that the Cr3Al compound with a DO3 structure …
Improvement Of Thermoelectric Properties And Their Correlations With Electron Effective Mass In Cu1.98sxse1−X, Lanling Zhao, Frank Yun Fei, Jun Wang, Funing Wang, Chunlei Wang, Jichao Li, Ji-Yang Wang, Zhenxiang Cheng, Shi Xue Dou, Xiaolin Wang
Improvement Of Thermoelectric Properties And Their Correlations With Electron Effective Mass In Cu1.98sxse1−X, Lanling Zhao, Frank Yun Fei, Jun Wang, Funing Wang, Chunlei Wang, Jichao Li, Ji-Yang Wang, Zhenxiang Cheng, Shi Xue Dou, Xiaolin Wang
Australian Institute for Innovative Materials - Papers
Sulphur doping effects on the crystal structures, thermoelectric properties, density-of-states, and effective mass in Cu1.98SxSe1−x were studied based on the electrical and thermal transport property measurements, and first-principles calculations. The X-ray diffraction patterns and Rietveld refinements indicate that room temperature Cu1.98SxSe1−x (x=0, 0.02, 0.08, 0.16) and Cu1.98SxSe1−x (x=0.8, 0.9, 1.0) have the same crystal structure as monoclinic-Cu2Se and orthorhombic-Cu2S, respectively. Sulphur doping can greatly enhance zT values when x is in the range of 0.8≤x≤1.0. Furthermore, all doped samples show stable thermoelectric compatibility factors over a broad temperature range from 700 to 1000K, which could greatly benefit their practical applications. …
Systematic Elongation Of Thienyl Linkers And Their Effect On Optical And Electrochemical Properties In Carbazole-Bodipy Donor-Acceptor Systems, Alina Brzeczek, Katarzyna Piwowar, Wojciech Domagala, Mikotaj M. Mikotajczyk, Krzysztof Walczak, Pawel W. Wagner
Systematic Elongation Of Thienyl Linkers And Their Effect On Optical And Electrochemical Properties In Carbazole-Bodipy Donor-Acceptor Systems, Alina Brzeczek, Katarzyna Piwowar, Wojciech Domagala, Mikotaj M. Mikotajczyk, Krzysztof Walczak, Pawel W. Wagner
Australian Institute for Innovative Materials - Papers
Synthesis, spectral and electrochemical properties of a series of new panchromatic BODIPY donor-acceptor-donor derivatives, comprising carbazole conjugated with systematically elongated framework by thiophene-based linkers were investigated. It has been found that elongation of the π-system with one thiophene unit shifts the spectra toward near infrared, while incorporation of next thiophene derivatives has only limited influence on the lowest energy transition, causing no further shift of absorption maxima. Elongation of π-conjugation of the donor arm tunes the electron properties, influencing the ionization potential (IP) and electron affinity (EA) values of the molecules. The experimental results are supported by quantum chemical computations …
Β -Nmr Investigation Of The Depth-Dependent Magnetic Properties Of An Antiferromagnetic Surface, David L. Cortie, T Buck, M Dehn, V L. Karner, R F. Kiefl, C D. P Levy, R M. L Mcfadden, G D. Morris, I Mckenzie, M R. Pearson, Xiaolin Wang, W A. Macfarlane
Β -Nmr Investigation Of The Depth-Dependent Magnetic Properties Of An Antiferromagnetic Surface, David L. Cortie, T Buck, M Dehn, V L. Karner, R F. Kiefl, C D. P Levy, R M. L Mcfadden, G D. Morris, I Mckenzie, M R. Pearson, Xiaolin Wang, W A. Macfarlane
Australian Institute for Innovative Materials - Papers
By measuring the prototypical antiferromagnet α-Fe2O3, we show that it is possible to determine the static spin orientation and dynamic spin correlations within nanometers from an antiferromagnetic surface using the nuclear spin polarization of implanted 8Liþ ions detected with β-NMR. Remarkably, the firstorder Morin spin reorientation in single crystal α-Fe2O3 occurs at the same temperature at all depths between 1 and 100 nm from the (110) surface; however, the implanted nuclear spin experiences an increased 1=T1 relaxation rate at shallow depths revealing soft-surface magnons. The surface-localized dynamics decay towards the bulk with a characteristic length of ϵ ¼ 11 1 …
Improved Superconducting Properties In The Mg11b2 Low Activation Superconductor Prepared By Low-Temperature Sintering, Fang Cheng, Yongchang Liu, Zongqing Ma, M Shahriar Al Hossain, Mehmet Somer
Improved Superconducting Properties In The Mg11b2 Low Activation Superconductor Prepared By Low-Temperature Sintering, Fang Cheng, Yongchang Liu, Zongqing Ma, M Shahriar Al Hossain, Mehmet Somer
Australian Institute for Innovative Materials - Papers
Mg11B2 has a great application prospect in the superconducting coils for fusion reactor as the "low activation superconductors". The un-doped Mg11B2 and Cu-doped Mg11B2 bulks using 11B as a boron precursor were fabricated by low-temperature sintering in present work. It was found that the prepared Mg11B2 low activation superconductors exhibit better Jc performance than all of other Mg11B2 samples reported in previous studies. As for Cu doped Mg11B2, minor Cu addition can obviously improve the Mg11B2 grain crystallization and reduce the amount of MgO impurity. Hence, improved grain connectivity and higher Jc at low fields is obtained in Cu doped …
Ferroelectric And Magnetic Properties Of Aurivillius Bim+1ti3fem−3o3m+3 Thin Films, Tingting Jia, Hideo Kimura, Zhenxiang Cheng, Hongyang Zhao
Ferroelectric And Magnetic Properties Of Aurivillius Bim+1ti3fem−3o3m+3 Thin Films, Tingting Jia, Hideo Kimura, Zhenxiang Cheng, Hongyang Zhao
Australian Institute for Innovative Materials - Papers
Aurivillius Bim+1Ti3Fem−3O3m+3 (m = 4, 5, 6) thin films have been deposited by a pulsed laser deposition system. The x-ray diffraction patterns indicate the formation of orthorhombic phase. The remanent polarization (2Pr) of Bim+1Ti3Fem−3O3m+3 thin films is decreased with the m-number. Positive-up-negative-down measurements indicate the presence of ferroelectric (FE) polarization in as-obtained thin films. Piezoresponse force microscopy investigations confirm the existence of FE domains and the switchable polarization. Weak magnetic moment is detected in the Aurivillius films at room temperature. The present work …
Modulation Of Photocatalytic Properties By Strain In 2d Biobr Nanosheets, Haifeng Feng, Zhongfei Xu, Liang Wang, Youxing Yu, David R. G Mitchell, Dandan Cui, Xun Xu, Ji Shi, Takumi Sannomiya, Yi Du, Weichang Hao, S X. Dou
Modulation Of Photocatalytic Properties By Strain In 2d Biobr Nanosheets, Haifeng Feng, Zhongfei Xu, Liang Wang, Youxing Yu, David R. G Mitchell, Dandan Cui, Xun Xu, Ji Shi, Takumi Sannomiya, Yi Du, Weichang Hao, S X. Dou
Australian Institute for Innovative Materials - Papers
BiOBr nanosheets with highly reactive {001} facets exposed were selectively synthesized by a facile hydrothermal method. The inner strain in the BiOBr nanosheets has been tuned continuously by the pH value. The photocatalytic performance of BiOBr in dye degradation can be manipulated by the strain effect. The low-strain BiOBr nanosheets show improved photocatalytic activity. Density functional calculations suggest that strain can modify the band structure and symmetry in BiOBr. The enhanced photocatalytic activity in low-strain BiOBr nanosheets is due to improved charge separation attributable to a highly dispersive band structure with an indirect band gap.
An Investigation Of The Nanomechanical Properties Of 0.5ba(Ti0.8zr0.2)O3-0.5(Ba0.7ca0.3)Tio3 Thin Films, Zhong-Lan Cai, Zeng-Mei Wang, Huan-Huan Wang, Zhenxiang Cheng, Baowen Li, Xin-Li Guo, Hideo Kimura, Akira Kasahara
An Investigation Of The Nanomechanical Properties Of 0.5ba(Ti0.8zr0.2)O3-0.5(Ba0.7ca0.3)Tio3 Thin Films, Zhong-Lan Cai, Zeng-Mei Wang, Huan-Huan Wang, Zhenxiang Cheng, Baowen Li, Xin-Li Guo, Hideo Kimura, Akira Kasahara
Australian Institute for Innovative Materials - Papers
For practical application, the functional piezoelectric film in microelectromechanical systems should meet the requirement of physical properties, as well as the mechanical properties. In this article, 0.5Ba(Ti0.8Zr0.2)O3-0.5(Ba0.7Ca0.3)TiO3 (0.5BZT-0.5BCT) thin films with varied properties were prepared on (100) Si substrates via a sol-gel technique at different annealing temperatures. The effects of the annealing temperature on the morphology, piezoelectricity, hardness, and elastic modulus were studied. Particular attention was paid to the surface frictional behavior of films, and the changes in the friction force can be radically explained in terms of differences in the hardness/elastic modulus ratio and the residual stress of films. …
Anomalies In Magnetoelastic Properties Of Dyfe11.2nb0.8 Compound, Jianli Wang, M F. Md Din, Shane J. Kennedy, Zhenxiang Cheng, Stewart J. Campbell, Justin A. Kimpton, S X. Dou
Anomalies In Magnetoelastic Properties Of Dyfe11.2nb0.8 Compound, Jianli Wang, M F. Md Din, Shane J. Kennedy, Zhenxiang Cheng, Stewart J. Campbell, Justin A. Kimpton, S X. Dou
Australian Institute for Innovative Materials - Papers
The structural and magnetic properties of DyFe11.2Nb0.8 compound have been investigated by high intensity, high resolution synchrotron x-ray diffraction, ac magnetic susceptibility, and dc magnetization measurements as well as Mössbauer spectroscopy (5-300 K). The easy magnetization direction at room temperature is along the c-axis. With decreasing temperature, the magnetocrystalline anisotropy changes from easy-axis to easy-cone at Tsr2 (∼202 K), then to easy plane at Tsr1 (∼94 K). The thermal expansion coefficient obtained from the synchrotron x-ray study exhibits clear anomalies around both of the spin reorientation transition temperatures. The 57Fe hyperfine interaction parameters and …
A Facile Method To Enhance Ferroelectric Properties In Pvdf Nanocomposites, Mohammad Mahdi Abolhasani, Fatemeh Zarejousheghani, Zhenxiang Cheng, Minoo Naebe
A Facile Method To Enhance Ferroelectric Properties In Pvdf Nanocomposites, Mohammad Mahdi Abolhasani, Fatemeh Zarejousheghani, Zhenxiang Cheng, Minoo Naebe
Australian Institute for Innovative Materials - Papers
Poly(vinylidene fluoride) (PVDF)/nanoclay composites were prepared using melt compounding. The effect of acrylic rubber (ACM) as a compatibilizer on different polymorph formation and on the ferroelectric properties of nanocomposites were investigated. The intercalation and morphological structure of the samples were studied using X-ray diffraction (XRD) and transmission electron microscopy (TEM). The infrared spectroscopy and X-ray analysis revealed the coexistence of beta and gamma crystalline forms in PVDF-clay nanocomposite, while in partially miscible PVDF/ACM/clay hybrids, three polymorphs of alpha, beta and g coexisted. The coefficients of electric field-polarization (E-P) Taylor expansion were calculated based on the Lorentz theory. Using a genetic …
Influence Of Biopolymer Loading On The Physiochemical And Electrochemical Properties Of Inherently Conducting Polymer Biomaterials, Paul J. Molino, Peter C. Innis, Michael J. Higgins, Robert M. I Kapsa, Gordon G. Wallace
Influence Of Biopolymer Loading On The Physiochemical And Electrochemical Properties Of Inherently Conducting Polymer Biomaterials, Paul J. Molino, Peter C. Innis, Michael J. Higgins, Robert M. I Kapsa, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
The physicochemical and electrochemical properties of polypyrrole (PPy) doped with the biological dopant dextran sulphate (DS) were shown to be significantly altered as a function of varying the salt concentration (0.2, 2 or 20 mg/ml) in the polymerisation electrolyte. Films grown in the presence of 0.2 mg/ml DS generated the highest potential during galvanostatic growth, with the potential decreasing with each subsequent increase in DS concentration. The electroactivity of the polymers was similar for all three DS concentrations, with the 20 mg/ml film drawing slightly more current upon reduction in PBS. Increasing the DS concentration reduced film interfacial roughness and …
Sodium And Lithium Storage Properties Of Spray-Dried Molybdenum Disulfide-Graphene Hierarchical Microspheres, Sujith Kalluri, Kuok Hau Seng, Zaiping Guo, Aijun Du, Konstantin K. Konstantinov, Hua-Kun Liu, S X. Dou
Sodium And Lithium Storage Properties Of Spray-Dried Molybdenum Disulfide-Graphene Hierarchical Microspheres, Sujith Kalluri, Kuok Hau Seng, Zaiping Guo, Aijun Du, Konstantin K. Konstantinov, Hua-Kun Liu, S X. Dou
Australian Institute for Innovative Materials - Papers
Developing nano/micro-structures which can effectively upgrade the intriguing properties of electrode materials for energy storage devices is always a key research topic. Ultrathin nanosheets were proved to be one of the potential nanostructures due to their high specific surface area, good active contact areas and porous channels. Herein, we report a unique hierarchical micro-spherical morphology of well-stacked and completely miscible molybdenum disulfide (MoS2) nanosheets and graphene sheets, were successfully synthesized via a simple and industrial scale spray-drying technique to take the advantages of both MoS2 and graphene in terms of their high practical capacity values and high …
Porous Amorphous Ge/C Composites With Excellent Electrochemical Properties, Xiu Li, Wei Guo, Qian Wan, Jianmin Ma
Porous Amorphous Ge/C Composites With Excellent Electrochemical Properties, Xiu Li, Wei Guo, Qian Wan, Jianmin Ma
Australian Institute for Innovative Materials - Papers
Porous amorphous germanium/carbon (Ge/C) composites, which were synthesized through the reduction/carbonization of germanium oxide/oleic acid precursors, could exhibit a high-capacity, high-rate and long-life performance due to the synergistic effect of the porous structure and carbon.
Modeling Transport Properties Of Inhomogeneous Superconductor-Metal Composites, A Borroto, L Del Rio, M Arronte, Tom Johansen, E Altshuler
Modeling Transport Properties Of Inhomogeneous Superconductor-Metal Composites, A Borroto, L Del Rio, M Arronte, Tom Johansen, E Altshuler
Australian Institute for Innovative Materials - Papers
We propose a model for a superconductor-metal composite that allows to derive intrinsic transport properties of the superconducting phase based on 2D images of its cross section, and a minimal set of parameters. The method is tested experimentally by using, as model composite, a "transversal bridge" made on a Bi2Sr2Ca2Cu3O10+x (BSCCO)-Ag multi-filamentary tape. It is shown that the approach allows to predict the measured I−⟨E⟩ curves of the filaments. In addition, one can determine the critical current anisotropy between the longitudinal and transverse directions of the Ag-BSCCO tape, and also of …
Impacts Of Crystal Orientation Of Gaas On The Interfacial Structures And Electrical Properties Of Hf0.6la0.4ox Films, Tingting Jia, Hideo Kimura, Hongyang Zhao, Qiwen Yao, Zhenxiang Cheng, Xinghong Cheng, Yuehui Yu
Impacts Of Crystal Orientation Of Gaas On The Interfacial Structures And Electrical Properties Of Hf0.6la0.4ox Films, Tingting Jia, Hideo Kimura, Hongyang Zhao, Qiwen Yao, Zhenxiang Cheng, Xinghong Cheng, Yuehui Yu
Australian Institute for Innovative Materials - Papers
One of the major challenges in realizing the GaAs channel in the metal oxide semiconductor field effect transistor is the degrading in electron transport properties at the interface between GaAs and the gate oxide. In this study, Hf0.6La0.4Ox gate oxide films were deposited at a low temperature (200 °C) on GaAs(111)A and GaAs(100) substrates by plasma enhanced atomic layer deposition. Microstructure analysis indicates that residuals of gallium oxide, arsenic oxide, and As element remained at the interface of Hf0.6La0.4Ox/GaAs(100). On contrast, a smoother interface is observed between Hf0.6 …
Magnetic Properties And Magnetocaloric Effect In Layered Ndmn1.9ti0.1si2, M F. Md Din, Jianli Wang, Shane J. Kennedy, Stewart J. Campbell, S X. Dou
Magnetic Properties And Magnetocaloric Effect In Layered Ndmn1.9ti0.1si2, M F. Md Din, Jianli Wang, Shane J. Kennedy, Stewart J. Campbell, S X. Dou
Australian Institute for Innovative Materials - Papers
The structural and magnetic properties of the NdMn1.9Ti0.1Si2 compund have been studied by high-intensity x-ray and high-resolution neutron powder diffraction, specific heat, dc magnetization, and differential scanning calorimetry measurements over the temperature range of 3-450 K. The Curie temperature and Néel temperature of layered NdMn1.9Ti0.1Si2 are indicated as TC ~ 22 K and TN ~ 374 K respectively. The first order magnetic transition from antiferromagnetic [AFil-type] to ferromagnetic [F(Nd)+Fmc] around TC is found in layered NdMn1.9Ti0.1Si2 and is …
Hydrostatic Piezoelectric Properties Of [011] Poled Pb(Mg 1/3nb2/3)O3-Pbtio3 Single Crystals And 2-2 Lamellar Composites, Lili Li, Shujun Zhang, Zhuo Xu, Xuecang Geng, Fei Wen, Jun Luo, Thomas R. Shrout
Hydrostatic Piezoelectric Properties Of [011] Poled Pb(Mg 1/3nb2/3)O3-Pbtio3 Single Crystals And 2-2 Lamellar Composites, Lili Li, Shujun Zhang, Zhuo Xu, Xuecang Geng, Fei Wen, Jun Luo, Thomas R. Shrout
Australian Institute for Innovative Materials - Papers
The hydrostatic piezoelectric properties of [011] poled Pb(Mg 1/3Nb2/3)O3-PbTiO3 (PMN-PT) crystals and corresponding 2-2 crystal/epoxy composites were investigated. The crystal volume ratio and compositional dependencies of the hydrostatic charge and voltage coefficients (dh and gh) and hydrostatic figure of merit (FOM) dh x gh were determined, where large FOM value of 3.2 pm2/N with high stability as a function of hydrostatic pressure was achieved for rhombohedral crystal composites. In addition, the stress amplification effects of the face-plate and different epoxy matrixes were investigated, with maximum FOM value being on the order of 92 pm2/N, indicating that 2-2 crystal/epoxy composites are …
Magnetic Properties And Magnetocaloric Effect In Layered Ndmn 1.9v0.1si2, M F. Md Din, Jianli Wang, R Zeng, Shane Kennedy, S J. Campbell, S X. Dou
Magnetic Properties And Magnetocaloric Effect In Layered Ndmn 1.9v0.1si2, M F. Md Din, Jianli Wang, R Zeng, Shane Kennedy, S J. Campbell, S X. Dou
Australian Institute for Innovative Materials - Papers
The structural and magnetic properties of the compounds NdMn2-xVxSi2 have been studied by x-ray and high resolution neutron powder diffraction, specific heat, dc magnetization, and differential scanning calorimetry measurements over the temperature range 3-450 K. The Curie temperature and Néel temperature of layered NdMn1.9V0.1Si2 are been indicate at TC ~ 24 K and TN ~ 376 K respectively. The giant magnetocaloric effect (GMCE) around TC is found in layered NdMn1.9V0.1Si2 associated with first order magnetic transition from antiferromagnetic [AFil-type] to ferromagnetic [F(Nd)+Fmc]. This behaviorhas been confirmed as contribution of the magnetostructural coupling by using neutron powder diffraction. The magnetic entropy …
Enhanced Electrochemical Properties Of Cobalt Doped Manganese Dioxide Nanowires, Byoung Chul Kim, C Justin Raj, W J. Cho, W G. Lee, Hyeon Taek Jeong, K H. Yu
Enhanced Electrochemical Properties Of Cobalt Doped Manganese Dioxide Nanowires, Byoung Chul Kim, C Justin Raj, W J. Cho, W G. Lee, Hyeon Taek Jeong, K H. Yu
Australian Institute for Innovative Materials - Papers
The various molar concentrations of cobalt doped manganese dioxide (Co-MnO2) nanostructures were synthesized by an hydrothermal technique for electrochemical supercapacitor application. The X-ray diffraction analysis showed that the samples were composed of multiphase of MnO2 with dominant reflections of γ-MnO2 structure of crystallization. The morphological studies displayed the existence of MnO 2 nanowires with the width of 10-20 nm and showing a good degree of crystallization. The electrochemical characterization was performed using cyclic voltammetry, galvanostatic charge/discharge test and impedance spectroscopy in 1 M Na2SO4 aqueous electrolyte. All the samples exhibit a typical ideal capacitive behavior with an increasing order of …
Magnetic Properties And Magnetocaloric Effect Of Ndmn2-Xcuxsi2 Compounds, M F. Md Din, Jianli Wang, M Avdeev, Q F. Gu, R Zeng, S J. Campbell, S J. Kennedy, S X. Dou
Magnetic Properties And Magnetocaloric Effect Of Ndmn2-Xcuxsi2 Compounds, M F. Md Din, Jianli Wang, M Avdeev, Q F. Gu, R Zeng, S J. Campbell, S J. Kennedy, S X. Dou
Australian Institute for Innovative Materials - Papers
Structural and magnetic properties of NdMn2−x Cu xSi2 compounds (x = 0-1.0) have been investigated by high intensity x-ray and resolution neutron diffraction (3-450 K), specific heat, dc magnetization, and differential scanning calorimetry measurements. Substitution of Cu for Mn leads to an increase in the lattice parameter a but a decrease in c at room temperature. Two magnetic phase transitions have been found for NdMn2−x Cu xSi2 compounds with TN for the antiferromagnetic ordering of Mn-sublatttice and TC for the Nd-sublattice ferromagnetic ordering, respectively. TC increases significantly with increasing Cu content from 36 K at x = 0 to 100 …
Interplay Between Boron Precursors And Ni-Co-B Nanoparticle Doping In The Fabrication Of Mgb2 Superconductor With Improved Electromagnetic Properties, Mislav Mustapic, Josip Horvat, Zeljko Skoko, Md Shahriar Hossain, S X. Dou
Interplay Between Boron Precursors And Ni-Co-B Nanoparticle Doping In The Fabrication Of Mgb2 Superconductor With Improved Electromagnetic Properties, Mislav Mustapic, Josip Horvat, Zeljko Skoko, Md Shahriar Hossain, S X. Dou
Australian Institute for Innovative Materials - Papers
The influence of different boron precursor powders on the critical current density of MgB2 superconductor with added Ni-Co-B nanoparticles is investigated. Different types of boron have different morphologies, particle sizes and impurity content, all of which have a strong impact on the critical current density (Jc). The boron samples investigated in this study include three different boron powders: semicrystalline boron (denoted as SC), with nanosized particles and high purity (99%) supplied from Specialty Materials, Inc. (USA); amorphous boron (denoted as AB), with nanosized particles and high purity (99%) supplied from Russia; and finally pure crystalline boron (denoted as CB), with …
Synthesis And Electrochemical Properties Of Wo3/C For Lithium Ion Batteries, Hong Gao, Shuijin S. Yang, Chuanqi Feng, Jiazhao Wang, Zaiping Guo
Synthesis And Electrochemical Properties Of Wo3/C For Lithium Ion Batteries, Hong Gao, Shuijin S. Yang, Chuanqi Feng, Jiazhao Wang, Zaiping Guo
Australian Institute for Innovative Materials - Papers
WO3/C nanorods were prepared by a combination of hydrothermal synthesis method and the solid phase reaction method, using (NH4)10H2(W2O7)6, H2C2O4·2H2O and glucose(carbon source) as raw materials. The effects of different proportions of glucose on the morphologies and electrochemical properties of the final products were systematically investigated. The results showed that the WO3/C nanorods prepared with the 10 wt.% glucose as carbon source exhibited the highest reversible specific capacity (807 mAh g-1) at current density …
Recent Progress On Synthesis, Multi-Scale Structure, And Properties Of Y-Si-O Oxides, Ziqi Sun, M S. Li, Y C. Zhou
Recent Progress On Synthesis, Multi-Scale Structure, And Properties Of Y-Si-O Oxides, Ziqi Sun, M S. Li, Y C. Zhou
Australian Institute for Innovative Materials - Papers
Yttrium silicates (Y-Si-O oxides), including Y2Si2O7, Y2SiO5, and Y4·67(SiO4)3O apatite, have attracted wide attentions from material scientists and engineers, because of their extensive polymorphisms and important roles as grain boundary phases in improving the high-temperature mechanical/thermal properties of Si3N4 and SiC ceramics. Recent interest in these materials has been renewed by their potential applications as high-temperature structural ceramics, oxidation protective coatings, and environmental barrier coatings (EBCs). The salient properties of Y-Si-O oxides are strongly related to their unique chemical bonds and …
Magnetic Properties And Magnetocaloric Effect Of Ndmn2−Xtixsi2 Compounds, M F. Md Din, Jianli Wang, S J. Campbell, R Zeng, W D. Hutchison, M Avdeev, S J. Kennedy, S X. Dou
Magnetic Properties And Magnetocaloric Effect Of Ndmn2−Xtixsi2 Compounds, M F. Md Din, Jianli Wang, S J. Campbell, R Zeng, W D. Hutchison, M Avdeev, S J. Kennedy, S X. Dou
Australian Institute for Innovative Materials - Papers
The structural and magnetic properties of the intermetallic compounds NdMn2−xTixSi2(x = 0, 0.1, 0.2, and 0.3) have been studied by x-ray and high resolution neutron powder diffraction, specific heat, dc magnetization, and differential scanning calorimetry measurements over the temperature range 3–450 K. The Curie temperature and Néel temperature of NdMn2Si2 decrease from TC = 36 K and TN = 380 K to TC = 14 K and TN = 360 K, respectively, on substitution of Ti (x = 0.3) for Mn. The magnetocaloric effect …
Modulation Of The Properties Of Thin Ferromagnetic Films With An Externally Applied Electric Field In Ferromagnetic/Piezoelectric/Ferromagnetic Hybrids, D Stamopoulos, M Zeibekis, Shujun Zhang
Modulation Of The Properties Of Thin Ferromagnetic Films With An Externally Applied Electric Field In Ferromagnetic/Piezoelectric/Ferromagnetic Hybrids, D Stamopoulos, M Zeibekis, Shujun Zhang
Australian Institute for Innovative Materials - Papers
In many cases, technological advances are based on artificial low-dimensional structures of heterogeneous constituents, thus called hybrids, that when come together they provide stand-alone entities that exhibit entirely different properties. Such hybrids are nowadays intensively studied since they are attractive for both basic research and oncoming practical applications. Here, we studied hybrids constituted of piezoelectric (PE) and ferromagnetic (FM) components in the form FM/PE/FM, ultimately aiming to provide means for the controlled modulation of the properties of the FM electrodes, originating from the strain imposed to them by the PE mediator when an electric field is applied. The PE component …
Effect Of Sintering Temperature On The Superconducting Properties Of Graphene Doped Mgb2, K S B De Silva, X Xu, Sanjeev Gambhir, D C K Wong, W X Li, Q Y. Hu
Effect Of Sintering Temperature On The Superconducting Properties Of Graphene Doped Mgb2, K S B De Silva, X Xu, Sanjeev Gambhir, D C K Wong, W X Li, Q Y. Hu
Australian Institute for Innovative Materials - Papers
A comprehensive study on the effects of sintering temperature on graphene-doped MgB2 superconductor was conducted. Graphene has emerged as an effective dopant that is capable of improving the critical current density (J-{\rm c}) and flux pinning at a very low doping level, with only a slight reduction of the critical temperature (T-{\rm c}). MgB2 undoped and graphene-doped bulk samples were prepared by the in situ method and sintered within a temperature range from 650 to 950 {\circ}\hbox{C}. It is surprising to note that at the doping level of 1 at.% the sample sintered at 850 {\circ}\hbox{C} shows a J\rm c …
Band Structure, Magnetic, And Transport Properties Of Two Dimensional Compounds Sr2-Xgdxcoo4, Q W Yao, Xiaolin Wang, H Kimura, S X. Dou, Konstantin Konstantinov, Z X. Cheng, F Hong, H Zhao, H Qiu, Kiyoshi Ozawa
Band Structure, Magnetic, And Transport Properties Of Two Dimensional Compounds Sr2-Xgdxcoo4, Q W Yao, Xiaolin Wang, H Kimura, S X. Dou, Konstantin Konstantinov, Z X. Cheng, F Hong, H Zhao, H Qiu, Kiyoshi Ozawa
Australian Institute for Innovative Materials - Papers
The layered perovskite compound Sr2-xGdxCoO 4 has not yet been subjected to detailed study so far. In this report, structures, transport, magnetic properties, and first principle calculations will be reported for the two dimensional compounds Sr 2-xGdxCoO4 (x 0.5, 0.75, 1, 1.25). Rietveld refinement revealed that these compounds are crystallized in K2NiF 4-type structures with space group I4/mmm. It was found that the lattice parameter c decreases as x increases. Through the Curies Weiss fitting of the temperature dependent magnetization, it was found that the Sr 1.25Gd0.75CoO4 sample exhibits a weak ferromagnetic to paramagnetic transition at about 62 K, with …