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Articles 1 - 5 of 5
Full-Text Articles in Physical Sciences and Mathematics
Flexible And Compressible Goretex-Pedot Membrane Electrodes For Solid-State Dye-Sensitized Solar Cells, Attila J. Mozer, Dillip K. Panda, Sanjeev Gambhir, Anthony C. Romeo, Bjorn Winther-Jensen, Gordon G. Wallace
Flexible And Compressible Goretex-Pedot Membrane Electrodes For Solid-State Dye-Sensitized Solar Cells, Attila J. Mozer, Dillip K. Panda, Sanjeev Gambhir, Anthony C. Romeo, Bjorn Winther-Jensen, Gordon G. Wallace
Faculty of Science - Papers (Archive)
A porous, flexible electrode based on a PTFE (Teflon) membrane (Goretex) coated with a metallic current collector and a conducting polymer (poly(3,4-ethylenedioxythiophene), PEDOT) has been developed for applications in solidstate dye-sensitized solar cells. Its low sheet resistance and compressibility make it an ideal electrode on uneven TiO2 surfaces with high efficiency and reproducibility. The porous nature of the electrode enables the feed-through of reactants and treatment agents, which opens up exciting opportunities to interface these photoelectrochemical devices with electrocatalytic, energy conversion, and storage systems. Postfabrication bonding of the photoanode and the Goretex-Au-PEDOT electrode is demonstrated.
Ionic Liquid Electrolyte Porphyrin Dye Sensitised Solar Cells, Vanessa Armel, Jennifer Pringle, Maria Forsyth, Douglas Macfarlane, David L. Officer, Pawel W. Wagner
Ionic Liquid Electrolyte Porphyrin Dye Sensitised Solar Cells, Vanessa Armel, Jennifer Pringle, Maria Forsyth, Douglas Macfarlane, David L. Officer, Pawel W. Wagner
Faculty of Science - Papers (Archive)
Ionic liquid electrolytes based on a number of imidazolium, quaternary ammonium and phosphonium cations have been developed for porphyrin dye sensitised solar cells yielding efficiencies of up to 5.2% at 0.68 Sun.
Microsecond Dye Regeneration Kinetics In Efficient Solid State Dye-Sensitized Solar Cells Using A Photoelectrochemically Deposited Pedot Hole Conductor, Attila J. Mozer, Dillip K. Panda, Sanjeev Gambhir, B. Winther-Jensen, Gordon G. Wallace
Microsecond Dye Regeneration Kinetics In Efficient Solid State Dye-Sensitized Solar Cells Using A Photoelectrochemically Deposited Pedot Hole Conductor, Attila J. Mozer, Dillip K. Panda, Sanjeev Gambhir, B. Winther-Jensen, Gordon G. Wallace
Faculty of Science - Papers (Archive)
Microsecond dye-regeneration kinetics was observed in efficient solid state dye-sensitized solar cells using photoelectrochemically deposited poly(3,4-ethylenedioxythiophene (PEDOT) hole conductors using transient absorption spectroscopy. The dye-regeneration rate is orders of magnitude slower than the case using the I-/I3- redox couple or commonly used small molecule hole conductor and is attributed to the low dye to PEDOT ratio within the films.
Catalytic Solar Water Splitting Inspired By Photosynthesis. Homogeneous Catalysts With A Mechanical ("Machine-Like") Action, Gerhard F. Swiegers, G Charles Dismukes, Leone Spiccia, Robin Brimblecombe, Annette Koo, Jun Chen, Gordon G. Wallace
Catalytic Solar Water Splitting Inspired By Photosynthesis. Homogeneous Catalysts With A Mechanical ("Machine-Like") Action, Gerhard F. Swiegers, G Charles Dismukes, Leone Spiccia, Robin Brimblecombe, Annette Koo, Jun Chen, Gordon G. Wallace
Faculty of Science - Papers (Archive)
Chemical reactions may be controlled by either: the minimum threshold energy that must be overcome during collisions between reactant molecules / atoms (the Activation Energy, Ea), or: the rate at which reactant collisions occur (the Collision Frequency, A) (for reactions with low Ea). Reactions of type (2) are governed by the physical, mechanical interaction of the reactants. Such mechanical processes are unusual, but not unknown in molecular catalysts. We examine the catalytic action and macroscopic properties of several abiological mechanical catalysts and show that they display distinct similarities to enzymes in general. An abiological model of the Photosystem II Water …
Evidence Of Solar And Tropical-Ocean Forcing Of Hydroclimate Cycles In Southeastern Australia For The Past 6500 Years, Hamish A. Mcgowan, Samuel K. Marx, Joshua Soderholm, John Denholm
Evidence Of Solar And Tropical-Ocean Forcing Of Hydroclimate Cycles In Southeastern Australia For The Past 6500 Years, Hamish A. Mcgowan, Samuel K. Marx, Joshua Soderholm, John Denholm
Faculty of Science - Papers (Archive)
Evidence of solar and tropical‐ocean forcing of climate cycles has been found in numerous palaeoclimate records. Numerical modelling studies show physical mechanisms by which direct and indirect solar forcing may affect climate, while there is mounting evidence of solar forcing of tropical ocean‐atmosphere teleconnections. This study has developed a 6500 year record of dust deposition, a proxy for regional hydroclimate variability for the Snowy Mountains region of Australia. Spectral analysis of the record provides evidence of statistically significant cycles in dust deposition of 35–43 years, 62–73 years, 161 years and 2200 years. These correlate with variability in solar irradiance and …