Open Access. Powered by Scholars. Published by Universities.®
Physical Sciences and Mathematics Commons™
Open Access. Powered by Scholars. Published by Universities.®
- Keyword
-
- Self-assembly (8)
- Drug delivery (7)
- Nanoparticle (6)
- Nanoparticles (5)
- Polymers (5)
-
- Doping (3)
- Nanomaterials (3)
- Nanotechnology (3)
- Polymer (3)
- Antimicrobials (2)
- Block Copolymers (2)
- Conjugated polymer (2)
- Conjugated polymers (2)
- Elastocapillarity (2)
- Fluorenone (2)
- Gold nanoparticle (2)
- Graphene (2)
- Mass Spectrometry (2)
- Mass spectrometry (2)
- Mesoscale (2)
- Micelle (2)
- Morphology (2)
- Organic Photovoltaics (2)
- Organic photovoltaics (2)
- Perovskite (2)
- Phase separation (2)
- Photovoltaics (2)
- Porous materials (2)
- Protein detection (2)
- Reaction Path Hamiltonian (2)
- Publication Year
- Publication
- Publication Type
- File Type
Articles 1 - 30 of 82
Full-Text Articles in Physical Sciences and Mathematics
Data For Dopant-Induced Energetic Disorder In Conjugated Polymers: Determinant Roles Of Polymer-Dopant Distance And Composite Electronic Structures, Michael Lu Diaz, Muhamed Duhandzic, Simon Harrity, Subhayan Samanta, Zlatan Aksamija, Dhandapani Venkataraman
Data For Dopant-Induced Energetic Disorder In Conjugated Polymers: Determinant Roles Of Polymer-Dopant Distance And Composite Electronic Structures, Michael Lu Diaz, Muhamed Duhandzic, Simon Harrity, Subhayan Samanta, Zlatan Aksamija, Dhandapani Venkataraman
Data and Datasets
The data here is the raw data for Figures in the publication "Dopant-Induced Energetic Disorder in Conjugated Polymers: Determinant Roles of Polymer−Dopant Distance and Composite Electronic Structures" In the Journal of Physical Chemistry C. (https://doi.org/10.1021/acs.jpcc.3c07197)
Polymer-Based Nanotherapeutics To Combat Difficult-To-Treat Bacterial Infections, Jessa Marie V. Makabenta
Polymer-Based Nanotherapeutics To Combat Difficult-To-Treat Bacterial Infections, Jessa Marie V. Makabenta
Doctoral Dissertations
The continuous emergence and spread of antibiotic-resistant bacteria are a global health emergency, debilitating the capability to prevent and cure various infectious diseases that were once treatable. Antibiotic therapy is further rendered ineffective due to biofilm formation and the ability of bacteria to thrive and colonize inside mammalian cells. Given the diminishing efficacy of available antibiotics combined with the scarcity of new therapeutics entering the antibiotic pipeline, innovative treatment strategies are urgently in demand. Nanomaterial-based strategies offer ‘outside of the box’ approach for the treatment of antibiotic-resistant bacterial infections. Nanomaterials feature tunable physicochemical properties that can be carefully modified to …
Reactive Chemistries For Protein Labeling, Degradation, And Stimuli Responsive Delivery, Myrat Kurbanov
Reactive Chemistries For Protein Labeling, Degradation, And Stimuli Responsive Delivery, Myrat Kurbanov
Doctoral Dissertations
Reactive chemistries for protein chemical modification play an instrumental role in chemical biology, proteomics, and therapeutics. Depending on the application, the selectivity of these modifications can range from precise modification of an amino acid sequence by genetic manipulation of protein expression machinery to a stochastic modification of lysine residues on the protein surface. Ligand-Directed (LD) chemistry is one of the few methods for targeted modification of endogenous proteins without genetic engineering. However, current LD strategies are limited by stringent amino acid selectivity. To bridge this gap, this thesis focuses on the development of highly reactive LD Triggerable Michael Acceptors (LD-TMAcs) …
Applying Density Functional Theory Simulations To Study The Charge Balancing And Structure Directing Roles Of Fluoride In Zeolite Synthesis, Tongkun Wang
Doctoral Dissertations
Zeolites represent a major cornerstone of today’s energy industry as the most-used petrochemical catalyst by weight in the world. Constituted by tetrahedra of T-atoms including Si, Al, Ge and Ti, zeolites form a huge family of nano-porous crystalline materials which also provide reliable candidates for novel, energy related applications such as efficient separations, hydrogen-purifying/storing and conversions from biomass to biofuel. However, the formation mechanism of zeolite is still not clear, as synthesis processes are complicated by requirements including structure directing agents (SDAs), hydroxide or fluoride medium, and experimental conditions like temperature. Attempts for designing new zeolite structures still fall in …
Scanning Probe And Spectroscopic Investigations Of Polarization-Driven Electronic Interactions At The Inorganic/Organic Interface Of 2d Materials, Nicholas Hight-Huf
Scanning Probe And Spectroscopic Investigations Of Polarization-Driven Electronic Interactions At The Inorganic/Organic Interface Of 2d Materials, Nicholas Hight-Huf
Doctoral Dissertations
My thesis focuses on understanding the changes in electronic properties of two-dimensional materials produced by surface interactions not limited to charge exchange. Recent work from our group demonstrated that both small molecules and polymers can function as effective charge dopants for monolayered 2D materials such as MoS2 and graphene, changing the Fermi energy by either donating or accepting electron density to/from the 2D material. Additionally, the underlying support material was found to play a significant role, where higher dielectric constant supports result in larger magnitude of Fermi energy shift of the 2D material because less of the dopant interaction …
Vapor Deposition Strategies For Tuning Surface And Interface Chemistry For Optoelectronics And Biosensors, Kwang-Won Park
Vapor Deposition Strategies For Tuning Surface And Interface Chemistry For Optoelectronics And Biosensors, Kwang-Won Park
Doctoral Dissertations
Ordered assemblies of molecular semiconductors have been of particular interest for their integral role in organic optoelectronics, originating from interesting optical and charge transport properties. Compared with disordered films, organized nanostructured organic semiconductors display enhanced optoelectronic characteristics. However, past studies using template layer and self-assembly strategies are not applicable to molecular heterointerfaces and cannot be practically integrated into existing device fabrication routines to achieve large-area optoelectronic devices. This dissertation demonstrates unprecedented strategies to create one-dimensional (1D) nanostructures of molecular semiconductors using vapor deposition techniques. We begin this work by investigating how the interplay between dipole-dipole and van der Waals interactions …
Frontiers In The Self-Assembly Of Charged Macromolecules, Khatcher O. Margossian
Frontiers In The Self-Assembly Of Charged Macromolecules, Khatcher O. Margossian
Doctoral Dissertations
The self-assembly of charged macromolecules forms the basis of all life on earth. From the synthesis and replication of nucleic acids, to the association of DNA to chromatin, to the targeting of RNA to various cellular compartments, to the astonishingly consistent folding of proteins, all life depends on the physics of the organization and dynamics of charged polymers. In this dissertation, I address several of the newest challenges in the assembly of these types of materials. First, I describe the exciting new physics of the complexation between polyzwitterions and polyelectrolytes. These materials open new questions and possibilities within the context …
Elucidating The Function Of Ions In Hybrid Perovskite Photovoltaics, Emily C. Smith
Elucidating The Function Of Ions In Hybrid Perovskite Photovoltaics, Emily C. Smith
Doctoral Dissertations
Perovskite solar cells (PSCs) have risen to the forefront of versatile thin-film technologies with power conversion efficiencies rivaling traditional silicon and the potential to be fabricated at a fraction of the cost. However, one crucial drawback to PSCs is their instability to illumination, which is likely due in part to mobile ions during operation. It is difficult to predict the influences of ion dynamics in devices, and the exact nature and impact of these ions remain elusive. In this dissertation work, I have set out to unravel the complex interplay between ions and device operation in PSCs. Through the development …
Formation Of Doped Semiconductor Nanocrystals From Doped Molecular Clusters, Jillian E. Denhardt
Formation Of Doped Semiconductor Nanocrystals From Doped Molecular Clusters, Jillian E. Denhardt
Doctoral Dissertations
Transition metal doping of semiconductor nanomaterials, particularly magnetic dopant ions, is of great interest for the synthesis of diluted magnetic semiconductors (DMS) with spintronic-based applications. The incorporation of magnetic ions into quantum dots (QDs) would be particularly useful since the quantum confinement of these materials is theorized to enhance magneto-optical related properties. One major challenge in this field is the segregation of dopant ions towards the outer regions of the QD due to the exclusion of dopants during the nucleation process, thereby inhibiting the magneto-optical properties. In this dissertation, we address the dopant segregation challenge by exploring the underlying mechanisms …
Molecular Vibrations And Shape-Selectivity: A Computational Model Of Biofuel Precursors In Zeolites, Babgen Manookian
Molecular Vibrations And Shape-Selectivity: A Computational Model Of Biofuel Precursors In Zeolites, Babgen Manookian
Doctoral Dissertations
We have used Density Functional Theory (DFT) to model acyclic and cyclic olefins in acidic zeolites. We have studied the impact of host-guest interactions between adsorbed molecules and zeolite frameworks through the lens of molecular vibrations and shape-selectivity. This work considered three zeolite frameworks with varying pore structures and environments: large pore zeolite HMOR and medium pore zeolites HZSM-5 and HZSM-22. A key finding is that for acyclic olefins in acidic zeolites there exists two regimes of host-guest interaction: a strong interaction leading to protonation and a weak interaction between charged guest and zeolite framework. We found that these interactions …
Synthesis, Fabrication, And Assembly Of Mesoscale Polymer Filaments, Dylan M. Barber
Synthesis, Fabrication, And Assembly Of Mesoscale Polymer Filaments, Dylan M. Barber
Doctoral Dissertations
Mesoscale materials, with feature sizes in the range of one hundred nanometers to tens of micrometers, are ubiquitous in Nature. In organisms, mesoscale building blocks connect the properties of underlying molecular and nanoscructures to those of macroscale, organism-scale materials through hierarchical assemblies of recurring structural motifs. The collective action of large numbers of mesoscale features can afford stunning features like the structural color of the morpho butterfly wing, calcium ion-mediated movement in muscle, and wood structures like xylem that can support enormous external compressive loads and negative internal pressure to transport nutrients throughout an organism. In synthetic systems, the design, …
The Thermoelectric, Thermoresistive, And Hygroresistive Properties And Applications Of Vapor Printed Pedot-Cl, Linden K. Allison
The Thermoelectric, Thermoresistive, And Hygroresistive Properties And Applications Of Vapor Printed Pedot-Cl, Linden K. Allison
Doctoral Dissertations
Wearable electronics are a valuable tool to increase consumer access to real-time and long-term health care monitoring. The development of these technologies can also lead to major advancements in the field, such as self-charging systems that are completely removed from the electrical grid. However, much of the wearable technology available commercially contain rigid components, use unsustainable synthetic methods, or undesirable materials. The field has thus been moving towards wearables that mimic textiles or use textiles as a substrate. Herein, we discuss the use of oxidative chemical vapor deposition (oCVD) to produce textiles coated with poly(3,4-ethylenedioxythiophene) known as PEDOT-Cl. We evaluate …
Tailoring Interfaces And Composition For Stable And Efficient Perovskite Solar Cells, Hamza Javaid
Tailoring Interfaces And Composition For Stable And Efficient Perovskite Solar Cells, Hamza Javaid
Doctoral Dissertations
Metal halide perovskite solar cells (PSCs) have revolutionized the field of thin film photovoltaics. Within a decade, the power conversion efficiencies (PCEs) have increased at a phenomenal rate, rising from 3.8% to more than 25% in single-junction devices, moving them ahead of the current silicon-based technology. The high efficiencies of perovskite solar cells (PSCs) and their other unique properties arise from a combination of organic and inorganic components and electronic-ionic conduction, making them excellent candidates for a plethora of applications. However, PSCs face a significant—and ironic—roadblock to commercialization: these light-harvesting materials degrade under sunlight—the very condition they would need …
Manipulating The Properties Of Light-Responsive Active Lipid Bilayer Membranes: Measuring Mechanics And Probing Mechanisms, Arash Manafirad
Manipulating The Properties Of Light-Responsive Active Lipid Bilayer Membranes: Measuring Mechanics And Probing Mechanisms, Arash Manafirad
Doctoral Dissertations
This thesis explores an experimental system probing the effect of energy input (in light-responsive bilayers) on membrane physicomechanical properties and dynamics of response to a trigger. We were inspired by the ability of cell membranes to alter their elastic and permeability properties and shape in response to energy input, change in lipid chemistry, or bilayer composition. Our work demonstrates and sheds new light on the roles of lipid chemical character, light-responsive moieties' incorporation in the membrane, and the lipid bilayer's mechanical properties on membrane response to chemical tuning or energy input. To observe how lipid chemistry affects membrane physical properties …
Source Data For Self-Spinning Filaments For Autonomously Linked Microfibers, Dylan M. Barber, Todd S. Emrick, Gregory Grason, Alfred Crosby
Source Data For Self-Spinning Filaments For Autonomously Linked Microfibers, Dylan M. Barber, Todd S. Emrick, Gregory Grason, Alfred Crosby
Data and Datasets
Filamentous bundles are ubiquitous in Nature, achieving highly adaptive functions and structural integrity from assembly of diverse mesoscale supramolecular elements. Engineering routes to synthetic, topologically integrated analogs demands precisely coordinated control of multiple filaments’ shapes and positions, a major challenge when performed without complex machinery or labor-intensive processing. Here, we demonstrate a photocreasing design that encodes local curvature and twist into mesoscale polymer filaments, enabling their programmed transformation into target 3-dimensional geometries. Importantly, patterned photocreasing of filament arrays drives autonomous spinning to form linked filament bundles that are highly entangled and structurally robust. In individual filaments, photocreases unlock paths 16 …
Behavioral Modulation Of Supramolecular Assemblies Via Covalent And Non-Covalent Interfacial Transformations, Ann Fernandez
Behavioral Modulation Of Supramolecular Assemblies Via Covalent And Non-Covalent Interfacial Transformations, Ann Fernandez
Doctoral Dissertations
There are several molecular level mechanisms at the origin of biological functions that serve as inspiration for the development of the “next generation” of materials that display adaptive and interactive properties. However, it will take time for synthetic materials to approach the level of complexity, robustness, and adaptability of biological systems. Although there are switchable platforms that respond via sensitized molecular components, there are currently no examples of materials that truly possess the type of autonomous behavior seen in biological systems. Even though these concepts are common in living organisms, their translation into a synthetic platform remains challenging to this …
Manipulating The Aliovalent Magnetic Dopants In Ti(Iv)-Based Oxide Nanocrystals, Muhammad Abdullah
Manipulating The Aliovalent Magnetic Dopants In Ti(Iv)-Based Oxide Nanocrystals, Muhammad Abdullah
Doctoral Dissertations
The intentional incorporation of impurities or dopants in semiconductors is fundamental to manipulate the properties that render them useful for spintronics, photocatalysis, and optoelectronics. One long-standing challenge in integrating the doped semiconductors in various applications is the design of materials with controlled individual dopant properties such as dopants speciation, valence state, and spin dynamics. Despite several elegant studies to circumvent these material challenges, the quest for new materials with tunable dopant properties to address the theoretical and experimental understanding continues. In this work, we combine synthetic chemistry and various spectroscopies to study a class of materials possessing both substitutional magnetic …
Design Of Resposive Oligomeric And Polymeric Interfaces For Sensing And Controlled Release Applications, . Manisha
Doctoral Dissertations
Nature has designed magnificent responsive systems by constructing several interacting molecular level networks for the recognition and propagation of chemical and biochemical information. One of the eminent characteristics of these systems is their capability to quickly transduce molecular scale recognition events into macroscopic or visually observable responses. Inspired by these systems present in nature, we became interested in developing artificial responsive systems with similar capabilities. This dissertation will feature four such systems that employ amphiphilic oligomers and polymers which were chosen as the scaffolds because of their high thermodynamic stability, low critical aggregation concentrations, convenient handles to incorporate functional group …
Thermoelectric Transport In Disordered Organic And Inorganic Semiconductors, Meenakshi Upadhyaya
Thermoelectric Transport In Disordered Organic And Inorganic Semiconductors, Meenakshi Upadhyaya
Doctoral Dissertations
The need for alternative energy sources has led to extensive research on optimizing the conversion efficiency of thermoelectric (TE) materials. TE efficiency is governed by figure-of-merit (ZT) and it has been an enormously challenging task to increase ZT > 1 despite decades of research due to the interdependence of material properties. Most doped inorganic semiconductors have a high electrical conductivity and moderate Seebeck coefficient, but ZT is still limited by their high lattice thermal conductivity. One approach to address this problem is to decrease thermal conductivity by means of alloying and nanostructuring, another is to consider materials with an inherently low …
Photothermal And Photochemical Strategies For Lightinduced Shape-Morphing Of Soft Materials, Alexa Simone Kuenstler
Photothermal And Photochemical Strategies For Lightinduced Shape-Morphing Of Soft Materials, Alexa Simone Kuenstler
Doctoral Dissertations
Engineering materials with the capability to transform energy from photons into mechanical work is an outstanding technical challenge with implications across myriad disciplines. Despite decades of work in this area, comprehensive understanding of how to prescribe shape change and work output in photoactive systems remains limited. To this end, this dissertation explores strategies to assemble photothermal and photochemical moieties in soft material systems to fabricate photoaddressable devices capable of specific shape changes upon illumination. Chapters 2 and 3 describe a methodology for spatially patterning plasmonic nanoparticles in liquid crystal elastomer fibers and sheets to specify local photothermally-induced strain profiles. Using …
Engineering Stimuli-Responsive Polymeric Nanoassemblies: Rational Designs For Intracellular Delivery Of Biologics, Kingshuk Dutta
Engineering Stimuli-Responsive Polymeric Nanoassemblies: Rational Designs For Intracellular Delivery Of Biologics, Kingshuk Dutta
Doctoral Dissertations
Biologic drugs have gained enormous research attention in recent years as reflected by the development of multiple candidates to the clinical pipelines and an increased percentage of FDA approval. This is reasoned by the fact that biologics have been proven to deliver more predictive and promising benefits for many hard-to-cure diseases by ‘drugging the undruggable’ targets. However, the challenges associated with biologic drug development are multi-fold, viz, poor encapsulation efficacy, systemic instability, low cellular internalization and endosomal escape capability. Thus, it is essential to develop new molecular strategies that can not only address the associated drug delivery challenges, but also …
Investigating The Accumulation, Sub-Organ Distribution, And Biochemical Effects Of Nanomaterials Using Mass Spectrometry, Kristen Nicole Sikora
Investigating The Accumulation, Sub-Organ Distribution, And Biochemical Effects Of Nanomaterials Using Mass Spectrometry, Kristen Nicole Sikora
Doctoral Dissertations
Gold nanoparticles (AuNPs) are attractive materials for use in various biomedical applications, such as therapeutic delivery, due to their unique chemical properties and modular tunability. Mass spectrometry methods, including laser desorption/ionization mass spectrometry (LDI-MS) and inductively coupled plasma mass spectrometry (ICP-MS) have been successfully used to evaluate the distribution of AuNPs in complex biological systems. As new AuNP-based materials are developed for applications in therapeutic delivery, it is essential to simultaneously develop analytical techniques that can comprehensively assess their behavior in vivo. In this dissertation, novel mass spectrometric methods have been developed and utilized to evaluate the uptake, distribution, …
Chemical Manipulation Of Macrophages: Nanomaterial And Molecular Approaches, Joseph Hardie
Chemical Manipulation Of Macrophages: Nanomaterial And Molecular Approaches, Joseph Hardie
Doctoral Dissertations
Macrophages, phagocytic cells of the innate immune system, are the body’s first line of defense against pathogens and are responsible for tissue maintenance. Macrophages are capable of sensing and internalizing external stimuli, and in response change their morphology and phenotype accordingly. Because macrophages are integral to immune function and tissue maintenance, dysregulation of macrophage behavior is associated with a range of diseases including infections, cancer, autoimmune disorders, atherosclerosis, and more. Because of the implications of macrophage failure, there is interest in creating new materials to manipulate macrophage behavior for a therapeutic effect. In this thesis, I describe the application of …
Powering Advances In Next-Generation Photovoltaics Through Materials Synthesis And Characterization, Christie L.C. Ellis
Powering Advances In Next-Generation Photovoltaics Through Materials Synthesis And Characterization, Christie L.C. Ellis
Doctoral Dissertations
Solar energy is our most abundant natural resource: the energy from sunlight that strikes the Earth in one hour is more than the energy consumed globally in a year. This makes photovoltaics, which convert solar energy into electrical energy, a critical technology to pursue. 95% of the photovoltaic market is dominated by silicon; its high efficiency, stability, and plummeting manufacturing costs made it the clear choice for commercialization. However, silicon solar cells are thick, heavy, opaque, and rigid, limiting potential applications. They are energy- and resource-intensive to produce, and their manufacturing process uses and produces several toxic substances. “Next-generation” photovoltaic …
Fluorescence Spectroscopy And Microscopy Studies Of Chromophore Coupling In Isolated Small Molecule Nanostructures, Sarah R. Marques
Fluorescence Spectroscopy And Microscopy Studies Of Chromophore Coupling In Isolated Small Molecule Nanostructures, Sarah R. Marques
Doctoral Dissertations
My thesis focused on understanding the structural changes producing different spectral signatures seen in aggregates of 7,8,15,16- tetrazaterrylene (TAT). Recent work from our group showed crystallographically selective directional charge-separation within isolated extended TAT crystals without the need of an interface. Aggregates of different size not only exhibited different exciton recombination kinetics, but different spectral signatures. The motivation for understanding the change in the structural properties producing the unique spectral signatures is elucidating the mechanism of this directional charge-separation, intrinsic or extrinsic. In this case, an intrinsic mechanism means it is caused by molecular design and packing, and extrinsic mechanism means …
Protein Detection And Structural Characterization By Mass Spectrometry Using Supramolecular Assemblies And Small Molecules, Bo Zhao
Doctoral Dissertations
Mass spectrometry (MS) has played an increasingly prominent role in proteomics and structure biology because it shows superior capabilities in identification, quantification and structural characterization of proteins. To realize its full potential in protein analysis, significant progress has been made in developing innovative techniques and reagents that can couple to MS detection. This dissertation demonstrates the use of polymeric supramolecular assemblies for enhanced protein detection in complex biological mixtures by MS. An amphiphilic random co-polymer scaffold is developed to form functional supramolecular assemblies for protein/ peptide enrichment. The influences of charge density and functional group pKa on host-guest interactions …
Top-Down And Bottom-Up Fabrication Of Key Components In Miniature Energy Storage Devices, Wenhao Li
Top-Down And Bottom-Up Fabrication Of Key Components In Miniature Energy Storage Devices, Wenhao Li
Doctoral Dissertations
The advent of miniature electronic devices demands power sources of commensurate form factors. This spurs the research of micro energy storage devices, e.g., 3D microbatteries. A 3D microbattery contains nonplanar microelectrodes with high aspect ratio and high surface area, separated by a nanoscale electrolyte. The device takes up a total volume as small as 10 mm3, allowing it to serve on a chip and to provide power in-situ. The marriage of nanotechnology and electrochemical energy storage makes microbattery research a fascinating field with both scientific excitement and application prospect. However, successful fabrication of well-functioned key components …
Model-Form Uncertainty Quantification For Predictive Probabilistic Graphical Models, Jinchao Feng
Model-Form Uncertainty Quantification For Predictive Probabilistic Graphical Models, Jinchao Feng
Doctoral Dissertations
In this thesis, we focus on Uncertainty Quantification and Sensitivity Analysis, which can provide performance guarantees for predictive models built with both aleatoric and epistemic uncertainties, as well as data, and identify which components in a model have the most influence on predictions of our quantities of interest. In the first part (Chapter 2), we propose non-parametric methods for both local and global sensitivity analysis of chemical reaction models with correlated parameter dependencies. The developed mathematical and statistical tools are applied to a benchmark Langmuir competitive adsorption model on a close packed platinum surface, whose parameters, estimated from quantum-scale computations, …
Reactive And Stimuli-Responsive Sulfonium-Based Polymer Zwitterions, Cristiam Santa Chalarca
Reactive And Stimuli-Responsive Sulfonium-Based Polymer Zwitterions, Cristiam Santa Chalarca
Doctoral Dissertations
This dissertation describes the synthesis and characterization of novel monomers and (co)polymer zwitterions that incorporate trialkylsulfonium cations. The novel materials presented herein constitute a unique type of polymer zwitterions that exhibit salt- and temperature-dependent water solubility as well as inherent reactivity. The behavior of these polymers in aqueous solutions, as nanostructures, and at liquid-liquid interfaces was studied; in all cases, the inherent reactivity of the polymers was harnessed towards the fabrication of novel polymers and soft materials. Following an introductory chapter, Chapter 2 describes the synthesis of sulfonium sulfonate monomers and polymer zwitterions. Both styrenic and methacrylic monomers were synthesized …
Synthesis Of Magnetic Ion Doped Ii-Vi Benzenechalcogenolate Molecular Clusters, Fumitoshi Kato
Synthesis Of Magnetic Ion Doped Ii-Vi Benzenechalcogenolate Molecular Clusters, Fumitoshi Kato
Doctoral Dissertations
Diluted magnetic semiconductor quantum dots (DMS-QDs) is a class of material prepared by introducing a small percentage of magnetic impurities to impart new magneto-optical properties to the host nanocrystal (NC). Such materials are regarded as promising candidates for their potential application in spintronic devices. The overall functionality of the DMS‑QD is highly dependent on the dopant position within the host structure. A thorough understanding of the doping mechanism is, therefore, critical to gain better control over the dopant speciation in nanocrystal lattice and material properties. In this work, we utilized II‑VI molecular clusters that are analogous to bulk semiconductors as …