Physical Sciences and Mathematics Commons^™

Analyze Informant-Based Questionnaire For The Early Diagnosis Of Senile Dementia Using Deep Learning, Fubao Zhu, Xiaonan Li, Daniel Mcgonigle, Haipeng Tang, Zhuo He, Chaoyang Zhang, Guang-Uei Hung, Pai-Yi Chu, Weihua Zhou

Faculty Publications

Objective: This paper proposes a multiclass deep learning method for the classification of dementia using an informant-based questionnaire.

Methods: A deep neural network classification model based on Keras framework is proposed in this paper. To evaluate the advantages of our proposed method, we compared the performance of our model with industry-standard machine learning approaches. We enrolled 6,701 individuals, which were randomly divided into training data sets (6030 participants) and test data sets (671 participants). We evaluated each diagnostic model in the test set using accuracy, precision, recall, and F1-Score.

Results: Compared with the seven conventional machine learning …

Multi-Point Flux Approximations Via The O-Method, Christen Leggett

Master's Theses

When an oil refining company is drilling for oil, much of the oil gets left behind after the first drilling. Enhanced oil recovery techniques can be used to recover more of that oil, but these methods are quite expensive. When a company is deciding if it is worth their time and money to use enhanced oil recovery methods, simulations can be used to model oil flow, showing the behavior and location of the oil. While methods do exist to model this flow, these methods are often very slow and inaccurate due to a large domain and wide variance in coefficients. …

Effects Of Water Table Depth And Edaphic Characteristics On Plant Diversity In A Southern Mississippi Pitcher Plant Bog, Patrick Kirby

Master's Theses

This study examined the effects that water table depth and soil characteristics have on plant species richness and species composition within pitcher plant bogs across seasons. Eight piezometers were installed at random distances to monitor long-term water table depth and pressure fluctuations along a ~710-meter line transect traversing upland and bog habitats. Vegetation sampling quadrats (n=128) were set up near each piezometer. Cover data and water table depths were collected in spring and late summer. Soil samples collected from each treatment group were used to obtain soil texture and nutrient data. The summer collection period yielded a total gdiversity of …

Fracture Analysis Of The Lower Oceanic Crust, Atlantis Bank, Southwest Indian Ridge, Trent Jackson

Master's Theses

Atlantis Bank (AB) is an oceanic core complex (OCC), formed at the slow-spreading (spreading rate/yr) Southwest Indian Ridge (SWIR)-Atlantis II transform junction. AB is a domal massif composed of lower crustal and upper mantle rocks exhumed along a normal-sense detachment shear zone/fault. OCCs are of high interest since oceanic crust comprises the majority of Earth’s crust and OCCs form up to 15% of the crust that is formed at slow-spreading ridges. Brittle deformation, such as faults and fractures provide pathways for fluids to interact with the crust, which increases heat and mass exchange between the crust and hydrosphere, and is …

Adsorption Of Polyisobutylene-Based Dispersants Onto Carbon Black, Travis Paul Holbrook

Dissertations

The formation of carbonaceous by-products (e.g. soot) during the operation of an internal combustion engine is unavoidable and the aggregation of this soot leads to deleterious effects including abrasive wear of the engine, increased oil viscosities, and sludge deposition. Dispersants, which are composed of a hydrophobic tail and a polar headgroup, are used as oil additives to aid in the suspension and stabilization of the soot particles. Polyisobutylene succinimide (PIBSI) is the most well-studied class of dispersants and is characterized by a linear architecture and polyamine headgroup that interacts with soot by acid-base and dipole-dipole interactions. As such, there remains …

The Antimicrobial Activity And Cellular Targets Of Plant Derived Aldehydes And Degradable Pro-Antimicrobial Networks In Pseudomonas Aeruginosa, Yetunde Adewunmi

Dissertations

Essential oils (EOs) are plant-derived products that have been long exploited for their antimicrobial activities in medicine, agriculture, and food preservation. EOs represent a promising alternative to conventional antibiotics due to the broad-range antimicrobial activity, low toxicity to human commensal bacteria, and the capacity to kill microorganisms without promoting resistance. Despite the progress in the understanding of the biological activity of EOs, many aspects of their mode of action remain inconclusive. The overarching aim of this work was to address these gaps by studying molecular interactions between antimicrobial plant aldehydes and the opportunistic human pathogen Pseudomonas aeruginosa. We initiated …

Developing A Computational Framework For A Construction Scheduling Decision Support Web Based Expert System, Feroz Ahmed

Dissertations

Decision-making is one of the basic cognitive processes of human behaviors by which a preferred option or a course of action is chosen from among a set of alternatives based on certain criteria. Decision-making is the thought process of selecting a logical choice from the available options. When trying to make a good decision, all the positives and negatives of each option should be evaluated. This decision-making process is particularly challenging during the preparation of a construction schedule, where it is difficult for a human to analyze all possible outcomes of each and every situation because, construction of a project …

Establishing The Role Of The Mississippi-Alabama Barrier Islands In Mississippi Sound And Bight Circulation Using Observational Data Analysis And A Coastal Model, Laura Hode

Dissertations

The Mississippi-Alabama barrier islands restrict exchange between the Mississippi Sound and Mississippi Bight in the northern Gulf of Mexico. The islands also act as storm breaks for tropical cyclones, so their continued existence sustains marine ecosystems and protects coastal communities. However, the chain has undergone extensive segmentation, erosion, and westward migration in the past two hundred years. The islands are now more susceptible to further erosion (Pendleton et al., 2013; Morton, 2007). Additional reduction in island subaerial land extent would alter circulation in the Mississippi Sound and Bight.

Consequently, this study targeted the two most vulnerable barrier islands in the …

Dynamic Accretion Beneath A Slow-Spreading Ridge Segment: Iodp Hole 1473a And The Atlantis Bank Oceanic Core Complex, Henry J.B. Dick, Christopher J. Macleod, Peter Blum, Natsue Abe, Donna K. Blackman, Julie A. Bowles, M.J. Cheadle, K. Cho, Jakub Ciazela, Jeremy Deans, Virginia P. Edgcomb, C. Ferrando, Lyderic France, B. Ghosh, Benoit Ildefonse, Barbara John, Mark A. Kendrick, J. Koepke, James A.M. Leong, C. Liu, Q. Ma, T. Morishita, A. Morris, J.H. Natland, T. Nozaka, O. Pluemper, A. Sanflippo, J.B. Sylvan, Maurice A. Tivey, R. Tribuzio, G. Viegas

Faculty Publications

809 deep IODP Hole U1473A at Atlantis Bank, SWIR, is 2.2 km from 1,508‐m Hole 735B and 1.4 from 158‐m Hole 1105A. With mapping, it provides the first 3‐D view of the upper levels of a 660‐km² lower crustal batholith. It is laterally and vertically zoned, representing a complex interplay of cyclic intrusion, and ongoing deformation, with kilometer‐scale upward and lateral migration of interstial melt. Transform wall dives over the gabbro‐peridotite contact found only evolved gabbro intruded directly into the mantle near the transform. There was no high‐level melt lens, rather the gabbros crystallized at depth, and then emplaced …

Towards The Synthesis Of An Artificial Fluorescent Siderophore, Ashley Burns

Honors Theses

Siderophores are molecules capable of binding ferric ions with high affinity (Ka = 1052). This thesis outlines our attempts to synthesize an artificial siderophore, which incorporates a signaling group to help monitor the uptake of ferric ions. The artificial siderophore is a tripodal molecular receptor synthesized in a five-step procedure with a proposed final sixth step. Rhodamine 6G azide (95.0% yield) was formed from rhodamine 6G and the synthesis of 2-azidoethanamine was modified from the literature. The tripodal arm portion of the sensor was successfully synthesized by protecting the catechol of 2,3-dihydroxybenzaldehyde to form 3-formyl-1,2-phenylene dimethanesulfonate (98.8% yield). The reduction …

The Variability Of High-Frequency Motions And Their Interactions With The Mesoscale On The Mississippi Shelf, Jordan Earls

Master's Theses

In this study, we examine the spatial and temporal variability of high-frequency and low-frequency motions across the Mississippi Shelf and how the high-frequency motions are modulated by low-frequency mesoscale motions. For this purpose, we use Acoustic Doppler Current Profiler (ADCP) measurements collected at nearshore (23 m), mid-shelf (60 m), and shelf break (88 m) stations. High-frequency motions are defined as motions with periods less than 36 hours, whereas mesoscale motions have larger periods. The collected datasets are analyzed through bandpass filtering, least square harmonic analysis, spectral analysis, and empirical orthogonal functions (EOF). We find that along-shelf barotropic mesoscale motions contain …

Stretchable Self-Healable Semiconducting Polymer Film For Active-Matrix Strain-Sensing Array, Jin Young Oh, Donghee Son, Toru Katsumata, Yeongjun Lee, Yeongin Kim, Jeffrey Lopez, Hung-Chin Wu, Jiheong Kang, Joonsuk Park, Xiaodan Gu, Jaewan Mun, Nathan Ging-Ji Wang, Yikai Yin, Wei Cai, Youngjun Yun, Jeffrey B.-H. Tok, Zhenan Bao

Faculty Publications

Skin-like sensory devidces shoud be stretchable and self-healable to meet the demands for future electronic skin applications. Despite recent notable advances in skin-inspired electronic materials, it remains challenging to confer these desired functionalities to an active semiconductor. Here, we report a strain-sensitive, stretchable, and autonomously self-healable semiconducting film achieved through blending of a polymer semiconductor and a self-healable elastomer, both of which are dynamically cross-linked by metal coordination. We observed that by controlling the percolation threshold of the polymer semiconductor, the blend film became strain sensitive, with a gauge factor of 5.75 x 10⁵ at 100% strain in a …

Short Term Effects Of Hurricane Irma And Cyanobacterial Blooms On Ammonium Cycling Along A Freshwater-Estuarine Continuum In South Florida, Justyna J. Hampel, Mark J. Mccarthy, Megan H. Reed, Silvia E. Newell

Faculty Publications

Lacustrine and coastal systems are vulnerable to the increasing number and intensity of tropical storms driven by climate change. Strong winds associated with tropical storms can mobilize nutrients in sediments and alter nitrogen and phosphorus cycling, leading to amplification of preexisting conditions, such as eutrophication and cyanobacterial blooms (cyanoHABs). In 2016, Florida declared a State of Emergency within and downstream of Lake Okeechobee (LO) due to toxic cyanobacterial blooms (primarily Microcystis). The blooms originated in LO, but flood control measures released water from LO to the brackish St. Lucie Estuary (SLE). In September 2017, Hurricane Irma traversed the Florida …

Egestion Versus Excretion: A Meta-Analysis Examining Nutrient Release Rates And Ratios Across Freshwater Fauna, Halvor Halvorson, Carla Atkinson

Faculty Publications

In aquatic settings, animals directly affect ecosystem functions through excretion of dissolved nutrients. However, the comparative role of egestion as an animal-mediated nutrient flux remains understudied. We conducted a literature survey and meta-analysis to directly compare nitrogen (N), phosphorus (P), and N:P of egestion compared to excretion rates and ratios across freshwater animals. Synthesizing 215 datasets across 47 animal species (all primary consumers or omnivores), we show that the total N and P egestion rates exceed inorganic N and P excretion rates but not total N and P excretion rates, and that proportions of P egested compared to excreted depend …

Calibration Of The Lisst-Vsf To Derive The Volume Scattering Functions In Clear Waters, Lianbo Hu, Xiaodong Zhang, Yuanheng Xiong, Ming-Xia He

Faculty Publications

The recently commercialized LISST-VSF instrument measures the volume scattering function (VSF) from 0.1° to 15° with a traditional laser diffraction unit (LISST) and from 15° to 155° with an eyeball component. Between these two optical components, only the LISST unit is calibrated. The eyeball measurements are scaled using the VSFs at 15° that are measured by both components. As this relative calibration relies on a valid measurement at 15° by the LISST, it might fail in clear oceanic waters, where the forward scattering is relative weak either due to a lack of large particles or an overall low concentration of …

Extended-Range Oscillations And The First Sharp Diffraction Peak In Amorphous Silicon: A Systematic Study, Devilal Dahal

Master's Theses

The first sharp diffraction peak (FSDP), which characterizes the static structure factor of many glassy systems near the wave vector region of 1-2 Å^-1 has been observed depending on the temperature, pressure and the degree of annealing of the system. The presence of the FSDP is indicative of the intermediate range order (IRO). In current work, we study the role of the extended- range oscillations on the parameters of the FSDP, i.e., intensity, position, area, and the full width at half maximum (FWHM) by using high-quality simulated models of amorphous silicon. The radial distance up to half of the …

Morphological Study Of Voids In Ultra-Large Models Of Amorphous Silicon, Durga Prasad Paudel

Dissertations

The microstructure of voids in pure and hydrogen-rich amorphous silicon (a:Si) network was studied in ultra-large models of amorphous silicon, using classical and quantum- mechanical simulations, on the nanometer length scale. The nanostructure, particularly voids of device grade ultra-large models of a:Si was studied, in which observed three-dimensional realistic voids were extended using geometrical approach within the experimental limit of void-volume fractions. In device-grade simulated models, the effect of void morphology; size, shape, number density, and distribution on simulated scattering intensities in small- angle region were investigated. The evolution of voids on annealing below the crystallization temperature …

Response And Recovery Of Horn And Petit Bois Islands, Mississippi, Usa To Tropical Cyclone Impacts: 2004 – 2016, Shara Gremillion

Master's Theses

Horn and Petit Bois islands are two of five Mississippi (MS) barrier islands that provide physical protection from tropical cyclones threatening the MS Gulf Coast, in addition to critical habitat for the northern Gulf of Mexico (GOM). In September 2004, Hurricane Ivan removed a large volume of sediment from the eastern ends of Horn and Petit Bois islands with its 1-2 m storm surge and ~194 kph wind speeds. Then, in August 2005 Hurricane Katrina severely impacted the two islands again with its 3.5-5.5 m storm surge on Horn and Petit Bois islands, and up to 204 kph wind speeds …

Krylov Subspace Spectral Methods With Non-Homogenous Boundary Conditions, Abbie Hendley

Master's Theses

For this thesis, Krylov Subspace Spectral (KSS) methods, developed by Dr. James Lambers, will be used to solve a one-dimensional, heat equation with non-homogenous boundary conditions. While current methods such as Finite Difference are able to carry out these computations efficiently, their accuracy and scalability can be improved. We will solve the heat equation in one-dimension with two cases to observe the behaviors of the errors using KSS methods. The first case will implement KSS methods with trigonometric initial conditions, then another case where the initial conditions are polynomial functions. We will also look at both the time-independent and time-dependent …

Stratigraphic Interpretations Of Eocene Winona And Tallahatta Formations In The Duffee Quadrangle, Ms, Sydney Kennedy

Honors Theses

Outcrops and exposures of the Winona and Tallahatta formations in the Duffee Quadrangle in Newton and Lauderdale counties were mapped and analyzed. The rock type, composition, structures, and fossils were identified at each site; unit thicknesses were measured, and stratigraphic relationships were analyzed for available exposures. Using GPS coordinates, each site was mapped on Google Earth Pro. The data collected at each site, aerial photographs, and topographic maps were used to identify each formation. The variability between previous works and this study was analyzed. The primary rock type found in the Tallahatta Formation is siliciclastic silty claystone and sandstone; some …

A Compilation Of Global Bio-Optical In Situ Data For Ocean-Colour Satellite Applications: Version Two, André Valente, Shubha Sathyendranath, Vanda Brotas, Steve Groom, Michael Grant, Malcolm Taberner, David Antoine, Robert Arnone, William M. Balch, Kathryn Baker, Ray Barlow, Simon Bélanger, Jean-François Berthon, Şükrü Beşiktepe, Yngve Borsheim, Astrid Bracher, Vittorio Brando, Elisabetta Canuti, Francisco Chavez, Andrés Cianca, Hervé Claustre, Lesley Clementson, Richard Crout, Robert Frounin, Carlos García-Soto, Stuart W. Gibb, Richard Gould, Stanford B. Hooker, Mati Kahru, Milton Kampel, Holger Klein, Susanne Kratzer, Raphael Kudela, Jesus Ledesma, Hubert Loisel, Patricia Matrai, David Mckee, Brian G. Mitchell, Tiffany Moisan, Frank Muller-Karger, Leonie O'Dowd, Michael Ondrusek, Trevor Platt, Alex J. Poulton, Michael Repecaud, Thomas Schroeder, Timothy Smyth, Denise Smyth-Wright, Heidi M. Sosik, Michael Twardoski, Vincenzo Vellucci, Kenneth Voss, Jeremy Werdell, Marcel Wernand, Simon Wright, Giuseppe Zibordi

Faculty Publications

A global compilation of in situ data is useful to evaluate the quality of ocean-colour satellite data records. Here we describe the data compiled for the validation of the ocean-colour products from the ESA Ocean Colour Climate Change Initiative (OC-CCI). The data were acquired from several sources (including, inter alia, MOBY, BOUSSOLE, AERONET-OC, SeaBASS, NOMAD, MERMAID, AMT, ICES, HOT and GeP&CO) and span the period from 1997 to 2018. Observations of the following variables were compiled: spectral remote-sensing reflectances, concentrations of chlorophyll a, spectral inherent optical properties, spectral diffuse attenuation coefficients and total suspended matter. The data were from …

Rf Energy Harvesting Wireless Communication: Rf Environment, Device Hardware And Practical Issues, Yu Luo, Lina Pu, Guodong Wang, Yanxiao Zhao

Faculty Publications

Radio frequency (RF) based wireless power transfer provides an attractive solution to extend the lifetime of power-constrained wireless sensor networks. Through harvesting RF energy from surrounding environments or dedicated energy sources, low-power wireless devices can be self-sustaining and environment-friendly. These features make the RF energy harvesting wireless communication (RF-EHWC) technique attractive to a wide range of applications. The objective of this article is to investigate the latest research activities on the practical RF-EHWC design. The distribution of RF energy in the real environment, the hardware design of RF-EHWC devices and the practical issues in the implementation of RF-EHWC networks are …

A Sustained Ocean Observing System In The Indian Ocean For Climate Related Scientific Knowledge And Societal Needs, J.C. Hermes, Y. Masumoto, L.M. Beal, M.K. Roxy, J. Vialard, M. Andres, H. Annamalai, S. Behera, N. D'Adamo, T. Doi, M. Feng, W. Han, N. Hardman-Mountford, H. Hendon, R. Hood, S. Kido, C. Lee, T. Lee, M. Lengaigne, J. Li, R. Lumpkin, K.N. Navaneeth, B. Milligan, M.J. Mcphaden, M. Ravichandran, T. Shinoda, A. Singh, B. Sloyan, P.G. Strutton, A.C. Subramanian, S. Thurston, T. Tozuka, C.C. Ummenhofer, A.S. Unnikrishnan, R. Venkatesan, D. Wang, J. Wiggert, L. Yu, W. Yu

Faculty Publications

The Indian Ocean is warming faster than any of the global oceans and its climate is uniquely driven by the presence of a landmass at low latitudes, which causes monsoonal winds and reversing currents. The food, water, and energy security in the Indian Ocean rim countries and islands are intrinsically tied to its climate, with marine environmental goods and services, as well as trade within the basin, underpinning their economies. Hence, there are a range of societal needs for Indian Ocean observation arising from the influence of regional phenomena and climate change on, for instance, marine ecosystems, monsoon rains, and …

Modeling Atmosphere-Ocean Radiative Transfer: A Pace Mission Perspective, Jacek Chowdhary, Peng-Wang Zhai, Emmanuel Boss, Heidi Dierssen, Robert Frouin, Amir Ibrahim, Zhongping Lee, Lorraine A. Remer, Michael Twardowski, Feng Xu, Xiaodong Zhang, Matteo Ottaviani, William Reed Espinosa, Didier Ramon

Faculty Publications

The research frontiers of radiative transfer (RT) in coupled atmosphere-ocean systems are explored to enable new science and specifically to support the upcoming Plankton, Aerosol, Cloud ocean Ecosystem (PACE) satellite mission. Given (i) the multitude of atmospheric and oceanic constituents at any given moment that each exhibits a large variety of physical and chemical properties and (ii) the diversity of light-matter interactions (scattering, absorption, and emission), tackling all outstanding RT aspects related to interpreting and/or simulating light reflected by atmosphere-ocean systems becomes impossible. Instead, we focus on both theoretical and experimental studies of RT topics important to the science threshold …

Melt Electrospinning Designs For Nanofiber Fabrication For Different Applications, Yasseen S. Ibrahim, Essraa A. Hussein, Moustafa M. Zagho, Ghada G. Abdo, Ahmed A. Elzatahry

Faculty Publications

Nanofibers have been attracting growing attention owing to their outstanding physicochemical and structural properties as well as diverse and intriguing applications. Electrospinning has been known as a simple, flexible, and multipurpose technique for the fabrication of submicro scale fibers. Throughout the last two decades, numerous investigations have focused on the employment of electrospinning techniques to improve the characteristics of fabricated fibers. This review highlights the state of the art of melt electrospinning and clarifies the major categories based on multitemperature control, gas assist, laser melt, coaxial, and needleless designs. In addition, we represent the effect of melt electrospinning process parameters …

Deep-Ocean Mixing Driving By Small-Scale Internal Tides, Clément Vic, Alberto C. Naveira Garabato, J.A. Mattias Green, Amy F. Waterhouse, Angélique Melet, Casimir De Lavergne, Maarten C. Buijsman, Gordon R. Stephenson

Faculty Publications

Turbulent mixing in the ocean is key to regulate the transport of heat, freshwater and biogeochemical tracers, with strong implications for Earth's climate. In the deep ocean, tides supply much of the mechanical energy required to sustain mixing via the generation of internal waves, known as internal tides, whose fate-the relative importance of their local versus remote breaking into turbulence-remains uncertain. Here, we combine a semi-analytical model of internal tide generation with satellite and in situ measurements to show that from an energetic viewpoint, small-scale internal tides, hitherto overlooked, account for the bulk (>50%) of global internal tide generation, …

Gogo: An Improved Algorithm To Measure The Semantic Similarity Between Gene Ontology Terms, Chenguang Zhao

Master's Theses

Measuring the semantic similarity between Gene Ontology (GO) terms is an essential step in functional bioinformatics research. We implemented a software named GOGO for calculating the semantic similarity between GO terms. GOGO has the advantages of both information-content-based and hybrid methods, such as Resnik’s and Wang’s methods. Moreover, GOGO is relatively fast and does not need to calculate information content (IC) from a large gene annotation corpus but still has the advantage of using IC. This is achieved by considering the number of children nodes in the GO directed acyclic graphs when calculating the semantic contribution of an ancestor node …

Detecting Coastal Marsh Change From Aerial Imagery Using Spectral And Textural Methods: Pascagoula River Estuary, Mississippi, 1955-2014, Margaret Claire Bell Waldron

Master's Theses

As sea level rise accelerates, coastal marsh ecosystems are increasingly vulnerable. Vertical accretion rates must exceed or keep pace with rates of sea level rise to prevent transition to open water or inland migration of marsh vegetation. While some marsh systems along the northern Gulf of Mexico coast have remained stable, others, e.g., the marshes of the Louisiana Gulf Coast, have experienced high rates of conversion to open water. This study examined the historical extent of intertidal marsh at the mouth of the Pascagoula River in Jackson County, Mississippi to determine whether marsh extent changed during the period 1955-2014 and …

The Use Of Heterocycles As Important Structures In Medicinal Chemistry, Sayre Weast

Honors Theses

Heterocycles have many applications in the discipline of medicinal chemistry. These structures are found in various natural products with relevant biological activity. Our research group, in collaboration with two others, is particularly interested in one heterocycle, quinoline, as a scaffold for HIV-1 integrase inhibitors. A synthetic route has been developed to produce a derivatized structure on small scale. One goal of this thesis was to expand the scale of this route to provide increased quantities of the quinoline scaffold. Procedures were adapted to accommodate the increase in scale to convert commercially available anthranilic acids to quinolines via the isatoic anhydride. …

A High-Spin Ground-State Donor-Acceptor Conjugated Polymer, A.E. London, H. Chen, M.A. Sabuj, J. Tropp, M. Saghayezhian, N. Eedugurala, B.A. Zhang, Y. Liu, X. Gu, B.M. Wong, N. Rai, M.K. Bowman, J.D. Azoulay

Faculty Publications

Interest in high-spin organic materials is driven by opportunities to enable far-reaching fundamental science and develop technologies that integrate light element spin, magnetic, and quantum functionalities. Although extensively studied, the intrinsic instability of these materials complicates synthesis and precludes an understanding of how fundamental properties associated with the nature of the chemical bond and electron pairing in organic materials systems manifest in practical applications. Here, we demonstrate a conjugated polymer semiconductor, based on alternating cyclopentadithiophene and thiadiazoloquinoxaline units, that is a ground-state triplet in its neutral form. Electron paramagnetic resonance and magnetic susceptibility measurements are consistent with a high-to-low spin …