Physical Sciences and Mathematics Commons^™

Landscape/Atmosphere Interactions And Carbon-Dioxide Dynamics In The Great Onyx Groundwater Basin, Mammoth Cave National Park, Kentucky, Meghan Raines

Masters Theses & Specialist Projects

An increase in atmospheric CO2 since the Industrial Revolution has altered rates of global climate change and has motivated a need to better quantify the flux of carbon between Earth’s reservoirs. Attempts to quantify the exchange of atmospheric carbon between sources and sinks have led to an increasing interest in the terrestrial landscape, including the continental carbon sink associated with carbonate-mineral dissolution. This research sought to better inform an understanding of karst landscapes and their relationship with global climate change through carbon cycling. The study utilized high-resolution data collection of pH, temperature, and specific conductance of waters in the Cascade …

Hydrological Dynamics Of Surface-Groundwater Interactions Between Major Springs Of Mammoth Cave And The Green River, Kentucky, Usa, Matthew Cecil

Masters Theses & Specialist Projects

Mammoth Cave is an iconic example of the cave and karst systems that underlie over 50% of the United States and provide around 13% of the world’s population with water resources. These environmental features are vulnerable to drought, pollution, and human impacts. The complex hydrological regime of the Mammoth Cave system has been studied in the past, but there are improvements and updates that can be made to the past research. The dynamics of the surface-groundwater system, particularly reversals of the Green River and how it backfloods into the cave, are some examples. Echo River and River Styx Springs provide …

A Predictive Flood Model For Urban Karst Groundwater Systems, Trayson Lawler

Masters Theses & Specialist Projects

Urban karst environments are often plagued by groundwater flooding, which occurs when water rises from the subsurface to the surface through the underlying caves and other karst features. The heterogeneity and interconnectedness of karst systems often makes them very unpredictable, especially during intense storm events; urbanization exacerbates the problem with the addition of many impervious surfaces. Residents in such areas are frequently disturbed and financially burdened by the effects of karst groundwater flooding. The Federal Emergency Management Agency (FEMA) offers limited protection to citizens living near flood-prone areas as they primarily focus on the areas near surface bodies of water. …

Investigating Epikarst Recharge Dynamics Under Agricultural Landuse Using Hydrometeorological And Isotopic Tracers, Austin Shane Deering

Masters Theses & Specialist Projects

Epikarst systems have complex recharge – discharge processes in telogenetic karst systems, including highly variable storage, flowpaths, and mixing dynamics. This research aimed to characterize the epikarst zone using hydrogen and oxygen isotopic tracers of these processes within south-central Kentucky’s Crumps Cave system located in the Pennyroyal Sinkhole Plain. Data and statistical analyses were applied to highresolution rainfall (RF), lysimeter (10 cm, 20 cm, 30 cm depths), and an epikarst Waterfall 1 (WF1) isotope data collected on a weekly basis between 2011-2018. These data were coupled with WF1 discharge measurements and weather station data collected at Crumps Cave Preserve during …

An Adaptive Hazard Planning And Mitigation Framework For Responding To Urban Contamination In Karst Aquifer Systems, James Edward Troxell

Masters Theses & Specialist Projects

Environmental hazards in karst regions are damaging and often go unnoticed until an issue has escalated to a point of affecting life or property. The field of emergency and environmental contamination response lacks planning or preparedness focused on remediating groundwater contamination in karst systems. A lack of preplanning before an incident can lead to confusion, delayed response, and the inability to remediate the contaminant. Due to the rapid movement of contaminants through urban karst groundwater aquifers, an efficient response plan that leverages localized data in a GIS should be developed and maintained in order to adequately respond. The objective of …

Application Of Excitation-Emission Matrices To Fluorescent Dye Tracing Of Groundwater Flow, Cayla M. Baughn

Masters Theses & Specialist Projects

Fluorescent dye tracing of groundwater is a technique employed particularly in carbonate rock karst regions to examine karst hydrology by mapping underground flow paths. It is important to understand the hydrology of karst environments because solutionally-enlarged conduits may allow the rapid influx of contaminants into the groundwater system. Fluorescent dye tracing involves the injection of a fluorescent dye into an appropriate injection site (sinking streams, sinkholes, or even through soil flushed with water) and is followed by sampling at sites where the dye may be recovered (typically springs). Various methods exist by which sampling may occur, but all methods ultimately …

Impacts Of Forest Management And Timber Harvest Practices On Karst Critical Zone Processes In Tongass National Forest, Alaska, Anna Gwendolyn Harris

Masters Theses & Specialist Projects

This study characterizes the throughfall, hydrogeochemistry, dissolution rates, and carbon sources of two proximate temperate rainforest cave systems within the Tongass National Forest in Southeast Alaska (Tongass). Study sites include: an old-growth forest, characterized by having never been logged (containing Walkabout Cave system); and a previously logged – within thirty years, second-growth forest (containing Zina Cave system). Precipitation data were recorded over a five-month period at 10-minute intervals, to understand the effects of throughfall between the altering old and second-growth canopies. At each major spring for the two cave systems, high-resolution data were collected from June 29 through November 21, …

Hydrogeochemical Characterization And Speleogenesis Of Sistema Huautla In Oaxaca, Mexico, Fernando Hernandez

Masters Theses & Specialist Projects

Sierra Mazateca, Mexico is home to Sistema Huautla, the deepest cave in the Western hemisphere with 1,560 meters of depth and 90 kilometers of passage, including 26 entrances distributed in a high-relief, karstified terrain, within the Sistema Huautla Karst Groundwater Basin. Exploration of the cave has generated research questions about its evolution and geomorphology given the different vadose and phreatic zones impacted by tectonic and incision processes. Dye traces during this study of Cueva de La Peña Colorada confirmed it is a fossil resurgence of the cave system. An additional cave, Cueva Elysium, was connected hydrologically in 2019, expanding the …

Influence Of Spring Flow Reversals On Cave Dissolution In A Telogenetic Karst Aquifer, Mammoth Cave, Ky, Chelsey Kipper

Masters Theses & Specialist Projects

An often overlooked connection between karst groundwater systems and surface water is spring flow reversal, the flow of river water into karst springs caused by changes in hydraulic gradient. Karst aquifers are subject to the intrusion of river water when the hydraulic head of a base level river is higher than the hydraulic head of a base level spring. When this occurs, the flow out of the spring reverses, allowing river water to enter base level conduits. River water thus becomes a source of recharge into karst basins, transporting both valuable nutrients and harmful contaminants into karst aquifers. The rapid …

An Urban Karst Aquifer Resource Evaluation And Monitoring Toolbox, Rachel Anne Kaiser

Masters Theses & Specialist Projects

In urban karst areas, such as the City of Bowling Green, Kentucky and the Tampa Bay Metropolitan Area, groundwater quality faces a variety of threats. The development of residential, commercial, and industrial landuse types allows for a wide variety of groundwater pollutants to enter the karst groundwater systems. Various different models and indices have attempted evaluative approaches to identify issues in urban karst areas, but the methods vary by location and lack a focus on urban karst groundwater quality. There also exists a lack of a data-driven approach that is able to capture short- and long-term changes in threats to …

Monitoring And Evaluating The Influences Of Class V Injection Wells On Urban Karst Hydrology, James Adam Shelley

Masters Theses & Specialist Projects

The response of a karst aquifer to storm events is often faster and more severe than that of a non-karst aquifer. This distinction is often problematic for planners and municipalities, because karst flooding does not typically occur along perennial water courses; thus, traditional flood management strategies are usually ineffective. The City of Bowling Green (CoBG), Kentucky is a representative example of an area plagued by karst flooding. The CoBG, is an urban karst area (UKA), that uses Class V Injection Wells to lessen the severity of flooding. The overall effectiveness, siting, and flooding impact of Injection Wells in UKA’s is …

Controls On Speleogenesis In The Upper-Mississippian Pennington Formation On The Western Cumberland Plateau Escarpment, Hali Steinmann

Masters Theses & Specialist Projects

Much of the pioneering work on caves of the Cumberland Plateau (province spanning Tennessee, Kentucky, Alabama, and Georgia) has been stratigraphically located within the Mississippian Bangor and Monteagle Limestones, wherein some of the region’s largest and most spectacular caves occur. Of interest to the understanding of this karst landscape, but severely underrepresented in the literature thereof, are caves and karst features in a heterogeneous sequence of clastics and carbonates known collectively as the Pennington Formation (Upper Mississippian). This work consisted of a regional study of Pennington caves on the western Cumberland Plateau escarpment (Alabama and Tennessee), and a case study …

Shower Atomization, Chirag Ayappa Ravishankar,

Masters Theses & Specialist Projects

The research will help to design a shower for Dr. Chelson’s shelter, which can control the water flow, pressure and duration of the shower, which optimizes the utilization of water. The showers could be used in drought-hit areas where water is very scarce, as daily sanitation needs are necessary to keep a person safe and healthy without wasting water. The report from, World Health Organization shows that showers consume the most water. A timed shower could help resolve this issue through eliminating the wastage. Eco-friendly environmentalists may also be attracted to the showers, as their main purposes are to save …

Characterizing South American Mesoscale Convective Complexes Using Isotope Hydrology, Kyle J. Hogancamp

Masters Theses & Specialist Projects

Mesoscale convective complexes (MCCs) over subtropical South America contribute an average annual volume of precipitation equal to approximately seven km3 and occur with an average regularity in the region, with more than 30 per warm season. Isotopic characteristics of precipitation, such as δ2H and δ18O values, provide information that can be used to identify unique processes and sources related to precipitation events. The largest database of isotope characteristics of precipitation within the region is the Global Network of Isotopes in Precipitation (GNIP), which provides varying temporal resolution data from stations around the world, including subtropical South America.

Using this database, …

An Investigation Of Groundwater Flow In The Vicinity Of Patoka Dam, Indiana, Lee Anne Bledsoe

Masters Theses & Specialist Projects

Several dams throughout the United States have been built on karst terrains, where soluble limestone bedrock has been dissolved to form features such as caves, sinkholes, and underground rivers. In such karst regions, subsurface hydrology can play an integral role in the condition, operation, and safety of dams and should be considered during risk assessment. Patoka Dam, near Jasper, Indiana, is situated on a well-developed karst landscape/aquifer system, faces significant potential challenges, and recently underwent risk assessment. A groundwater flow investigation using multiple fluorescent tracer tests, analysis of water-table elevations, isopach mapping of the Glen Dean Limestone, and spring hydrograph …

Trophic Dynamic Interactions In A Temperate Karst River, Elizabeth Malloy

Masters Theses & Specialist Projects

Surface streams in karst landscapes are often characterized by high nutrient levels due to incomplete filtration through series of innumerable, below-ground conduits. Seasonal growth of the filamentous alga, Cladophora, is typically associated with nutrient-rich waters. This research compared macroinvertebrate food web structure between riverine reaches with contrasting underlying karst topography, nutrient levels, and Cladophora cover during summer 2012 and autumn 2013. Recent work in these reaches found a high correlation between Cladophora cover and nutrient content, particularly nitrate. Four questions were addressed during this study: 1. Do longitudinal trends in algal and consumer δ13C values relate to decreased DIC availability …

Carbon Cycling Dynamics Inferred From Carbon Isotope Sourcing In A Mid-Latitude Karst-Influenced River, Kegan N. Mcclanahan

Masters Theses & Specialist Projects

As ever-increasing levels of carbon dioxide alter the chemistry of the Earth’s atmosphere, understanding the global carbon cycle becomes increasingly important. A particularly important component is the riverine carbon cycle, as rivers are the primary conduits for dissolved inorganic carbon from terrestrial watersheds to ocean basins. Stable carbon isotopes (13C/12C) were collected weekly and input into the mixing model IsoSource to delineate seasonal carbon sourcing along two nested basins in the upper Green River System, Kentucky. In the more siliciclastic upstream catchment, dissolved inorganic carbon (DIC) was primarily derived from soil respiration (34%). Groundwater dissolving carbonate bedrock and carbonate dissolution/precipitation …

Evaluating The Effectiveness Of Regulatory Stormwater Monitoring Protocols On Groundwater Quality In Urbanized Karst Regions, Daniel C. Nedvidek

Masters Theses & Specialist Projects

Non-point pollution from stormwater runoff is one of the greatest threats to water quality in the United States today, particularly in urban karst settings. In these settings, the use of karst features and injection wells for stormwater management results in virtually untreated water being directed into the karst aquifer. Currently, no policies exist specifically to provide water quality protections to karst environments. This study utilized a combination of karst stormwater quality data, along with survey data collected from MS4 Phase II communities, and an analysis of current federal, local, and state water quality regulations, to assess the need for karst-specific …

Impacts Of Carbonate Mineral Weathering On Hydrochemistry Of The Upper Green River Basin, Kentucky, Laura Leigh Osterhoudt

Masters Theses & Specialist Projects

Kentucky’s Upper Green River Basin has received significant attention due to the area’s high biodiversity and spectacular karst development. While carbonate bedrock is present throughout the watershed, it is more extensive and homogenous along the river between Greensburg and Munfordville than upstream from Greensburg where the geology is more heterogeneous. This research quantitatively evaluated how lithological differences between the two catchment areas impact hydrochemistry and inorganic carbon cycling. This first required correcting catchment boundaries on previous US Geological Survey Hydrologic Unit Maps to account for areas where the boundaries cross sinkhole plains. Basin boundaries using existing Kentucky Division of Water …

Addressing Water Resource Issues In Barbados Through An Isotopic And Atmospheric Characterization Of Precipitation Variability, Veronica Hall

Masters Theses & Specialist Projects

Numerous studies have analyzed isotopic variation of meteoric and dripwater in karst environments for paleoclimate reconstructions or aquifer recharge capacity. What is poorly understood is how the isotopic signal of δ¹⁸O and δ²H is transferred through the hydrologic cycle based upon storm type, frequency, intensity, and teleconnection activity in the tropical karst areas. At Harrison’s Cave, Barbados, a Hobo Onset event data logger was attached to a tipping bucket rain gauge to count the tips and record the total rainfall every 10 minutes. In the cave a Hobo data logger was used to record relative humidity …

Investigating Telogenetic Karst Aquifer Processes And Evolution In South-Central Kentucky, U.S., Using High-Resolution Storm Hydrology And Geochemistry Monitoring, Nicholas Lawhon

Masters Theses & Specialist Projects

Recent studies have investigated the hydrological and geochemical characteristics of karst aquifers in different settings; however, telogenetic karst aquifer processes remain poorly understood. In south-central Kentucky, the iconic Lost River Cave and Valley represents a large, complex telogenetic karst drainage basin with a series of discharge points along a collapsed section of the cave. Two Campbell Scientific® CR1000 automated dataloggers were installed at Blue Hole Four, a primary discharge point of the Lost River Karst Aquifer (LRKA). These dataloggers recorded spring discharge, water temperature, specific conductance (SpC), and pH at ten-minute intervals from January to November, 2013. During the year, …

Sources Of Co2 Controlling The Carbonate Chemistry Of The Logsdon River, Mammoth Cave, Kentucky, Bruce Elliott Hatcher

Masters Theses & Specialist Projects

Logsdon River is a major, base-level stream within the Turnhole Bend Drainage basin of the Mammoth Cave System. The Logsdon River system has provided a unique opportunity to examine the geochemical evolution of a stream flowing through a major karst conduit that can be traversed for 10 km. This study examines CO₂ inputs at the upstream portion of the river, which provide major control for the river’s hydrochemistry. Samples were collected from the upstream portion of Logsdon River at what is referred to as the S-188 sump and also nearby at Crowbar Dome over the course of 44 weeks …

The Use Of The Ostracode Cyprideis Americana (Sharpe) As A Proxy For Salinity In Bahamian Lake Systems, Rachel E. Bowles

Masters Theses & Specialist Projects

Ostracodes, bi-valved crustaceans, are potentially excellent proxies for salinity.They are abundant, react to changes in salinity, and secrete low-magnesium calcite shells that preserve information about their host water chemistry. Changes in valve trace element concentration, stable isotope composition, and sieve pore shape values have been linked to changes in salinity. This study analyzed the response of the euryhaline ostracode, Cyprideis americana, to salinity in six lakes from two Bahamian islands across two seasons. The purpose of this work was to determine which compositional and morphological variables in C. americana are the most useful for paleosalinity reconstructions.Ostracode and water samples were …

Late Holocene Paleoenvironmental Reconstruction In Barbados, Gilman Reno Ouellette

Masters Theses & Specialist Projects

Barbados is the easternmost island in the Caribbean region, and is uniquely situated between the Atlantic Ocean and Caribbean Sea. Being an isolated island with a karstified aquifer providing the majority of the nation’s water resources, Barbados has found itself in water scarce situations in recent years. In order to better understand natural shifts in groundwater recharge (which is determined by shifts in precipitation), longer records of precipitation are needed than are available from modern measurements. This study presents a paleoclimate reconstruction for the late Holocene on Barbados using stable and radiogenic isotope ratios in speleothem lamina as proxies. In …

Multiple Storm Event Impacts On Epikarst Storage And Transport Of Organic Soil Amendments In South-Central Kentucky, Sean M. Vanderhoff

Masters Theses & Specialist Projects

The groundwater in agricultural karst areas is susceptible to contamination from organic soil amendments and pesticides. During major storm events during 2011, dye traces were initiated using sulphorhodamine-B, fluorescein and eosine in a groundwater recharge area where manure was applied to the ground. Fecal coliform samples were collected from significant storm events from January-September 2011. Water samples and geochemical data were collected every four hours before, during, and between the storm events from a waterfall in Crumps cave flowing from the known recharge area to track the transport and residence time of the epikarst water and organic soil amendments during …

Determining The Viability Of A Hybrid Experiential And Distance Learning Educational Model For Water Treatment Plant Operators In Kentucky, Jana R. Fattic

Masters Theses & Specialist Projects

Drinking water and wastewater industries are facing a nationwide workforce shortfall of qualified treatment plant operators due to factors including the en masse retirement of baby boomers and the tightening of regulatory requirements regarding the hands-on experience required prior to licensure. Rural areas are hardest hit due to the lack of educational and experiential opportunities available to them within a reasonable proximity. Using a variety of demographic and industry data, a geographic analysis of Kentucky was conducted to assess the viability of the traditional classroom delivery model versus a hybrid experiential and distance learning educational model (HEDLEM). Although this analysis …

Spatio-Temporal Analysis Of Observed Soil Moisture From Nebraska, Ashley Littell

Masters Theses & Specialist Projects

Soil moisture is a measure of the water content in a soil that is dependent upon precipitation, evapotranspiration, runoff, drainage, and irrigation. Nebraska is one of the few states that measures soil moisture in an extensive network that records weather variables on a daily basis. Daily soil moisture observations are collected from depths of 10, 25, 50, and 100 centimeters and analyzed in this research. Data from these stations are evaluated on the spatial and temporal scales using spatial interpolations, time-series analysis, and cross-correlations to better understand the variations of soil moisture in the Northern Great Plains. Spatial interpolation grids …

Storm Response And Water Balance Of Temperate Rainforest Karst Watersheds: Tongass National Forest, Alaska, Johanna Kovarik

Masters Theses & Specialist Projects

The Tongass National Forest in southeast Alaska contains 2,176 square kilometers of karst. As part of the evolving Tongass Land Management Plan, research into the function of karst systems is crucial in understanding how forest management affects not only karst areas but also surrounding ecosystems. Dye trace and water balance results in two watersheds on the north end of Prince of Wales Island demonstrate the difficulty in containing the effects of management, as water can enter karst catchments from unknown sources at different flow regimes. A dye trace was conducted in Windgate and Canyon Block watersheds. Two sinking streams were …

An Analysis Of Key Aspects Of Warm And Cool Season Flash Flooding In The Southern Appalachians, William Baldwin

Masters Theses & Specialist Projects

Flash flooding kills more people in the United States than any other severe weather phenomenon. One of the most vulnerable areas for flooding is the southern Appalachians. These mountains lie in a geographical location that places them near the Atlantic Ocean and the Gulf of Mexico, two major moisture source regions. This ample supply of moisture, mid-latitude circulation patterns, and orographic lifting leads to annual precipitation totals in the southern Appalachians that are comparable to locations along the Gulf coast. The present study investigates eight non-tropical flash flood events. Four of the events occurred in the cool season and four …

Agricultural Contaminant Source And Transport In A Karst Groundwater Basin, Patricia Kambesis

Masters Theses & Specialist Projects

Agricultural land use in areas that are located in karst groundwater basins negatively impact groundwater quality because karst terrains provide multiple, direct hydrologic connections from the surface into karst aquifers. The connections and rapid velocities associated with surface and subsurface flow in karst aquifers allow for contaminants to move quickly into and through a groundwater basin. When groundwater returns to the surface via a spring or springs, any contaminants within the water become part of surface streams and rivers. These in turn, impact water quality in areas located downstream of the spring or springs. The purpose of this study was …