Physical Sciences and Mathematics Commons^™

Per- And Polyfluoroalkyl Substances (Pfas) In Treated Sewage Sludge From Michigan Wastewater Treatment Plants, Garrett Wesley Link

Masters Theses

Concentrations, compositions, and variability of Per- and Polyfluoroalkyl Substances (PFAS) in sewage sludge are characterized using an extensive dataset of 350 samples from 190 wastewater treatment plants (WWTPs) across Michigan. All samples are comprised of final treated sewage sludge generated at the end of the wastewater treatment process. Concentrations of Σ₂₄ PFAS are log normally distributed with a range of 1 to 3200 ng/g dry wt. and of average 108 ± 277 ng/g dry wt. Compounds with carboxyl and sulfonic functional groups comprised 29% and 71% of Σ₂₄ PFAS concentrations, respectively, on average. Primary sample variability is associated …

Per- And Polyfluoroalkyl Substances (Pfas) In Treated Sewage Sludge From Michigan Wastewater Treatment Plants, Garrett Wesley Link

Masters Theses

Concentrations, compositions, and variability of Per- and Polyfluoroalkyl Substances (PFAS) in sewage sludge are characterized using an extensive dataset of 350 samples from 190 wastewater treatment plants (WWTPs) across Michigan. All samples are comprised of final treated sewage sludge generated at the end of the wastewater treatment process. Concentrations of Σ₂₄ PFAS are log normally distributed with a range of 1 to 3200 ng/g dry wt. and of average 108 ± 277 ng/g dry wt. Compounds with carboxyl and sulfonic functional groups comprised 29% and 71% of Σ24 PFAS concentrations, respectively, on average. Primary sample variability is associated with …

Factors Affecting Groundwater Nitrate Concentration In Madinah Area, Saudi Arabia, Majed M. Almutairi

Masters Theses

High levels of nitrate in groundwater are a serious problem in Madinah Area, Saudi Arabia. Identifying factors affecting groundwater nitrate contamination is important for managing groundwater quality. This study examined factors that have significant impacts on the high level of groundwater nitrate in Madinah Area. Factors examined included well-depth and land cover. Relationships between variables were explored using three statistical approaches: the Kruskal-Wallis test and two types of regression (ordinary least squares [OLS] and geographically weighted regression [GWR]).

Nitrate concentration data show that 73% of obtained groundwater samples exceeded the United States Environmental Protection Agency (EPA) maximum contaminant level (MCL) …

Quantifying Surface Water Capture By Municipal Pumping Wells In An Urban Watershed Impacted By Road Salt, Austen York

Masters Theses

The Spring Valley sub-watershed is located within the Kalamazoo Township contains Spring Valley Lake, a man-made impoundment that ultimately discharges into the Kalamazoo River. Elevated chloride levels in pumped water from the Kalamazoo Station 14 municipal wellfield, located along the shoreline of Spring Valley Lake, has resulted in less than ideal corrosivity values for the water distribution system. Specific project objectives include: (1) identifying the cause of elevated chloride, (2) assessing surface water capture by the Station 14 wellfield, and (3) characterizing of water quality in Spring Valley Lake. Monitoring along a series of sampling transects spanning the sub-watershed, focused …

Understanding Potential Climate Change Impacts On Water Resources Within A Fractured Rock Watershed In Northern Togo, Mahawa-Essa Mabossani Akara

Dissertations

More than 72% of sub-Saharan Africa land surface is comprised of hard rock with fractured rock aquifers supplying water to an estimated 25% of the rural population. Given low porosity and storativity, fractured rock aquifers are particularly vulnerable to stresses such as projected population growth and climate variability. General circulation models of sub-Saharan Africa predict increases in temperature and in occurrences of extreme precipitation trends, such as flooding and drought. Adaptation strategies that promote optimal uses of water resources have emerged, although, most focus exclusively on surface water resources. This project investigates the potential impact of climate change on surface …

Using Low-Flow Sampling Data To Estimate Hydraulic Conductivity In Aquifers, Joy Kiefer

Masters Theses

Hydrogeologists sample wells to test aquifer water quality and use slug tests to estimate aquifer permeability. Robbins et al. (2009) proposed a more efficient way to obtain the goals of the two tests—the use of low-flow sampling and the use of the resulting flow rate and drawdown data to estimate aquifer hydraulic conductivity (K). The Robbins et al. method calculates K by using the slope of the best fit line from the graph of flow rate vs. drawdown for all low-flow pumping data collected at a well. When the method was applied to low-flow data from four Kalamazoo, MI, it …

An Integrated Approach For The Assessment And Monitoring Of Land Deformation In The Riyadh City And Its Surroundings For Identifying The Controlling Factors, Abdulaziz Ibrahim Aljammaz

Dissertations

An integrated approach (remote sensing, field, geodesy, geology, and hydrogeology) was conducted to assess and monitor land deformation at Riyadh city and its surroundings. Two settings were investigated. The first, Jinadriyah area (1.5 km²), an urban area located east of Riyadh city, was selected to assess deformation associated with urbanization over desert lands. The second location was Al Kharj area (19,790 km²) to the south of Riyadh city, a reclaimed desert land that was selected to assess the deformation associated with agricultural groundwater extraction from fossil aquifers. My investigations revealed high subsidence rates (up to -30 …

Response Of Deep Aquifers To Climate Variability, Karem Fathy Abdelgaber Abdelmohsen

Dissertations

Our recent analysis of Temporal Gravity Recovery and Climate Experiment (GRACE) solutions over the largest aquifer system in Africa (the Nubian Sandstone Aquifer System: NSAS) revealed that while the response of deep aquifers to climatic variations remains a relatively slow process that takes thousands to tens of thousands of years, there is a much faster response in aquifers that are characterized by dense networks of faults, fractures and karst as is the case with the NSAS. This rapid groundwater flow, when it occurs, is detected as an increase in GRACE_TWS over areas downgradient and distant (hundreds of km) from …

Agricultural Irrigation Induced Evaporation In A Temperate Study Area: A Stable Isotope Approach, Lincoln Grevengoed

Masters Theses

In regions where groundwater is used for irrigation, significant water losses take place due to evaporation. Previous studies demonstrated the utility of stable oxygen and hydrogen isotopes in estimating evaporative water loss experienced during return flow back to an aquifer. Unlike arid regions where the other studies took place, this study examined the region around Kalamazoo, Michigan, the United States, which experiences a more temperate climate. Irrigation in the Kalamazoo area primarily uses center-pivot systems supplied by wells, unlike flood irrigation in previous study areas. Water samples were taken periodically from wells close to center-pivot irrigation systems. Water losses due …

Statistical Downscaling Techniques To Enhance The Spatial Resolution Of The Grace Satellite Data And To Fill Temporal Gaps, Hossein Sahour

Dissertations

The Gravity Recovery and Climate Experiment (GRACE) has been successfully used to monitor variations in terrestrial water storage (GRACE_TWS ) and groundwater storage (GRACE_GWS) across the globe, yet such applications are hindered on local scales by the limited spatial resolution of GRACE data. Using the Lower Peninsula of Michigan as a test site, I developed optimum procedures to downscale GRACE Release-06 monthly mascon solutions. A four-fold exercise is conducted. Cluster analysis is performed to identify the optimum number and distribution of clusters (areas) of contiguous pixels of similar geophysical signals (GRACE_TWS time series); three clusters are …

An Integrated Approach (Remote Sensing, Hydrogeology, Gis, And Statistical Modeling) To Identify The Distribution Of Shallow Groundwater Occurrences Over Southwest Saudi Arabia, Fahad Khudier Alshehri

Dissertations

Identifying shallow (near-surface) groundwater in arid and hyper-arid areas has significant societal benefits, yet it is a costly operation when traditional methods (geophysics and drilling) are applied over large domains. In this study, we developed and successfully applied methodologies that rely heavily on readily available temporal, visible and near-infrared, radar, and thermal remote sensing data sets and field data, as well as statistical approaches to map the distribution of shallow (1–5 m deep) groundwater occurrences in Al Qunfudah Province, Saudi Arabia and to identify the factors controlling their development. A four-fold approach was adopted: (1) constructing a digital database to …

Field And Numerical Evaluation Of Nitrogen Transport From Septic Systems In Surfical Aquifer Systems To Charlotte Harbor, Florida, Tanten T. Buszka

Masters Theses

Shallow water tables in coastal surficial aquifers limit effective treatment of septic effluent which can result in excess nutrient loading into nearby surface water bodies. Approximately 45,000 septic systems in Charlotte County, Florida transmit effluent into an under studied surficial aquifer and contribute to harmful algal blooms and outbreaks of E. coli. An undeveloped field site was characterized using standard hydrogeologic methods, including a one-year duration natural gradient tracer test, to obtain representative lithology of the sandy surficial aquifer and estimates of groundwater velocity, flow directions, effective porosity and dispersion. These data were used to support the development of a …

An Analysis Of Large Displacement Pneumatic Slug Tests For The Characterization Of Aquifer Parameters – Guidelines For An Alternative Field Procedure, Madison E. Wayt

Masters Theses

Variations in hydraulic conductivity (K) between larger scale aquifer tests and smaller scale slug tests, and within individual aquifer tests, have been linked to method bias and aquifer heterogeneity. The impacts of varying slug sizes on K, which represents K dependence on a smaller scale, is not as well understood. To examine the relationship between K and slug size, a series of slug tests with a range of initial displacements were performed in three intermediate to high K, unconfined aquifers encompassing homogeneous, mildly heterogeneous, and moderate to highly heterogeneous conditions. Slug test estimated K values at Asylum Lake are compared …

Assessing Land Deformation And Sea Encroachment In The Nile Delta, Egypt, Esayas Gebremichael

Research and Creative Activities Poster Day

Persistent scatterer interferometric analyses were conducted on a stack of 84 Envisat ASAR scenes spanning 7 years (2004 to 2010) over the entire Nile Delta of Egypt and surroundings to monitor the ongoing spatial and temporal land deformation, identify the factors controlling the deformation, and model the interplay between sea level rise and land subsidence to identify areas and populations threatened by sea encroachment by the end of the 21st century. Findings include: (1) general patterns of subsidence in the northern delta, near-steady (none) subsidence in the southern delta, separated by a previously mapped flexure zone undergoing uplift; (2) high …

An Lntegrated Approach (Remote Sensing, Hydrogeology, Geotechnical, And Geoinformatics) To Assess And Monitor Fossil Aquifers And Associated Land Deformation Over The Arabian Peninsula, Abdullah Ghurmullah Saeed Othman

Dissertations

Deformational features such as subsidence, sinkholes, fissures, settling and cracks in buildings and structures, and earthquakes are being reported from many of the world’s arid lands, in areas where fossil aquifers are being excessively exploited. Using the Lower Mega Aquifer System (LMAS) in Arabia as a test site, I applied an integrated approach (remote sensing, geodesy, GIS, geology, hydrogeology, and geotechnical) to identify nature, intensity, spatial distribution, and factors controlling the observed deformation in the central (Al-Qassim and Ha'il regions; area: 16×10⁴ km²) and the northern (Wadi As-Sirhan Basin; area: ~10.9×10⁴ km²) Arabia. A four -fold approach was adopted to …

Karst Sub-Basin Delineation Via Dye Trace Study Near Turnhole Bend, Mammoth Cave National Park, Jake Tholen

Honors Theses

Establishing watershed boundaries is a critical stage in understanding the local water cycle. Drainage basins are typically identified by topographic divides; water flows to successively lower locations along the most direct path available. The karst terrain in Mammoth Cave National Park, however, presents additional challenges in identifying the boundaries of these basins. Underground drainages in the form of caves or conduits often do not correspond with surface topography. These passages can redirect water far from the most immediate surface release.

A dye trace study is designed to identify flow paths from the surface to springs along the Green River. Three …

Modeling Channel Response To Dam Removal In Lansing, Michigan, Using Swat, Ryan Filbin

Masters Theses

The removal of dams has increased in recent decades in the United States, largely resulting from decaying infrastructure and greater efforts to restore rivers to a more natural, free-flowing state. Dam removal presents the opportunity for increased public safety, improved environmental prosperity, and improved economic prosperity in conjunction with riverfront revitalization projects. The City of Lansing, Michigan, contains two moderate-to high-risk dams along the Grand River that pose a significant risk to the surrounding area in the event of structural failure.

The Soil and Water Assessment Tool (SWAT) is applied to model the impacts of the Moores Park Dam and …

Extent Of Capillary Rise In Sands And Silts, Rachel Lynn Salim

Masters Theses

The values reported in literature for the height of capillary rise in fine sands, silts, and clays are contradictory. Most of the values were based on mathematical models, which used estimated rather than measured input data. This work measured capillary rise values in laboratory experiments in fine-grained sands and silts.

Two uniform sands with grains 0.35--0.7 mm in diameter and 0.3-0.6 mm in diameter, silt with an average grain size below 40 microns, and 0.35--0.7 mm sand coated with a water-repellant spray were carefully packed into two-inch diameter glass columns. These columns were placed into clear plastic tanks with water …

Characterizing Groundwater Recharge And Streamflow Using Stable Isotopes Of Oxygen And Hydrogen, Chanse M. Ford

Masters Theses

Potential changes to climate and precipitation patterns from anthropogenic influences like global climate change could have an impact on Michigan’s groundwater resources. Indirectly this could have an effect on Michigan’s surface waters as well, since groundwater and surface waters are intimately linked to form one system.

This investigation utilized stable isotopes of oxygen and hydrogen found in precipitation, groundwater and surface waters to better understand the contribution of different types of precipitation to recharge of a shallow aquifer in Manistee National Forest, MI. The study also examines the contribution of this shallow groundwater to streamflow in the nearby White River. …

Lnfluence Of Persulfate On Solidification/Stabilization Characteristics Of Iss Treatment, Jeffrey M. Hudson

Masters Theses

Two environmental remediation technologies that lend themselves well to being combined in a single application are In Situ Chemical Oxidation (ISCO) using activated persulfate (PS), and In Situ Stabilization (ISS). Persulfate can be activated by increasing the pH to 10.5 and/or increasing temperatures to 30ºC. Many common ISS amendments increase temperature to 30°C and/or pH to 10.5 when in contact with soil water. Laboratory experiments were conducted with various soils to determine the ability of eight ISS amendments to activate persulfate. All eight ISS amendments activated persulfate. This work also showed that the relative contribution of heat vs. alkaline activation …

Slug Tests In Unconfined Aquifers, Rozkar Izzaddin Ismael

Masters Theses

This research presents a hydraulic conductivity (K) analysis of unconfined aquifers using slug tests. Slug tests are used to determine in situ aquifer hydraulic conductivity more quickly and economically than by a pump test. This study examines how to best conduct a slug test using a physical slug. Different common slug test analysis methods are compared, including Bouwer and Rice (1976), Hvorslev (1951), Dagan (1978) and Kansas Geological Survey (KGS, 1994). Questions that motivated this study include: Which methods are better for performing and analyzing slug tests? Does the size of the physical slug affect the results? Do large initial …

Determining Discharge From The Fallasburg Dam And The Hydrology Of The Flat River Bypass Channel, Lowell, Michigan, Seth Kuiper

Masters Theses

The Fallasburg Dam on the Flat River is required to release 110 cfs to the Bypass Channel. Residents have often reported low flows in the river, especially during the summer. The hydrology of the Bypass Channel downstream from the dam was investigated to determine whether the required flow was being released. Discharge measured at multiple transects reveal a shifts from gaining to losing conditions during the year. Gaining conditions occur during the spring and after significant rain events; losing conditions occur in the summer during dry periods. Five discharge measurements in 2013 and three in 2014 reveal flows less than …

Comparing Slug Test Methods For Unconfined Aquifers, Hussain Jaber Alfaifi

Dissertations

Slug test methods are used to determine in situ aquifer hydraulic conductivity (K) more quickly and economically than a pump test can. This study compares slug test methods for unconfined aquifers, looking at how to conduct a test using a physical slug, and at different analysis methods including Bouwer and Rice (1976), Kansas Geological Survey (KGS 1994), Hvorslev (1951) and Dagan (1978). Questions that motivated this study include: How well does the Bouwer and Rice method work? What is the most effective way to conduct a slug test? Does using a large physical slug relative to the well diameter and …

Influence Of Road Salt Deicers On Anaerobic Respiration And Metal Speciation In Soils, Danielle Dupuis

Honors Theses

Road salt deicers, especially NaCl and CaCl₂, are used throughout the world on paved areas during the winter. Previous studies suggest that road salt deicers can alter the biogeochemistry of sediment located near roadways and influence the mobility of heavy metals. The goal of this study is to investigate the influence of CaCl₂ on wetland soil biogeochemistry, especially trace metal speciation. Sediment cores were collected in the fall from a freshwater wetland near an urban kettle lake (Asylum Lake, Kalamazoo, MI) and incubated for 100 days in deionized water (control), 5 g/L of CaCl₂, or …

Effects Of Road Salt On Asylum Lake Geochemistry, Davina A. Wyman

Masters Theses

Several studies indicate that seasonal applications of road deicers can lead to saline runoff entering surface water and groundwater, which can in turn change the chemistry, density, and physical mixing patterns of urban lakes. An investigation at Asylum Lake, an urban lake located near three major roadways, was conducted to determine the degree of road salt contamination in the lake, to determine if salt loading disrupts seasonal mixing patterns, and to determine the extent of redox stratification present due to eutrophic conditions. Samples were collected monthly from the deepest point in Asylum Lake over a 19-month period and analyzed for …

Integrated Approach For Hydrogeologic Investigations In Africa: Inferences From Space-Borne And Land-Based Gravity, Aeromagnetic, Gis, And Remote Sensing Data, Mohamed El Sayed Ahmed Ahmed

Dissertations

An integrated (space-borne and land-based gravity, aeromagnetic, GIS, and remote sensing) approach was developed, tested, and applied to investigate the following on regional scales (Africa) or local scales (El Qaa Plain, Sinai): (1) assess the capability of GRACE data (04/2002 to 08/2011) for monitoring elements of hydrologic systems on the sub-basin level (Task 1); (2) address the nature and the controlling factors (e.g., climatic and/or human pressure-related) affecting the inter-annual GRACE-derived Terrestrial Water Storage (TWS) trends over a large suite of hydrologic systems and domains in (Africa) (Task 2); and (3) identify the structural, geologic and hydrologic settings as well …

Geophysical And Remote Sensing Applications For A Better Understanding Of The Structural Controls On Groundwater Flow In The Lucerne Valley, California, Dale R. Dailey

Masters Theses

An integrated study was conducted in the Mojave Basin to investigate the potential role of faults and basement uplifts for groundwater flow in the Mojave Desert. Observations made include: 1) Very Low Frequency (VLF) measurements across mapped (using LIDAR and Geoeye-1 imagery) fault traces showed significant radio field dip angles indicative of presence of shallow sub-vertical, sheet-like conductors; many of the VLF tilt peaks coincided with changes in the magnetic profiles; 2) Vertical Electric Soundings indicate shallow basement west of, and parallel to, the Helendale Fault and deep saturated zones east of the fault/basement outcrop (F/B); and 3) isotopic analyses …

A Localized Investigation Of High Resolution Groundwater Flow Properties Of The Saginaw Aquifer Mason, Michigan, Amanda Hayden

Masters Theses

High resolution groundwater models can aid in better management of groundwater resources through more accurate characterization and quantification of aquifer systems. Detailed assessments of flow properties in the context of sedimentary facies can provide high quality data input for more accurate groundwater models.

The Pennsylvanian Grand River and Saginaw bedrock formations comprise the Saginaw Aquifer located in the Lansing, Michigan Tri-County region. The Saginaw Aquifer consists of a predominately shale and sandstone successions. These sandstone facies range up to 40 meters thick, and supply a significant amount water resources to the Lansing Tri-County area. Data used in this study was …

Integrating Depositional Facies And Stratigraphy In Characterizing Hydrothermal Dolomite Reservoirs: Trenton Group Of The Albion-Scipio Trend, Michigan, Marcel R. Robinson

Masters Theses

Reservoir characterization of carbonate rocks requires understanding the role of depositional and diagenetic parameters in reservoir distribution. This is especially true for the diagenetically-altered and structurally-influenced Trenton-Black River reservoirs of the Michigan Basin. Evaluating the depositional evolution and reservoir characteristics of component depositional facies through modeling and stratigraphic reconstruction would aid in exploration and characterization through providing a prediction tool for reservoir distribution, both within and outside of the Michigan Basin.

Results indicate that reservoir development is controlled by primary rock fabric related to depositional facies. Depositional and stratigraphic reconstructions show facies distribution trends occur consistently and therefore predictably away …

Low-Level Pharmaceuticals And Personal Care Products In The Waters Of Michigan, Lisa M. Anderson

Dissertations

The results of this research are the product of a two year study funded by the Michigan Department of Environmental Quality with monies from the Clean Michigan Initiative. Low-level (part per billion range) pharmaceuticals and personal care products (PPCPs) in the waters of Michigan were investigated. Five rivers in the State were sampled; including the Clinton, Grand, Kalamazoo, Muskegon, and Saginaw. Groundwater samples were obtained from two shallow municipal water wells also; one on the Grand River and one on the Kalamazoo River. The wells were sampled to determine if PPCPs in the river water were being drawn in by …