Physical Sciences and Mathematics Commons^™

Controls On Plastic Debris Capture In Urban Stormwater Drains Of London, Canada: A Study Within The Great Lakes Watershed, Nina Kozikowski

Electronic Thesis and Dissertation Repository

Land-based sources are the greatest contributors of plastic pollution in aquatic environments. Prior to this investigation, there were no available studies concerning the number and types of plastic debris items between 1 mm and 5 mm captured in urban stormwater drains. The present study examined macroplastic (>5 mm) and large microplastic (1-5 mm) debris that accumulated in LittaTrap^TM devices at six drain sites over four seasonal periods in London, Ontario, Canada. Macroplastics (MaPs) and microplastics (MPs) were found in all 36 samples, and the totals ranged from 5-158 MaPs and 18-359 MPs per trap. Out of the 118 …

Deformation And Evolution Of Achondrite Parent Bodies, Yaozhu Li

Electronic Thesis and Dissertation Repository

Minerals in planetary bodies record accumulated strain from deformation events such as hypervelocity impacts but potentially also parent body processes such as gravitational compaction. This work investigates olivine microstructural features that may distinguish between different impact levels versus parent body plastic deformation regimes. Achondritic meteorites from the ureilite parent body, the Moon, Mars as well as terrestrial basalt and mantle xenolith have been investigated using micro-XRD, EBSD, micro-XRF and other methods to study their parent body deformation history. A Matlab® method, unit segment length (USL), is herein developed to visualize the crystal boundary geometry and quantify the apparent subboundary density …

Terrestrial Craters As Analogues For Degraded Craters On Titan, Taylor M. Duncan

Electronic Thesis and Dissertation Repository

Besides Earth, Titan is the only planetary body in our Solar System to currently have flowing liquid on its surface. Previous works note that dendritic and rectangular stream networks are present on a global scale on Titan, but do not map networks in the vicinity of Titan’s impact craters: Selk and Sinlap. The objective of this work is to understand how stream networks form adjacent to Titan’s impact craters. This information will inform future missions to Titan (i.e., Dragonfly) about the fluvial morphology of streams near their landing site. I conduct an analogue study with the stream networks at three …

Towards Automated Mineral Identification In Martian Rocks From X-Ray Diffraction Patterns, Luke Tambakis

Electronic Thesis and Dissertation Repository

The CheMin (Chemistry and Mineralogy) instrument on the Curiosity rover has provided a rich set of X-ray diffraction (XRD) patterns from Martian rocks and regolith. These XRD patterns have allowed geologists to make exciting new discoveries about the mineralogy and the geological history of Mars. These discoveries pave the way for further Martian exploration and provide a deeper understanding of Martian geology. The Curiosity rover is very slow by design, travelling at about 4 cm/s. New, faster rovers are being developed to increase scientific throughput and exploration. XRD is valuable for future missions as it can produce new discov- eries …

Late Neoarchean To Middle Paleoproterozoic Geology Of Devon And Ellesmere Islands, Canadian Arctic, Joshua P. Laughton

Electronic Thesis and Dissertation Repository

The northernmost exposure of the Laurentian shield in Canada outcrops on Devon and Ellesmere islands within the Canadian Arctic Archipelago. Due to the remote location, the basement rocks of these islands have received little attention. From this study, zircon crystallization ages demonstrate that Devon Island is underlain by a late Neoarchean terrane comprising orthogneisses emplaced at ca. 2.55–2.51 Ga and an interleaved metasedimentary sequence deposited at ca. ≥2.47 Ga. On northern Devon Island, younger metasedimentary sequence(s) were deposited at ca. 2.2–1.9 Ga and intruded by ca. 2.01–1.95 Ga granitoids. Devon and Ellesmere islands experienced widespread metamorphic activity associated with the …

The Fate Of Carbonate Rocks During Hypervelocity Impacts: Case Studies From Three Impact Structures On Earth, Nicolas D. Garroni

Electronic Thesis and Dissertation Repository

Approximately 28% of all hypervelocity impact structures discovered on Earth exist in a carbonate-dominated target sequence. Despite decades of research, how carbonate rocks and minerals react to shock metamorphism is still poorly understood. In this contribution, three impact structures on Earth were studied to determine the effects of shock metamorphism on carbonate minerals: Chicxulub, Crooked Creek and Jebel Waqf as Suwwan.

At Chicxulub, carbonates from the impact-melt bearing breccia of drill core, M0077A were characterized petrographically and geochemically. Calcite was the only carbonate mineral present and is abundant throughout the impact breccia in five distinct varieties: limestone clasts …

The Origin And Evolution Of Impact Crater Lakes: A Case Study Of The Ries Impact Structure, Germany, Matthew J. O. Svensson

Electronic Thesis and Dissertation Repository

Impact events are known to generate hydrothermal systems, which can subsequently vent into an overlying crater lake and potentially create ideal conditions for some microbial life-forms. Thus, early post-impact sedimentary deposits would be excellent targets for Mars sample return, and as such, the robust characterization of such deposits on Earth is critical. In this thesis, we establish an improved understanding of how the Ries crater lake formed, and how an active impact-generated hydrothermal system influenced its early evolution. The ~14.8 Ma Ries impact structure hosts the majority of its paleolake deposits within the structure's central basin with some deposits situated …

Characterization Of Some Natural Copper Samples From The Keweenaw Peninsula Of Lake Superior Using Electron Microscopy And X-Ray Tomography Techniques, Emilie Mk Landry

Electronic Thesis and Dissertation Repository

Copper corrosion is of interest to Canada’s Nuclear Waste Management Organization as it relates to their multi-barrier system for nuclear waste disposal in deep geologic repositories. Spent fuel canisters coated with a thin copper layer must persist for up to one million years. Natural copper from the Keweenaw Peninsula in Michigan, USA, has persisted for over 1 billion years and is here characterized to understand copper corrosion over geological time. Copper samples representing three rock types were characterized using optical microscopy, scanning electron microscopy techniques (energy dispersive X-ray spectroscopy and electron backscatter diffraction), and micro-computed X-ray tomography (microCT) to establish …

Complex Unicellular Microfossils From The 1.9 Ga Gunflint Chert, Canada, Ana L. González Flores

Electronic Thesis and Dissertation Repository

The presence of eukaryotic life during the early Paleoproterozoic has been a matter of debate because well-preserved fossils older than 1.8 Ga rarely exhibit eukaryotic cellular microstructures. In this study, microfossils from the 1.9 Ga Gunflint Chert were studied using the extended-focal-depth imaging technique, combined with scanning electron microscopy, resulting in recognition of three types of large (10–35 μm diameter) complex unicellular bodies (CUBs) and one type of “multicellular body” (< 50 μm diameter). The CUBs show the following eukaryotic cyst-like structures: (1) radially arranged internal strands similar to those in some acritarchs and dinoflagellates; (2) regularly spaced long tubular processes, stubby pustules, and/or robust podia on the cell surface; (3) reticulate cell-wall sculpturing such as pits, ridges, and scale-like ornaments; and (4) internal bodies that may represent membrane-bounded organelles. These morphological features provide strong evidence for the presence of protists in the late Paleoproterozoic.

Among the three types of CUBs from the Gunflint microbiota, a new species, Germinosphaera gunflinta sp. nov., was recognized. This species has the diagnostic characteristics of Germinosphaera, such …

White Micas As A Tool For Tracking Pegmatite Evolution And Its Use In Li Exploration. A Case Study Of Wekusko Lake, Manitoba, Canada., David N. Benn

Electronic Thesis and Dissertation Repository

The Wekusko Lake pegmatite field is part of the Green Bay Group of pegmatites located near Snow Lake, Manitoba, Canada. Within this field, there are at least 13 spodumene-bearing pegmatites of varying degrees of mineralization. The abundance of white micas and the chemical affinity to incorporate Li and other trace elements into its crystalline structure makes white micas an ideal indicator mineral. The evolution of a melt can be tracked using trace elements in white mica. The K/Rb ratio vs Cs is used to determine a link between increasing evolution and increased Li contents of both the white mica and …

Deformation Conditions Of Quartz-Rich Mylonites Of The Grenville Front Tectonic Zone And Application To The Crustal Strength, Xueke Chang

Electronic Thesis and Dissertation Repository

This thesis analyzes a suite of mylonites from the Grenville Front shear zone exposed southeast of Sudbury, Ontario. Lattice preferred orientations, titanium-in-quartz thermometer, and dynamically recrystallized grain size piezometer measurements were applied to obtain the deformation mechanisms, deformation temperatures (T), and differential stresses (σ), respectively. Results show that these mylonites were formed in the shear zone during the terminal stage of the Grenville Orogeny. The dominant deformation mechanism is by regime 2 dislocation creep. The deformation temperature is between 425-567 °C, and the differential stress is between 56-133 MPa. These results are discussed in the context of wet quartzite flow …

Modeling Of Fluid Injection-Related Processes In Hydrocarbon Reservoirs In Alberta, Canada, Negar Nazari

Electronic Thesis and Dissertation Repository

In the last decade, with the development of horizontal drilling and multistage hydraulic fracturing technology, extraction of unconventional resources has significantly increased in western Canada. These industrial activities have been associated with the rise in the seismicity rate. This thesis aimed to improve the quality of the available geomechanical models of the injection-induced seismicity in the Western Canada Sedimentary Basin, by incorporating detailed geoscience characterization for two unconventional reservoirs of the Duvernay Formation in the Fox Creek area and the Cardium Formation in West Pembina. Hydraulic fracturing has induced seismicity in the first area, but no induced seismicity has been …

Stable Carbon And Oxygen Isotopes Of Early Silurian Pentameride Brachiopods From Québec, Ontario, And Nunavut, And Paleoenvironmental Implications, Jordan N. Siewnarine

Electronic Thesis and Dissertation Repository

Analysis of low-Mg calcite brachiopod shells for δ¹⁸O and δ¹³C signatures provide quantitative independent geochemical data for paleoenvironmental interpretations. We analyzed 59 brachiopod shells from lower Silurian carbonate rocks of Anticosti Island, the Hudson Bay Lowlands and Niagara regions for spaciotemporal isotopic trends for the early Silurian. Screening tests using scanning electron microscopy, cathodoluminescence and trace element analysis demonstrate exceptional preservation, suggesting retention of primary isotopic values.

δ¹³C and δ¹⁸O values of shells range from 0.2‰ to 2.9‰ and -6.9‰ to -4.3‰ (VPDB), respectively. Temporally, increases in δ¹³C and δ …

Effects Of Glutamine Deamidation On The Oxygen Isotope Compositions Of Bone Collagen, Curtis W. Russell

Electronic Thesis and Dissertation Repository

The oxygen (O) isotope composition of mammalian collagen has the potential to provide information about the drinking water and hence geographic location and climate during the life of modern and ancient animals. An accurate and reproducible O-isotope analysis of collagen, however, has been elusive. Here, the O-isotope compositions of collagen from cortical bone of four megaherbivores were compared using two extraction procedures: the traditional Longin (HCl) method and the less commonly employed EDTA method. Preservation of O-isotope compositions was evaluated by measuring collagen peptide-chain masses, specifically the glutamine deamidation level (GDL). The EDTA method yielded collagen with a GDL of …

Lunar Regolith Simulant Behaviours Affected By Shock Metamorphism And Mineralogy, Xiao Chen Zhang

Electronic Thesis and Dissertation Repository

There are still many gaps in improving the fidelity of lunar regolith simulants to simulate more properties. This study compares some fundamental physical and mineralogical properties of three types of lunar highland regolith simulants: LHS-1, a commercial product with high mineralogical fidelity; UWO-1G, an original simulant that is the main component of LHS-1; and UWO-1S, another original product that is attempted to produce shocked grains in lunar simulants from pulverizing and mixing impact rocks sourced from the Mistastin Crater.

Preliminary results indicated that even though all simulants are composed of mostly plagioclase minerals and have similar particle size distribution patterns, …

In Situ Study Of Geological Fluid Inclusions Using 23na Nuclear Magnetic Resonance Spectroscopy, Stephen Pilar

Electronic Thesis and Dissertation Repository

²³Na Magic Angle Spinning Solid State Nuclear Magnetic Resonance (MAS SS NMR) spectroscopy has been used to study natural geological samples of halite, fluorite, and quartz to evaluate the efficacy of NMR spectroscopy for in situ fluid inclusion analysis. NaCl calibration standards yielded a strong linear correlation (R²=0.9919) for salinity, albeit only over a ~1 ppm breadth of chemical shift. Fluid inclusions were successfully identified in all three types of minerals studied using MAS NMR. Chemical analysis with Inductively Coupled Plasma -- Mass Spectrometry (ICP-MS) was employed to quantify elemental contaminants in halite samples. Powder X-Ray Diffraction …

Reconstructing Impact And Fluid Histories On Earth And Mars By Nanoscale Measurements, Gabriel A. Arcuri

Electronic Thesis and Dissertation Repository

The U-Pb geochronology minerals zircon (ZrSiO₄) and baddeleyite (ZrO₂) occur as microscopic grains in many planetary rocks, are among the oldest known solids, and preserve robust records of chemical, isotopic and orientation microstructures useful for reconstructing the evolution of early planetary lithospheres and hydrosphere. Less well known are the nanoscale characteristics of these long-lived minerals, and their connections, if any, to processes that operated at larger length scales in the crust important to habitability such as global planetary bombardment and fluid flow. The aim of this thesis was therefore to develop and apply nanoscale analytical techniques, …

Allostratigraphy Of The Lower Colorado Group (Cretaceous) In South-West Alberta, Slavena Galic

Electronic Thesis and Dissertation Repository

Clastic, upper Albian-lower Cenomanian strata were deposited in a low-accommodation backbulge depozone of the Western Canada Foreland Basin in SW Alberta. These strata are lithologically very heterogeneous and encompass a spectrum of depositional environments along an alluvial to offshore transect. These rocks are assigned, in subsurface, to the Lower Colorado Group, and in outcrop to the upper Blairmore Group. Lithological heterogeneity, as a result of rapid lateral facies changes, resulted in diverse nomenclature that obscured genetic relationships between time-equivalent strata. The present study integrates wireline log, core, and outcrop data to establish a high-resolution allostratigraphic framework which allowed recognition of …

Combined Geochemical, Mineralogical, And Structural Investigation Of Auriferous Quartz Veins At The Vertigo Target, White Gold District, West-Central Yukon Territory, Canada, James C M Alexander

Electronic Thesis and Dissertation Repository

The Vertigo target on the southwestern JP Ross property is a gold-mineralized showing ~70 km south of Dawson City in the White Gold district, west-central Yukon Territory, Canada. Favourable gold-mineralized zones occur with pathfinder elements As-Ag-Te-Pb-Bi. This study uses digital borehole logging, petrography, electron probe microanalysis, and micro-x-ray fluorescence to evaluate the spatial, geochemical, and mineralogical distribution of Au mineralization at the Vertigo target. Petrographic and structural interpretations are contextualized with synchrotron radiation x-ray diffraction on 120 drill sample pulps. The clustering of diffraction patterns has revealed characteristic signatures of Au-mineralization with structural geometries coincident with the mineralogical clusters. The …

The Physical Properties Of Volcanic And Impact Melt, Gavin Douglas Tolometti

Electronic Thesis and Dissertation Repository

The emplacement mechanisms of lunar impact melt flows, that form from hypervelocity impact events, have been a subject of debate in the lunar science community, because of their unique physical properties that separate them from other geologic features. Understanding how lunar impact melt flows were emplaced on the surface of the Moon will not only grant us new information about the flow dynamics of impact melt but provide insight into the production and distribution of impact melt and how it built and modified the surfaces of planetary surfaces.

Lunar impact melt flows exhibit surface roughness textures and morphologies that are …

Investigation Of Shocked Basalts From Vargeão Dome And Vista Alegre: Implications For The Search For Life On Mars, Nikol Posnov

Electronic Thesis and Dissertation Repository

Impact craters represent excellent astrobiological targets for planetary exploration missions to Mars. The impact of an asteroid or comet into a crystalline, H₂O-bearing target may result in development of a hydrothermal system and increase the habitability of the substrate for the colonization of endolithic microorganisms. Given that Mars’ surface is covered by cratered basaltic rock, this study investigated target rocks and impact breccias from Vargeão Dome and Vista Alegre impact structures that formed in basalt in the Paraná Basin of Brazil.

Utilizing petrography and micro-X-ray diffraction (μXRD), the degree of shock metamorphism in plagioclase was quantitively determined. Measuring …

Organic Geochemistry, Organic Petrography And Basin Modelling Of The Upper Cretaceous Second White Specks And Upper Belle Fourche Alloformations In The Western Canada Foreland Basin, Mailyng Angelica Aviles

Electronic Thesis and Dissertation Repository

The Second White Specks is an unconventional shale play in the Western Canada Foreland Basin, endowed with over 450 billion barrels of light oil in place. Inconsistent production performance, however, has hindered its economic viability as a resource play. One potential explanation for erratic production behavior, on local and regional scales, is heterogeneous distribution of retained oil charge in the source rock. This study focuses on the analysis of geochemical properties and thermal history of the organic matter to assess lateral variability in generated hydrocarbon in the Second White Specks.

The methodology comprised characterization of the organic matter integrating organic …

An Assessment Of The Spatial And Temporal Distribution Of Microplastics In Surface And Subsurface Sediment Of Lake Huron, North America, Sara L. Belontz

Electronic Thesis and Dissertation Repository

The awareness of and the data on the prevalence of microplastic (plastic particles <5mm) pollution in freshwater environments is rapidly increasing, as low-degrading polymers are being detected in various environmental matrices of the Laurentian Great Lakes. However, the accumulation, distribution and deposition of microplastics in offshore depositional environments of the Great Lakes, and particularly Lake Huron, is relatively unknown. In this study, benthic sediment from various Lake Huron waterbodies (main basin, Georgian Bay, the North Channel, and Saginaw Bay) was quantified for microplastic particles (fibres, fragments, films, and beads). The North Channel contained the greatest microplastic abundances, averaging 47,398 particles per kg^-1 dry weight sediment (p kg^-1 dw), followed by Georgian Bay (21,390 p kg^-1 dw), the main basin (15,910 p kg^-1 dw) and Saginaw Bay (1,592 p kg^-1 dw). The results suggest that microplastic abundances in offshore settings are positively correlated with increasing water depth (p=0.004) and are controlled by lake bottom geomorphology. Hydrodynamic processes are a prevailing force driving microplastic dispersion and deposition into the offshore, in contrast to source-based drivers closer to the shoreline. Sediment cores were examined from …

Geological, Mineralogical And Geochemical Process Controls On Ni Tenor Variations In The Metasedimentary-Hosted Thompson 1d Orebody At Vale’S Thompson Mine (T3), Northern Manitoba, Canada, Povilas G. Grigutis

Electronic Thesis and Dissertation Repository

The Proterozoic Thompson Nickel Belt (TNB) contains rift-related mafic-ultramafic igneous rocks, in a collisional belt at the NW margin of the Archean Superior province in Northern Manitoba, Canada. The TNB hosts world class Ni-Cu-(PGE) mineralization, that has undergone polyphase deformation (D₁ – D₄) and upper amphibolite to lower granulite facies metamorphism, up to ~750ºC and 7.5 kbars (Lightfoot et al., 2017). Komatiitic magmas (1880 ± 5 Ma; Hulbert et al., 2005) fertile in Ni & PGE elements intruded Ospwagan Group metasedimentary sequences and through sulfur assimilation and segregation produced primary magmatic sulfides (Lesher and Burnham, 2001).

The …

An Investigation On Flow Field Partitioning Related To The Rheological Heterogeneities And Its Application To Geological Examples, Ankit Bhandari

Electronic Thesis and Dissertation Repository

Earth’s lithosphere is heterogeneous and composed of rheologically distinct elements at various scales of observations. This causes the flow of rocks to vary with space and time, which may influence the formation of various kinds of geological rock records. This thesis provides quantitative solutions to some first-order problems in structural geology regarding this heterogeneous flow variation and thereby the development of various geological rock records at different scales of observations.

Pressure in a rheologically heterogeneous element may deviate from its ambient value and if significant, may influence the metamorphic assemblages. This might cause problems in the routine use of geothermobarometry-based …

Plastic Debris In The Laurentian Great Lakes System, North America: Analysis Of Types, Abundances, And Sources, Ian A. Arturo

Electronic Thesis and Dissertation Repository

Understanding plastic pollution in the Laurentian Great Lakes system requires investigation of all plastic debris sizes and categories. Visible polymeric debris (VPD) mainly characterize shorelines, and microplastics (MPs;mm) are found in benthic and beach sediment. Field sampling of VPD from all five Great Lakes, visual and chemical identification of VPD types, and implementation of a matrix scoring technique (MST) indicate that plastic industries, urban areas, and shoreline recreation are major sources of VPD. Sampling for MPs in the St. Clair system, followed by preliminary density separation, and microscopy, suggest that wastewater treatment plants are a major source. This work is …

Hydrothermal Alteration Footprint Of The Monument Bay Project, Manitoba, Canada, Juliana Casali

Electronic Thesis and Dissertation Repository

The Monument Bay (MB) project is a greenstone hosted gold deposit, located in NE Manitoba. Previous studies show significant gold grades in the area. This research aims to characterize and delineate the mineralogical and geochemical characteristics of the hydrothermal footprint and mineralization of MB. Combined synchrotron X-ray fluorescence, synchrotron X-ray diffraction, petrography, and electron microprobe techniques were used to support this study. Results indicate sericite and carbonate are the main hydrothermal alteration minerals with homogeneity in their mineralogical, textural, and geochemical characteristics across the deposit. Also, a strong relationship between Au, sericite alteration, and arsenopyrite grains is observed associating the …

Geometallurgy And Gold Mineralization Of The Monument Bay Project, Stull Lake Greenstone Belt, Manitoba, Canada, Chunyi Hao

Electronic Thesis and Dissertation Repository

The Monument Bay Project is located in the Archean Stull Lake Greenstone Belt, in Northern Manitoba, Canada. This thesis focuses on the geometallurgy and gold mineralization of the Monument Bay Deposit in order to better understand the multiple gold mineralizing events and provide a pathfinder to gold mineralization. Traditional microscopy is used in combination with geochemical and mineralogical analytical techniques (Electron Probe Microanalysis (EPMA) and Energy-dispersive X-ray Spectroscopy (EDS)/(WDS) element map) and synchrotron geochemical techniques (synchrotron X-ray Diffraction (SR-XRD), synchrotron micro X-ray fluorescence (SR-µXRF) mapping, X-ray Absorption Near-edge Structure (XANES) Spectroscopy). Metallic gold (Au⁰) exists as free gold …

Impact Of Interlayer Cation Composition And Strongly Bound Water On Smectite ẟ²H, As Determined By A Modified Tcea Method, Nadine J. Kanik

Electronic Thesis and Dissertation Repository

Interlayer cation composition and cation hydration enthalpy can potentially affect the excess hydrogen-yield and δ²H of smectitic clays. Complexities arise from condensed atmospheric water adsorbed on the clay, as it constitutes a potential additional source of hydrogen when attempting to measure the δ²H of structural OH groups. To approach this problem, the δ²H of different cation-saturated, dried forms of six Clay Minerals Society Source Clay smectites were measured. A modified sample drying and on-line High-Temperature-Conversion-Elemental-Analysis (TCEA) Continuous-Flow-Isotope-Ratio-Mass-Spectrometry protocol, facilitated isotopic measurements. A stronger interlayer cation hydration enthalpy (Ca²⁺>Na⁺>K⁺), …

Clay Mineral Characterization And Production In Impact Settings: A Case Study On The Chicxulub Impact Structure, Mexico, Sarah L. Simpson

Electronic Thesis and Dissertation Repository

Impact cratering is the most ubiquitous geologic process shaping the surface of solid bodies in our Solar System. Despite their deleterious effects, impacts have the potential to initiate transient hydrothermal systems, making them attractive targets in the search for water and extraterrestrial life. The relatively low temperature nature of these environments and poor preservation state of craters on Earth leads to difficulties in determining the provenance of many alteration phases, particularly clay minerals. This becomes especially problematic on other clay-rich planetary bodies (e.g., Mars) where limited geologic information can lead to ambiguous and/or inaccurate interpretations. This thesis presents a case …