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Full-Text Articles in Physical Sciences and Mathematics
Hydraulic And Electrokinetic Delivery Of Remediants For In-Situ Remediation, Ahmed I. A. Chowdhury
Hydraulic And Electrokinetic Delivery Of Remediants For In-Situ Remediation, Ahmed I. A. Chowdhury
Electronic Thesis and Dissertation Repository
Nano-scale zero valent iron (nZVI) has shown promising mobility and in-situ reactivity with chlorinated volatile organic compounds when injected into saturated porous media. The current study evaluated nZVI mobility and subsequent reactivity with in-situ contaminants in a variably saturated porous media. The nZVI particles, synthesized onsite at subzero temperatures, demonstrated complete trichloroethene (TCE) degradation within the target area. Furthermore, a three dimensional finite difference model (CompSim) was utilized to investigate nZVI mobility in variably saturated zones. Model predicted well head data were in very good agreement with field observations. Simulation results showed that the injected slurry migrated radially outward from …
Improving The Treatment Of Non-Aqueous Phase Tce In Low Permeability Zones With Permanganate, Chanat Chokejaroenrat, Steve D. Comfort, Chainarong Sakulthaew, Bruce I. Dvoark
Improving The Treatment Of Non-Aqueous Phase Tce In Low Permeability Zones With Permanganate, Chanat Chokejaroenrat, Steve D. Comfort, Chainarong Sakulthaew, Bruce I. Dvoark
Faculty Publications from The Water Center
Treating dense non-aqueous phase liquids (DNAPLs) embedded in low permeability zones (LPZs) is aparticularly challenging issue for injection-based remedial treatments. Our objective was to improve thesweeping efficiency of permanganate (MnO4−) into LPZs to treat high concentrations of TCE. This wasaccomplished by conducting transport experiments that quantified the penetration of various perman-ganate flooding solutions into a LPZ that was spiked with non-aqueous phase14C-TCE. The treatments weevaluated included permanganate paired with: (i) a shear-thinning polymer (xanthan); (ii) stabilizationaids that minimized MnO2rind formation and (iii) a phase-transfer catalyst. In addition, we quantifiedthe ability of these flooding solutions to improve TCE destruction under batch …
Improving The Sweeping Efficiency Of Permanganate Into Low Permeable Zones To Treat Tce: Experimental Results And Model Development, Chanat Chokejaroenrat, Negin Kananizadeh, Chainarong Sakulthaew, Steve D. Comfort, Yusong Li
Improving The Sweeping Efficiency Of Permanganate Into Low Permeable Zones To Treat Tce: Experimental Results And Model Development, Chanat Chokejaroenrat, Negin Kananizadeh, Chainarong Sakulthaew, Steve D. Comfort, Yusong Li
Faculty Publications from The Water Center
The residual buildup and treatment of dissolved contaminants in low permeable zones (LPZs) is a particularly challenging issue for injection-based remedial treatments. Our objective was to improve the sweeping efficiency of permanganate into LPZs to treat dissolved-phase TCE. This was accomplished by conducting transport experiments that quantified the ability of xanthan-MnO4− solutions to penetrate and cover (i.e., sweep) an LPZ that was surrounded by transmissive sands. By incorporating the non-Newtonian fluid xanthan with MnO4−, penetration of MnO4− into the LPZ improved dramatically and sweeping efficiency reached 100% in fewer pore volumes. To quantify …
Using Slow-Release Permanganate Candles To Remove Tce From A Low Permeable Aquifer At A Former Landfill, Mark D. Christenson, Ann Kambhu, Steve D. Comfort
Using Slow-Release Permanganate Candles To Remove Tce From A Low Permeable Aquifer At A Former Landfill, Mark D. Christenson, Ann Kambhu, Steve D. Comfort
Papers in Natural Resources
Past disposal of industrial solvents into unregulated landfills is a significant source of groundwater contamination. In 2009, we began investigating a former unregulated landfill with known trichloroethene (TCE) contamination. Our objective was to pinpoint the location of the plume and treat the TCE using in situ chemical oxidation (ISCO). We accomplished this by using electrical resistivity imaging (ERI) to survey the landfill and map the subsurface lithology. We then used the ERI survey maps to guide direct push groundwater sampling. A TCE plume (100-600 µg L-1) was identified in a low permeable silty-clay aquifer (Kh = 0.5 …