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Articles 1 - 6 of 6
Full-Text Articles in Physical Sciences and Mathematics
Thermochemistry Of Amino Acids And Constrained Diamines, Erica Jane Tullo
Thermochemistry Of Amino Acids And Constrained Diamines, Erica Jane Tullo
Dissertations, Theses, and Masters Projects
The gas-phase proton affinities of several highly basic amino acids and diamines were determined using the extended kinetic method in an ESI-quadrupole ion trap instrument. The non-protein amino acid L-canavanine is structurally related to L-arginine with an oxygen substituted for the terminal methylene group of L-arginine and is highly toxic to humans. The proton affinity of L-arginine, a protein amino acid, was determined to be 1036 kJ mol -1, whereas the proton affinity of L-canavanine was determined to be 1005 kJ mol-1. Thus, substitution of an oxyguanidino group for the guanidine group in L-arginine results in a large decrease in …
Luminescent Nitrogen And Sulfure Adducts Of Cui Disubstituted Piperazine Complexes, Jason P. Safko
Luminescent Nitrogen And Sulfure Adducts Of Cui Disubstituted Piperazine Complexes, Jason P. Safko
Dissertations, Theses, and Masters Projects
No abstract provided.
Dark Matter In The Heavens And At Colliders: Models And Constraints, Reinard Primulando
Dark Matter In The Heavens And At Colliders: Models And Constraints, Reinard Primulando
Dissertations, Theses, and Masters Projects
In this dissertation, we investigate various aspects of dark matter detection and model building. Motivated by the cosmic ray positron excess observed by PAMELA, we construct models of decaying dark matter to explain the excess. Specifically we present an explicit, TeV-scale model of decaying dark matter in which the approximate stability of the dark matter candidate is a consequence of a global symmetry that is broken only by instanton-induced operators generated by a non-Abelian dark gauge group. Alternatively, the decaying operator can arise as a Planck suppressed correction in a model with an Abelian discrete symmetry and vector-like states at …
Effects Of Nucleophile Strength On Selectivity In Bibr3 Catalyzed Cyclic Ether Construction, Ajara A. Rahman
Effects Of Nucleophile Strength On Selectivity In Bibr3 Catalyzed Cyclic Ether Construction, Ajara A. Rahman
Dissertations, Theses, and Masters Projects
No abstract provided.
The Role Of Small Carboxylic Acids During Poly(Amide) 11 Hydrolysis, John-Andrew Samuel Hocker
The Role Of Small Carboxylic Acids During Poly(Amide) 11 Hydrolysis, John-Andrew Samuel Hocker
Dissertations, Theses, and Masters Projects
No abstract provided.
Fluorescence Quenching Of Ppv-So And Bodipy-Naphthalene Systems, Brooklynd Dawn Saar
Fluorescence Quenching Of Ppv-So And Bodipy-Naphthalene Systems, Brooklynd Dawn Saar
Dissertations, Theses, and Masters Projects
No abstract provided.