Physical Sciences and Mathematics Commons^™

Modelling Three-Phase Flow In Metallurgical Processes, Christoph Goniva, Gijsbert Wierink, Kari Heiskanen, Stefan Pirker, Christoph Kloss

Gijsbert Wierink

The interaction between gasses, liquids, and solids plays a critical role in many processes, such as coating, granulation and the blast furnace process. In this paper we present a comprehensive numerical model for three phase flow including droplets, particles and gas. By means of a coupled Computational Fluid Dynamics (CFD) - Discrete Element Method (DEM) approach the physical core phenomena are pictured at a detailed level. Sub-models for droplet deformation, breakup and coalescence as well as droplet-particle and wet particle-particle interaction are applied. The feasibility of this model approach is demonstrated by its application to a rotating drum coater. The …

An Exercise With The He’S Variation Iteration Method To A Fractional Bernoulli Equation Arising In A Transient Conduction With A Non-Linear Boundary Heat Flux, Jordan Hristov

Jordan Hristov

Surface temperature evolution of a body subjected to a nonlinear heat flux involving counteracting convection heating and radiation cooling has been solved by the variations iteration method (VIM) of He. The surface temperature equations comes as a combination of the time-fractional (half-time) subdiffusion model of the heat conduction and the boundary condition relating the temperature field gradient at the surface through the Riemann-Liouville fractional integral. The result of this equation is a Bernoulli-type ordinary fractional equation with a nonlinear term of 4th order. Two approaches in the identification of the general Lagrange multiplier and a consequent application of VIM have …

Capacitively Coupled Radio-Frequency Discharges In Nitrogen At Low Pressures, L. L Alves, L. Marques, C. D Pintassilgo, W. Wattieaux, Et. Es-Sebbar, J. Berndt, E. Kovačević, N. Carrasco, L. Boufendi, G. Cernogora

Dr. Et-touhami Es-sebbar

This paper uses experiments and modelling to study capacitively coupled radio-frequency (rf) discharges in pure nitrogen, at 13.56 MHz frequency, 0.1–1 mbar pressures and 2–30 W coupled powers. Experiments performed on two similar (not twin) setups, existing in the LATMOS and the GREMI laboratories, include electrical and optical emission spectroscopy (OES) measurements. Electrical measurements give the rf-applied and the direct-current-self-bias voltages, the effective power coupled to the plasma and the average electron density. OES diagnostics measure the intensities of radiative transitions with the nitrogen second-positive and first-negative systems, and with the 811.5 nm atomic line of argon (present as an …

Ionization Photophysics And Rydberg Spectroscopy Of Diacetylene, M. Schwell, Y. Benilan, N.. Fray, M.-C. Gazeau, Et. Es-Sebbar, F.-G. Levrel, N. Campion, S. Leach

Dr. Et-touhami Es-sebbar

Photoionization of diacetylene was studied using synchrotron radiation over the range 8–24 eV, with photoelectron-photoion coincidence (PEPICO) and threshold photoelectron–photoion coincidence (TPEPICO) techniques. Mass spectra, ion yields, total and partial ionization cross-sections were measured. The adiabatic ionization energy of diacetylene was determined as IEad = (10.17 ± 0.01) eV, and the appearance energy of the principal fragment ion C4H+ as AE = (16.15 ± 0.03) eV. Calculated appearance energies of other fragment ions were used to infer aspects of dissociation pathways forming the weaker fragment ions , C3H+, and C2H+. Structured autoionization features observed in the PEPICO spectrum of diacetylene …

Integral-Balance Solution To The Stokes’ First Problem Of A Viscoelastic Generalized Second Grade Fluid, Jordan Hristov

Jordan Hristov

Integral balance solution employing entire domain approximation and the penetration dept concept to the Stokes’ first problem of a viscoelastic generalized second grade fluid has been developed. The solution has been performed by a parabolic profile with an unspecified exponent allowing optimization through minimization of the norm over the domain of the penetration depth. The closed form solution explicitly defines two dimensionless similarity variables and , responsible for the viscous and the elastic responses of the fluid to the step jump at the boundary. The solution was developed with three forms of the governing equation through its two dimensional forms …

Thermal Impedance At The Interface Of Contacting Bodies: 1-D Example Solved By Semi-Derivatives, Jordan Hristov

Jordan Hristov

Simple 1-D semi-infinite heat conduction problems enable to demonstrate the potential of the fractional calculus in determination of transient thermal impedances of two bodies with different initial temperatures contacting at the interface ( ) at . The approach is purely analytic and uses only semi-derivatives (half-time) and semi-integrals in the Riemann-Liouville sense. The example solved clearly reveals that the fractional calculus is more effective in calculation the thermal resistances than the entire domain solutions

Replacing −Ch2ch2– With −Conh– Does Not Significantly Change Rates Of Charge Transport Through Agts-Sam//Ga2o3/Egain Junctions, Martin M. Thuo, William F. Reus, Felice C. Simeone, Choongik Kim, Michael D. Schulz, Hyo Jae Yoon, George M. Whitesides

Martin M. Thuo

This paper describes physical-organic studies of charge transport by tunneling through self-assembled monolayers (SAMs), based on systematic variations of the structure of the molecules constituting the SAM. Replacing a −CH2CH2– group with a −CONH– group changes the dipole moment and polarizability of a portion of the molecule and has, in principle, the potential to change the rate of charge transport through the SAM. In practice, this substitution produces no significant change in the rate of charge transport across junctions of the structure AgTS-S(CH2)mX(CH2)nH//Ga2O3/EGaIn (TS = template stripped, X = −CH2CH2– or −CONH–, and EGaIn = eutectic alloy of gallium and …

Magnetic Properties And Short-Range Structure Analysis Of Granular Cobalt Silicon Nitride Multilayers, Félix Jiménez-Villacorta, A. Espinosa, E. Cespedes, C. Prieto

Felix Jiménez-Villacorta

The magnetic properties and local order of cobalt/silicon nitride metal-insulator multilayered system have been studied. Magnetization characterization reveals an evolution of the magnetic features by varying the metal layer thickness. Results show that multilayers with larger metal thickness (t) present a pure ferromagnetic character, whereas samples with t  < 2 nm exhibit a granular superparamagnetic behavior, as it corresponds to discontinuous metal-insulator materials. An important decrease in the magnetization values for the clustered samples has also been observed. X-ray absorption near edge spectroscopy (XANES) and extended x-ray absorption fine structure (EXAFS) at the Co K-edge have been used to determine the …

Measuring Markers Of Liver Function Using A Micropatterned Paper Device Designed For Blood From A Fingerstick, Sarah J. Vella, Patrick Beattie, Rebecca Cademartiri, Anna Laromaine, Andres W. Martinez, Scott T. Phillips, Katherine A. Mirica, George M. Whitesides

Rebecca Cademartiri

This paper describes a paper-based microfluidic device that measures two enzymatic markers of liver function (alkaline phosphatase, ALP, and aspartate aminotransferase, AST) and total serum protein. A device consists of four components: (i) a top plastic sheet, (ii) a filter membrane, (iii) a patterned paper chip containing the reagents necessary for analysis, and (iv) a bottom plastic sheet. The device performs both the sample preparation (separating blood plasma from erythrocytes) and the assays; it also enables both qualitative and quantitative analysis of data. The data obtained from the paper-microfluidic devices show standard deviations in calibration runs and “spiked” standards that …

Volatile Products Controlling Titan’S Tholins Production, N. Carrasco, T. Gautier, Et. Es-Sebbar, P. Pernot, G. Cernogora

Dr. Et-touhami Es-sebbar

A quantitative agreement between nitrile relative abundances and Titan’s atmospheric composition was recently shown with a reactor simulating the global chemistry occurring in Titan’s atmosphere [Gautier et al. (2011) Icarus, 213: 625]. Here we present a complementary study on the same reactor using an in-situ diagnostic of the gas phase composition. Various initial N2-CH4 gas mixtures (methane varying from 1 to 10%) are studied, with a monitoring of the methane consumption and of the stable gas neutrals by in-situ mass spectrometry. Atomic hydrogen is also measured by optical emission spectroscopy. A positive correlation is found between atomic hydrogen abundance and …

Statistical Tools For Analyzing Measurements Of Charge Transport, William F. Reus, Christian A. Nijhuis, Jabulani R. Barber, Martin M. Thuo, Simon Tricard, George M. Whitesides

Martin M. Thuo

This paper applies statistical methods to analyze the large, noisy data sets produced in measurements of tunneling current density (J) through self-assembled monolayers (SAMs) in large-area junctions. It describes and compares the accuracy and precision of procedures for summarizing data for individual SAMs, for comparing two or more SAMs, and for determining the parameters of the Simmons model (β and J0). For data that contain significant numbers of outliers (i.e., most measurements of charge transport), commonly used statistical techniques—e.g., summarizing data with arithmetic mean and standard deviation and fitting data using a linear, least-squares algorithm—are prone to large errors. The …

Electrical Resistance Of Agts–S(Ch2)N−1ch3//Ga2o3/Egain Tunneling Junctions, Ludovico Cademartiri, Martin M. Thuo, Christian A. Nijhuis, William F. Reus, Simon Tricard, Jubulani R. Barber, Rana N.S. Sodhi, Peter Brodersen, Choongik Kim, Ryan C. Chiechi, George M. Whitesides

Martin M. Thuo

Tunneling junctions having the structure AgTS–S(CH2)n−1CH3//Ga2O3/EGaIn allow physical–organic studies of charge transport across self-assembled monolayers (SAMs). In ambient conditions, the surface of the liquid metal electrode (EGaIn, 75.5 wt % Ga, 24.5 wt % In, mp 15.7 °C) oxidizes and adsorbs―like other high-energy surfaces―adventitious contaminants. The interface between the EGaIn and the SAM thus includes a film of metal oxide, and probably also organic material adsorbed on this film; this interface will influence the properties and operation of the junctions. A combination of structural, chemical, and electrical characterizations leads to four conclusions about AgTS–S(CH2)n−1CH3//Ga2O3/EGaIn junctions. (i) The oxide is ∼0.7 …

Vuv Photoionization Of Acetamide Studied By Electron / Ion Coincidence Spectroscopy In The 8-24 Ev Photon Energy Range, M. Schwell, Y. Bénilan, N. Fray, M.-C Gazeau, Et. Es-Sebbar, Gustavo A. Garcia, L. Nahon, N. Champion, S. Leach

Dr. Et-touhami Es-sebbar

A VUV photoionization study of acetamide was carried out over the 8-24 eV photon energy range using synchrotron radiation and photoelectron/photoion coincidence (PEPICO) spectroscopy. Threshold photoelectron photoion coincidence (TPEPICO) measurements were also made. Photoion yield curves and branching ratios were measured for the parent ion and six fragment ions. The adiabatic ionization energy of acetamide was determined as I.E (12A’) = (9.71±0.02) eV, in agreement with an earlier reported photoionization mass spectrometry (PIMS) value. The adiabatic energy of the first excited state of the ion, 12A”, was determined to be ≈ 10.1 eV. Assignments of the fragment ions and the …

An Examination Of The Thermodynamics Of Fusion, Vaporization, And Sublimation Of (R,S)- And (R)-Flurbiprofen By Correlation Gas Chromatography, Patamaporn Umnahanant, Darrell Hasty, James Chickos

James Chickos

No abstract provided.

Nanocrystalline Amn2o4 (A = Co, Ni, Cu) Spinels For Remediation Of Volatile Organic Compounds—Synthesis, Characterization And Catalytic Performance, Ali Hosseini, Ali Niaei, Darioush Salari, Reza Nabavi

Seyed Reza nabavi

Nanocrystalline AMn2O4 (A = Co, Ni, Cu) manganite spinels were prepared by using the sol–gel auto combustion method under the same

synthesis conditions and their physico-chemical properties were studied by XRD, UV–vis DRS, SEM, BET and FTIR. Besides, the reducibility of

oxides was studied by temperature-programmed reduction (TPR). The relationship between the properties and activity of spinels in oxidation of 2-

propanol and toluene was investigated. Among all, nickel manganite exhibited the most promising activity, in which the completed conversion of 2-

propanol and toluene occurred at 250 and 350 8C, respectively. Higher activity of nickel manganite oxide was explained …

Kinetic Analytical Method For Determination Of Uric Acid In Human Urine Using Analyte Pulse Perturbation Technique, Zeljko D. Cupic

Zeljko D Cupic

No abstract provided.

Applications Of Colloidal Gas Aphrons For Pollution Remediation, Mohd Ali Hashim Dr, Soumyadeep Mukhopadhyay Dr, Jaya Narayan Sahu Dr, Bhaskar Sen Gupta Dr

Soumyadeep Mukhopadhyay Dr

Colloidal gas aphrons (CGAs), first described by Felix Sebba in his book "Foams and Biliquid Foams - Aphrons" in 1987, consist of a system of spherical microbubbles with diameter mostly above 25 μm and classified as kugelschaums (ball foam). They possess some colloidal properties and can be pumped at uniform rate through pipes and channels, much like liquids. Also, they have high stability due to very small size and thick surfactant shells. Research works published over the period of the past two decades indicate effective applications of CGAs for clarification of particles and microorganisms, protein separation, gas and nutrient transfer …

Pyrite. History, Chemistry, And Metallurgy, Fathi Habashi

Fathi Habashi

The Book covers the history of pyrite - - how it was a strategic mineral necessary for the production of elemental sulfur needed for making gunpowder for military purposes and for the production of SO2 needed for making sulfuric acid for the chemical industry. Now its presence is a nuisance in tailings ponds. The book also covers the processing of pyrite containing gold, its chemistry and technology, the processing of pyrite cinder for the production of a variety of metals, and its behaviour towards autotrophic microorganisms.

Ogólnotechniczne Podstawy Biotechnologii Z Elementami Grafiki Inżynierskiej Ćw., Wojciech M. Budzianowski

Wojciech Budzianowski

No abstract provided.

Materiały Odstresowujące, Wojciech M. Budzianowski

Wojciech Budzianowski

No abstract provided.

Oxidative Carbonylation Of 2-Propyn-1-Ol And 2-Methyl-3-Butyn-2-Ol In An Oscillatory Mode, Sergey N. Gorodsky

Sergey N. Gorodsky

No abstract provided.

Mox/Cnts Hetero-Structures For Gas Sensing Applications: Role Of Cnts Defects, G. Neri, S. G. Leonardi, N. Donato, C. Marichy, Jean-Philippe Tessonnier, M.-G. Willinger, Kyeong-Hwan Lee, N. Pinna

Jean-Philippe Tessonnier

The preparation, characterization and sensing properties of CNT composites with a thin metal oxide (MOx) surface layer is presented. Atomic layer deposition (ALD) was applied for the coating of the inner and outer CNTs walls with thin films of ZnO and SnO2 of precisely controlled thicknesses. Differently treated CNTs with different degree of surface functionalization were used as support for the oxide films. The sensing properties of the obtained composite materials towards NO2 were investigated and related to the morphological and microstructural characteristics of both the coating and support. SnO2-based composites on CNTs treated at 700 °C show enhanced performance …

Controlling Nanoparticles Formation In Molten Metallic Bilayers By Pulsed-Laser Interference Heating, Mikhail Khenner, Sagar Yadavali, Ramki Kalyanaraman

Mikhail Khenner

The impacts of the two-beam interference heating on the number of core-shell and embedded nanoparticles and on nanostructure coarsening are studied numerically based on the non-linear dynamical model for dewetting of the pulsed-laser irradiated, thin (< 20 nm) metallic bilayers. The model incorporates thermocapillary forces and disjoining pressures, and assumes dewetting from the optically transparent substrate atop of the reflective support layer, which results in the complicated dependence of light reflectivity and absorption on the thicknesses of the layers. Stabilizing thermocapillary effect is due to the local thickness-dependent, steady- state temperature profile in the liquid, which is derived based on the mean substrate temperature estimated from the elaborate thermal model of transient heating and melting/freezing. Linear stability analysis of the model equations set for Ag/Co bilayer predicts the dewetting length scales in the qualitative agreement with experiment.

Materials For Diabetes Therapeutics, Kaitlin M. Bratlie, Roger L. York, Michael A. Invernale, Robert Langer, Daniel G. Anderson

Kaitlin M. Bratlie

This review is focused on the materials and methods used to fabricate closedloop systems for type 1 diabetes therapy. Herein, we give a brief overview of current methods used for patient care and discuss two types of possible treatments and the materials used for these therapies-(i) artificial pancreases, comprised of insulin producing cells embedded in a polymeric biomaterial, and (ii) totally synthetic pancreases formulated by integrating continuous glucose monitors with controlled insulin release through degradable polymers and glucose-responsive polymer systems. Both the artificial and the completely synthetic pancreas have two major design requirements: the device must be both biocompatible and …

Labeling And Monitoring The Distribution Of Anchoring Sites On Functionalized Cnts By Atomic Layer Deposition, Catherine Marichy, Jean-Philippe Tessonnier, Marta C. Ferro, Kyeong-Hwan Lee, Robert Schlogl, Nicola Pinna, Marc-Georg Willinger

Jean-Philippe Tessonnier

The chemical inertness of graphite and, in the case of tubes, of rolled up few layer graphene sheets, requires some degree of "defect engineering" for the fabrication of carbon based heterostructured materials. It is shown that atomic layer deposition provides a means to specifically label anchoring sites and can be used to characterize the surface functionality of differently treated carbon nanotubes. Direct observation of deposited titania by analytical transmission electron microscopy reveals the location and density of anchoring sites as well as structure related concentrations of functional groups on the surface of the tubes. Controlled functionalization of the tubes therefore …

Hydrogen Production From Biogas By Oxy-Reforming: Reaction System Analysis, Aleksandra Terlecka, Wojciech M. Budzianowski

Wojciech Budzianowski

Oxy-reforming is emerging as an interesting alternative to conventional methods of hydrogen generation. The current article characterises this process through analysis of individual reactions: SMR (steam methane reforming), WGS (water gas shift) and CPO (catalytic partial oxidation). Analyses relate to optimisation of thermal conditions thus enabling cost-effectivenes of the process.

Extractive Metallurgy Of Copper, Fathi Habashi

Fathi Habashi