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Vanadium Trichloride Thermochemical Solar Energy Storage System Analysis., Caleb Michael Rogers

Electronic Theses and Dissertations

As annual energy consumption grows, developing renewable solar energy conversion systems, storage systems, and high density electrical energy production systems is growing increasingly important. The proposed system utilizes vanadium trichloride thermal decomposition to produce chlorine gas and vanadium dichloride. A second reaction combines gaseous hydrogen chloride and the product vanadium dichloride to reform vanadium trichloride and produce hydrogen gas. Hydrogen gas and chlorine gas can be stored indefinitely and electrical energy is obtained from the chemicals by a non-humidified dry membrane hydrogen – chlorine fuel cell. The fuel cell produces the gaseous hydrogen chloride needed to reform vanadium trichloride. The …