Engineering Commons^™

A Characterization Of Different Alkali Chemical Agents For Alkaline Flooding Enhanced Oil Recovery Operations: An Experimental Investigation, Sherif Fakher, Hesham Abdelaal, Youssef Elgahawy, Abdulmohsin Imqam

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Alkaline injection is a chemical enhanced oil recovery method that is used to increase oil recovery by reacting with the crude oil and creating an in situ surfactant. Many chemical agents can be used as an alkali during injection all of which have several advantages and disadvantages. This research focuses on the innate properties of three alkali agents and their ability to alter pH and temperature downhole. Alkali solutions were prepared with five different concentrations including 0.2, 1, 2, 3, and 4 wt%. The impact of varying the alkali concentration, monovalent cations manifested in sodium chloride, and divalent cations manifested …

Application Of Artificial Neural Networks In The Drilling Processes: Can Equivalent Circulation Density Be Estimated Prior To Drilling?, Husam Hasan Alkinani, Abo Taleb Al-Hameedi, Shari Dunn-Norman, David Lian

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

As the drilling environment became more challenging nowadays, managing equivalent circulating density (ECD) is a key factor to minimize non-productive time (NPT) due to many drilling obstacles such as stuck pipe, formation fracturing, and lost circulation. The goal of this work was to predict ECD prior to drilling by using artificial neural network (ANN). Once ECD is recognized, the crucial drilling variables impact ECD can be modified to control ECD within the acceptable ranges. Data from over 2000 wells collected worldwide were used in this study to create an ANN to predict ECD prior to drilling. Into training, validation, and …

Polyball: A New Adsorbent For The Efficient Removal Of Endotoxin From Biopharmaceuticals, Sidharth Razdan, Jee-Ching Wang, Sutapa Barua

Chemical and Biochemical Engineering Faculty Research & Creative Works

The presence of endotoxin, also known as lipopolysaccharides (LPS), as a side product appears to be a major drawback for the production of certain biomolecules that are essential for research, pharmaceutical, and industrial applications. In the biotechnology industry, gram-negative bacteria (e.g., Escherichia coli ) are widely used to produce recombinant products such as proteins, plasmid DNAs and vaccines. These products are contaminated with LPS, which may cause side effects when administered to animals or humans. Purification of LPS often suffers from product loss. For this reason, special attention must be paid when purifying proteins aiming a product as free as …

Extraction And Visualization Of Orientation Data From Virtual Geologic Surfaces With Matlab®, Avery J. Welker, John Patrick Hogan, Andreas Eckert

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

High-resolution visualization of surfaces of geologic interest, at a multitude of scales, using 3D point cloud technologies provides an opportunity to analyze spatial relationships of surfaces using orientation data. We present a MATLAB® script that produces planar geologic attitude data (e.g., strike, dip, and dip-direction data) from 3D datasets (e.g., point clouds, 3D scanning). The method utilizes Cartesian coordinates of triangular planar surfaces and converts them into matrices of conventional geologic attitude data. Spatial relationships among data points can be investigated, using polar tangent diagrams, stereographic analysis, or geologic curvature analysis. We utilize this script to create "synthetic" graphical plots …

Decorative Articles Based On Polymeric Materials, Bassant Hussein, Yaser M. Asal, M. A. Radwan, M. A. Sadek, Hany A. Elazab

Chemical and Biochemical Engineering Faculty Research & Creative Works

The aim of the research is to create decorative articles based on polymeric materials, study the effects of fillers and the type of moulds that it can cope with the exothermic reaction nature of resin to create a scientific background on the usage of the resins in daily life products. The polymeric materials that will be concentrated on are the unsaturated polyester resins and epoxy resins. The unsaturated polyester is of many types and chemical constituents, the used experimentally is a general-purpose type and the epoxy also have different types and the used is a commercially 3D floor coating type. …

Microwave Assisted Synthesis Of Binary Metallic Oxides For Catalysis Applications, Abdelrahman Mostafa Kamal, Sherif Bahgat, Mohamed Hammam, M. A. Radwan, M. A. Sadek, Hany A. Elazab

Chemical and Biochemical Engineering Faculty Research & Creative Works

Herein, versatile, and reproducible method to prepare binary metal oxides via microwave assisted synthesis. Catalysts are substances that basically speeds up chemical reactions. Ideally, bonds are formed between the catalysts and the reactants. Also, catalysts permit formation of products from the reactants. These formed products, splits off the catalyst without affecting or changing it. Catalytic kinetics studies the correlate chemical reaction rate with some properties of reactants and/or products for instance, temperature, concentration and pressure. The aim of the project is to prepare pure and bi-metal iron-based catalyst by co-precipitation method and to characterize the prepared sample using X-ray diffraction. …

Composite Materials Based On Twaron And Nano Materials, Omnia Hamdy, Remon A. Mankarious, M. A. Radwan, M. A. Sadek, Hany A. Elazab

Chemical and Biochemical Engineering Faculty Research & Creative Works

This research aims to participate in producing body shield that can overcome pervious drawbacks using behavior of shear thickening fluid. Initially, the rheological behavior of silica-polyethylene glycol shear thickening fluid is examined at different concentrations. Then, ballistic fabric samples are impregnated into silica-polyethylene glycol shear thickening fluid at various concentrations of silica and tested using gas gun simulating real ballistic threat. After that, the impact of rubbery hot water pack filled with around 66.67 wt% starch in water is tested using gas gun. Results showed as the concentration of silica increases, the indentation depth in the impregnated fabric decreases which …

Novel Adsorbent For Industrial Wastewater Treatment Applications, Ahmed Y. Zakaria, Dalia A. Ali, Islam M. Al-Akraa, Hoda A. Elsawy, Hany A. Elazab

Chemical and Biochemical Engineering Faculty Research & Creative Works

In this study, the hydroxyapatite powder is investigated for both of methylene blue and thymol blue in aqueous solution. The physical and chemical properties of the adsorbent were evaluated systematically using the different techniques including Microsoft Excel programming, linear regression model and also the coefficient of determination. Batch adsorption experiments were conducted to determine the effect of contact time, solution pH, initial dye concentrations, and also the adsorbent dosage on adsorption. The adsorption kinetic parameters confirmed the better fitting of pseudo-second order kinetic model for both of methylene blue and thymol blue. The isotherm data of methylene blue and thymol …

A Review Of Materials For Managing Bone Loss In Revision Total Knee Arthroplasty, Romina Shafaghi, Omar Rodriguez, Emil H. Schemitsch, Paul Zalzal, Stephen D. Waldman, Marcello Papini, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

In 2014–2015, 61,421 total knee arthroplasties (TKAs) were performed in Canada; an increase of about 20% over 2000–2001. Revision total knee arthroplasties (rTKAs) accounted for 6.8% of TKAs performed between 2014 and 2015, and this is estimated to grow another 12% by 2025. rTKAs are typically more complicated than primary TKAs due to the significant loss of femoral and tibial bone stock. The escalating demand and limitations associated with total knee arthroplasty and their revision drives the development of novel treatments. A variety of materials have been utilized to facilitate regeneration of healthy bone around the site of a knee …

Hydrothermal Preparation Of Palladium Supported On Magnetite For Catalysis Applications, Hany A. Elazab, S. A. Hassan, M. A. Radwan, M. A. Sadek

Chemical and Biochemical Engineering Faculty Research & Creative Works

Herein, versatile, and reproducible method to prepare Pd/Fe₃O₄ via hydrothermal synthesis. The vital role of this catalyst is in its potential use in CO oxidation catalysis. The Pd/Fe₃O₄ shows a distinctive activity. TEM images confirmed that Pd nanoparticles of 8-12 nm have a well dispersion on the surface of magnetite (Fe₃O₄). Moreover, the prepared catalyst is recycled with remarkable catalytic activity. This outstanding activity is mainly a direct result of the strong metal-support interaction. The defect sites in the reduced iron oxide act as nucleation centers that enable anchoring of …

The Effect Of Tantalum Incorporation On The Physical And Chemical Properties Of Ternary Silicon–Calcium–Phosphorous Mesoporous Bioactive Glasses, Andrew Mendonca, Md Saidur Rahman, Adel Alhalawani, Omar Rodriguez, Reid C. Gallant, Heyu Ni, Owen M. Clarkin, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

Synthesis and characterization of the first mesoporous bioactive glasses (MBGs) containing tantalum are reported here, along with their potential application as hemostats. Silica MBGs were synthesized using with the molar composition of (80-x)% Si, 15% Ca, 5% P, and x% Ta. It was found that incorporation of >1 mol % Ta into the MBGs changes their physical and chemical properties. Increasing Ta content from 0 to 10 mol % causes a decrease in the surface area and pore volume of ~20 and ~35%, respectively. This is due to the increase in nonbridging oxygens and mismatch of thermal expansion coefficient which …

Sequencing Heparan Sulfate Using Hilic Lc-Netd-Ms/Ms, Jiandong Wu, Juan Wei, Pradeep Chopra, Geert Jan Boons, Cheng Lin, Joseph Zaia

Chemical and Biochemical Engineering Faculty Research & Creative Works

Heparan Sulfate (HS) Mediates a Wide Range of Protein Binding Interactions Key to Normal and Pathological Physiology. Though Liquid Chromatography Coupled with Mass Spectrometry (LC-MS) based Disaccharide Composition Analysis is Able to Profile Changes in HS Composition, the Heterogeneity of Modifications and the Labile Sulfate Group Present Major Challenges for Liquid Chromatography Tandem Mass Spectrometry (LC-MS/MS) Sequencing of the HS Oligosaccharides that Represent Protein Binding Determinants. Here, We Report Online LC-MS/MS Sequencing of HS Oligosaccharides using Hydrophilic Interaction Liquid Chromatography (HILIC) and Negative Electron Transfer Dissociation (NETD). a Series of Synthetic HS Oligosaccharides Varying in Chain Length (Tetramers and Hexamers), …

Measurement Of Adhesion Of Sternal Wires To A Novel Bioactive Glass-Based Adhesive, Varinder Pal Singh Sidhu, Mark R. Towler, Marcello Papini

Chemical and Biochemical Engineering Faculty Research & Creative Works

Stainless steel wires are the standard method for sternal closure because of their strength and rigidity, the simplicity of the process, and the short healing time that results from their application. Despite this, problems still exist with sternal stability due to micromotion between the two halves of the dissected and wired sternum. Recently, a novel glass-based adhesive was developed which, in cadaveric trials and in conjunction with wiring, was shown to restrict this micromotion. However, in order to avoid complications during resternotomy, the adhesive should adhere only to the bone and not the sternal wire. In this study, sternal wires …

The Potential Of Using Micro-Sized Crosslinked Polymer Gel To Remediate Water Leakage In Cement Sheaths, Murad Abdulfarraj, Abdulmohsin Imqam

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Cementing is a major step in the construction and sealing of hydrocarbon wells. During the life cycle of the well, cement is prone to cracking due to a change in downhole conditions. This research investigates the use of micro-sized crosslinked polymer gel as a sealant material to mitigate cracked cement sheaths. Two experimental setups were designed to investigate water leakage through cement. The impact of polymer gel strength on the gel's ability to seal cement cracks was investigated using four gel strengths, including 500 pa, 1200 pa, 1450 pa, and 2440 pa. The impact of the width of the cement …

Novel Coupling Smart Water-Co₂ Flooding For Sandstone Reservoirs, Hasan N. Al-Saedi, Ralph E. Flori

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

CO₂ flooding is an environmentally friendly and cost-effective EOR technique that can be used to unlock residual oil from oil reservoirs. Smart water is any water that is engineered by manipulating the ionic composition, regardless of the resulting salinity of the water. One CO2 flooding mechanism is wettability alteration, which meets with the main smart water flooding function. Injecting CO₂ alone increases the likelihood of an early breakthrough and gravity override problems, which have already been solved using water-alternating-gas (WAG) using regular water. WAG is an emerging enhanced oil recovery process designed to enhance sweep efficiency during gas …

Bioactive Glass Fiber Fabrication Via A Combination Of Sol-Gel Process With Electro-Spinning Technique, Malvika Nagrath, Adel Alhalawani, Alireza Rahimnejad Yazdi, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

Notes On The Economics Of Residential Hybrid Energy System, Mahelet G. Fikru, Gregory M. Gelles, Ana M. Ichim, Joseph D. Smith

Economics Faculty Research & Creative Works

Despite advances in small-scale hybrid renewable energy technologies, there are limited economic frameworks that model the different decisions made by a residential hybrid system owner. We present a comprehensive review of studies that examine the techno-economic feasibility of small-scale hybrid energy systems, and we find that the most common approach is to compare the annualized life-time costs to the expected energy output and choose the system with the lowest cost per output. While practical, this type of benefit—cost analysis misses out on other production and consumption decisions that are simultaneously made when adopting a hybrid energy system. In this paper, …

High Octane Number Gasoline-Ether Blend, Tarek M. Aboul-Fotouh, Sherif K. Ibrahim, M. A. Sadek, Hany A. Elazab

Chemical and Biochemical Engineering Faculty Research & Creative Works

Gasoline produced in Egypt is a low-grade gasoline that contains high concentration of harmful components that are having a toll on our environment. In addition, those pollutants cause countless diseases and deaths annually to the Egyptian population. This paper targets two main sectors in the production of commercial gasoline. The improvement engine efficiency through the upgrading of octane number is first experimented by using a blend stock that ranges from gasoline fractions and Isomerates. An optimum was then chosen depending on the results obtained from different tests. Through those experiments, it was determined which samples obeyed the EU regulation for …

Advanced Measurement Techniques For Enabling Multiphase Reactors And Flow Systems For Sustainable And Cleaner Processes, Muthanna H. Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

Physico-Chemical Characteristics Of Ethanol–Diesel Blend Fuel, Tarek M. Aboul-Fotouh, Eslam Alaa, M. A. Sadek, Hany A. Elazab

Chemical and Biochemical Engineering Faculty Research & Creative Works

In this research we are discussing the physicochemical characteristics of sweet diesel after desulphurization alone and also these characteristics are tested with the adding of high purity HPLC ethanol (99.9%). Those fuel properties of ethanol blended with diesel were experimentally determined to find their stability and to increase their properties and efficiency in the diesel engines. First, we made 4 blends of diesel with ethanol and the fifth sample was pure diesel. The samples were 0% ethanol and 100 % diesel, the second sample was 5% ethanol and 95 % diesel, the third sample was 10 % ethanol and 90% …

Method Of Forming Microparticles For Use In Cell Seeding, Sutapa Barua, Chase Herman

Chemical and Biochemical Engineering Faculty Research & Creative Works

The present invention is directed to methods for forming microparticles useful for cell seeding and for conjugating protein to the surface of the microparticles. The method comprises co-injecting an organic solution of PLGA or other polymer with an aqueous solution into a flow focusing tube.

Novel Coupling Smart Water-Co₂ Flooding For Sandstone Reservoirs; Smart Seawater-Alternating-Co₂ Flooding (Smsw-Agf), Hasan N. Al-Saedi, Ralph E. Flori

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

CO₂ flooding is an environmentally friendly and cost-effective EOR technique that can be used to unlock residual oil from oil reservoirs. Smart water is any water that is engineered by manipulating the ionic composition, regardless of the resulting salinity of the water. One CO₂ flooding mechanism is wettability alteration, which meets with the main smart water flooding function. Injecting CO₂ alone raise an early breakthrough and gravity override problems, which have already been solved using water alternating gas (WAG) using regular water. WAG is an emerging enhanced oil recovery process designed to enhance sweep efficiency during gas …

Slightly Fluorination Of Al₂O₃ Ald Coating On Li₁.₂Mn₀.₅₄Coo.₁₃Ni₀.₁₃O₂ Electrodes: Interface Reaction To Create Stable Solid Permeable Interphase Layer, Han Yu, Yan Gao, Xinhua Liang

Chemical and Biochemical Engineering Faculty Research & Creative Works

Improving the performance of cathodes by using surface coatings has proven to be an effective method for improving the stability of Li-ion batteries (LIBs), while a high-quality film satisfying all requirements of electrochemical inertia, chemical stability, and lithium ion conductivity has not been found. In this study, a composite film composed of Al₂O₃ and AlF₃ layers was coated on the surface of Li_1.2Mn_0.54Co_0.13Ni_0.13O₂ (Li-rich NMC) based electrodes by atomic layer deposition (ALD). By varying the ratio of Al₂O₃ and AlF₃, an optimal …

Mud Loss Estimation Using Machine Learning Approach, Abo Taleb T. Al-Hameedi, Husam H. Alkinani, Shari Dunn-Norman, Ralph E. Flori, Steven Austin Hilgedick, Ahmed S. Amer, Mortadha Alsaba

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Lost circulation costs are a significant expense in drilling oil and gas wells. Drilling anywhere in the Rumaila field, one the world's largest oilfields, requires penetrating the Dammam formation, which is notorious for lost circulation issues and thus a great source of information on lost circulation events. This paper presents a new, more precise model to predict lost circulation volumes, equivalent circulation density (ECD), and rate of penetration (ROP) in the Dammam formation. A larger data set, more systematic statistical approach, and a machine-learning algorithm have produced statistical models that give a better prediction of the lost circulation volumes, ECD, …

Influence Of Frictional Or Rotational Kinetic Energy On Wellbore-Fluid/Temperature Profiles During Drilling Operations, Ahmed Q. Al Saedi, Ralph E. Flori, C. Shah Kabir

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Temperature-profile distributions in a wellbore during drilling operations might take different forms when applying the energy balance in the overall system. For steady-state conditions, wherein the wellbore is considered a closed system, adding any source of additional energy to this system can influence the predicted temperature profiles. This study presents a new analytical model to investigate the influence of rotational energy arising from the drillstring operation on the wellbore-temperature behavior.

A significant part of the drilling operation is rotation of the drillstring. Depending on the drilling rig, various equipment provides this kind of energy, such as the rotary table or …

Follow-Up And Kinetic Model Selection Of Dinitro Pentamethylene Tetramine (Dpt), Hany A. Elazab, M. M. Seleet, Said M.A. Hassanein, M. A. Radwan, M. A. Sadek

Chemical and Biochemical Engineering Faculty Research & Creative Works

The Synthetic route of Cyclotetramethylene Tetramine is implemented through the reaction of hexamine and nitrating mixture that is formed as a result of a reaction between ammonium nitrate and fuming nitric acid. The reaction medium includes acetic acid, acetic anhydride and p-formaldehyde. This synthetic pathway is relatively long and both of hexamine dinitrate and Dinitro Pentamethylene Tetramine (DPT) are considered as the two main intermediate compounds. The former compound (hexamine dinitrate) was prepared, purified, and then characterized. Conversion of hexamine dinitrate into DPT has been followed up experimentally at different temperatures. Various factors including temperature and time has been investigated. …

Investigation Of Microwave-Assisted Synthesis Of Palladium Nanoparticles Supported On Fe3o4 As Efficient Recyclable Magnetic Catalysts For Suzuki-Miyaura Cross-Coupling, Hany A. Elazab

Chemical and Biochemical Engineering Faculty Research & Creative Works

In this research, a facile and reproducible approach was implemented for the synthesis of palladium nanoparticles supported on Fe₃O₄ with remarkable activity as an ideal catalyst for Suzuki-Miyaura cross-coupling. Magnetite supported Pd nanoparticles reveal high activity in Suzuki-Miyaura coupling reactions since they could be recycled up to seven times with the same high catalytic activity. This adopted method of catalyst synthesis has many advantages, including reproducibility and the reliability of the adopted synthetic method. The produced catalyst has unique magnetic properties to facilitate catalyst recovery from the reaction mixture by using a strong magnet as an external …

A Review Of Field Oil-Production Response Of Injection-Well Gel Treatments, Munqith Aldhaheri, Mingzhen Wei, Na Zhang, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

As life-span extenders, bulk gels have been widely applied to rejuvenate oil production from uneconomic producers in mature oil fields by improving the sweep efficiency of improved-oil-recovery (IOR)/enhanced-oil-recovery (EOR) floods. This paper presents a comprehensive review of the responses of injection-well gel treatments implemented between 1985 and 2014. The survey includes 61 field projects compiled from SPE papers and US Department of Energy reports. Seven parameters related to the oil-production response were evaluated according to the reservoir lithology, formation type, and recovery process, using univariate analysis and stacked histograms. The interquartile-range (IQR) method was used to detect the underperforming and …

Revisiting The Butler-Mokrys Model For The Vapor-Extraction Process, Vijitha Mohan, Partho Neogi, Baojun Bai

Chemical and Biochemical Engineering Faculty Research & Creative Works

The dynamics of a process in which a solvent in the form of a vapor or gas is introduced in a heavy-oil reservoir is considered. The process is called the solvent vapor-extraction process (VAPEX). When the vapor dissolves in the oil, it reduces its viscosity, allowing oil to flow under gravity and be collected at the bottom producer well. The conservation-of-species equation is analyzed to obtain a more-appropriate equation that differentiates between the velocity within the oil and the velocity at the interface, which can be solved to obtain a concentration profile of the solvent in oil. We diverge from …

3d Printed Zeolite Monoliths For Co₂ Removal, Fateme Rezaei, Harshul V. Thakkar

Chemical and Biochemical Engineering Faculty Research & Creative Works

Carbon dioxide (CO₂) capture materials comprising one or more 3D-printed zeolite monoliths for the capture and or removal of CO₂ from air or gases in enclosed compartments, including gases or mixtures of gases having less than about 5% CO₂. Methods for preparing 3D-printed zeolite monoliths useful as CO₂ capture materials and filters, as well as methods of removing CO₂ from a gas or mixture of gases in an enclosed compartment using 3D-printed zeolite monoliths are provided.