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Full-Text Articles in Engineering

Influence Of Pressure, Temperature And Organic Surface Concentration On Hydrogen Wettability Of Caprock, Implications For Hydrogen Geo-Storage, Muhammad Ali, Nurudeen Yekeen, Nilanjan Pal, Alireza Keshavarz, Stefan Iglauer, Hussein Hoteit Nov 2021

Influence Of Pressure, Temperature And Organic Surface Concentration On Hydrogen Wettability Of Caprock, Implications For Hydrogen Geo-Storage, Muhammad Ali, Nurudeen Yekeen, Nilanjan Pal, Alireza Keshavarz, Stefan Iglauer, Hussein Hoteit

Research outputs 2014 to 2021

Hydrogen (H2) as a cleaner fuel has been suggested as a viable method of achieving the de-carbonization objectives and meeting increasing global energy demand. However, successful implementation of a full-scale hydrogen economy requires large-scale hydrogen storage (as hydrogen is highly compressible). A potential solution to this challenge is injecting hydrogen into geologic formations from where it can be withdrawn again at later stages for utilization purposes. The geo-storage capacity of a porous formation is a function of its wetting characteristics, which strongly influence residual saturations, fluid flow, rate of injection, rate of withdrawal, and containment security. However, literature …


Co2-Wettability Reversal Of Cap-Rock By Alumina Nanofluid: Implications For Co2 Geo-Storage, Muhammad Ali, Adnan Aftab, Faisal Ur Rahman Awan, Hamed Akhondzadeh, Alireza Keshavarz, Ali Saeedi, Stefan Iglauer, Mohammad Sarmadivaleh Apr 2021

Co2-Wettability Reversal Of Cap-Rock By Alumina Nanofluid: Implications For Co2 Geo-Storage, Muhammad Ali, Adnan Aftab, Faisal Ur Rahman Awan, Hamed Akhondzadeh, Alireza Keshavarz, Ali Saeedi, Stefan Iglauer, Mohammad Sarmadivaleh

Research outputs 2014 to 2021

© 2021 Elsevier B.V. The usage of nanofluids is vast in different applications of nano-energy. These minute nanoparticles can be used to alter the hydrophobicity into hydrophilicity for CO2-brine-mineral systems in the presence of organic acids. Nonetheless, the literature lacks the information for the behavior of nanoparticles and its associated concentrations in the presence of organic acids at the reservoir (high temperature and high pressure) conditions. In this study, we have investigated that how different alkyl chain organic acids impact the wettability of mica muscovite for different ageing times (7 days and one year) and how this impact can be …


Effect Of Humic Acid On Co2-Wettability In Sandstone Formation, Mujahid Ali, Faisal Ur Rahman Awan, Muhammad Ali, Ahmed Al-Yaseri, Muhammad Arif, Mónica Sánchez-Román, Alireza Keshavarz, Stefan Iglauer Apr 2021

Effect Of Humic Acid On Co2-Wettability In Sandstone Formation, Mujahid Ali, Faisal Ur Rahman Awan, Muhammad Ali, Ahmed Al-Yaseri, Muhammad Arif, Mónica Sánchez-Román, Alireza Keshavarz, Stefan Iglauer

Research outputs 2014 to 2021

© 2020 Elsevier Inc. Hypothesis: Millions of tons of CO2 are stored in CO2 geological storage (CGS) formations (depleted oil reservoirs and deep saline aquifers) every year. These CGS formations naturally contain small concentrations of water-soluble organic components in particular humic acid (HA), which may drastically affect the rock wettability - a significant factor determining storage capacities and containment security. Hence, it is essential to characterise the effect of humic acid concentration on CO2-wettability and its associated impact on storage capacity. Experimental: To achieve this, we measured advancing and receding contact angles at reservoir conditions using the pendant drop tilted …


Effect Of Co2 Flooding On The Wettability Evolution Of Sand-Stone, Cut Aja Fauziah, Ahmed Al-Yaseri, Emad Al-Khdheeawi, Nilesh Kumar Jha, Hussein R. Abid, Stefan Iglauer, Christopher Lagat, Ahmed Barifcani Jan 2021

Effect Of Co2 Flooding On The Wettability Evolution Of Sand-Stone, Cut Aja Fauziah, Ahmed Al-Yaseri, Emad Al-Khdheeawi, Nilesh Kumar Jha, Hussein R. Abid, Stefan Iglauer, Christopher Lagat, Ahmed Barifcani

Research outputs 2014 to 2021

Wettability is one of the main parameters controlling CO2 injectivity and the movement of CO2 plume during geological CO2 sequestration. Despite significant research efforts, there is still a high uncertainty associated with the wettability of CO2/brine/rock systems and how they evolve with CO2 exposure. This study, therefore, aims to measure the contact angle of sandstone samples with varying clay content before and after laboratory core flooding at different reservoir pressures, of 10 MPa and 15 MPa, and a temperature of 323 K. The samples’ microstructural changes are also assessed to investigate any potential alteration …


Shale Adhesion Force Measurements Via Atomic Force Microscopy, Nikolai Mitiurev, Michael Verrall, Svetlana Shilobreeva, Alireza Keshavarz, Stefan Iglauer Jan 2021

Shale Adhesion Force Measurements Via Atomic Force Microscopy, Nikolai Mitiurev, Michael Verrall, Svetlana Shilobreeva, Alireza Keshavarz, Stefan Iglauer

Research outputs 2014 to 2021

Wettability of sedimentary rock surface is an essential parameter that defines oil recovery and production rates of a reservoir. The discovery of wettability alteration in reservoirs, as well as complications that occur in analysis of heterogeneous sample, such as shale, for instance, have prompted scientists to look for the methods of wettability assessment at nanoscale. At the same time, bulk techniques, which are commonly applied, such as USBM (United States Bureau of Mines) or Amott tests, are not sensitive enough in cases with mixed wettability of rocks as they provide average wettability values of a core plug. Atomic Force Microscopy …


Co2 – Brine – Sandstone Wettability Evaluation At Reservoir Conditions Via Nuclear Magnetic Resonance Measurements, Auby Baban, Ahmed Al-Yaseri, Alireza Keshavarz, R. Amin, Stefan Iglauer Jan 2021

Co2 – Brine – Sandstone Wettability Evaluation At Reservoir Conditions Via Nuclear Magnetic Resonance Measurements, Auby Baban, Ahmed Al-Yaseri, Alireza Keshavarz, R. Amin, Stefan Iglauer

Research outputs 2014 to 2021

CO2-rock wettability is a key parameter which governs CO2 trapping capacities and containment security in the context of CO2 geo-sequestration schemes. However, significant uncertainties still exist in terms of predicting CO2 rock wettability at true reservoir conditions. This study thus reports on wettability measurements via independent Nuclear Magnetic Resonance (NMR) experiments on sandstone (CO2–brine systems) to quantify Wettability Indices (WI) using the United States Bureau of Mines (USBM) scale. The results show that CO2 (either molecularly dissolved or as a separate supercritical phase) significantly reduced the hydrophilicity of the sandstone from strongly …


Improving Basalt Wettability To De-Risk Co2 Geo-Storage In Basaltic Formations, Stefan Iglauer, Ahmed Al-Yaseri Jan 2021

Improving Basalt Wettability To De-Risk Co2 Geo-Storage In Basaltic Formations, Stefan Iglauer, Ahmed Al-Yaseri

Research outputs 2014 to 2021

CO2 geo-storage in basaltic formations has recently been identified as a viable option to rapidly dispose large quantities of CO2, hence mitigating anthropogenic CO2 emissions. However, it has been shown that basalt is weakly water-wet or intermediate-wet at typical storage conditions, which reduces capillary trapping capacities and increases lateral and vertical spreading of the CO2 plume; and these effects increase project risk. We thus propose here to prime basalt surfaces with anionic surfactant (here we used sodium dodecyl benzene sulfonate), and demonstrate that such priming is highly efficient, and renders the basalt completely water-wet even …


Experimental Investigation Of The Effect Of Vitagnus Plant Extract On Enhanced Oil Recovery Process Using Interfacial Tension (Ift) Reduction And Wettability Alteration Mechanisms, Seyed Ramin Mousavi Dashtaki, Jagar A. Ali, Abbas Khaksar Manshad, Iman Nowrouzi, Amir H. Mohammadi, Alireza Keshavarz Oct 2020

Experimental Investigation Of The Effect Of Vitagnus Plant Extract On Enhanced Oil Recovery Process Using Interfacial Tension (Ift) Reduction And Wettability Alteration Mechanisms, Seyed Ramin Mousavi Dashtaki, Jagar A. Ali, Abbas Khaksar Manshad, Iman Nowrouzi, Amir H. Mohammadi, Alireza Keshavarz

Research outputs 2014 to 2021

© 2020, The Author(s). Surfactant flooding is a chemical enhanced oil recovery (cEOR) process wherein anionic, cationic, non-ionic, and amphoteric surfactants are injected into oil reservoirs to produce more hydrocarbon. These chemical and industrial agents might cause some economic and environmental challenges. Recently, injection of natural surfactants, as new environmentally friendly EOR agents, for improving oil recovery has been proposed by researchers. In this study, the extract of Vitagnus, a natural surfactant, was used to minimize the interfacial tension (IFT) and alter the rock wettability towards the strong water-wet system, thereby improving the oil recovery from the carbonate rock The …


Basalt-Co2-Brine Wettability At Storage Conditions In Basaltic Formations, Stefan Iglauer, Ahmed Zarzor Al-Yaseri, Domenik Wolff-Boenisch Jan 2020

Basalt-Co2-Brine Wettability At Storage Conditions In Basaltic Formations, Stefan Iglauer, Ahmed Zarzor Al-Yaseri, Domenik Wolff-Boenisch

Research outputs 2014 to 2021

© 2020 Elsevier Ltd CO2 geo-storage in basaltic formations has recently been demonstrated as a viable solution to rapidly sequester and mineralize CO2. In case CO2 is injected into such basalt reservoirs in supercritical form, a two-phase system (reservoir brine and supercritical CO2) is created, and it is of key importance to specify the associated CO2-basalt wettability so that fluid distributions and CO2 flow through the reservoir can be predicted. However, there is a serious lack of data for basalt CO2-wettability. We therefore measured water contact angles on basalt substrates in CO2 atmosphere. The results indicate that at shallow depth …


Reversible And Irreversible Adsorption Of Bare And Hybrid Silica Nanoparticles Onto Carbonate Surface At Reservoir Condition, Zain-Ul-Abedin Arain, Sarmad Al-Anssari, Muhammad Ali, Shoaib Memon, Masood Ahmed Bhatti, Christopher Lagat, Mohammad Sarmadivaleh Jan 2020

Reversible And Irreversible Adsorption Of Bare And Hybrid Silica Nanoparticles Onto Carbonate Surface At Reservoir Condition, Zain-Ul-Abedin Arain, Sarmad Al-Anssari, Muhammad Ali, Shoaib Memon, Masood Ahmed Bhatti, Christopher Lagat, Mohammad Sarmadivaleh

Research outputs 2014 to 2021

© 2020 Southwest Petroleum University Realistic implementation of nanofluids in subsurface projects including carbon geosequestration and enhanced oil recovery requires full understanding of nanoparticles (NPs) adsorption behaviour in the porous media. The physicochemical interactions between NPs and between the NP and the porous media grain surface control the adsorption behavior of NPs. This study investigates the reversible and irreversible adsorption of silica NPs onto oil-wet and water-wet carbonate surfaces at reservoir conditions. Each carbonate sample was treated with different concentrations of silica nanofluid to investigate NP adsorption in terms of nanoparticles initial size and hydrophobicity at different temperatures, and pressures. …


In Situ Wettability Investigation Of Aging Of Sandstone Surface In Alkane Via X-Ray Microtomography, Nilesh Kumar Jha, Maxim Lebedev, Stefan Iglauer, Jitendra S. Sangwai, Mohammad Sarmadivaleh Jan 2020

In Situ Wettability Investigation Of Aging Of Sandstone Surface In Alkane Via X-Ray Microtomography, Nilesh Kumar Jha, Maxim Lebedev, Stefan Iglauer, Jitendra S. Sangwai, Mohammad Sarmadivaleh

Research outputs 2014 to 2021

© 2020 by the authors. Licensee MDPI, Basel, Switzerland. Wettability of surfaces remains of paramount importance for understanding various natural and artificial colloidal and interfacial phenomena at various length and time scales. One of the problems discussed in this work is the wettability alteration of a three-phase system comprising high salinity brine as the aqueous phase, Doddington sandstone as porous rock, and decane as the nonaqueous phase liquid. The study utilizes the technique of in situ contact angle measurements of the several 2D projections of the identified 3D oil phase droplets from the 3D images of the saturated sandstone miniature …


Experimental Investigation Into L-Arg And L-Cys Eco-Friendly Surfactants In Enhanced Oil Recovery By Considering Ift Reduction And Wettability Alteration, Hamed Foroughi Asl, Ghasem Zargar, Abbas Khaksar Manshad, Mohammad Ali Takassi, Jagar A. Ali, Alireza Keshavarz Jan 2020

Experimental Investigation Into L-Arg And L-Cys Eco-Friendly Surfactants In Enhanced Oil Recovery By Considering Ift Reduction And Wettability Alteration, Hamed Foroughi Asl, Ghasem Zargar, Abbas Khaksar Manshad, Mohammad Ali Takassi, Jagar A. Ali, Alireza Keshavarz

Research outputs 2014 to 2021

Surfactant flooding is an important technique used to improve oil recovery from mature oil reservoirs due to minimizing the interfacial tension (IFT) between oil and water and/or altering the rock wettability toward water-wet using various surfactant agents including cationic, anionic, non-ionic, and amphoteric varieties. In this study, two amino-acid based surfactants, named lauroyl arginine (l-Arg) and lauroyl cysteine (l-Cys), were synthesized and used to reduce the IFT of oil–water systems and alter the wettability of carbonate rocks, thus improving oil recovery from oil-wet carbonate reservoirs. The synthesized surfactants were characterized using Fourier transform infrared spectroscopy and nuclear magnetic resonance analyses, …


Effect Of Environment-Friendly Non-Ionic Surfactant On Interfacial Tension Reduction And Wettability Alteration; Implications For Enhanced Oil Recovery, Omid Mosalman Haghighi, Ghasem Zargar, Abbas Khaksar Manshad, Muhammad Ali, Mohammad Ali Takassi, Jagar A. Ali, Alireza Keshavarz Jan 2020

Effect Of Environment-Friendly Non-Ionic Surfactant On Interfacial Tension Reduction And Wettability Alteration; Implications For Enhanced Oil Recovery, Omid Mosalman Haghighi, Ghasem Zargar, Abbas Khaksar Manshad, Muhammad Ali, Mohammad Ali Takassi, Jagar A. Ali, Alireza Keshavarz

Research outputs 2014 to 2021

© 2020 by the authors. Licensee MDPI, Basel, Switzerland. Production from mature oil reservoirs can be optimized by using the surfactant flooding technique. This can be achieved by reducing oil and water interfacial tension (IFT) and modifying wettability to hydrophilic conditions. In this study, a novel green non-ionic surfactant (dodecanoyl-glucosamine surfactant) was synthesized and used to modify the wettability of carbonate reservoirs to hydrophilic conditions as well as to decrease the IFT of hydrophobic oil-water systems. The synthesized non-ionic surfactant was characterized by Fourier transform infrared spectroscopy (FTIR) and chemical shift nuclear magnetic resonance (HNMR) analyses. Further pH, turbidity, density, …


Co 2 -Wettability Of Sandstones Exposed To Traces Of Organic Acids: Implications For Co 2 Geo-Storage, Muhammad Ali, Muhammad Arif, Muhammad Faraz Sahito, Sarmad Al-Anssari, Alireza Keshavarz, Ahmed Barifcani, Linda Stalker, Mohammad Sarmadivaleh, Stefan Iglauer Jan 2019

Co 2 -Wettability Of Sandstones Exposed To Traces Of Organic Acids: Implications For Co 2 Geo-Storage, Muhammad Ali, Muhammad Arif, Muhammad Faraz Sahito, Sarmad Al-Anssari, Alireza Keshavarz, Ahmed Barifcani, Linda Stalker, Mohammad Sarmadivaleh, Stefan Iglauer

Research outputs 2014 to 2021

Wettability of CO 2 -brine-mineral systems plays a vital role during geological CO 2 -storage. Residual trapping is lower in deep saline aquifers where the CO 2 is migrating through quartz rich reservoirs but CO 2 accumulation within a three-way structural closure would have a high storage volume due to higher CO 2 saturation in hydrophobic quartz rich reservoir rock. However, such wettability is only poorly understood at realistic subsurface conditions, which are anoxic or reducing. As a consequence of the reducing environment, the geological formations (i.e. deep saline aquifers) contain appreciable concentrations of various organic acids. We thus demonstrate …


Local Instabilities During Capillary-Dominated Immiscible Displacement In Porous Media, Yang Liu, Stefan Iglauer, Jianchao Cai, Mohammad A. Amooie, Chaozhong Qin Jan 2019

Local Instabilities During Capillary-Dominated Immiscible Displacement In Porous Media, Yang Liu, Stefan Iglauer, Jianchao Cai, Mohammad A. Amooie, Chaozhong Qin

Research outputs 2014 to 2021

Fully understanding the mechanism of pore-scale immiscible displacement dominated by capillary forces, especially local instabilities and their influence on flow patterns, is essential for various industrial and environmental applications such as enhanced oil recovery, CO2 geo-sequestration and remediation of contaminated aquifers. It is well known that such immiscible displacement is extremely sensitive to the fluid properties and pore structure, especially the wetting properties of the porous medium which affect not only local interfacial instabilities at the micro-scale, but also displacement patterns at the macro-scale. In this review, local interfacial instabilities under three typical wetting conditions, namely Haines jump events …