Engineering Commons^™

Spray-Dried Cellulose Nanofibril-Reinforced Polypropylene Composites For Extrusion-Based Additive Manufacturing, Lu Wang

Electronic Theses and Dissertations

Compared to conventional manufacturing process, additive manufacturing (AM) offers free-form design, lighter and more ergonomic products, short lead time and less waste. Extrusion-based AM can be used to print thermoplastics. However, extrusion-based AM has processing challenges in printing semi-crystalline thermoplastics, for instance, polypropylene (PP). Cellulose nanofibrils (CNF) are one type of cellulose nanofibers that are produced from pulp fibers. CNF has extraordinary properties which make it an ideal candidate to reinforce polymers. Spray-dried CNF (SDCNF) is able to be incorporated into thermoplastic matrices without modifying conventional processing procedures.

The mechanical properties of 3D printed plastic parts have been considered significantly …

Production Of Bio-Oil With Different Oxygen Content And Characterization Of Catalytic Upgrading To Transportation Fuel, Mubarak Mohammed Khlewee

Electronic Theses and Dissertations

The world’s increasing population requires an increase in transportation fuel production. The lack of production of transportation fuels due to the shortage of fossil fuel resources combined with concerns about global emissions of carbon dioxide from fossil fuel combustion are the two major issues that have driven researchers to actively pursue alternative sources for oil production. Biomass is being considered as an alternative feedstock to produce fuel and chemicals due to its abundance and renewability. It has many features that make it suitable as a source of transportation fuel production. However, the bio-oil produced by the fast pyrolysis process has …

Dynamic Modeling And Extreme Tension Analysis Of Mooring System For A Floating Offshore Wind Turbine, Wei Ting Hsu

Electronic Theses and Dissertations

For offshore wind industry, exploiting the dynamic behaviors of mooring lines is of increasing importance in floating offshore wind turbine (FOWT) mooring system design. Currently, the design philosophy for structures and moorings is based on principles and practices adopted in offshore oil and gas, including mooring systems that are optimized for applications in deeper waters. However, the design of FOWT mooring systems is facing several challenges, including installation costs, the stability of light-weight minimalistic platforms, and shallow water depths (50-300m). The extreme tension in mooring lines of a light displacement platform in shallow water is dominated by snap loads. Hence …

Modeling Of A Head - Neck Assembly Drop Tower Impact Test Using Abaqus, Hussein Sharqi Owaid

Electronic Theses and Dissertations

There are numerous potential causes of traumatic brain injury (TBI) and concussions, including traffic accidents, contact during sports and falls. Protection from these injuries is paramount because of the problems that result from TBI, such as loss of thinking and memory capability. Head impact from falls, especially in elderly, can also result in severe to fatal injury and some effects of brain injury are often not visible. For these reasons and more a need exists for protective head gear that can keep persons safe during at risk physical activity and that can protect fall prone persons from accidental injuries. Part …

Habitat Use Of Blacktip Sharks (Carcharhinus Limbatus) At Fishing Piers, Kelsey L. Spencer

Electronic Theses and Dissertations

Blacktip sharks (Carcharhinus limbatus) can be observed near fishing piers throughout the summer along the northeast coast of South Carolina. These piers attract and support a wide variety of potential prey and sharks are able to forage on fishers’ discards with minimal energetic cost. I tagged 12 blacktip sharks with acoustic transmitters, monitored piers with acoustic receivers, and conducted pier-creel surveys to determine the habitat use of blacktip sharks at fishing piers, factors that influenced residence time and presence/absence at piers, and any cyclical patterns in visits to piers. Data were analyzed with pier association indices (PAI), mixed models, and …

Cellulose Nanofiber-Reinforced Impact Modified Polypropylene: Assessing Material Properties From Fused Layer Modeling And Injection Molding Processing, Jordan Elliott Sanders

Electronic Theses and Dissertations

The purpose of this research was to investigate the use of cellulose nanofibers (CNF) compounded into an impact modified polypropylene (IMPP) matrix. A IMPP was used because it shrinks less than a PP homopolymer during FLM processing. An assessment of material properties from fused layer modeling (FLM), an additive manufacturing (AM) method, and injection molding (IM) was conducted. Results showed that material property measurements in neat PP were statistically similar between IM and FLM for density, strain at yield and flexural stiffness. Additionally, PP plus the coupling agent maleic anhydride (MA) showed statistically similar results in comparison of IM and …

Operational Limits Of Blade Coating With High Aspect Ratio Pigments, Lisa Weeks

Electronic Theses and Dissertations

During the blade coating of paper, operational issues such as stalagmite formation, scratches or spits can develop at high solids content and high web speeds. For coatings that contain high aspect ratio pigments, these difficulties appear at lower solids concentrations and slower machine speeds than with more spherical shaped pigments. These operational issues are important because plate shaped particles have good properties in publication and barrier grades. A number of possible mechanisms have been described in the literature, but a clear cause has not been established nor have methods to estimate the operational limits been proposed.

The influence of particle …

A Framework For Clustering And Adaptive Topic Tracking On Evolving Text And Social Media Data Streams., Gopi Chand Nutakki

Electronic Theses and Dissertations

Recent advances and widespread usage of online web services and social media platforms, coupled with ubiquitous low cost devices, mobile technologies, and increasing capacity of lower cost storage, has led to a proliferation of Big data, ranging from, news, e-commerce clickstreams, and online business transactions to continuous event logs and social media expressions. These large amounts of online data, often referred to as data streams, because they get generated at extremely high throughputs or velocity, can make conventional and classical data analytics methodologies obsolete. For these reasons, the issues of management and analysis of data streams have been researched extensively …

Queue Stability Analysis In Network Coded Wireless Multicast., Nadieh Mohamadi-Moghadam

Electronic Theses and Dissertations

In this dissertation queue stability in wireless multicast networks with packet erasure channels is studied. Our focus is on optimizing packet scheduling so as to maximize throughput. Specifically, new queuing strategies consisting of several sub-queues are introduced, where all newly arrived packets are first stored in the main sub-queue on a first-come-first-served basis. Using the receiver feedback, the transmitter combines packets from different sub-queues for transmission. Our objective is to maximize the input rate under the queue stability constraints. Two packet scheduling and encoding algorithms have been developed. First, the optimization problem is formulated as a linear programming (LP) problem, …

Material Properties Design Using Simulations And Experiments For Powder Injection Molding Of Lead Zirconate Titanate (Pzt)., Bhushan Pramod Bandiwadekar

Electronic Theses and Dissertations

Powder injection molding (PIM) process simulations can be performed to minimize the number of injection molding experiments by estimating material properties necessary for PIM simulations. In current work, lead zirconate titanate (PZT) powder-polymer binder feedstock was compounded for 45 vol. % and 52 vol. % solids loading. PIM experiments on designed micro-pillar array geometry were performed using 52 vol. % PZT. Using PIM experiments results as basis, PIM simulations were performed on designed micro-pillar array geometries to understand the effectiveness of PIM simulations with the use of estimated feedstock properties in predicting molding behavior that have micro-features. Additionally, PIM simulations …

Control Of Power Electronic Interfaces In Distributed Generation., Mohammad Mohebbi

Electronic Theses and Dissertations

Renewable energy has gained popularity as an alternative resource for electric power generation. As such, Distributed Generation (DG) is expected to open new horizons to electric power generation. Most renewable energy sources cannot be connected to the load directly. Integration of the renewable energy sources with the load has brought new challenges in terms of the system’s stability, voltage regulation and power quality issues. For example, the output power, voltage and frequency of an example wind turbine depend on the wind speed, which fluctuate over time and cannot be forecasted accurately. At the same time, the nonlinearity of residential electrical …

Artificial Olfactory System For Multi-Component Analysis Of Gas Mixtures., Alexander Aleksandrovich Larin

Electronic Theses and Dissertations

Gas analysis is an important part of our world and gas sensing technology is becoming more essential for various aspects of our life. A novel approach for gas mixture analysis by using portable gas chromatography in combination with an array of highly integrated and selective metal oxide (MOX) sensors has been studied. We developed a system with small size (7 x 13 x 16 inches), low power consumption (~10 W) and absence of special carrier gases designed for portable field analysis (assuming apriori calibration). Low ppb and even sub-ppb level of detection for some VOCs was achieved during the analysis …

Testing And Modeling Of The Thixotropic Behavior Of Cementitious Materials., Bashir Hasanzadeh

Electronic Theses and Dissertations

During construction, concrete goes under various operations. It is normally transported to the job site, be placed and consolidated in the formwork, etc. The easiness and quality of these operations are very much related to the intrinsic rheological properties of concrete. Therefore, a good understanding of rheological behavior of concrete under various conditions are needed. Thixotropy is an important part of rheology. The thixotropic behaviors of concrete can be good representatives of its flow behaviors on the job site. For example, the breakdown aspect of thixotropy can help to explain how its flow behavior can impact concrete pumping and its …

Fused Filament Fabrication 3d Printing Using Low-Melting Alloys., Nirupama Warrier

Electronic Theses and Dissertations

Fused Filament Fabrication (FFF) 3D printing technology has been a popular method of creating prototypes using plastics in the timeliest and most affordable manner for electronic, automotive, and biomedical applications. 3D printing of metals and alloys using FFF technology could provide low-cost alternatives and solutions to the Laser-Powder Bed Fusion Process (L-PBF) and Binder Jetting processes (BJ). In current work, low melting alloys have been used as a starting material and evaluated for FFF 3D printing using two methodologies. In the first methodology, Sn60Bi40 alloy in the form of wire was used as the feedstock for FFF extrusion and process …

Design, Development, And Characterization Of Breathforce : A Respiratory Training System For Patients With Spinal Cord Injuries., Kevin L Tran

Electronic Theses and Dissertations

Pulmonary and cardiovascular dysfunction are consistently reported as the leading causes of morbidity and mortality among the 1,275,000 people who are living with chronic spinal cord injury (SCI) in the United States. Respiratory-cardiovascular complications from neurological disorders (primarily COPD and sleep apnea) are currently the number one cause of death and disability in the US.

The main goal of this project is to develop an inspiratory-expiratory training device for use in the rehabilitation of patients with respiratory motor and cardiovascular deficits that incorporates existing technologies and promotes successful training methodologies performed at the clinic and at home.

An embedded microprocessor …

Design, Analysis, And Application Of A Cellular Material/Structure Model For Metal Based Additive Manufacturing Process., Shanshan Zhang

Electronic Theses and Dissertations

Powder bed fusion additive manufacturing (PBF-AM) has been broadly utilized to fabricate lightweight cellular structures, which have promising potentials in many engineering applications such as biomedical prosthesis, aerospace, and architectural structures due to their high performance-to-weight ratios and unique property tailorabilities. To date, there is still a lack of adequate understanding of how the cellular materials are influenced by both the geometry designs and process parameters, which significantly hinders the effective design of cellular structures fabricated by PBF-AM for critical applications. This study aims to demonstrate a cellular structure design methodology that integrates geometrical design and process-material property designs. Utilizing …

A Novel Approach To Assess Minimally Invasive Surgical Device Failure Utilizing Adverse Event Outcome Severity And Design Complexity., Marie K. Riggs

Electronic Theses and Dissertations

Medical device failure and misuse have the potential to cause serious injury and death. Given the intricate nature of the instruments utilized specifically in minimally invasive surgery (MIS), users and manufacturers of surgical devices share a responsibility in preventing user error and device failure. A novel approach was presented for the evaluation of minimally invasive device failures, which involved assessing the severity of adverse event outcomes associated with the failures modes and investigating aspects of the devices’ design that may contribute to failure. The goals of this research were to 1) characterize the design attributes, failure modes, and adverse events …

Geophysical Delineation Of Megaporosity And Fluid Migration Pathways For Geohazard Characterization Within The Delaware Basin, Culberson County, Texas, Jonathan David Woodard

Electronic Theses and Dissertations

ABSTRACT

Differential dissolution of gypsum karst within the Delaware Basin poses a significant threat to infrastructure that society depends on. The study area is located in Culberson County, Texas and traverses a distance of approximately 54 kilometers along RM 652 within the Gypsum Plain which is situated on the northern margin of the Chihuahua Desert and includes outcrops of Castile and Rustler strata that host karst geohazards. Regions of karst geohazard potential have been physically surveyed proximal to the study area in evaporites throughout the Castile Formation outcrop; minimal hazards, in comparison to the Castile Formation, have been documented in …

Water Chemistry Dynamics In Four Vernal Pools In Maine, Usa, Lydia H. Kifner

Electronic Theses and Dissertations

Vernal pools are small seasonal wetlands that are a common landscape feature that contribute to biodiversity in northeastern North American forests. However, even basic information about their biogeochemical functions, such as carbon cycling, is limited. Dissolved gas concentrations (CH₄, CO₂) and other water chemistry parameters were monitored weekly at the bottom and surface of four vernal pools in central and eastern Maine, USA, from April to August 2016. The vernal pools were supersaturated with respect to CH₄ and CO₂ at all sampling dates and locations. Concentrations of dissolved CH₄ and CO₂ ranged …

Transformation Of Nonlinear Waves In The Presence Of Wind, Current, And Vegetation, Haifei Chen

Electronic Theses and Dissertations

Accurate prediction of extreme wave events is crucial for the safe maritime activities and offshore operations. Improved knowledge of wave dissipation mechanisms due to breaking and vegetation leads to accurate wave forecast, protecting life and property along the coast. The scope of the thesis is to examine the wave transformations in the presence of wind, current, and vegetation, using a two-phase flow solver based on the open-source platform OpenFOAM. The Reynolds-Averaged Navier-Stokes (RANS) equations are coupled with a Volume of Fluid (VOF) surface capturing scheme and a turbulence closure model. This RANS-VOF model is adapted to develop a numerical wind-wave-current …

Heterogenization Of Complexes With Redox Active Ligands For Hydrogen Evolution Reaction., Wuyu Zhang

Electronic Theses and Dissertations

Hydrogen fuel is a promising future energy carrier with many applications. Thermodynamically, 1.23 V is needed for the water electrolysis, which is a clean method to generate hydrogen gas. In practice excess potential is required, which is called overpotential, due to kinetic barriers. Catalysts to reduce the overpotential for the hydrogen evolution reaction (HER) include many homogeneous catalysts and heterogeneous catalysts. Heterogenization of homogeneous catalysts on electrode surfaces is an ideal way to study a catalyst by combining homogeneous and heterogeneous study together. In this dissertation, several characterization techniques have been employed, include cyclic voltammetry, linear sweep voltammetry, electrochemical impedance …

A Comparison Of Mean Age Theory And Residence Time Distributions In Mixed Systems., Nolan Theaker

Electronic Theses and Dissertations

A comparison between mean age theory and conventional residence time distributions over a range of quantified mixing levels was conducted using computational fluid dynamics (CFD). The system was a stirred tubular reactor. The model was validated by comparing computationally derived RTD curves with experimentally obtained RTD curves, with quantified differences less than 3%. Mixing was quantified using the Tanks-in-Series model. Mixing levels were set by varying flow rate and impeller rpm. Mean age distributions at the outlet, where experimental RTD’s were measured, were very narrow for all levels of mixing studied. RTD’s showed expected characteristics; a wider distribution and long …

Computational Prediction Of Conductivities Of Disk-Shaped Particulate Composites, Jian Qiu

Electronic Theses and Dissertations

The effective conductivities are determined for randomly oriented disk-shaped particles using an efficient computational algorithm based on the finite element method. The pairwise intersection criteria of disks are developed using a set of vector operations. An element partition scheme has been implemented to connect the elements on different disks across the lines of intersection. The computed conductivity is expressed as a function of the density and the size of the circular disks or elliptical plates. It is further expressed in a power-law form with the key parameters determined from curve fittings. The particle number and the trial number of simulations …

Integrated Environment And Proximity Sensing For Uav Applications, Shawn S. Brackett

Electronic Theses and Dissertations

As Unmanned Aerial Vehicle (UAV), or “drone” applications expand, new methods for sensing, navigating and avoiding obstacles need to be developed. The project applies an Extended Kalman Filter (EKF) to a simulated quadcopter vehicle though Matlab in order to estimate not only the vehicle state but the world state around the vehicle. The EKF integrates multiple sensor readings from range sensors, IMU sensors, and radiation sensors and combines this information to optimize state estimates. The result is an estimated world map to be used in vehicle navigation and obstacle avoidance.

The simulation handles the physics behind the vehicle flight. As …

Characterization Of Catalysts For Hydrodeoxygenation Of Bio-Oils Using Phenol As A Model Compound, Abdulazeez Mohammed Khlewee

Electronic Theses and Dissertations

Due to the environmental considerations, depletion of fossil fuel reserves and fluctuating non-renewable fuel price, converting non-edible lignocellulosic biomass into renewable energy resources has gained significant importance. Phenol has been chosen as a model compound for catalytic screening because it is abundant in bio-oil composition and shows a high resistance to oxygen removal during hydrodeoxygenation (HDO) reactions. HDO of phenol produces chemicals that can be used as transportation fuels (Aromatics) or fuel additives. Theoretically, HDO of phenol has two distinct reduction pathways: direct deoxygenation (DDO) and hydrogenation (HYD). The previous results published by our group showed a precedent activity and …

So2-Alcohol-Water Fractionation Of Sugarcane Straw, Asif Sharazi

Electronic Theses and Dissertations

Climate change resulting from fossil fuels combustion is motivating researchers to explore feasible routes to convert renewable biomass into biofuels and biochemicals for a sustainable society. Typically, biofuel is produced from corn or sugarcane but both feedstocks compete with human food supply. Thus, lignocellulosics as renewable feedstock represent a more ethical and ecofriendly approach. Sugarcane straw (SCS) is a cheap and abundantly available feedstock which potentially can be used for biofuels/biochemicals production. It can also help to mitigate environmental and health problems resulting from conventional practice of SCS burning in the fields.

There are different biomass conversion technologies for production …

Characterization Of Paper Dusting, Gregory K. Yum

Electronic Theses and Dissertations

Dusting of paper in various printing and processing operations is a common problem. The dusting tendency of a paper is difficult to characterize with standard laboratory methods; there is currently no standard test available. As the trend to create grades with high filler content continues, the issue of dusting will remain important. The goal of this thesis was to explore various methods to characterize the dusting and linting in a laboratory environment with limited samples and time.

Techniques to cause and collect dust are compared that include a tape pull test, a bending test, and an abrasion test. Methods to …

Creating Renewable Tunable Polymers From Hydroxymethylfurfural, Meredith C. Allen

Electronic Theses and Dissertations

The research here deals with the conversion of 5-hydroxymethylfurfural (HMF) into a tunable polymer. HMF is a known derivative that can be acquired from biomass via hydrolysis of cellulose followed by isomerization and finally selective dehydration. The process considered here is being developed to create tunable polymers from HMF and involves several different steps, three of which are covered here. The first step, an etherification, is the reaction of HMF with an alcohol. This step is significant because in this step the R-group from the alcohol is added to HMF and the branching portion formed is carried over to the …

Structural Behavior Of Inflatable, Reinforced, Braided, Tubular Members, Joshua Clapp

Electronic Theses and Dissertations

The Hypersonic Inflatable Aerodynamic Decelerator (HIAD) system being developed by the National Aeronautics and Space Administration (NASA) is an inflatable structure composed of multiple, concentric, pressurized tori, load straps, and a thermal protection system. The HIAD overcomes limitations inherent with the use of rigid decelerators since the deployed diameter is much larger than the packed size, which makes it an enabling technology for new opportunities in space exploration. The HIAD is designed to decelerate and protect spacecraft during atmospheric re-entry. The objective of this research was to improve understanding of structural behavior of HIAD components through material testing, structural testing …

Window Inserts And The People Adopting Them: Building Sustainable Communities In Maine, Daniel Sean Mistro

Electronic Theses and Dissertations

Residents of Maine face a large monetary expense to heat their homes in the winter. In Maine it takes 540 gallons of heating oil each year to heat a typical home [1]. Interior window inserts may be a practical solution to improve comfort, save money, and consume less environmentally harmful fossil fuels during cold winter months. The window inserts discussed in this paper are custom measured to fit into a window and consist of a wooden frame that is wrapped in two layers of polyolefin film and weather stripped for a snug fit. Commercial inserts cost $20-$36/square foot, or approximately …