Engineering Commons^™

General Design Procedure For Free And Open-Source Hardware For Scientific Equipment, Shane W. Oberloier, Joshua M. Pearce

Department of Materials Science and Engineering Publications

Distributed digital manufacturing of free and open-source scientific hardware (FOSH) used for scientific experiments has been shown to in general reduce the costs of scientific hardware by 90–99%. In part due to these cost savings, the manufacturing of scientific equipment is beginning to move away from a central paradigm of purchasing proprietary equipment to one in which scientists themselves download open-source designs, fabricate components with digital manufacturing technology, and then assemble the equipment themselves. This trend introduces a need for new formal design procedures that designers can follow when targeting this scientific audience. This study provides five steps in the …

Preparation Of Nis2 Nanosheet And Its Application In Asymmetric Supercapacitor, Yuan-You Wang, Ya-Nan Liu, Dang-Qin Jin

Journal of Electrochemistry

In this work, the NiS₂ nanosheets have been synthesized using Ni(OH)₂ as a precursor through a sacrificial template method. The microstructure and chemical composition of as-prepared NiS₂ were characterized by XRD, EDS, BET, SEM and TEM techniques. The results showed that both Ni(OH)₂ and NiS₂ were composed of nanoplates. The electrochemical tests revealed that NiS₂ exhibited the high specific capacitance of 1067.3 F•g^-1 at a current density of 1 A•g^-1 and excellent rate performance. Furthermore, in order to evaluate the practical application of NiS₂, an asymmetric supercapacitor, NiS₂ as …

Effect Of Fe2+/Fe3+Interconvertion On Reduction Behavior Of Fe3+ In Acidic Electrolytes, Jian-Xin Qin, Feng Lin, Wen-Ping Liu, Chao Chen, Meng-De Ren

Journal of Electrochemistry

The influences of ferrous/ferric (Fe²⁺/Fe³⁺) interconvertion on electrochemical reduction and electrode reaction of Fe³⁺ were investigated by using linear sweep voltammetry, potentiostatic method and cyclic voltammetry (CV) in acidic electrolytes containing chloride ion (Cl^- ) and sulfate ion (SO₄^2-). It was shown that the reduction process of Fe³⁺/Fe²⁺ would take place in two independent stages: (1) the reduction of Fe³⁺ to Fe²⁺ at E=0.35V and (2) the co-precipitation of Fe²⁺ by forming Fe(OH)₂ (E≤-0.3 V) instead of Fe. The major effect of Fe^{2+ …}

Effect Of Peg-Coating On Properties Of Lithium-Sulfur Battery Cathode Material Containing Carbon Fiber Conductive Agent, Jie-Cheng Tan, Yan-Hong Tian, Xue-Jun Zhang, Kai-Le Fan

Journal of Electrochemistry

The composite materials contained high modulus carbon fiber (HMCF) were successfully prepared by employing a ball-milling process based on the coating treatment of polyethylene glycol (PEG), and their structures and morphologies were characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) techniques．The influences of PEG content on sulfur cathode capacity, cycle stability and rate performance were systematically studied. It was found that by the pre-coating of PEG, the cathode exhibited the high initial discharge specific capacity of 1312.5 mAh•g^-1 at a current rate of 0.2C, and the reversible discharge capacity of 650 mAh•g …

Effects Of Jet Milling And Classifying Process On The Performance Of Lifepo4/C In Full Batteries, Xing-Liang Liu, Mao-Ping Yang, Wei-Wei Wang, Yong Cao

Journal of Electrochemistry

The carbon coated lithium iron phosphate (LiFePO₄/C) composite cathode material was prepared by using iron phosphate process. The effects of jet milling and classifying process on the electrochemical performance of LiFePO₄/C cathode material in full batteries were investigted. Scanning electron microscopic analyses suggested that the globose secondary particles were crustily crushed during the jet milling and classifying process, which would further result in lower tap density and carbon content. The LiFeP₄/C composite cathode materials with different physical characteristics were further tested in full batteries to evaluate the electrochemical properties. The results showed no obvious …

Cobalt-Based Nitrogen-Doped Carbon Non-Noble Metal Catalysts For Oxygen Reduction Reaction, Meng-Xiu Jiang, Jing Zhang, Yue-Hua Li, Rong Zhang

Journal of Electrochemistry

Transition metal-nitrogen co-doped carbon catalysts have attracted significant attention because of their reasonable activity and remarkable selectivity toward oxygen reduction reaction (ORR) as cathodic reaction in fuel cells. However, the role of transition metal in the active sites of the catalysts still is uncertain. In this work, the Co_x-N_y/C-T catalysts were prepared with BP2000 as a carbon source, urea (Ur) as a nitrogen source and Co(OAc)₂•4H₂O as a metal precursor by a simple chemical method. Meanwhile, in order to optimize the ORR activity, the catalysts were synthesized with different amounts of Co …

Core-Shell Pd@Pt Ultrathin Nanowires As Durable Oxygen Reduction Electrocatalysts, Xin Wang, Yun-Jie Xiong, Liang-Liang Zou, Qing-Hong Huang, Zhi-Qing Zou, Hui Yang

Journal of Electrochemistry

This paper describes a simple CO-assisted reduction approach for the controllable synthesis of ultrathin Pd nanowires along the one-dimensional (1D) direction. Ultrathin Pt films from one to several atomic layers were successfully decorated onto ultrathin Pd nanowires by utilizing Cu UPD deposition, and followed by in-situ redox replacement reaction of UPD Cu by Pt. The core–shell structure and composition of the Pd@Pt ultrathin nanowires have been verified using transmission electron microscopy and energy dispersive X-ray spectrometry. The core–shell Pd@Pt ultrathin nanowires exhibited comparative electrocatalytic activity and improved durability for the oxygen reduction reaction in comparison with commercial Pt black. The …

Kinetics And Mechanism Toward Electrochemical Reductions Of Sodium Bromide And Methanol Over Iron Electrodes, Qun Liao, Shu-Feng Zhang, Wen-Hua Leng

Journal of Electrochemistry

It is of technological value and scientific interest to the electro-synthesis of ferrocene, conversion of carbon dioxide (CO₂) and organic electro-synthesis in non-aqueous solutions by investigating the kinetics and mechanism toward electrochemical reductions of sodium bromide (NaBr) and methanol over iron electrodes. However, few reports in the related researches are available. In this article, the kinetics and mechanism toward electrochemical reductions of NaBr and methanol over iron electrodes were examined in detail by carrying out the polarization curve and electrochemical impedance spectroscopic measurements. The results showed that methanol was the reactant, while Na⁺ ions were functioned only …

Engineering The Electrochemical Capacitive Properties Of Activated Carbon By Correct Selection Of Ionic-Liquid Electrolytes, Qiu-Hong Zhang, Bao-Shou Shen, Song-Lin Zuo, Xin-Yu Wei

Journal of Electrochemistry

In order to improve the electrochemical capacitive properties and to apply coconut shell activated carbon (AC) serving as electrode materials in ionic liquid (IL)-based supercapacitor (SC), the coconut shell AC material was re-activated using a steam as an activating agent in this work, forming a secondary AC (W-AC). The results showed that the specific capacitance of the W-AC electrode was much larger than that of the raw activated carbon electrode (R-AC) in 1-ethyl-3-methylimidazolium tetrafluoroborate ([EMIM]BF₄). The electrochemical techniques including cyclic voltammetry (CV), galvanostatic charge/discharge (GCD) measurement, and electrochemical impedance spectroscopy (EIS) were used to systematically study the capacitive …

Capacity Fading Analyses Of Lini 0.5Co 0.2Mn 0.3O2And Lini 0.5Co 0.2Mn 0.3O2/Lifepo4 Cathode Materials For Lithium-Ion Battery, Yi Hu, Xiang-Zhu He, Zhong-De Deng, Ling-Yong Kong, Wei-Li Shang

Journal of Electrochemistry

The LiNi _0.5Co _0.2Mn _0.3O₂/LiFePO₄ (NMC532/LFP) composite cathode material for lithium-ion battery was prepared by wet ball-milling. The capacity fading behaviors of LiNi _0.5Co _0.2Mn _0.3O₂ (NMC532) and LiNi _0.5Co _0.2Mn _0.3O₂/LiFePO₄ (NMC532/LFP) were analyzed by X-ray diffraction (XRD), scanning electron microscope (SEM), charge/discharge and electrochemical impedance spectroscopy (EIS) tests. The results indicated that the capacity retention values of NMC532/LFP were 97.80% and 86.48%, respectively, after 50 cycles and 60℃ high temperature storage. The NMC532/LFP exhibited better cycle performance and high temperature storage performance. …

Applications Of N-Methyl-N-Butyl-Pyrrolidinium Bromide And N-Methyl-N-Ethyl-Pyrrolidinium Bromide In Zn-Br Flow Batteries, Zhang Qi, Miao-Miao Zhang, Meng Lin

Journal of Electrochemistry

It is extremely important for battery performance and safety in Zn-Br flow battery to use quaternary ammonium salts as complex agents for bromine. In this work, the effects of electrolyte compositions and concentrations on the electrode reactions and battery performances were studied in the absence and presences of N-methyl-N-ethyl-pyrrolidinium bromide (MEP) or N-methyl-N-butyl-pyrrolidinium bromide (MBP). The conductivities in the electrolytes containing different constitutions and concentrations were measured by EIS method. The charge-discharge performance for the battery and the complex ability for bromine in different electrolytes were also investigated. The results showed that the electrolyte containing MBP was better than that …

Electroactivities Of Pd/Fe3O4-C Catalysts For Electro-Oxidation Of Methanol, Ethanol And Propanol, Tao Zou, Qing-Feng Yi, Yuan-Yuan Zhang, Xiao-Ping Liu, Guo-Rong Xu, Hui-Dong Nie, Xiu-Lin Zhou

Journal of Electrochemistry

Development of palladium (Pd) catalysts with high electroactivity for alcohol oxidation is significant for alcohol fuel cells. In this work, Pd nanoparticles were formed by sodium borohydride (NaBH₄) reduction method and subsequently deposited on the surface of carbon supported ferriferrous oxide (Fe₃O₄/C) composites to obtain the Pd/Fe₃O₄-C catalysts with different Fe₃O₄ loadings. Their transmission electron microscopic (TEM) images show that the Pd nanoparticles were uniformly dispersed on the Fe₃O₄/C. Electroactivities of the prepared Pd/Fe₃O₄-C catalysts toward oxidations of C1-C3 …

Luminescence Of Defects In The Structural Transformation Of Layered Tin Dichalcogenides, Peter Sutter, H.P. Komsa, A. V. Krasheninnikov, Y Huang, Eli A. Sutter

Department of Electrical and Computer Engineering: Faculty Publications

Layered tin sulfide semiconductors are both of fundamental interest and attractive for energy conversion applications. Sn sulfides crystallize in several stable bulk phases with different Sn:S ratios (SnS2, Sn2, S3, and SnS), which can transform into phases with a lower sulfur concentration by introduction of sulfur vacancies (VS). How this complex behavior affects the optoelectronic properties remains largely unknown but is of key importance for understanding light-matter interactions in this family of layered materials. Here, we use the capability to induce VS and drive a transformation between few-layer SnS2 and SnS by electron beam irradiation, combined with in-situ cathodoluminescence spectroscopy …

A Post-American World? Assessing The Cognitive And Attitudinal Impacts Of Challenges To American Exceptionalism, Jason A. Gilmore, Charles Rowling

Languages, Philosophy, and Communication Studies Faculty Publications

A number of voices have emerged in U.S. political discourse questioning the legitimacy of American exceptionalism, suggesting we are in a “post-American world.” Our research examines the effects that political messages that explicitly challenge American exceptionalism can have on U.S. public opinion. Drawing upon social identity theory, we find that explicit challenges to American exceptionalism significantly impact Americans’ views toward their own nation, their willingness to denigrate foreign publics, and their broader foreign policy preferences.

Inorganic Biodegradable Substrates For Devices And Systems, Chang-Soo Kim, Richard K. Brow, D. E. Day

Electrical and Computer Engineering Faculty Research & Creative Works

Disclosed are biodegradable glass substrates that are useful as functional elements of solid-state devices. In particular, biodegradable glass substrates having a rapidly degradable glass and a slowly degradable glass provide a structural platform that completely dissolves following a desired operational lifetime of devices such as implanted electronic devices, implanted sensor devices, and optical fibers.

Silver Photodiffusion Into Ge-Rich Amorphous Germanium Sulfide—Neutron Reflectivity Study, Y. Sakaguchi, H. Asaoka, M. Mitkova

Electrical and Computer Engineering Faculty Publications and Presentations

Silver diffuses into chalcogenide films upon light exposure, and the kinetics of photodiffusion has been a subject of various investigations because of the difficulties in the in situ determination of the time-dependent Ag reaction and diffusion development in the chalcogenide layers. In this paper, we report the results of time-resolved neutron reflectivity measurement of Ag/Ge₄₀S₆₀/Si substrates under light exposure to clarify the kinetics of Ag photodiffusion into Ge-rich Ge chalcogenides. It reveals that Ag ions diffuse all over the Ge chalcogenide host layer once Ag dissolves into the layer without forming a metastable reaction layer unlike …

Intelligent Advancements In Location Management And C-Ran Power-Aware Resource Allocation, Emad Ali Aqeeli

Electronic Thesis and Dissertation Repository

The evolving of cellular networks within the last decade continues to focus on delivering a robust and reliable means to cope with the increasing number of users and demanded capacity. Recent advancements of cellular networks such as Long-Term Evolution (LTE) and LTE-advanced offer a remarkable high bandwidth connectivity delivered to the users. Signalling overhead is one of the vital issues that impact the cellular behavior. Causing a significant load in the core network hence effecting the cellular network reliability. Moreover, the signaling overhead decreases the Quality of Experience (QoE) of users. The first topic of the thesis attempts to reduce …

Line Start Permanent Magnet Synchronous Motor For Multi Speed Application, Bikrant Poudel

University of New Orleans Theses and Dissertations

This thesis aims to design and develop LSPM motors capable of operating in two distant synchronous speeds with good starting torque and steady state characteristics for variety of industrial applications, in particular offshore and maritime applications. The proposed designs are based on variable pole numbers for the stator and the rotor. The stator winding consist of two independent windings with different pole numbers to switch the winding and change the operating pole count for low and high speed applications. For the motor to operate in these two distinct operating speeds, the rotor must be capable of creating two different magnetic …

Parameter Estimation Technique For Models In Pss/E Using Real-Time Data And Automation, Malavika Vasudevan Menon

University of New Orleans Theses and Dissertations

The purpose of this thesis is to use automation to create appropriate models in PSS/E with the data from Hardware-in-Loop real-time simulations. With the increase in technology of power electronics, the use of High Voltage Direct Current Technology and Flexible Alternating Current Transmission System devices in the electrical power system have increased tremendously. Static Var Compensators are widely used and it is important to have accurate and reliable models for studies relating to power systems planning and interaction. An automation method is proposed to find the parameters of an SVC model in PSS/E with the data from the Hardware-in- loop …

Underwater Acoustic Signal Analysis Toolkit, Kirk Bienvenu Jr

University of New Orleans Theses and Dissertations

This project started early in the summer of 2016 when it became evident there was a need for an effective and efficient signal analysis toolkit for the Littoral Acoustic Demonstration Center Gulf Ecological Monitoring and Modeling (LADC-GEMM) Research Consortium. LADC-GEMM collected underwater acoustic data in the northern Gulf of Mexico during the summer of 2015 using Environmental Acoustic Recording Systems (EARS) buoys. Much of the visualization of data was handled through short scripts and executed through terminal commands, each time requiring the data to be loaded into memory and parameters to be fed through arguments. The vision was to develop …

Femtosecond Laser Micromachining Of Low-Temperature Co-Fired Ceramic And Glass Fiber Reinforced Polymer Printed Circuit Boards Materials, Raif Farkouh

Department of Electrical and Computer Engineering: Dissertations, Theses, and Student Research

Low-temperature co-fired ceramic (LTCC), and glass fiber reinforced polymer (GFRP) printed circuit boards (PCBs) are two materials used for the packaging of electronics. The excellent mechanical and electrical properties of LTCC, combined with the ability to embed passive components offer superior radio frequency (RF) performance and device miniaturization for high-frequency applications. Due to its unique properties, LTCC provides superior performance in applications as diverse as military radar, imaging systems, advanced automotive sensing, telecommunications, and satellites. The use of LTCC in these applications has created a demand for the micromachining of holes, channels, and cavities with specific geometries and structures. Likewise, …

Harmonics Elimination In Three Phase Cascade H-Bridge Multilevel Inverter Using Virtual Stage Pwm, Amro Quedan

Durham School of Architectural Engineering and Construction: Dissertations, Thesis, and Student Research

The multilevel inverters are one of the great solutions that are proposed to satisfy the demand for high-power application and the significant integration of renewable energy. The conversion process from DC to AC must be done at high efficiency to decrease the energy loss and to ensure the electric grid power quality. The Total Harmonic Distortion (THD) is the most important feature that indicates the efficiency of the conversion process. In this research, due to the advantages of the cascade H-bridge inverter over other topologies, it has been used with the virtual stage PWM technique to investigate two different methods …

Algorithm For Computational Imaging On A Real-Time Hardware, Manish Bhattarai

Electrical and Computer Engineering ETDs

DRAMATIC advances in the field of computational and medical imaging over the past decades have enabled many critical applications such as night vision, medical diagnosis, quality control, and remote sensing. The increasing demand for image quality and its fidelity requires an increase in pixel count and a sophisticated post-processing mechanism to efficiently store, transmit, and analyze this massive data. There is an inherent trade-off between the generation of big data by such imaging systems and efficiency in extraction of useful information within real-time constraints, limiting the efficacy of such sensors in real-time decision-making systems. The traditional imaging system gets burdened …

Displacement Measurement Using A Laser Doppler Vibrometer Mounted On An Unmanned Aerial Vehicles, Piyush Garg

Electrical and Computer Engineering ETDs

The railroad network in the united states is one of the best in the world, handling around 40 percent of all US freight movement. To maintain the serviceability and cost-effective operation of the railway infrastructure, regular monitoring is essential. Bridges are a critical part of the railway infrastructure and their timely maintenance and repair are important. Measuring transverse bridge displacement under train loading can assist to determine the bridge condition. The traditional methods available for transverse displacement measurement include Linear Variable Differential Transducers (LVDT). However, irregular terrain, remote and inaccessible locations, and the height of railroad bridges make implementation of …

Tiled Time Delay Estimation In Mobile Cloud Computing Environments, Ruairí De Fréin

Conference papers

We present a tiled delay estimation technique in the context of Mobile Cloud Computing (MCC) environments. We examine its accuracy in the presence of multiple sources for (1) sub-sample delays and also (2) in the presence of phase-wrap around. Phase wrap-around is prevalent in MCC because the separation of acoustic sources may be large. We show that tiling a histogram of instantaneous phase estimates can improve delay estimates when phase-wrap around is sig- nificantly present and also when multiple sources are present. We report that error in the delay estimator is generally less than 5% of a sample, when the …

Ros-Enabled Framework For A Miniature Hexapod As A Mobile Robot Research Platform, Joseph Michael Kloeppel

Electrical and Computer Engineering ETDs

The purpose of this thesis is to investigate and develop a framework for connected six-legged robots which can be used as a Robotic Operating System (ROS) based research platform. The research presented aims to purvey the necessary engineering and scientific steps needed to evolve a consumer-grade connected toy into a fully functioning and highly capable robotic system. Such a platform can be used to simulate and implement novel biologically inspired swarm research. Crawling robots have the advantage of being able to scale terrains which wheeled mobile robots may not and possess many interesting characteristics. The miniROaCH, miniature ROS-enabled and Crawling …

A Low Power High Speed Mobile Memory I/O Interface Using Reconfigurable Multi-Band Multi-Modulation Signaling, Yue Yu

Electrical Engineering Theses and Dissertations

This research mainly focuses on the design of a novel memory I/O interface with high bandwidth and high energy-efficient for mobile computing systems in order to dramatically enhance the circuit and system bandwidth and power efficiency. The proposed memory I/O interface, exploiting multi-modulation and multi-band signaling, is capable of supporting simultaneous bidirectional data transition of 4 separate data streams across a single-ended off-chip transmission line to achieve both high speed data rate and low power consumption. This multi-band multi-modulation interface (MMI) consists of multiple RF-band transceivers which utilize ASK modulation, and baseband transceivers which utilize 4-PAM modulation to increase the …

Development Of A Curriculum Analysis And Simulation Library With Applications In Curricular Analytics, Michael S. Hickman

Electrical and Computer Engineering ETDs

Higher education institutions are currently investing significant resources in attempts to improve student success by improving instruction quality, implementing tutoring programs, and providing other services to help students. While these are all worth- while, one area that tends to be overlooked is the structure of the curricula that are offered. When viewing curricula as data, or more specifically, a graph, it is intuitive to see how its structure can influence a student’s ability to move through it. How- ever, there are currently no tools to analyze a curriculum’s structural properties and how they might affect student success. This thesis describes …

Reconstruction Algorithms For Novel Joint Imaging Techniques In Pet, Homayoon Ranjbar

McKelvey School of Engineering Theses & Dissertations

Positron emission tomography (PET) is an important functional in vivo imaging modality with many clinical applications. Its enormously wide range of applications has made both research and industry combine it with other imaging modalities such as X-ray computed tomography (CT) or magnetic resonance imaging (MRI). The general purpose of this work is to study two cases in PET where the goal is to perform image reconstruction jointly on two data types.

The first case is the Beta-Gamma image reconstruction. Positron emitting isotopes, such as ¹¹C, ¹³N, and ¹⁸F, can be used to label molecules, and tracers, such …

Bio-Inspired Multi-Spectral And Polarization Imaging Sensors For Image-Guided Surgery, Nimrod Missael Garcia

McKelvey School of Engineering Theses & Dissertations

Image-guided surgery (IGS) can enhance cancer treatment by decreasing, and ideally eliminating, positive tumor margins and iatrogenic damage to healthy tissue. Current state-of-the-art near-infrared fluorescence imaging systems are bulky, costly, lack sensitivity under surgical illumination, and lack co-registration accuracy between multimodal images. As a result, an overwhelming majority of physicians still rely on their unaided eyes and palpation as the primary sensing modalities to distinguish cancerous from healthy tissue. In my thesis, I have addressed these challenges in IGC by mimicking the visual systems of several animals to construct low power, compact and highly sensitive multi-spectral and color-polarization sensors. I …