Engineering Commons^™

Catalyzed Oxidation Of Ig-110 Nuclear Graphite By Simulated Fission Products Ag And Pd Nanoparticles, Junhua Jiang, John Stempien, Yaqiao Wu

Materials Science and Engineering Faculty Publications and Presentations

To evaluate the stability of nuclear materials in high temperature gas reactors under air ingress conditions, catalytic oxidation of IG-110 graphite by two simulated fission products, metallic Pd and Ag, was studied in oxidative atmosphere and at temperatures up to 1000 °C using an integrated furnace, mass spectroscopy and infrared spectroscopy system. Transmission electron microscopy and X-ray diffraction studies show that Pd and Ag nanoparticles were successfully introduced onto powdery IG-110 graphite through an impregnation and subsequent heat-treatment process. The combined mass spectroscopy and infrared spectroscopy methods allow simultaneous analysis of two gaseous products, CO and CO₂, and …