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Mathematical Simulations Of Reactors For Catalytic Conversion Of Methane To Syngas With Forced Concentration Cycling, Krzysztof Gosiewski
Mathematical Simulations Of Reactors For Catalytic Conversion Of Methane To Syngas With Forced Concentration Cycling, Krzysztof Gosiewski
Krzysztof Gosiewski
In this paper simulation results are presented concerning the partial catalytic oxidation of methane (PCOM) in a reactor with forced composition cycling and packed with a pelletized Pt/MgO catalyst. The reactor operates in two cycles, namely, the ‘hot’ cycle, H, during which mainly the reactants of the strongly exothermal complete combustion reaction (CH4 and O2) are supplied, and the ‘cold’cycle , C, in which mainly the components of the endothermal reforming reactions are introduced (CH4 and H2O or, optionally CO2). The simulations are supplemented with a thermodynamic analysis of the conditions of permanent carbon deposits forming in such a reactor. …