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Articles

1997

Azobenzene polyesters

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Diffraction From Polarization Holographic Gratings With Surface Relief In Side-Chain Azobenzene Polyesters, Izabela Naydenova, Ludmila Nikolova, Todor Todorov, N.C.R. Holme, P.S. Ramanujam, S. Hvilsted Jan 1997

Diffraction From Polarization Holographic Gratings With Surface Relief In Side-Chain Azobenzene Polyesters, Izabela Naydenova, Ludmila Nikolova, Todor Todorov, N.C.R. Holme, P.S. Ramanujam, S. Hvilsted

Articles

We investigate the polarization properties of holographic gratings in side-chain azobenzene polyesters in which an anisotropic grating that is due to photoinduced linear and circular birefringence is recorded in the volume of the material and a relief grating appears on the surface. A theoretical model is proposed to explain the experimental results, making it possible to understand the influence of the different photoinduced effects. It is shown that at low intensity the polarization properties of the diffraction at these gratings are determined by the interaction of the linear and circular photobirefringences, and at larger intensity the influence of the surface …