Digital Commons Network^™

2016 Fall - Commencement Program, Office Of The Registrar, East Tennessee State University

ETSU Commencement Ceremonies and Programs

No abstract provided.

Mole Street Journal, December 2016, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

Microstructural Evolution During The Homogenization Heat Treatment Of 6xxx And 7xxx Aluminum Alloys, Pikee Priya

Open Access Dissertations

Homogenization heat treatment of as-cast billets is an important step in the processing of aluminum extrusions. Microstructural evolution during homogenization involves elimination of the eutectic morphology by spheroidisation of the interdendritic phases, minimization of the microsegregation across the grains through diffusion, dissolution of the low-melting phases, which enhances the surface finish of the extrusions, and precipitation of nano-sized dispersoids (for Cr-, Zr-, Mn-, Sc-containing alloys), which inhibit grain boundary motion to prevent recrystallization. Post-homogenization cooling reprecipitates some of the phases, changing the flow stress required for subsequent extrusion. These precipitates, however, are deleterious for the mechanical properties of the alloy …

Computational Quantum Chemistry Studies Of The Stabilities Of Radical Intermediates Formed During The Oxidation Of Melatonin, Constance E. Warden

Electronic Theses and Dissertations

Melatonin, a nontoxic natural antioxidant, is of interest as a possible spin trap for use in spectroscopic methods to observe and identify short-lived free radicals, which have been linked to oxidative stress that may result in serious health problems. However, the reaction mechanisms for the oxidation of melatonin to form the product N¹-acetyl-N²-formyl-5-methoxykynuramine are still not well understood. Computational quantum chemistry studies have been done on four proposed reaction mechanisms, involving the following major intermediate structures: a dioxetane, an epoxide, a melatonin radical cation, and a spin radical adduct. Molecular geometries were optimized at the …

Is It Scholarly? A Lesson Plan For Collaborative Chemistry Information Literacy, Barbara C. Harvey

Books and Contributions to Books

This chapter describes a lesson plan that incorporates information literacy into an introductory chemistry course. The learning outcomes of the activity include becoming familiar with the peer-review process, knowing how to locate original research articles based on “clues” in a general news article, and differentiating between popular and scholarly periodicals. Students work in small groups in a collaborative classroom setting. The activities of the lesson plan are mapped to the Framework for Information Literacy for Higher Education. The lesson plan is supported by a literature review outlining the importance of collaborative, active learning in STEM courses, and highlights the correlation …

Continuing The Career: An Oral History Of An Emeritus Professor, Kimberly Read

USF Tampa Graduate Theses and Dissertations

The purpose of this study was to describe and explain the perspectives of a professor emeritus regarding his life experiences in the discipline of chemistry and in a career dedicated to research, service and teaching. Another purpose, interwoven within the perspective of this one individual, was to explore the potential influence a professor emeritus can have on his institution, and the impact the institution, its changing culture, and its shifting priorities may have on a member of the professoriate dedicated to this chosen career path. The research guiding questions for this study were: (a) What elements of this professor emeritus’ …

The Role Of Low-Energy (≤ 20 Ev) Electrons In Astrochemistry, Michael C. Boyer, Nathalie Rivas, Audrey A. Tran, Clarissa A. Verish, Christopher R. Arumainayagam

Faculty Research and Scholarship

UV photon-driven condensed phase cosmic ice reactions have been the main focus in understanding the extraterrestrial synthesis of complex organic molecules. Low-energy (≤20 eV) electron-induced reactions, on the other hand, have been largely ignored. In this article, we review studies employing surface science techniques to study low-energy electron-induced condensed phase reactions relevant to astrochemistry. In particular, we show that low-energy electron irradiation of methanol ices leads to the synthesis of many of the same complex molecules formed through UV irradiation. Moreover, our results are qualitatively consistent with the hypothesis that high-energy condensed phase radiolysis is mediated by low-energy electron-induced reactions. …

Mole Street Journal, October 2016, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

Measurements By Controlled Meteorological Balloons In Coastal Areas Of Antarctica, Lars R. Hole, Alexis Pérez Bello, Tjarda J. Roberts, Paul B. Voss, Timo Vihma

Engineering: Faculty Publications

An experiment applying controlled meteorological (CMET) balloons near the coast of Dronning Maud Land, Antarctica, in January 2013 is described. Two balloons were airborne for 60 and 106 hours with trajectory lengths of 885.8 km and 2367.4 km, respectively. The balloons carried out multiple controlled soundings on the atmospheric pressure, temperature and humidity up to 3.3 km. Wind speed and direction were derived from the balloon drift. Observations were compared with radiosonde sounding profiles from the Halley Research Station, and applied in evaluating simulations carried out with the weather research and forecasting (WRF) mesoscale atmospheric model. The most interesting feature …

Pushing And Pulling Sara: A Case Study Of The Contrasting Influences Of High School And University Experiences On Engineering Agency, Identity, And Participation, Allison Godwin, Geoff Potvin

School of Engineering Education Faculty Publications

This manuscript reports on a longitudinal case study of how one woman, Sara, who had previously considered dropping out of high school authored strong mathematics and science identities and purposefully exhibited agency through her experiences in high school science. These experiences empowered her to choose an engineering major in college; however, her introductory university engineering experiences ultimately pushed her out of engineering. Drawing on critical agency theory, we argue that by paying careful attention to how and why women author their identities and build agency through their experiences in high school, we may gain insight into why women may choose …

Theoretical Study Of Photoelectrochemical Reactions And Ec-Sers On Spr Metallic Electrodes Of Silver And Gold, Yuan-Fei Wu, Ran Pang, Meng Zhang, Jian-Zhang Zhou, Bin Ren, Zhong-Qun Tian, De-Yin Wu

Journal of Electrochemistry

At present photoelectrochemistry has received much concern back to nanostructures of noble metals from semiconductor electrodes. This is due to the surface plasmon resonance (SPR) effect of metallic nanostructures, which can effectively convert the far-field light to the near-field light and concentrate the photonic energy to the local surface area with high energy density. Thus, the different enhancement mechanisms, such as the local optical field enhancement, the formation of light generated hot carriers (hot electron-hole pairs), or the photothermal effect, have been proposed in literatures. On the basis of the SPR enhancement effect, the surface-enhanced Raman spectroscopy (SERS) can be …

Mole Street Journal, August 2016, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

August 2016 Commencement Program, Bowling Green State University

Commencement Programs

No abstract provided.

Development Of Biocompatible Small-Molecule Spacers As Metal Oxide Nanoparticles' Stabilizing Agents, Galina Goloverda, Huy Do, Ezinne U. Agwaramgbo, Anastasia Labeaud, Rajesh Komati, Vladimir Kolesnichenko

Nanotechnology in Medicine: From Molecules to Humans

Development and study of the magnetic nanoparticles for biological and clinical applications remains one of the challenging research areas in chemistry and materials science. The performance of these particles as, for example, drug delivery, MRI, hyperthermia or cell tracking agents, depends on their magnetic susceptibility. Their ability to form stable aqueous colloids, the mobility, and diffusion properties in biological media, rely on organic coating, which is usually composed of hydrophilic biocompatible polymers such as dextrans or poly(ethylene glycol)s. Some areas of biomedical imaging, labeling and delivery application can benefit from magnetic nanoparticles with higher mobility and penetration, stronger interaction with …

Chemistry, Saint Mary's College Of California

Undergraduate Academic Catalog

No abstract provided.

Quantum Dot Metrics For Preparative Chemistry And Fluorescence Applications, Yi Shen

Theses and Dissertations

Colloidal semiconductor quantum dots (QDs) are considered to be a promising candidate for bio-imaging and solar cells because of their extraordinary photo-physical properties. The ultimate goal of this dissertation is to design a reliable matrix and a reproducible method to prepare QDs-based biocompatible probe for fluorescence applications. Synthesis of quantum dots requires a large amount of ligands to improve the stability at high temperature. However, for further application and surface modification of QDs, excess ligands must be removed. In this dissertation, I will first describe using gel permeation chromatography (GPC) as a media to purify different types of QDs. A …

Development And Implementation Of Problem-Based Chemistry Experiments For Engineering Students In A Multi-Disciplinary Course, Tiffany Hesser, Stephanie R. Bunyea

Chemistry and Chemical Engineering Faculty Publications

This paper will describe the implementation and continuing development of five problem based laboratory experiments in a general chemistry course designed specifically for multiple disciplines of engineering students at the University of New Haven. The Problem Based Laboratory Experiments (PBLE) were developed to provide students with the opportunity to perform and develop experimental procedures working in interdisciplinary teams, while achieving a greater understanding of the role of chemistry in engineering fields. In each PBLE, students first complete a traditional chemistry experiment to gain an understanding of the chemical concepts and to become familiar with executing a written procedure with a …

Mole Street Journal, June 2016, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

Understanding College Students’ Exam Process In A General Chemistry Course, Angela Willson

Masters Theses

The main way most college chemistry courses assess what a student has learned is through a summative exam. After introductory science courses, such as general chemistry, many students cite poor teaching and disappointing grades in these courses as a reason for dropping out of STEM programs. There has been a lack of qualitative research on students’ experiences of the complete process of taking an exam from start to finish, or the exam process, which includes preparing for an exam, taking an exam, receiving feedback, and responding to feedback after the exam has been graded.

My goal in this exploratory study …

Commencement Convocation Program, Usf, Graduate, May 7, 2016, University Of South Florida

USF Graduation and Convocation Programs

Honorary Doctor of Marine Science - Samuel Philander

Computational Studies Of Spin Trapping Of Biologically Relevant Radicals By New Heteroaryl Nitrones, Eyram Asempa

Electronic Theses and Dissertations

Heteroaryl nitrone spin traps have been suggested to act as free radical scavengers. The geometry optimizations and the single-point energies of the spin trapping reactions of the heteroaryl nitrones, 5,5-dimethylpyrroline-N-oxide (DMPO) and α-phenyl-N-t-butylnitrone (PBN) have been computationally studied using ab initio (Hartree-Fock (HF) and second-order Møller-Plesset (MP2)) methods and Density Functional Theory (DFT) methods. The effects of new heteroaryl substituents on a parent nitrone spin trap have been examined at the HF and MP2 levels with the 6-31G*, and cc-pVnZ (n=D, T, Q) basis sets. The thermodynamics of the spin trapping at the C-site and O-site with •H, …

The Free Press Vol. 47, Issue No. 21, 04-25-2016, Krysteana Scribner

Free Press, The

Alumni band performs with two retiring professors -- The minds of USM showcase work at Thinking Matters -- Fourth annual day of electronic recycling -- Angus King joins climate change panel -- USM Chemistry Lab to Open Next Semester -- SGA: What you need to know about it -- Small businesses look for skilled lawyers

Monitoring Co2 At An Enhanced Oil Recovery And Carbon Capture And Storage Project, Farnsworth Unit, Texas, Robert Balch, Richard Esser, Ning Liu

CO2 Summit II: Technologies and Opportunities

The Southwest Partnership on Carbon Sequestration (SWP) is one of seven large scale CO2 sequestration projects sponsored by the U.S. Department of Energy, each with the goal of permanently sequestering at least 1,000,000 metric tonnes of CO₂. The SWP project is at an active Enhanced Oil Recovery (EOR) project in a mature waterflood in the Farnsworth Unit, Texas, which is undergoing conversion to a CO₂ flood. CO₂ for this project is anthropogenically sourced from a fertilizer plant in Borger, Texas and an ethanol plant in Liberal, Kansas. Currently, the field has 13 CO₂ injectors and …

The Lumberjack, April 6, 2016, The Lumberjack Staff

2016

The student newspaper of Humboldt State University

Mole Street Journal, April 2016, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

Use It Or Lose It? A Longitudinal Performance Assessment Of Undergraduate Business Students' Information Literacy, Ilana Stonebraker, Rachel Fundator

Libraries Faculty and Staff Scholarship and Research

No abstract provided.

Stream Energy Impacting Sediment Transport Through Low-Gradient Agricultural Streams, Paula Jane Pryor

Theses and Dissertations

Water quality can be severely impacted by increased sediment transport, particularly agriculturally-dominated systems like those found in central Illinois. Many low-gradient sediment studies focus on the fine material transported in suspension. However, coarse-material transport can be equally important for understanding sediment loads to surficial reservoirs for local drinking water. To address a general gap in knowledge of coarse-sediment transport through agricultural streams, seasonal changes and watershed differences in sediment transport were examined in a low-gradient system. This was accomplished through the installation of bedload traps, scour-fill markers, and bank erosion pins at two streams, Six Mile Creek and Money Creek …

Mole Street Journal, February 2016, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

Graduate School Of Oceanography Annual Report For Fy2016, Uri Graduate School Of Oceanography

Graduate School of Oceanography Publications

Annual report for the Graduate School Oceanography of the University of Rhode Island for the 2016 fiscal year.

Includes research projects by faculty and students, biographies of new faculty, events on the Bay campus and program development and list of donors

Force Field Development With Gomc A Fast New Monte Carlo Molecular Simulation Code, Jason Richard Mick

Wayne State University Dissertations

In this work GOMC (GPU Optimized Monte Carlo) a new fast, flexible, and free molecular Monte Carlo code for the simulation atomistic chemical systems is presented. The results of a large Lennard-Jonesium simulation in the Gibbs ensemble is presented. Force fields developed using the code are also presented. To fit the models a quantitative fitting process is outlined using a scoring function and heat maps. The presented n-6 force fields include force fields for noble gases and branched alkanes. These force fields are shown to be the most accurate LJ or n-6 force fields to date for these compounds, capable …