Digital Commons Network^™

The University Greening Movement: Is Carbon Neutrality Enough To Avert A Climate Crisis?, Sean R. Finlay

Student Theses 2015-Present

Because of the impact that educational institutions have on the intellect of the American youth, universities play a crucial role in our nation’s path towards sustainability because of their ability to guide educational focus toward the well-being of the environment. Through a unified movement among these institutions called the “University Greening Movement”, or UGM, campuses are utilizing current technological breakthroughs to their advantage by implementing them into the structures and foundations of their campuses to reduce and even eliminate carbon emissions. However, as monumental as these technological advancements and this movement has been, the question arises of whether or not …

Identifying The N Sources For Black Mangrove (Avicennia Germinans) In A South Texas Mangrove Forest, Ashley Elizabeth Murphy

Theses and Dissertations

Black mangrove (Avicennia germinans) in south Texas provide ecosystem services and benefits to humans including: habitat for wildlife, prevention of coastline erosion, and mitigation of natural disasters. One step to preserve their ecological functions is to identify and protect the source of their nitrogen (N). Nitrogen stable isotopes were sampled for one year beginning August 2018 and used as tracers to identify how mangroves obtain N. Total N in (A. germinans) and associated (Batis maritima) (plants) (2.1%) was more abundant than in cyanobacteria (0.6%) and sediment (0.1%). Plant d15N signatures (5.52‰) were more similar to sediment (5.21‰) than cyanobacteria (1.98‰), …

Cost Effectiveness Of Greenhouse Gas Reductions Through Afforestation Of Agricultural Land In The Arkansas Delta, Karli A. Moore

Graduate Theses and Dissertations

Sequestration of atmospheric carbon in forested lands offsets carbon emissions from other industries. Conversion of private lands, particularly agricultural tracts in marginal areas, to forests can bolster carbon abatement. The United States government agencies administer some voluntary, incentive-based programs to encourage landowners to adopt production practices with positive environmental outcomes. This policy stream can be used to increase transition of marginal agricultural land to forests, thereby creating new carbon sinks. We analyze an eleven-county study area in the Arkansas Delta to determine feasibility for a subsidy focused on carbon abatement through afforestation. This study area is significant for two reasons: …

Reconstructing Geographic And Trophic Histories Of Fish Using Bulk And Compound-Specific Stable Isotopes From Eye Lenses, Amy A. Wallace

USF Tampa Graduate Theses and Dissertations

The present research examined the viability and utility of eye lenses as a source of lifetime stable-isotope records in fish. It is presented in three sections. The first section compared bulk isotopic variation (bulk analysis) within fish eye-lenses at two temporal resolutions and compared patterns obtained from left and right eyes. The first temporal resolution was lower in an attempt to expose broad-scale isotopic changes during life while reducing effort and cost. This approach did reveal lifetime patterns, but tended to miss certain life events, particularly during early life. The second resolution was higher and provided detail that was missed …

Measurements Of The 16c + 12c And 16c + 13c Fusion Cross Sections With Implications For Astrophysics, Ashley Ann Hood

LSU Doctoral Dissertations

The fusion of neutron-rich nuclei is of interest to nuclear astrophysics and nuclear structure. X-ray superbursts are powered by runaway thermonuclear burning deep inside of a neutron star, where heating from the pycnonuclear fusion of neutron-rich isotopes is an important heat source. Experimental measurements of fusion cross sections of neutron-rich isotopes have provided insights regarding nucleon transfer and nuclear structure properties affecting fusion. Recently, the ¹⁵C + ¹²C total fusion cross section was measured using a ¹⁵C beam produced by the in-flight beam production facility, which is part of the Argonne Tandem LINAC Accelerator System (ATLAS) at …

Modifying Carbon Supports For Improved Ion-Exchange Capacity In Proton-Exchange Membrane Fuel Cells, Bryan Bill

All Theses

Sulfonated perfluorocyclobutyl phosphonate (s-PFCB-PO3) polymers are studied extensively in proton-exchange membrane (PEM) fuel-cell applications for their favorable ionic-conducting properties. Inspired by their high chemical, mechanical and thermal stability, PFCB polymers have been used by several groups as grafting compounds onto zirconia-decorated carbon black (ZrC) catalyst supports. The trifluorovinyl ether (TFVE) moiety of the aryl bis-TFVE monomer provides a template for polymerization by step-growth [2+2] cycloaddition to afford PFCB polymers which upon subsequent sulfonation can have high ion-exchange capacity and high proton conductivity. Aryl phosphonic acid substitution onto the terminal TFVE groups provides a route to anchoring the ionic polymers onto …

Life History Through The Eyes Of A Hogfish: Evidence Of Trophic Growth And Differential Juvenile Habitat Use, Meaghan E. Faletti

USF Tampa Graduate Theses and Dissertations

Understanding ontogenetic linkages among fish habitats is critical for conservation of fish populations and the ecosystems on which they rely. Natural tags such as stable isotopes are an effective tool commonly used to investigate ecological questions regarding fish movement and habitat use. Here, I analyzed stable isotopes from the sequentially deposited laminae of Hogfish (Lachnolaimus maximus) eye lenses from the eastern Gulf of Mexico (eGOM) to investigate trophic and geographic changes across individual life histories. I documented evidence of entire-life scale trophic growth through increases in δ15N. I also observed depth separation at the juvenile stage, evidenced by variation in …

Laser-Spark Multicharged Ion Implantation System ‒ Application In Ion Implantation And Neural Deposition Of Carbon In Nickel (111), Oguzhan Balki

Electrical & Computer Engineering Theses & Dissertations

Carbon ions generated by ablation of a carbon target using an Nd:YAG laser pulse (wavelength λ = 1064 nm, pulse width τ = 7 ns, and laser fluence of 10-110 J/cm²) are characterized. Time-of-flight analyzer, a three-mesh retarding field analyzer, and an electrostatic ion energy analyzer are used to study the charge and energy of carbon ions generated by laser ablation. The dependencies of the ion signal on the laser fluence, laser focal point position relative to target surface, and the acceleration voltage are described. Up to C⁴⁺ are observed. When no acceleration voltage is applied between …

Assessing The Agronomic And Ecological Relevance Of Mineral-Associated Organic Matter, Andrea Jilling

Doctoral Dissertations

As the largest terrestrial sink for carbon (C) and a critical source of nitrogen (N) for plants, soil organic matter (SOM) is a major driver of ecosystem function. It is critical to understand the mechanistic controls on SOM in order to improve models of global C cycling and to develop accurate measures of soil fertility. SOM consists of a wide spectrum of compounds, varying in chemical characteristics and function. The chemical and physical fractionation of SOM is a valuable tool for distilling this complexity into meaningful and distinct pools: detrital or particulate organic matter (POM), which contains mostly recent litter …

Spatial And Temporal Variation In The Diet Composition Of Zooplankton In Mission Bay, Bryanna Paulson

Theses

Analyses of quantitative data on zooplankton diets are vital for understanding the drivers of zooplankton abundance within an ecosystem. Such analyses also provide insight into trophic pathways within the lower planktonic food web, which support populations of higher trophic level species. This study used carbon and nitrogen stable isotope ratios of size-fractionated plankton in Mission Bay, San Diego, CA to examine the spatial and temporal variation in zooplankton trophic ecology and determine potential environmental drivers of zooplankton community structure. Carbon stable isotopes reflect primary production sources in an organism’s diet, and nitrogen stable isotope ratios can be used to estimate …

Influence Of Varying Inorganic Nutrients Supply On Ergosterol And Glucosamine Concentrations And Biomass Nutrient Stoichiometry In Ectomycorrhizal Fungi, Stephanie S. Koury

Master's Theses

Ectomycorrhizal (ECM) fungi are critical for the health of forest ecosystems where they can sequester large amounts of carbon in the form of soil organic matter, a matter of growing interest due to anthropogenic climate change. A clear understanding of their growth dynamics and responses to environmental changes is imperative for future work in forest management and the possible mitigation of increased atmospheric CO₂. Six ECM fungal species were grown in liquid culture under varying nitrogen and phosphorus concentrations and ratios to assess how exogenous nutrient supplies affect fungal biomass stoichiometry and the degree of elemental homeostasis. Additional …

Fungal Physiological Response To Temperature And Nitrogen Availability, Shana Whitney

Master's Theses and Capstones

Microbial carbon use efficiency (CUE; the proportion of assimilated C allocated towards biomass production) is a powerful regulator of global soil C stocks, and there is a need to integrate accurate and dynamic CUE parameters into C-cycling models. However, there is uncertainty in the CUE-response to warming and increased N deposition and how this response may vary among groups of microbes. Here, we conducted a laboratory incubation of ten photogenically diverse fungal isolates grown in liquid culture to evaluate potential environmental and physiological controls over CUE. Isolates were grown at 15ºC or 25ºC and under low or high N concentrations. …

Influence Of Salt Marsh Vegetation On Carbon Cycling And Microbial Communities, Aidan Barry

Master's Theses

No abstract provided.

Effects Of Corrugations On Stiffness Properties Of Composite Beams For Structural Applications, Jane Xiao

Master's Theses

Composites have high strength-to-weight ratios, which is particularly desired for applications with weight restrictions. Common composite materials such as carbon fiber reinforced plastic (CF) and fiber glass reinforced plastic (FG) were used in this research. While composite materials possess high stiffness and strength properties, the stiffness of composite laminates may be maximized by changing the geometry. By adding corrugations, the flexural stiffness is increased in one direction compared to the stiffness of a flat part with the same amount of material. Thus, stiffness increases without a change in weight. The primary goal of this research was to investigate the stiffness …

Facilitating Greenhouse Gas Reduction And Climate Change Adaptation Within The Coastal Zone: A Policy Analysis For The California Coastal Commission, Nicole Young

Master's Theses

California is already experiencing impacts to its coastline due to climate change, and more severe impacts are anticipated if greenhouse gas emissions continue to rise. These climate change impacts are especially strong within the California coastal zone, which falls under the jurisdiction of the California Coastal Commission. The Commission has a history of rigorous environmental protection and is committed to protecting California’s coast through proactive planning and regulation, however they will need to initiate coastal policies with ambitious targets to facilitate effective climate change adaptation and mitigation. This study analyzed existing California climate policies and Coastal Commission policies to identify …

Effects Of Grazer Exclusion On Carbon Cycling In Created Freshwater Wetlands, Delanie Spangler

Theses

Wetland ecosystems play a significant role in the global carbon cycle, and yet are increasingly threatened by human development, climate change, and shifts in populations of large grazers. The loss of intact wetland systems heightens the need for effective wetland creation and restoration. However, wetland ecosystems are highly complex, complicating efforts to replace the functionality and delivery of ecosystem services associated with natural wetlands. Increasing waterfowl populations pose a threat to the development and persistence of created wetlands, largely through intensive grazing that can shift vegetation community structure or altogether limit desired plant establishment. This study capitalizes on a long-term …

Exploring The Electrical Properties Of Twisted Bilayer Graphene, William Shannon

Senior Theses

Two-dimensional materials exhibit properties unlike anything else seen in conventional substances. Electrons in these materials are confined to move only in the plane. In order to explore the effects of these materials, we have built apparatus and refined procedures with which to create two-dimensional structures. Two-dimensional devices have been made using exfoliated graphene and placed on gold contacts. Their topography has been observed using Atomic Force Microscopy (AFM) confirming samples with monolayer, bilayer, and twisted bilayer structure. Relative work functions of each have been measured using Kelvin Probe Force Microscopy (KPFM) showing that twisted bilayer graphene has a surface potential …

Fungal Community And Soil Responses To Invasive Alliaria Petiolata (Garlic Mustard), Soil Warming, And Nitrogen Deposition, Mark Alan Anthony

Doctoral Dissertations

Non-native, invasive plants can fundamentally alter soil fungal communities and edaphic properties. In this dissertation, I first measured fungal and edaphic responses and recovery to invasive, Alliaria petiolata (garlic mustard; Brassicaceae) eradication across Southern New England. I conducted an experimental eradication and tracked fungal communities and soil properties for three years in relation to reference uninvaded plots and actively invaded plots. Neither the fungal community nor soil properties recovered (i.e. became similar to reference uninvaded plots) following eradication, and I discuss how altered soil properties likely prevented fungal communities from recovering via environmental filtering. I also measured fungal and edaphic …

Deposition Of Platinum Particles On Surface-Modified Carbon Ultramicroelectrodes, Caitlin Millsaps

Undergraduate Honors Theses

Nanoparticles are used as electrocatalysts due to their large surface area-to-volume ratios. Most studies of nanoparticle electrocatalysis are performed on collections of particles on a support, which represent ensemble average behavior influenced by spatial distribution of the nanoparticles. Therefore, recent emphasis has been placed on analyzing electrocatalytic behavior of single particles. The focus here is to develop carbon ultramicro- and nanoelectrode platforms for studying the electrocatalytic properties of single metal nanoparticles. Ultramicroelectrodes were prepared using chemical vapor deposition of carbon in pulled quartz capillaries. Electrode diameters were determined by cyclic voltammetry. Electrodes were modified using a soft nitriding technique to …

Endolithic Microbial Carbon Cycling In East Antarctica, Natalie Tyler

Theses and Dissertations

Microbes adapt to inhospitable conditions by colonizing niches that protect them from severe environmental conditions, making them model organisms in the search for life on other planets. Endoliths are globally ubiquitous microbes that colonize structural cavities within rocks, which protect them from environmental stressors while maintaining access to nutrition and light sources. Despite harsh katabatic winds, extreme temperature fluctuations, harmful UV radiation and exposure to desiccation, endolithic communities have been observed in Antarctica. Previous studies have found viable and abundant microbial biomass through microscopy and the addition of isotopic labels. However, due to the slow metabolic activity of these microbes, …

Environmental Controls On Dissolved Carbon Export And River Geochemistry - A Case Study In The Mississippi-Atchafalaya System, Jeremy Reiman

LSU Master's Theses

Rivers serve as an important medium for the exchange of elements between land, ocean, and atmosphere. This thesis consists of three interconnected studies with the overarching goal of analyzing the environmental factors influencing dissolved carbon dynamics and river geochemistry in large rivers. These studies utilized river water samples and in-stream measurements collected from the Mississippi and Atchafalaya Rivers at hourly to monthly intervals between 2013 to 2018, along with ambient river and meteorological data downloaded from public-access databases. Results indicate substantially higher dissolved organic carbon concentrations (DOC, 611 ±181 µmol L^-1) but lower concentrations of dissolved inorganic carbon …

New Method Of Manufacturing Carbon Foam, Matthew D. Artimez

Graduate Theses, Dissertations, and Problem Reports

Carbon foam is a product that has some unique features. Carbon foam is a light weight material that has a high crush strength. It is electrically conductive, but because it is composed of air space between the tendrils, it is not a thermal conductor. Since it contains no volatile content, it is noncombustible. All these features allow carbon foam to have many modern applications. Currently, there are only three methods of producing carbon foam, and all three are not cost- efficient enough to meet the demand of potential new markets.

In this thesis, a new procedure of producing carbon foam …

Electron Transport In One And Two Dimensional Materials, Samuel William Lagasse

Legacy Theses & Dissertations (2009 - 2024)

This dissertation presents theoretical and experimental studies in carbon nanotubes (CNTs), graphene, and van der Waals heterostructures. The first half of the dissertation focuses on cutting edge tight-binding-based quantum transport models which are used to study proton irradiation-induced single-event effects in carbon nanotubes [1], total ionizing dose effects in graphene [2], quantum hall effect in graded graphene p-n junctions [3], and ballistic electron focusing in graphene p-n junctions [4]. In each study, tight-binding models are developed, with heavy emphasis on tying to experimental data. Once benchmarked against experiment, properties of each system which are difficult to access in the laboratory, …

Biogeochemical Response To Vegetation And Hydrologic Change In An Alaskan Boreal Fen Ecosystem, Danielle L. Rupp

Dissertations, Master's Theses and Master's Reports

Boreal peatlands store approximately one third of the earth’s terrestrial carbon, locked away in currently waterlogged and frozen conditions. Peatlands of boreal and arctic ecosystems are affected increasingly by shifting hydrology caused by climate change. The consequences of these relatively rapid ecosystem changes on carbon cycling between the landscape and the atmosphere could provide an amplifying feedback to climate warming. Alternatively, the advancement of terrestrial vegetation into once waterlogged soils could uptake carbon as a sink. Previous work suggests that fens will become an increasingly dominant landscape feature in the boreal. However, studies investigating fens, their response to hydrologic and …

Mechanisms Underlying Production Stability In Temperate Deciduous Forests, Shea B. Wales

Theses and Dissertations

A persistent and reliable future terrestrial carbon (C) sink will depend on how stable forest production is under more variable climate conditions. We examined how age, forest structure, and disturbance history relate to the interannual variability of above-ground wood net primary production (NPPw). Our site in northern Michigan spans two experimental forest chronosequences and three late successional stands; the chronosequences have distinct disturbance histories, originating following either clear cut harvesting (“Cut Only”) or clear cut harvesting and fire (“Cut and Burn”), and range from 21 to 108 years old. Annual NPPw was estimated using dendrochronology and site specific allometric equations. …

Seasonal Soil Carbon Fluxes In Transitioning Agricultural Soils In Central Washington State: Relations To Land-Use, Environmental Factors And Soil Carbon-Nitrogen Characteristics, Brandon Kautzman

All Master's Theses

Changing agricultural land-use practices to increase soil carbon sequestration contributes to climate change mitigation and improved food security by moving CO₂ from the atmosphere into soil as soil organic carbon (SOC). In 2016, a farm in Thorp, Washington, Spoon Full Farm, began converting land historically farmed using conventional methods of tillage and synthetic fertilizers to conservation farming methods with direct seeding and organic soil amendments with a goal of sequestering carbon in the soil. This project evaluates relationships of soil CO₂ respiration and net ecological exchange (NEE) with land-use types, seasonal environmental factors (air temperature, relative humidity, soil …

Advanced Materials For Rechargeable Batteries, Haipeng Guo

University of Wollongong Thesis Collection 2017+

As the most successful energy storage system, lithium ion batteries (LIBs) have been utilized in many different fields, such as electric vehicles, smart phones, digital cameras, laptop computers, and so on. Even though enormous efforts have been devoted to improving the performance of these batteries, they still suffer from some intrinsic problems, including poor cycling stability, insufficient rate performance, and active materials aggregation. Therefore, it is important to develop advanced materials with outstanding performance for next-generation batteries. In particular, the anode material, as an important component of the battery, is critical for the improvement of its performance and is currently …

Synthesis Of Nanoporous Carbon Derived From Hybrid Metal Organic Frameworks For Symmetric Supercapacitor, Freddy Marpaung

University of Wollongong Thesis Collection 2017+

Metal-organic frameworks (MOFs) have received much interest due to their remarkable properties, such as high surface area, controllable porosity, high electrical conductivity, high thermal stability, and good chemical stability. In addition, the properties of a MOF could be tuned by incorporation with other compounds. More interestingly, their structure could be transformed into nanoporous carbon materials via the carbonization process. Nanoporous carbons (NPCs) are promising electrode materials for electrical energy storage (i.e., batteries and supercapacitors) due to their unique properties, such as good thermal and chemical stability, high surface area, and tunable pore structures.

Nowadays, the development of new electrode materials …