Digital Commons Network^™

Recruitment Sources Of Grass Carp (Ctenopharyngodon Idella) In The Great Lakes, Nicholas Steven Etter

Theses

Grass Carp (Ctenopharyngodon idella) is a species of concern in areas they have invaded, such the Laurentian Great Lakes, due to their potential to substantially reduce aquatic macrophyte coverage. Efforts to control Grass Carp in the Great Lakes have primarily been focused on two tributaries to the western basin of Lake Erie (i.e., Sandusky and Maumee rivers, Ohio) where reproduction has been documented, although other Great Lakes tributaries are known to have thermal and hydrological regimes suitable for Grass Carp spawning. Knowledge of sources contributing to the expanding population of invasive Grass Carp in the Great Lakes is key to …

Using The Diels-Alder Reaction In The Synthesis Of Biologically Interesting Molecules: Targets Of Opportunity, Ethan Michael Decicco

Theses

This thesis is composed of reports on two projects, which are described separately in two chapters.

The first project described (Chapter 1) involves the synthesis of a series of molecules that contain a 1,4-dimethyl-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxy-imide core structure. These types of molecules represent a class of analogues of the natural product cantharidin, a potent cytotoxic agent isolated from Meloidae insects. Cantharidin and cantharidin-like small molecules have been extensively studied in literature as potential leads in new anti-cancer medications. A series of 1,4-dimethyl-7-oxabicyclo[2.2.1]heptane-2,3- dicarboxy-imides are also being investigated by researchers at Bristol-Meyers-Squibb (BMS) as prospective treatments of prostate cancer (PC). PC is the …

Infrared Investigations Of The Composition And Structure Of Nearby Protoplanetary Disks, Valerie Ann Rapson

Theses

Near- to far-infrared imaging and spectroscopy of nearby (pc), low mass pre-main sequence stars that are orbited by gaseous and dusty circumstellar disks allow astronomers to probe the chemical composition and structure of protoplanetary disks, and further understand disk evolution and planet formation processes. In this dissertation, I present an infrared imaging and spectral analysis of the young star-disk systems V4046 Sgr, T Cha and MP Mus. V4046 Sgr is a nearby (D~73 pc), ~20 Myr-old spectroscopic binary surrounded by a large (R~350 AU) circumbinary disk. T Cha and MP Mus are similarly nearby (Dpc) and young (old) single-star systems …

Studies Of The Preparation Of Pi-Extended Anthracenes And Their Reactivity With An Emphasis On Their Photoreactivity, Hasnaa Abdelkareem Sadeq

Theses

Both 9,10-diaryl and 9,10-diarylethenyl substituted Anthracenes have recently been forwarded as light-regulated semiconducting materials, as well as potential constituent molecules in light-harvesting devices for the organic solar cell applications. So, it is of importance to understand whether such 9,10-substituted Anthracenes are stable under photo-irradiation for a long time, and what type of reactions they could undergo. In the present thesis, photochemistry of 9-anthranylacrylates and 9-aroylethenylanthracenes has been investigated. Anthranylacrylates and 9-aroylethenylanthracenes have been prepared by Wittig-olefination reaction from 9-anthranylcarbaldehyde. Bromination of these molecules was found to give an access to 10-aryl-9-aroylethenylanthracenes after Suzuki-Miyaura coupling reactions. While 9-ethenyl-substituted Anthracenes in principle …

The Effect Of Prior Knowledge In Undergraduate Performance In Chemistry: A Correlation – Prediction Study, Michael K. Seery

Theses

No abstract provided.

Solvent Targeting, Avoidance And Recovery Trials (Start), Kealan Allen

Theses

Solvent is the largest-volume raw material used at Janssen Pharmaceutical (Ire) Ltd. Over 2.2 million m³ were used in 2004. The top 13 solvents make up 99% of this amount. There are two main uses for solvent on site, processing and cleaning. Processing uses 55% of the total solvent used on site, cleaning uses the remainder.

Waste solvent forms the majority of the hazardous waste produced at Janssen. Three treatment options exist at present for this waste: incineration, recovery for reuse and energy recovery. All of the hazardous waste produced on site must be exported for these treatment options, …

Introduction To Pollution Prevention Concepts In Freshman Chemistry Through Simulations And Hypermidia, Aniraban Bhaumik

Theses

As citizens of the 20th century, a key issue we all are aware of is degradation of the environment. In the interest of teaching the environmental issues to freshmen engineers, this study develops a computer aided learning/teaching (CAL/T) tool.

This CAL/T tool consists of Internet based multimedia courseware and intelligent simulations. The courseware assembles the fundamentals of chemistry associated with current environmental issues such as air pollution, stratospheric ozone layer depletion and environmentally sensitive or 'clean' manufacturing. The courseware targets early and comprehensive understanding of pollution prevention concepts with a focus on environmentally friendly manufacturing. The courseware includes: on-line text, …

Remediation And Reuse Of Chromium Contaminated Soils Through Cold Top Ex-Site Vitrification, Wiwat Kamolpornwijit

Theses

More than 150 sites in Hudson County, New Jersey are identified as chromium contaminated sites. Hexavalent chromium, highly soluble in water, is considered as an environmental and health hazard, classified as a group A human carcinogen. In this research, the feasibility was performed to study the possibility of remediation of chromium contaminated soil by ex-situ vitrification and to evaluate reuse potential of vitrified products as highway construction aggregate. A series of physical and chemical analysis was conducted on nine soil samples collected from different chromium contaminated sites. Results were analyzed for their compatibility for vitrification. Sand and carbon were added …

Study Of The Temperature Dependence Of The Intrinsic Viscosity [Nu] For Polystyrene And Poly (Styrene - Co - Maleic Anhydride), Rong Su

Theses

The Mark-Houwink-Sukaroda (MHS) equation [r|J = K Mva is a very important relationship to relate polymer dilute solution's intrinsic viscosity and polymer's viscosity average molecular weight. But for a wide range of polymer (copolymer) - solvent systems, the constant K and exponent a values are usually not sufficiently available. Fox - Flory and Van Krevelen dilute solution theories are employed to correlate K and a values under different temperatures therefore prove that MHS constant K and exponent a are temperature dependent for polystyrene and styrene-co-maleic anhydride. For polystyrene, the exponent a value changes from 0.7165 at 25C to 0.7327 at …

The Kinetic Study Of Degradation Of The Azo Dyes By Photolytic Ozonation And Photolytic Hydorgen Peroxide Oxidation, Hung-Yee Shu

Theses

The experiments which study the decomposition of azo dyes such as acid red 1 and acid yellow 23 by using ozonation, photolytic ozonation and photolytic hydrogen peroxide oxidation have been studied in laboratory sized reactor and pilot scale reactor to determine the reaction rate constants.

The rate constants and mass transfer coefficients were obtained by a series of experiments of varying complexity. A reaction kinetic model which describes the contemplated experiments was developed and exercised using the Rosenbrock Hillclimb Optimization Algorithm with the Forth-Order Runge-Kutta method. The effects between different hydrogen peroxide dosages and pH level were also analyzed.

In …

Analysis Of Nitrated Polycyclic Hydrocarbons, Pah-Quinones And Related Compounds In Ambient Air, Yalan Wang

Theses

Studies were conducted to characterized airborne particulate extractable organic matter (EOM) with respect to chemical composition and biological activity. It has been well established that the nitrated polycyclic hydrocarbons (nitroPAH) are environmental contaminants. To identify nitro-PAH in ambient air sample, a technique was developed involving introduction of a reducer column into an reversephase high performance liquid chromatography (HPLC) system. Strong fluorescence signals were achieved from nitro-PAH and detected together with u.v. signals for the qualitative and quantitative analysis of nitro-PAH. 2-Nitrotriptycene was synthesized according to published procedures and used as an internal standard. By use of the above technique, 9nitroanthracene, …