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Magnetic Properties Of Ho2fe17-Xmnx - Influence Of Mn Substitution, Jianli Wang, Stewart J. Campbell, A J Studer, S J. Kennedy, Rong Zeng Jan 2010

Magnetic Properties Of Ho2fe17-Xmnx - Influence Of Mn Substitution, Jianli Wang, Stewart J. Campbell, A J Studer, S J. Kennedy, Rong Zeng

Australian Institute for Innovative Materials - Papers

The structural and magnetic properties of Ho2Fe17−xMnx (x=0-5) have been investigated by x-ray diffraction, Mössbauer spectroscopy and DC magnetization measurements (0-5 T) over the temperature range 4.5-350 K. Similar to other ferrimagnetic R2Fe17-xMnx systems, the unit cell volume generally increases with Mn content other than for low Mn values where a slight maximum is detected around x ∼ 0.5. The nature of the magnetic phase transitions around TC is shown by Arrot plot analysis to be second order for all samples. The Curie temperature remains essentially unchanged …


Magnetic Properties Of La Doped Bi2femno6 Ceramic And Film, Hongyang Zhao, Hideo Kimura, Zhenxiang Cheng, Xiaolin Wang, Kiyoshi Ozawa, Takashi Nishida Jan 2010

Magnetic Properties Of La Doped Bi2femno6 Ceramic And Film, Hongyang Zhao, Hideo Kimura, Zhenxiang Cheng, Xiaolin Wang, Kiyoshi Ozawa, Takashi Nishida

Australian Institute for Innovative Materials - Papers

We present a comprehensive study of the magnetic properties for La doped Bi2FeMnO6 (LBFM) ceramic and film which was first deposited on (100) SrTiO3 substrate by pulsed laser deposition method. The LBFM film is antiferromagnetic or weak ferrimagnetic at room temperature and it shows clear magnetic anisotropy. But it is not sure whether the spin-glass behavior is present in LBFM film because of the influence from substrate. Compared to the film, LBFM ceramic shows different magnetic properties. It has a lower TN and all the observations indicate that LBFM ceramic shows spin-glass behavior.


Magnetic Properties Of Bi2femno6: A Multiferroic Material With Double-Perovskite Structure, Yi Du, Zhenxiang Cheng, S X. Dou, Xiaolin Wang, Hua Zhao, Hideo Kimura Jan 2010

Magnetic Properties Of Bi2femno6: A Multiferroic Material With Double-Perovskite Structure, Yi Du, Zhenxiang Cheng, S X. Dou, Xiaolin Wang, Hua Zhao, Hideo Kimura

Australian Institute for Innovative Materials - Papers

Single phase Bi2FeMnO6 was synthesized on Si substrates by an electrospray method. Three peaks were observed in the temperature dependence of magnetization curve, which is attributed to the inhomogeneous distribution of Fe3+ and Mn3+. The observed magnetic peaks at 150 K, 260 K, and 440 K correspond to orderings of the ferrimagnetic Fe–O–Mn, and antiferromagnetic Mn–O–Mn and Fe–O–Fe, respectively. Heat capacity measurements were carried out to confirm these magnetic transitions. The Debye temperature of Bi2FeMnO6 is 339 K, calculated from Debye–Einstein fitting.


Superconducting Transition Width Under Magnetic Field In Mgb2 Polycrystalline Samples, C.C Wang, R Zeng, Xun Xu, S. X. Dou Jan 2010

Superconducting Transition Width Under Magnetic Field In Mgb2 Polycrystalline Samples, C.C Wang, R Zeng, Xun Xu, S. X. Dou

Faculty of Engineering - Papers (Archive)

A systematic study on the superconducting transition width as a function of the applied magnetic field was performed in polycrystalline MgB2. A quantitative, yet universal relation between the two parameters was observed in all of the ceramics. It was found that the width decreases linearly with decreasing field in pure MgB2 samples. Whereas, samples with boron and/or Mg atoms partially replaced by other elements show this linear relation in the temperature range below 0.7–0.8 of the superconducting transition temperature (corresponding to a field of about 2 T), at temperatures higher than this range, an abnormal upturn in …


Enhancement Of Co Substitution Induced By Eu Codoping In Zno-Based Diluted Magnetic Semiconducting Thin Films, P Photongkam, Y B Zhang, M.H.N Assadi, S Li, D Yu, Mihail Ionescu, Alexey V. Pan Jan 2010

Enhancement Of Co Substitution Induced By Eu Codoping In Zno-Based Diluted Magnetic Semiconducting Thin Films, P Photongkam, Y B Zhang, M.H.N Assadi, S Li, D Yu, Mihail Ionescu, Alexey V. Pan

Faculty of Engineering - Papers (Archive)

To avoid the occurrence of doped magnetic ion clustering is a challenge in fabrication of diluted magnetic semiconductors (DMSs). In this work, we report the intrinsic ferromagnetic behavior in Co-doped ZnO DMSs induced by Eu codoping. Both structural parameters and magnetic properties demonstrate the existence of an interaction between Co and Eu ions. The observation of multiplet structures for the localized Co 3d states in x-ray absorption and x-ray magnetic circular dichroism characterization evidences that the codoped Eu plays an important role in facilitating the Co substitution of Zn, leading to intrinsic ferromagnetism.


Flux Pinning And Inhomogeneity In Magnetic Nanoparticle Doped Mgb2/Fe Wires, Nikolina Novosel, Damir Pajic, Mislav Mustapic, Emil Babic, Andrey Shcherbakov, Josip Horvat, Zeljko Skoko, Kreso Zadro Jan 2010

Flux Pinning And Inhomogeneity In Magnetic Nanoparticle Doped Mgb2/Fe Wires, Nikolina Novosel, Damir Pajic, Mislav Mustapic, Emil Babic, Andrey Shcherbakov, Josip Horvat, Zeljko Skoko, Kreso Zadro

Faculty of Engineering - Papers (Archive)

The effects of magnetic nanoparticle doping on superconductivity of MgB2/Fe wires have been investigated. Fe2B and SiO2-coated Fe2B particles with average diameters 80 and 150 nm, respectively, were used as dopands. MgB2 wires with different nanoparticle contents (0, 3, 7.5, 12 wt.%) were sintered at temperature 750°C. The magnetoresistivity and critical current density Jc of wires were measured in the temperature range 2–40 K in magnetic field B ≤ 16 T. Both transport and magnetic Jc were determined. Superconducting transition temperature Tc of doped wires decreases quite rapidly with …


Magnetic Phase Transition In Mnfep0.5as0.4si 0.1, Jianli Wang, Stewart J. Campbell, O Tegus, E Bruck, S X. Dou Jan 2010

Magnetic Phase Transition In Mnfep0.5as0.4si 0.1, Jianli Wang, Stewart J. Campbell, O Tegus, E Bruck, S X. Dou

Australian Institute for Innovative Materials - Papers

We have carried out a detailed investigation of the magnetic phase transition in MnFeP0.5As0.4Si0.1. Temperature hysteresis has been observed in the variable temperature magnetization curves (Bappl = 0.01 T) with TC W ~ 302 K on warming and TC C ~ 292 K on cooling. The first order nature of this transition in MnFeP0.5As0.4Si0.1 is confirmed by the negative slope obtained from isotherms of M2 versus B/M around the critical temperature. Linear thermal expansion measurements reveal a large volume change, ΔV/V∼8.7×10-3, at the …


A Sign Of Field-Induced First Order Magnetic State Transition And Giant Reversible Magnetocaloric Effect In Cobalt Hydroxide Nanosheets, Precious Shamba, Rong Zeng, J Q Wang, S X. Dou Jan 2010

A Sign Of Field-Induced First Order Magnetic State Transition And Giant Reversible Magnetocaloric Effect In Cobalt Hydroxide Nanosheets, Precious Shamba, Rong Zeng, J Q Wang, S X. Dou

Australian Institute for Innovative Materials - Papers

We report the synthesis of β−Co(OH)2 nanosheets using microwave assisted hydrothermal and conventional chemical reaction methods. A magnetic transition at an onset temperature, T1 ~ 96 K, and a sign of antiferromagnetic state transition at the Néel temperature, TN=9~10 K, can be determined from M-T curves and M-H curves magnetic properties investigation. It is found that a sign of field-induced first order transition below 9 K, act as a role of reversing the magnetocaloric effect from negative to positive value. The large reversible magnetic-entropy change (∆SM) of 17 J/kg K around 11 K for …


Self-Doping Effect And Successive Magnetic Transitions In Superconducting Sr2 Vfeaso3, Guanghan Cao, Zhifeng Ma, Cao Wang, Yunlei Sun, Jinke Bao, Shuai Jiang, Yi Luo, Chunmu Feng, Yi Zhou, Zhi Xie, Fengchun Hu, Shiqiang Wei, I Nowik, I Felner, Lei Zhang, Zhu-An Xu, Fu-Chun Zhang Jan 2010

Self-Doping Effect And Successive Magnetic Transitions In Superconducting Sr2 Vfeaso3, Guanghan Cao, Zhifeng Ma, Cao Wang, Yunlei Sun, Jinke Bao, Shuai Jiang, Yi Luo, Chunmu Feng, Yi Zhou, Zhi Xie, Fengchun Hu, Shiqiang Wei, I Nowik, I Felner, Lei Zhang, Zhu-An Xu, Fu-Chun Zhang

Faculty of Engineering - Papers (Archive)

We have studied a quinary Fe-based superconductor Sr2VFeAsO3 by the measurements of x-ray diffraction, x-ray absorption, Mössbauer spectrum, resistivity, magnetization, and specific heat. This apparently undoped oxyarsenide is shown to be self-doped via electron transfer from the V3+ ions. We observed successive magnetic transitions within the VO2 layers: an antiferromagnetic transition at 150 K followed by a weak ferromagnetic transition at 55 K. The spin orderings within the VO2 planes are discussed based on mixed valence of V3+ and V4+.


Magnetic Field Dependent Neutron Powder Diffraction Studies Of Ru0.9sr2ycu2.1o7.9, Rashmi Nigam, Alexey V. Pan, S. X. Dou, S J. Kennedy, A J Studer, N Stuesser Jan 2010

Magnetic Field Dependent Neutron Powder Diffraction Studies Of Ru0.9sr2ycu2.1o7.9, Rashmi Nigam, Alexey V. Pan, S. X. Dou, S J. Kennedy, A J Studer, N Stuesser

Faculty of Engineering - Papers (Archive)

Temperature and magnetic field dependent neutron diffraction has been used to study the magnetic order in Ru0.9Sr2YCu2.1O7.9. The appearance of (1/2, 1/2, 1/2), (1/2, 1/2, 3/2), and (1/2, 1/2, 5/2) peaks below TM = 140 K manifests the antiferromagnetic order. Neutron diffraction patterns measured in applied magnetic fields from 0 to 6 T show the destruction of the antiferromagnetic order with increasing field. There is no evidence of spontaneous or field-induced long range ferromagnetic order. This latter result contradicts the vast majority of other experimental observations for this system.


Synthesis, Structural Characterization And Magnetic Properties Of Iron Boride Nanoparticles With Or Without Silicon Dioxide Coating, Mislav Mustapic, Damir Pajic, Nikolina Novosel, Emil Babic, Kreso Zadro, Marina Cindric, Josip Horvat, Zeljko Skoko, Mirjana Bijelic, Andrey Shcherbakov Jan 2010

Synthesis, Structural Characterization And Magnetic Properties Of Iron Boride Nanoparticles With Or Without Silicon Dioxide Coating, Mislav Mustapic, Damir Pajic, Nikolina Novosel, Emil Babic, Kreso Zadro, Marina Cindric, Josip Horvat, Zeljko Skoko, Mirjana Bijelic, Andrey Shcherbakov

Faculty of Engineering - Papers (Archive)

Nanoparticles of iron boride (Fe2B, Fe2B coated in SiO2, FexCo2xB coated in SiO2) were synthesized using the reduction of metal ions by sodium borohydride. X-ray diffraction confirms the amorphicity of the coated compounds and scanning electron microscope imaging revealed the nanoparticulated structure of all compounds. The splitting between zero-field-cooled and field-cooled temperature dependent magnetization curves point to the blocking of superparamagnetic particles magnetization. Magnetic hysteresis loops are however consistent with the combined effects of blocked superparamagnetic and ferromagnetic (multidomain) particles. The observed quite complex magnetic behaviour is in …


Magnetic Flux Penetration In Polycrystalline Smfeo0.75f0.2as, Zhi W. Lin, Yong Jian Li, Jian G. Zhu, Youguang Guo, Xiaolin Wang Jan 2010

Magnetic Flux Penetration In Polycrystalline Smfeo0.75f0.2as, Zhi W. Lin, Yong Jian Li, Jian G. Zhu, Youguang Guo, Xiaolin Wang

Australian Institute for Innovative Materials - Papers

The recently discovered Fe–As superconducting materials which show high potential ability to carry current due to their low anisotropy have attracted a great number of attentions to understand their superconductivity mechanism and explore their applications. This paper presents a method to synthesis SmFeO0.75F0.20As polycrystalline by hot press in detail. The magnetization at different temperatures and applied fields obtained by a superconducting quantum interference device are also discussed. In addition, the local magnetization process is presented by magneto-optical imaging technique at the conditions of zero-field-cooling and field-cooling. It is found that the collective magnetization process …


Magnetotransport Of La0.70ca0.3-Xsrxmno3(Ag): A Potential Room Temperature Bolometer And Magnetic Sensor, V P. Awana, Rahul Tripathi, Neeraj Kumar, H Kishan, G V. Bhalla, Rong Zeng, L.S Sharth Chandra, V Ganesan, H U. Habermeier Jan 2010

Magnetotransport Of La0.70ca0.3-Xsrxmno3(Ag): A Potential Room Temperature Bolometer And Magnetic Sensor, V P. Awana, Rahul Tripathi, Neeraj Kumar, H Kishan, G V. Bhalla, Rong Zeng, L.S Sharth Chandra, V Ganesan, H U. Habermeier

Australian Institute for Innovative Materials - Papers

Here we report the optimized magnetotransport properties of polycrystalline La0.70Ca0.3−xSrxMnO3 and their composites with Ag. The optimization was carried out by varying the Sr and Ag contents simultaneously to achieve large temperature coefficient of resistance (TCR) as well as low field magnetoresistance (MR) at room temperature. Sharpest paramagnetic (PM)-ferromagnetic (FM) and insulator-metal (IM) transition is observed in the vicinity of the room temperature (TC≈300 K ≈TIM) for the composition La0.70Ca0.20Sr0.10MnO3:Ag0.20. Partial substitution of larger Sr2+ ions at the …


Lanthanum Doped Multiferroic Dyfeo3: Structural And Magnetic Properties, Yi Du, Zhenxiang Cheng, Xiaolin Wang, S X. Dou Jan 2010

Lanthanum Doped Multiferroic Dyfeo3: Structural And Magnetic Properties, Yi Du, Zhenxiang Cheng, Xiaolin Wang, S X. Dou

Australian Institute for Innovative Materials - Papers

Lanthanum doped multiferroic DyFeO3 was synthesized by solid state reaction. X-ray diffraction and refinement show that the lattice parameters of Dy1−xLaxFeO3 increase linearly with the La content. Raman spectroscopy reveals that the short-range force constant in Dy1−xLaxFeO3 is decreased by La3+ ion substitution. The spin reorientation phase transition temperature (TSRPT) is observed to decrease along with the doping level. The antiferromagnetic ordering temperature TN of Fe3+ ions is depressed with increasing doping level. Both decreasing TSRPT and decreasing TN indicate that Fe–Dy and Fe–Fe …


Giant Magnetic Entropy Change In Colossal Magnetoresistance In La0.7ca0.3mno3 Material In Low Field, Jyotish Debnath, Rong Zeng, Jung Ho Kim, S X. Dou Jan 2010

Giant Magnetic Entropy Change In Colossal Magnetoresistance In La0.7ca0.3mno3 Material In Low Field, Jyotish Debnath, Rong Zeng, Jung Ho Kim, S X. Dou

Australian Institute for Innovative Materials - Papers

The structural, magnetic, and magnetocaloric properties of the manganite La0.7Ca0.3MnO3 have been studied. Change in the giant magnetic entropy was observed without any noticeable magnetic hysteresis but with small thermal hysteresis losses. We observed a first order magnetic phase transition around 251 K. The magnetic entropy change observed in this work is estimated to be 5.27 J/kg K for field changes from 0 to 1.5 T based on magnetization measurements. This value is about twice as large as those for other perovskite manganites and is even larger than for Gd-based magnetic materials at low fields. …


Structure, Magnetic, And Thermal Properties Of Nd1-Xlaxcro3 (0 ≤ X ≤ 1.0), Yi Du, Zhenxiang Cheng, Xiaolin Wang, S X. Dou Jan 2010

Structure, Magnetic, And Thermal Properties Of Nd1-Xlaxcro3 (0 ≤ X ≤ 1.0), Yi Du, Zhenxiang Cheng, Xiaolin Wang, S X. Dou

Australian Institute for Innovative Materials - Papers

Perovskite-type Nd1−xLaxCrO3(0 ≤ x ≤1.0) polycrystalline samples were synthesized using solid state reaction. Structural studies indicate that the lattice parameters, metal–oxygen bond lengths, and angles of Nd1−xLaxCrO3 strongly depend on the La content. Two magnetic transition temperatures, Cr3+ antiferromagnetic ordering temperature (TN) and the spin reorientation phase transition temperature (TSRPT), have been observed in the M-T curves. The increase in TN and decrease in TSRPT with increasing x value can be explained by the change in the magnetic interactions due to La …