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Towards The Electronic Response Of Carbon-Based Van Der Waals Heterostructures In A Diamond Anvil Cell, George Thomas Foskaris
Towards The Electronic Response Of Carbon-Based Van Der Waals Heterostructures In A Diamond Anvil Cell, George Thomas Foskaris
UNLV Theses, Dissertations, Professional Papers, and Capstones
The nanoscale regime of materials has been at the forefront of research and interest in condensed matter physics for many years. In a merger of the fields of two-dimensional (2D) materials and high pressure physics, we present an investigation of the electronic response of carbon-based, van der Waals (vdW) heterostructures in a diamond anvil cell (DAC). Combining these fields presents us with the ability to study the characteristics of such systems both optically, and through electrical transport. Properties such as conductance, band structure, and layer number are considered. The samples in this study are assembled using exfoliation and stacking techniques …
Studies Of Inner-Shell Chemistry Of Mercury Based Compounds At Extreme Conditions, Sarah Schyck
Studies Of Inner-Shell Chemistry Of Mercury Based Compounds At Extreme Conditions, Sarah Schyck
UNLV Theses, Dissertations, Professional Papers, and Capstones
It has been theoretically predicted that when mercury difluoride (HgF2) is pressurized to above 50 GPa in the presence of molecular fluorine, it will most likely transform into mercury tetrafluoride (HgF4), thus mercury will behave as a transition element at high pressure. However, there is no experimental evidence verifying this prediction yet. To begin with, the crystalline properties of pure HgF2 at high pressure were not experimentally established. In this thesis, the high pressure structural properties of HgF2 are investigated by means of synchrotron X-ray powder diffraction. Our results reveal that the predicted, ambient cubic structure of HgF2 with the …
High Pressure Behavior Of Mullite-Type Oxides: Phase Transitions, Amorphization, Negative Linear Compressibility And Microstructural Implications, Patricia Kalita
High Pressure Behavior Of Mullite-Type Oxides: Phase Transitions, Amorphization, Negative Linear Compressibility And Microstructural Implications, Patricia Kalita
UNLV Theses, Dissertations, Professional Papers, and Capstones
Even though mullite occurs rarely in nature, it is perhaps one of the most important phases in both traditional and advanced ceramics. Existing and emerging applications of mullite and mullite-type materials include: high-temperature composites, aerospace materials, ballistic shielding for military applications and even non-linear optical materials. There are many uncertainties regarding the basic physical properties of mullite-type materials, particularly in terms of their high-pressure structural stability and mechanical behavior that are important to address for emerging applications of mullites as engineering materials. This work is the first reported comprehensive investigation of the high –pressure structural behavior of several different mullites …