Digital Commons Network^™

Social Justice Mathematics: Classroom Practices That Give Students Rigor While Building Agency, Emily Marquise

Masters Theses

The purpose of this study is to examine the impact of a social justice approach to mathematics instruction. While many students have math aversion, students in low socioeconomic communities exhibit this to a higher degree putting them at a disadvantage as they progress through their educational career. More than 3.4 million K-12 students in the United States come from families that earn less than the median income yet achieve scores in the top percentile (Wyner et al., 2007). This raises the question of why so many students in low-socioeconomic settings are not given rigorous content that will keep them competitive …

Targeting Macrophytes: Increased Water Quality Through Optimized Vegetation Considerations For Constructed Wetlands, Austin Mcbrady

Masters Theses

This study of constructed wetland design investigated relationships between macrophyte species selection and planting density for water quality improvement. A lab-scale wetland was compared against a pilot-scale wetland in San Antonio, Texas at Mitchell Lake to measure differences in effluent water quality improvement using three native macrophyte species. Using a novel, two-phase method, a targeting macrophyte was identified from among other species based on its marked capability for improving water quality factors, then was planted in varied majority densities to compare differences in treatment effectiveness. The results of this study showed that this complimentary approach to wetland design displayed significant …

The Impacts Of Tilled-In Biodegradable Plastic Mulch On Soil Microbial Communities, Corissa L. Martin

Masters Theses

Plastics mulch films are used in agriculture to help increase crop production by regulating soil water retention and soil temperature while also preventing weed growth. Despite these benefits, plastic mulches have led to higher levels of microplastic pollution as weathering occurs. In response to this issue, biodegradable plastic mulches (BDMs) have been introduced to help reduce plastic pollution as they are designed to be tilled into soil after each growing season to continue degradation. Degradation of these mulch films is dependent on climate and, in some areas, complete degradation can take years. Since some biodegradable plastic mulches are made of …

Synthesis Of Block Copolymer Additives For Examining Phase Morphology And Improving Mechanical Properties Of Thermoplastics Elastomers., Bishal Upadhyay

Masters Theses

Polystyrene-block-poly(1,4-butaidene)-block-polystyrene (PS-PB-PS) triblock copolymers are one of the most widely studied thermoplastic elastomers (TPEs) due to their ease of synthesis, non-polar nature, and commercial applicability. Like many block copolymers, incompatibility between PS and PB causes these TPEs to undergo microphase segregation. Many studies have examined the mechanical properties of blends of TPEs and PS homopolymer additives. However, there have been few studies focused on understanding the morphology and mechanical properties of blends of TPEs and copolymer additives with different architectures. Herein, I describe the synthesis of linear and graft copolymer additives based on the random copolymers poly(methyl methacrylate-random-cyclohexyl methacrylate) (PrC). …

The Influence Of Ion-Ion Correlations On Conductivity In Concentrated Ionic Systems, Md Dipu Ahmed

Masters Theses

This study delves into the fascinating realm of concentrated ionic systems, such as ionic liquids, superionic materials, organic ionic plastic crystals, and polyelectrolytes, which hold immense potential for energy storage applications. The focus is on understanding the intricate role of ionic correlations in shaping their ionic conductivity behavior. These correlations can either boost or impede conductivity, yet their underlying mechanisms remain elusive. Through extensive investigation of various materials, including ionic liquids with differing anionic masses, pure organic ionic plastic crystals, and doped systems, this research employs advanced techniques like dielectric spectroscopy and innovative momentum conservation models to quantify these correlations. …

Assessing The Effects Of The Spring Hunting Season Start Date On Wild Turkey Seasonal Productivity And Hunter Behavior, Joseph Quehl

Masters Theses

Many states throughout the Southeast have documented declines in wild turkey (Meleagris gallopavo) harvest and estimates of recruitment in poult-per-hen ratios. Wild turkey populations are driven by seasonal productivity, so the decline in these parameters may indicate a decline in the overall population. One hypothesis as to why we are seeing a reduction in productivity and a potential population decline is that the spring hunting season is disrupting the reproductive cycle by harvesting too many males before they have had the opportunity to breed, or by harvesting dominant males and disrupting the social hierarchy of the flock. Our …

Intrusion Detection: Machine Learning Techniques For Software Defined Networks, Jacob S. Rodriguez

Masters Theses

In recent years, software defined networking (SDN) has gained popularity as a novel approach towards network management and architecture. Compared to traditional network architectures, this software-based approach offers greater flexibility, programmability, and automation. However, despite the advantages of this system, there still remains the possibility that it could be compromised. As we continue to explore new approaches to network management, we must also develop new ways of protecting those systems from threats. Throughout this paper, I will describe and test a network intrusion detection system (NIDS), and how it can be implemented within a software defined network. This system will …

Metagenomic Profiling Of Cave Biofilms, With A Focus On Chemolithoautotrophy And Pseudonocardiaceae, John A. Fulginiti

Masters Theses

The dark, humid, and nutrient depleted conditions of caves set limitations on habitability and result in microbial diversity and community structures that differ from surface environments. Recent studies investigating cave microbiomes reveal that Pseudonocardiaceae, a family of bacteria belonging to the phylum Actinomycetota, are abundant in cave sediment and on rocks as subaerial biofilms, however little work has been done on attempting to characterize their diversity and metabolism within the environment. This study used shotgun metagenomics to characterize the functional potential of Pseudonocardiaceae, as well as other cave microbes, in cave site KN14 located in Knox County, Tennessee. Functions of …

Expression And Purification Of Polyketide Synthase Domains To Investigate Protein-Protein Interactions In Polyketide Biosynthetic Pathways, Mujeeb Adeyinka Wakeel

Masters Theses

Polyketide synthases (PKSs) are multienzyme proteins catalyzing the production of the polyketide class of natural products with vast structural diversity. Type II PKSs catalyze polyketide biosynthesis using discrete (standalone) enzymes (domains), while type I PKSs use covalently linked enzymes arranged in a module to catalyze polyketide production. It is hypothesized that type II PKSs are the precursors to type I PKSs, proposing that the genes encoding individual discrete enzymes in type II PKSs fused to give the multienzyme modules of type I PKSs. We reasoned that the intramolecular-like reactions occurring in type I PKS modules might be a driving force …

Unsupervised Machine Learning Of Tornado-Producing Storms In The Southeastern United States, Morgan R. Steckler

Masters Theses

The east-southeastern US is uniquely affected by storm and tornado-related damages, costs, injuries, and deaths. Based on doppler radar, satellite, and modeled data, previous research sought to understand these different types of storms that produce strong tornadoes. Many approaches to storm classification are time intensive, complex, and vary significantly across the literature. The purpose of this work is to (1) explore the radar-derived data structure and spread of strong tornado-producing mesoscale storms in the east-southeastern US; (2) use K-Means unsupervised machine learning methods to elucidate clusters (storm types) and clustering attributes; and (3) assess the utility of K-Means as a …

Numerical And Experimental Constraints On Trace Element Fractionation During Lunar Magma Ocean Solidification, Dian Ji

Masters Theses

Traditional lunar magma ocean (LMO) theory suggests the anorthositic lunar crust formed by floating of buoyant plagioclase, one of the major products of LMO solidification, on the surface of LMO. To test this model, after applying experimentally determined LMO solidification sequences, we compared calculated Rare Earth Element (REE) concentrations of lunar plagioclase to plagioclase in Apollo ferroan anorthosites and lunar anorthositic meteorites. Several initial LMO compositions, and lunar-relevant mineral-melt partition coefficient predictive models were tested (where the partition coefficient is the concentration ratio of a specific element between two phases). Compared with plagioclase in the natural samples, modeled plagioclase directly …

Phosphatase Enzyme-Responsive Synthetic Lipids For Liposome Immolation Towards Enhanced Cargo Release, Justin Thomas Kirby

Masters Theses

Liposomal nanoscale delivery vehicles have been shown to aid in the delivery of therapeutic cargo due to their ability to encapsulate and improve the pharmacokinetic properties of a range of drug molecules. However, liposome therapeutic potential could be enhanced by exerting greater control over liposome cargo delivery and release. This is being pursued by designing lipids that are able to respond to specific stimuli, particularly those overexpressed in diseased cells. In this thesis, we describe stimuli-responsive liposomes in which the enzyme alkaline phosphatase is used as the stimulus. This trigger was selected since this enzyme is overexpressed in certain cancer …

Redox-Active Polymerization Catalysts And Their Applications, Nicholas M. Shawver

Masters Theses

Traditional catalyst systems are reliable means to produce polymers with well-defined architectures and thermomechanical properties; however, they are often limited by a narrow monomer scope and their ability access few, if any, advanced polymer architectures. To address this limitation, a new class of catalysts have recently emerged that feature redox-active moieties that may access advanced architectures through catalyst electronic modulation that arises from redox events occurring on the ligand scaffold or at the active metal center itself. For example, researchers have explored the ability of redox-active catalysts to impart “on-off” kinetic control during ring-opening polymerizations and their ability to access …

Per- And Polyfluoroalkyl Substances (Pfas) In Treated Sewage Sludge From Michigan Wastewater Treatment Plants, Garrett Wesley Link

Masters Theses

Concentrations, compositions, and variability of Per- and Polyfluoroalkyl Substances (PFAS) in sewage sludge are characterized using an extensive dataset of 350 samples from 190 wastewater treatment plants (WWTPs) across Michigan. All samples are comprised of final treated sewage sludge generated at the end of the wastewater treatment process. Concentrations of Σ₂₄ PFAS are log normally distributed with a range of 1 to 3200 ng/g dry wt. and of average 108 ± 277 ng/g dry wt. Compounds with carboxyl and sulfonic functional groups comprised 29% and 71% of Σ24 PFAS concentrations, respectively, on average. Primary sample variability is associated with …

Per- And Polyfluoroalkyl Substances (Pfas) In Treated Sewage Sludge From Michigan Wastewater Treatment Plants, Garrett Wesley Link

Masters Theses

Concentrations, compositions, and variability of Per- and Polyfluoroalkyl Substances (PFAS) in sewage sludge are characterized using an extensive dataset of 350 samples from 190 wastewater treatment plants (WWTPs) across Michigan. All samples are comprised of final treated sewage sludge generated at the end of the wastewater treatment process. Concentrations of Σ₂₄ PFAS are log normally distributed with a range of 1 to 3200 ng/g dry wt. and of average 108 ± 277 ng/g dry wt. Compounds with carboxyl and sulfonic functional groups comprised 29% and 71% of Σ₂₄ PFAS concentrations, respectively, on average. Primary sample variability is associated …

Interstice, Shravan Rao

Masters Theses

When I was about three years old, I distinctly remember being too small to see what was on top of the table. A couple of years later, when I could see those objects, I thought the world around me had grown smaller. In a way, it did, as I experienced, lived, captured, remembered, and shared the space repeatedly. This sense of the world shrinking was exaggerated during the Covid-19 pandemic, allowing new behaviours and modes of interaction to emerge. Continually shaping our modern lives, virtual technologies redefine how we access and share information and stories or even explore new places. …

Reintroducing Hemp (Rongony) In The Material Palette Of Madagascar: A Study On The Potential Of Hemp Clay Components And Its Impact On Social And Ecological Communities., Henintsoa Thierry Andrianambinina

Masters Theses

When mentioning the word hemp, especially in the local language of Madagascar, the literal translation does not set it apart from marijuana, as they are both called “rongony” - creating the stigma around hemp as the negative stereotype of marijuana. However, the material has been used by the ancestors of Madagascar, as well as across cultures, in its fibrous form to produce fabrication like textile goods and packaging. During colonization, the prohibition of hemp intensified, and since then, any activity related to either of these plants is prohibited and will end in severe punitive measures. This thesis explores the strengths …

Public-Ish, Aliah Werth

Masters Theses

Climate change affects public space, and architecture must establish tenets that prioritize pedestrians in this difficult era. Greywater re-use can be a mechanism for creating shade, and in turn, public space.

As heat waves grow more intense, the vast swaths of asphalt that connect commercial zones pose greater risks to public health and to urban vitality. This thesis records the typical material, spatial, and lived conditions of strip malls in urban heat islands, and demands more from infrastructure in public-ish space.

Heat violence weaves through Los Angeles’ built form. Parking space minimums, required setbacks, and height restrictions pull buildings away …

Beyond The Lines, Miranda-Max De Beer

Masters Theses

Long-held frameworks and philosophies developed over human history have rarely accounted for dynamic flux or shifts between parallel states of being; they’ve ignored the glaring consequences humanity’s brief occupation of the Geologic Timeline will have on the planet. These beliefs have enabled societies to operate through life as if there was no tomorrow, (ab)using the Earth without considering those who eventually reap what’s sown. Beyond the Lines identifies manifestations of the mindset that restricts how we understand living systems and the world around us as so much of what exists in tandem with contemporary society does not adhere to the …

Temporary Urbanism-Spatial Democracy In The Temporary City, Shijie Li

Masters Theses

This thesis is committed to exploring and discussing the way people behave in the temporary urbanism, perceive and deploy their space arrangement rights and how this nourishes relationships between people, between people and society, and brings a greater sense of spiritual identity and belonging to people.

The modern city is the result of the spatial distribution of material production, urban space is political and oriented to the distribution of power, and citizens are deprived of the subjective qualification and right to participate in the creation o f urban cultural space. Many factors have led to the monopolization of human participation …

Unearthing Complexity: Tangible Histories Of Water And Earth, Alexis Violet

Masters Theses

Unearthing Complexity investigates conceptions of time and surface through geological stories of the water and earth. Building on theories of deep time, hydrofeminism, critical zones, and grounding, I hope to foster a deeper awareness of time scales other than our own and a more tangible understanding of the embodied experience of matter in the universe. Working toward a new literacy of the water and earth in which they are recognized as living, changing bodies to which we are inherently tied at a molecular level, the site of this multiscalar inquiry occurs in the coastal zones of the Narragansett Bay where …

Wast3d Potential, Andrew Larsen

Masters Theses

Waste is obsolete. Standard building industry practices are harmful to the environment. Non-traditional construction methods were examined as alternatives. Circular design logic was the guiding principle in material choice. Additive manufacturing is a proven modern method for building construction. Research on 3D printing case studies revealed that recycled plastic is a proven material and readily available. Removing plastic waste from the environment and sequestering it in architectural components gives the material a new purpose. The component of focus was a building block for a wall assembly. Inspiration was taken from the hexagonal Basalt rock formations found near volcanic fault lines. …

Fungi In Flux | Designing Regenerative Materials And Products With Mycelium, Arvind Bhallamudi

Masters Theses

As the world grapples with the escalating crisis of climate threats and environmental degradation, this research delves into the synergistic potential of design and biology, developing safe and sustainable materials for applications in prototyping, furniture and interior design. Harnessing the power of a unique organism - fungi, the study proposes an accessible, efficient, and resilient material resource system. It utilizes local waste streams and mycelium (the vegetative part of fungi) to grow functional structures. An experimental and small-scale protocol is modeled by testing bio-fabrication and bio-printing methods. The composites' performance qualities and characteristics are evaluated through mechanical testing and a …

Access In Ambiguity, Moritz Lónyay

Masters Theses

The wealth of color present in nature has long been a major source of inspiration for works of art and design. Yet as more species become extinct due to habitat loss, climate change and unchecked hunting, will we face a less colorful, more monotonous future? How will this impact art and design and how could either be utilized as tools to counteract the loss of color? This thesis speculates upon such a future by the sixth wave of mass extinction and instigates a movement that celebrates color. Growing up in the Anthropocene, the first geological epoch in which human existence …

Copper-Indazolate Nanojars: Synthesis And Characterization, Nicholas Alexander Rudell

Masters Theses

The field of synthetic supramolecular chemistry has exploded since the first syntheses of crown ethers by Charles Pedersen in the 1960s, leading to further development in the area of macrocycles and incorporation into a vast array of metal-organic structures. Supramolecular chemistry came to the forefront of science with the 1987 Nobel Prize in Chemistry, awarded jointly to Donald J. Cram, Jean-Marie Lehn, and Charles Pedersen “for their development and use of molecules with structure-specific interactions of high selectivity.”

Nanojars are supramolecular metal-organic complexes with a high affinity for hydrophilic anions and can efficiently transfer such anions from water into organic …

Detecting Ai Generated Text Using Neural Networks, Jesus Guerrero

Masters Theses

For humans, distinguishing machine generated text from human written text is men- tally taxing and slow. NLP models have been created to do this more effectively and faster. But, what if some adversarial changes have been added to the machine generated text? This thesis discusses this issue and text detectors in general.

The primary goal of this thesis is to describe the current state of text detectors in research and to discuss a key adversarial issue in modern NLP transformers. To describe the current state of text detectors a Systematic Literature Review was done on 50 relevant papers to machine-centric …

Interactive Data Analysis Of Multi-Run Performance Data, Vanessa Lama

Masters Theses

Multi-dimensional performance data analysis presents challenges for programmers, and users. Developers have to choose library and compiler options for each platform, analyze raw performance data, and keep up with new technologies. Users run codes on different platforms, validate results with collaborators, and analyze performance data as applications scale up. Site operators use multiple profiling tools to optimize performance, requiring the analysis of multiple sources and data types. There is currently no comprehensive tool to support the structured analysis of unstructured data, when holistic performance data analysis can offer actionable insights and improve performance. In this work, we present thicket, a …

Mapping Past Land Use Changes And Modeling Future Urbanization Patterns In A Mid-Sized American City, Duncan P. Mccurry

Masters Theses

On a global scale, humans have been moving from rural to urban areas at an increasingly fast rate in a process called urbanization. It is crucial to understand and predict the impacts of urbanization because city expansion encroaches on farmland and woodland, reducing regional ecosystem services. Therefore, urbanization must be well planned in a forecasting manner. The objective of this study is to map the land use change in Knox County, Tennessee, from 2001-2019 to identify the urbanization trends and understand the dynamic geospatial relationships between the urban and rural areas. The geospatial mapping was done using USGS land use …

Survey Of Input Modalities In The Western World, John Ezat Sadik

Masters Theses

Having your account compromised can lead to serious complications in your life. One
way accounts become compromised is through the security risks associated with weak
passwords and reused passwords [22,23]. In this thesis, we seek to understand how
entering passwords on non-PC devices contributes to the problems of weak and reused
passwords. To do so, we conducted a survey that was distributed to people in the
the Western World. In our survey results, we found that users commented about
how the current password model was not created with a variety of device types in
mind, which created frustrations and complexity …

Evaluating Bulk Carbon And Nitrogen Isotope Compositions Of Acidic Hydrothermal Sediments On Earth– Implications For Mars Astrobiology, Chance Sturrup

Masters Theses

Carbon isotopes have been widely used as unique biosignatures because biologic processes commonly result in distinctive negative delta ¹³C values (-35 to -10 ‰) within organic material on Earth. However, the bulk delta ¹³C analysis in Gale crater sediments on Mars revealed a wider range of values, from -25 to +56 ‰ (Franz et al., 2020), which suggests a more complex origin. To determine if bulk isotope analysis can be successfully used to detect a microbial signature in a martian analog environment, we analyzed concentrations and isotope compositions of C within hydrothermal sediments in Iceland (Námafjall, Krýsuvík, Hveragerdi) …