Digital Commons Network^™

Master's Project: Morey Mountain Conservation Area Management Plan, James M. Nash-Howe

Rubenstein School Masters Project Publications

The acquisition of the Morey Mountain Conservation Area (MMCA) adds another important parcel into the Upper Valley Land Trust’s (UVLT) portfolio of conserved lands; however, the specific conservation values found on the parcel were not known until recently.

In the summer of 2019, I, Max Nash-Howe—as a graduate student at the University of Vermont Rubenstein School of Environment and Natural Resources—spent several weeks surveying the property to inventory forest types, unique natural communities, and other important conservation values. My findings and recommendations for how the UVLT should manage the parcel to ensure the integrity of the conservation values found on …

Master’S Project: Vermont Town Forest Recreation Planning And Community Assistance Program: The Future Of Forest-Based Outdoor Recreation, Taylor M. Luneau

Rubenstein School Masters Project Publications

The Vermont Town Forest Recreation Planning Community Assistance Program (VTFRP) was a comprehensive community planning process held in ten diverse towns across Vermont. Led by the Urban and Community Forestry Program and the SE Group, the VTFRP helped towns develop a vision for the future management of their forests through open house workshops, site visits, steering committee meetings, and community surveys. The process provided towns with a forest recreation planning toolkit and an individualized action-based forest stewardship and recreation plan. By analyzing data from the community surveys and open house activities across all ten towns, my project considered the recreation …

Master's Project: Maple: A Sap To Syrup Guide, A Manual For Career And Technical Centers Of Vermont, Lynn Michelle Wolfe

Rubenstein School Masters Project Publications

Maple syrup production is a very important aspect of Vermont life and history. Every year in the early spring, people of all ages find their way to the woods to tap trees, collect sap, and participate in the great tradition of producing maple syrup. Maple syrup production is an essential industry from a historical, cultural, agricultural, and economic perspective. As the industry continues to grow, it creates potential employment opportunities for people of all ages, including recent high school graduates.

Through a collaboration between Vermont high school agriculture/natural resources instructors, the UVM Extension Maple Specialist, Shelburne Farms, and the UVM …

Ecology Of Composted Bedded Pack And Its Impact On The Udder Microbiome With An Emphasis On Mastitis Epidemiology, Tucker Andrews

Graduate College Dissertations and Theses

Infections of the cow udder leading to mastitis and lower milk quality are a critical challenge facing northeast organic dairy farmers. Limited mastitis treatment options are available to organic producers and bedding systems impact cow health, including mastitis risk. Composted bedded pack, a system touted for increased cow comfort and well-being, allows stratified accumulation of bedding and manure in the barn. This method is gaining popularity among organic producers, yet little is known about the microbiota of the accumulated pack and its interaction with the cow mammary gland. An in-depth single farm study was conducted that surveyed bedded pack (microbiome …

Metal Catalyzed Group 14 And 15 Bond Forming Reactions: Heterodehydrocoupling And Hydrophosphination, Michael Cibuzar

Graduate College Dissertations and Theses

Investigation of catalytic main-group bond forming reactions is the basis of this dissertation. Coupling of group 14 and 15 elements by several different methods has been achieved. The influence of Si–N heterodehydrocoupling on the promotion of α-silylene elimination was realized. Efficient Si–N heterodehydrocoupling by a simple, earth abundant lanthanide catalyst was demonstrated. Significant advances in hydrophosphination by commercially available catalysts was achieved by photo-activation of a precious metal catalyst.

Exploration of (N3N)ZrNMe2 (N3N = N(CH2CH2NSiMe3)33–) as a catalyst for the cross-dehydrocoupling or heterodehydrocoupling of silanes and amines suggested silylene reactivity. Further studies of the catalysis and stoichiometric modeling reactions hint …

Quantum Entanglement Of One-Dimensional Spinless Fermions, Emanuel Casiano-Diaz

Graduate College Dissertations and Theses

The constituents of a quantum many-body system can be inextricably linked, a phenomenon known as quantum entanglement. Entanglement can be used as a resource for quantum computing, quantum communication and detecting phase transitions, among others. The amount of entanglement can be quantified via the von Neumann and Rényi entropies, which have their origins in information theory.

In this work, the quantum entanglement between subsystems of a one dimen- sional lattice model of fermions is quantified. The von Neumann and Rényi entropies were calculated for two types of subsystems. In the first study, the subsystems were treated as two subsets of …

A Multi-Frequency Study Of Arecibo Pulsars, Timothy Eugene Edward Olszanski

Graduate College Dissertations and Theses

Compact Objects (Neutron Stars) form in the last moments of a star's life, during the violent events known as supernovae. As the star's core fusion falters, matter undergoes a dramatic gravitational compression resulting in internal densities rivaling subatomic particles. Ever since their discovery in the mid-twentieth century, these highly magnetized and rapidly rotating balls of condensed matter have provided a bountiful playground for astronomers seeking out exotic physics.

Neutron Stars that emit electromagnetic radiation are seen by observers as Pulsars, named such for the pulse of intensity as the pulsar's radiation beam passes into our line of sight. These beams …

Spectroscopic Study Of The Formation And Degradation Of Metalated Tetrapyrroles By The Enzymes Cfba, Isdg, And Mhud, Ariel E. Schuelke-Sanchez

Graduate College Dissertations and Theses

Metal tetrapyrroles represent a large class of earth-abundant catalysts but are limited to naturally-occurring combinations. Chelatase enzymes are responsible for the catalyzed metal insertion into a specific tetrapyrrole. CfbA is a class II chelatase from Archaeaglobis

fulgidus that catalyzes the insertion of nickel into sirohydrochlorin to give rise to Coenzyme F430 required for methanogensis. This archaeal chelatase was used to study the substrate scope of divalent metals and tetrapyrroles to probe various metal tetrapyrrole

combinations. A spectroscopic study established that the CfbA is capable of binding to cobalt and nickel, in addition to various tetrapyrroles. Magnetic circular dichroism (MCD) established …

Local Farmer Knowledge Of Adaptive Management On Diversified Vegetable And Berry Farms In The Northeastern Us, Alissa White

Graduate College Dissertations and Theses

Agricultural adaptation to climate change is notoriously context specific. Recently updated projections for the Northeastern US forecast increasingly severe and erratic precipitation events which pose significant risks to every sector of agricultural production in the region. Vegetable and berry farmers are among the most vulnerable to the risks of severe precipitation and drought due to the intensive soil and crop management strategies which characterize of this kind of production. To successfully adapt to a changing climate, these farmers need information which is tailored for the unique challenges of vegetable and berry production, framed at the level of climate impacts, and …

Shining Light On The Storm: Using High-Frequency Optical Water Quality Sensors To Characterize And Interpret Storm Nutrient And Carbon Dynamics Among Contrasting Land Uses, Matthew Ch Vaughan

Graduate College Dissertations and Theses

Elevated nutrient concentrations present significant challenges to surface water quality management globally, and dissolved organic matter mediates several key biogeochemical processes. Storm events often dominate riverine loads of nitrate, phosphorus, and dissolved organic matter, and are expected to increase in frequency and intensity in many regions due to climate change. The recent development of in situ optical sensors has revolutionized water quality monitoring and has highlighted the important role storms play in water quality. This dissertation focuses on improving the application of in situ optical water quality sensors and interpreting the high-frequency data they produce to better understand biogeochemical and …

Vo(Dtpa) Complexes Immobilized On Mesoporous Silica: Structural Characterization And Mechanistic Investigation Of Sulfide And Alkene Oxidation Reactions, Jenna R. Taft

Graduate College Dissertations and Theses

It was recently shown that V-doped acid-prepared mesoporous silica (APMS) nanoparticles are active catalysts for the oxidation of the mustard gas analogue 2-chloroethyl ethyl sulfide (CEES) under ambient conditions in the presence of aldehydes, using O2 from air as the oxidation source. However, the vanadium ion leached from the surface when water was present, leading to decreased catalytic activity. Therefore, in this work, the environment around the vanadium is changed, using diethylenetriamine pentaacetic acid (dtpa) as a ligand and anchoring it to the surface of a mesoporous silica nanoparticle, to investigate its effect on vanadium’s ability to perform oxidation reactions. …

Modeling Agricultural Outcomes In A Warmer, Wetter Vermont, Rachel Mason

Graduate College Dissertations and Theses

This thesis aimed to model agricultural outcomes that are important to Vermont dairy farms and their surrounding communities -- runoff, erosion, nitrogen and phosphorus losses, crop yields, and timeliness of farm operations -- under a set of possible future climates. The Agricultural Policy/Environmental eXtender (APEX) model was used for this work, and the models were calibrated using data from a project that measured most of these outcomes on a set of local farms. The model setup and calibration methodology is thoroughly documented and may be a useful starting point for others who are new to agricultural modeling.

Applied to two …

Applications In Sentiment Analysis And Machine Learning For Identifying Public Health Variables Across Social Media, Eric Michael Clark

Graduate College Dissertations and Theses

Twitter, a popular social media outlet, has evolved into a vast source of linguistic data, rich with opinion, sentiment, and discussion. We mined data from several public Twitter endpoints to identify content relevant to healthcare providers and public health regulatory professionals. We began by compiling content related to electronic nicotine delivery systems (or e-cigarettes) as these had become popular alternatives to tobacco products. There was an apparent need to remove high frequency tweeting entities, called bots, that would spam messages, advertisements, and fabricate testimonials. Algorithms were constructed using natural language processing and machine learning to sift human responses from automated …

Strain Accommodation, Metamorphic Evolution, And 3d Kinematics Of Transpressional Flow Within The Lower Crust Of A Cretaceous Magmatic Arc In Fiordland, New Zealand, Griffin Amoss Moyer

Graduate College Dissertations and Theses

The George Sound Shear Zone (GSSZ) exposed in Bligh Sound within Fiordland, New Zealand allowed us to reconstruct the kinematics of transpressive flow in >100 km2 of exhumed Cretaceous lower crust. We compare the three-dimensional characteristics of the deformation to theoretical models of transpression that assume steady-state flow in a homogeneous medium. This assumption is rarely the case for shear zones that experience metamorphism during deformation. We determined the three-dimensional kinematics of the GSSZ and evaluated the effects of metamorphism on strain accommodation and structural fabric evolution in the GSSZ to determine if metamorphism is an important parameter that transpressional …

Expansion Of The Intramolecular Zwitterionic-1,3-Diaza-Claisen Rearrangement Beyond Bridged-Bicyclic Electron-Deficient Isothioureas To Generate Substituted Cyclic Guanidines, Matthew William Luedtke

Graduate College Dissertations and Theses

Guanidines are ubiquitous in nature and have important applications in biological chemistry and industry, presenting themselves in biomacromolecules and organic materials respectively. The zwitterionic-1,3-diaza-Claisen rearrangement has allowed facile access to a variety of highly-substituted, complex guanidines, which would otherwise require a significant amount of time or resources to synthesize.

Previously, the intramolecular version of the 1,3-diaza-Claisen rearrangement has been used to generate tricyclic guanidines from bridged, bicyclic electron-deficient isothioureas. Extension of this methodology to simpler electron-deficient isothioureas has afforded stable zwitterionic intermediates, which have been isolated via silica gel column chromatography with common organic solvents. Heating the zwitterionic intermediates in …

Modeling Electric Vehicle Energy Demand And Regional Electricity Generation Dispatch For New England And New York, Sarah E. Howerter

Graduate College Dissertations and Theses

The transportation sector is a largest emitter of greenhouse gases in the U.S., accounting for 28.6% of all 2016 emissions, the majority of which come from the passenger vehicle fleet [1,2]. One major technology that is being investigated by researchers, planners, and policy makers to help lower the emissions from the transportation sector is the plug-in electric vehicle (PEV). The focus of this work is to investigate and model the impacts of increased levels of PEVs on the regional electric power grid and on the net change in CO2 emissions due to the decrease tailpipe emissions and the increase in …

An Analysis Of Energy Transitions At Different Scales: Fossil Fuel Divestment In Higher Education And Individual Behavior, Elizabeth Palchak

Graduate College Dissertations and Theses

A sociotechnical energy transition requires both a shift to new technologies and attention to social issues like political movements, policy and human behavior. This dissertation investigates social elements of the renewable energy transition occurring at different scales. The core research questions are: How are universities creating and responding to the shifting language of fossil fuel investments? How and for whom do behavioral interventions work? And finally, do in-home displays (IHDs) change behaviors and attitudes of millennial energy users?

The three studies covered here occurred within higher education and reflect the importance of colleges and universities as dynamic players in energy …

Phosphorus Mobility And Speciation Under Dynamic Redox Conditions In Shallow Eutrophic Freshwater Systems, Austin Wilkes

Graduate College Dissertations and Theses

Internal loading of phosphorus (P) from lake sediments can delay the recovery of lakes from eutrophication for years to decades following decreases in external nutrient inputs. While internal P loading is a pervasive problem in freshwater systems, molecular speciation of P in benthic sediments of these systems remains poorly characterized. As different P species will exhibit different responses to changing sediment-water interface (SWI) geochemistry, quantifying P speciation in sediments is a critical step in understanding P dynamics in sediment-water systems. Here, various synchrotron-based techniques were employed to directly probe the bonding environments of P and iron (Fe) in natural and …

Measuring Linguistic And Cultural Evolution Using Books And Tweets, Tyler Gray

Graduate College Dissertations and Theses

Written language provides a snapshot of linguistic, cultural, and current events information for a given time period. Aggregating these snapshots by studying many texts over time reveals trends in the evolution of language, culture, and society. The ever-increasing amount of electronic text, both from the digitization of books and other paper documents to the increasing frequency with which electronic text is used as a means of communication, has given us an unprecedented opportunity to study these trends. In this dissertation, we use hundreds of thousands of books spanning two centuries scanned by Google, and over 100 billion messages, or ‘tweets’, …

Multiscale Expression Of Apatite Dissolution, Adele Conde

Graduate College Dissertations and Theses

The weathering of apatite is the foundation of the phosphorus cycle and essential to life, yet little is known about the nanoscale mechanisms driving apatite weathering. Deciphering nanoscale dissolution in apatite is a significant step to understand phosphate weathering behavior, that was key to the development of life. Determining what controls apatite weathering can impact many areas of environmental and medical mineralogy such as dentistry, contaminant scavenging, geochronology, and paleoenvironment studies. The aim of this study was to characterize apatite dissolution across scales with an emphasis on the nanoscale mechanisms. Recent research on the weathering of silicate minerals at the …

Residual Soil Phosphorus In Tropical Oxisols: An Opportunity To Enhance Fertilizer Use Efficiency?, Lauren Bomeisl

Graduate College Dissertations and Theses

Phosphorus (P) is essential to life on Earth and often the limiting nutrient in agricultural systems. P fertilizer is thus an essential resource to maintain food security. In the last half century, agricultural intensification has led to an increase in P fertilizer consumption from 4.6 to 17.5 Tg of P/year to meet rising global food demand. Mineral P (i.e., phosphate rock) is a non-renewable resource in the context of the Anthropocene, and its price is vulnerable to global market fluctuations. Increased efficiency of P use on farms is considered the most effective strategy to conserve P. The soybean industry demands …

Edge-Of-Field Hydrology And Nutrient Fluxes Within Northeastern Agroecosystems: Evaluation Of Alternative Management Practices And Water Quality Models, Cameron Robert Twombly

Graduate College Dissertations and Theses

Agricultural runoff is one of largest contributors of phosphorus (P), nitrogen (N), and sediment affecting freshwater systems in watersheds across the Northeastern U.S., including the Lake Champlain Basin in Vermont. Agricultural cropping systems, such as corn silage and haylands, used for dairy feed production have been shown to impact watershed hydrology and water quality. Agricultural best management practices (BMPs) have the potential to decrease runoff volumes and flow rates and the associated export of nutrients and sediment from agricultural fields. Many states in the Northeastern U.S., including Vermont, are beginning to require farmers to implement water quality BMPs and further …

Quadrature-Based Gravity Models For The Homogeneous Polyhedron, Jason Pearl

Graduate College Dissertations and Theses

A number of missions to comets and asteroids have been undertaken by major space organizations driving a need to accurately characterize their gravitational fields. This is complicated however by their irregular shapes. To accurately and safely navigate spacecraft in these environments, a simple point-mass gravity model is insufficient and instead higher-fidelity models are required. Several such models exist for this purpose but all posess drawbacks. Moreover, there are some applications for which the currently available models are not particular well suited.

In this dissertation, numerical quadrature and curvilinear meshing techniques are applied to the small body gravity problem. The goal …

I. Contorted Polycyclic Aromatic Hydrocarbons: Attempted Synthesis Of [12]Circulene Derivatives Ii. Synthesis And Characterization Of Novel [1]Benzothieno[3,2-B][1]Benzothiophene Derivatives, Jonathan Hollin

Graduate College Dissertations and Theses

There has been increasing interest in the development of organic materials due to their unique structural and electronic properties. Organic compounds have the advantage of being able to be deposited from solution, leading to low-cost, high-area electronics production. Contorted polycyclic aromatic hydrocarbons have been shown to have potential for use in organic field-effect transistors (OFETs) and organic photovoltaic devices (OPVs) due to their supramolecular properties and charge carrier mobilities. Thiophene-based materials have also shown great promise in OFETs due to their high charge carrier mobilities, stability during device operation, solubility in organic solvents, and structural versatility.

[n]Circulenes are a class …

Evaluation Of Mysis Partial Diel Vertical Migration, Brian Patrick O'Malley

Graduate College Dissertations and Theses

Mass animal migrations represent large movements of biomass, energy, and nutrients with predictable patterns and important ecosystem-level consequences. Diel vertical migration (DVM) in aquatic systems, the daily movement of organisms from deeper depths during the day to shallower depths in the water column at night, is widespread in freshwater and marine systems. Recent studies, however, suggest partial migration behavior, whereby only some portion of a population migrates, is the rule rather than the exception in a range of migratory fauna, including those that undergo DVM. Hypotheses to explain why partial migrations occur complicate traditional views on DVM and challenge conventional …

Rehab Tracker: Framework For Monitoring And Enhancing Nmes Patient Compliance, Timothy Stevens

Graduate College Dissertations and Theses

We describe the development of a cyber-physical system (Rehab Tracker) for improving patient compliance with at-home physical rehabilitation using neuromuscular electrical stimulation (NMES) therapy. Rehab Tracker consists of three components: 1) hardware modifications to sense and store use data from an FDA-approved NMES therapy device and provide Bluetooth communication capability, 2) an iOS-based smartphone/tablet application to receive and transmit NMES use data and serve as a conduit for patient-provider interactions and 3) a back-end server platform to receive device use data, display compliance data for provider review and provide automated positive and remedial push notifications to patients to improve compliance. …

Physicochemical Properties Of Residuals From Anaerobic Digestion Of Dairy Manure And Food Waste: Nutrient Cycling Implications And Opportunities For Edible Mushroom Cultivation, Brendan J. O'Brien

Graduate College Dissertations and Theses

Organics recycling is increasing in New England as multiple states have enacted laws to divert organic materials, including food scraps and food processing residuals, away from landfills. Anaerobic digesters on dairy farms represent an attractive approach to food waste recycling because existing infrastructure is in place and co-digestion of dairy manure with food waste can increase renewable biogas production. In addition, anaerobic digestion results in effluents that can be separated into solid and liquid residual materials, or 'digestates'. Screw-press separated solids consist of lignocellulosic biomass resistant to microbial degradation during anaerobic digestion. These separated solids are typically recycled on farms …

Climate Change And Land Use/Cover Change Impacts On Watershed Hydrology, Nutrient Dynamics – A Case Study In Missisquoi River Watershed, Linyuan Shang

Graduate College Dissertations and Theses

Watershed regulation of water, carbon and nutrient dynamics support food, drinking water and human development. Projected climate changes and land use/cover change (LUCC) have been identified as drivers of watershed nutrient and hydrological processes and are likely to happen jointly in the future decades. Studying climate change and LUCC impacts on watersheds' streamflow and nutrients dynamics is therefore essential for future watershed management.

This research aimed to unveil how climate change and LUCC affect water and nutrient dynamics in the Missisquoi River watershed, Vermont. We used 12 scenarios of future climate data (2021 – 2050) generated by three GCMs (ccsm4, …

Higher-Order Runge--Kutta Type Schemes Based On The Method Of Characteristics For Hyperbolic Equations With Crossing Characteristics, Jeffrey Steven Jewell

Graduate College Dissertations and Theses

The Method of Characteristics (MoC) is a well-known procedure used to find the numerical solution of systems of hyperbolic partial differential equations (PDEs). The main idea of the MoC is to integrate a system of ordinary differential equations (ODEs) along the characteristic curves admitted by the PDEs. In principle, this can be done by any appropriate numerical method for ODEs. In this thesis, we will examine the MoC applied to systems of hyperbolic PDEs with straight-line and crossing characteristics. So far, only first- and second-order accurate explicit MoC schemes for these types of systems have been reported. As such, the …

Uncovering The Drivers Of Non-Native Plant Invasions Using Ecological Data Synthesis, Marina Golivets

Graduate College Dissertations and Theses

Understanding what promotes invasiveness of species outside their native range and predicting which ecosystems and under which conditions will be invaded is an ultimate goal of the field of invasion ecology. Obtaining general answers to these questions requires synthesis of extensive yet heterogeneous empirical evidence, coupled with a solid theoretical background. In this dissertation, I sought to provide insight into the drivers of non-native plant invasions through combining and synthesizing ecological data from various sources using advanced statistical techniques. The results of this work are presented as three independent research studies.

In the first study, I aimed to understand what …