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Visualization Of Molecular Dynamics Simulation Data, Suroj Shrestha Nov 2012

Visualization Of Molecular Dynamics Simulation Data, Suroj Shrestha

Honors Theses

No abstract provided.


Numerical And Experimental Evaluation Of Preheated Premixed Flames At Lean And Rich Conditions, Joseph Edward Gibson Jan 2012

Numerical And Experimental Evaluation Of Preheated Premixed Flames At Lean And Rich Conditions, Joseph Edward Gibson

LSU Master's Theses

Preheating a combustible mixture enhances the laminar burning flux characteristic mad with high reaction firing rates. As a result, the flammable zone as defined by inlet conditions of equivalence ratio and temperature is expanded beyond that available at standard ambient conditions; however, fundamental questions in these combustion regimes have not been addressed. In this thesis, preheated lean and rich combustion of methane/air mixtures is studied numerically and experimentally to catalog and confirm expected trends in these regimes. Numerical simulations were completed using both GRI-Mech 3.0 and San Diego mechanisms in the combustion code Cantera. An adiabatic simulation data set …


Biodegradation And Distribution Of Crude Oil Sampled At Fourchon Beach, Kendall Ray Lemelle Jan 2012

Biodegradation And Distribution Of Crude Oil Sampled At Fourchon Beach, Kendall Ray Lemelle

LSU Master's Theses

This study was developed to determine the distribution and fate of crude oil spilled from the Deepwater Horizon oil rig starting on April 24, 2010. Crude oil from this spill contaminated portions of Fourchon Beach, Louisiana which was the study site for this thesis. Understanding the fate processes that affect crude oil once it’s released is important because the compounds that comprise oil can be hazardous to humans and wildlife. Composite and small surface residual ball (SSRB) samples were collected from the supratidal zone of Fourchon Beach and analyzed for PAHs and alkanes. Alkane concentrations decreased significantly over time, while …


Laboratory Evaluation Of Geosynthetics To Stabilize/Reinforce The Subgrade/Base In Unpaved Roadways, Imran Akond Jan 2012

Laboratory Evaluation Of Geosynthetics To Stabilize/Reinforce The Subgrade/Base In Unpaved Roadways, Imran Akond

LSU Master's Theses

This research study evaluates the performance of geosynthetic material for subgrade stabilization and base reinforcement of unpaved test sections. For this purpose, extensive large-scale in-box static plate load tests were conducted on several unreinforced and geosynthetic reinforced, unpaved test sections. This research was conducted in Geotechnical Engineering Research Laboratory (GERL) at Louisiana Transportation Research Center (LTRC). The in-box static plate load tests (ASTM D1196-93) were conducted to evaluate the performance and benefits of geosynthetic material for subgrade stabilization/base reinforcement. A total of forty-seven tests were performed in this regard. The quality control of the section was maintained using non-destructive in-situ …


Field Investigation Of Wave And Surge Attenuation In Salt Marsh Vegetation And Wave Climate In A Shallow Estuary, Ranjit S. Jadhav Jan 2012

Field Investigation Of Wave And Surge Attenuation In Salt Marsh Vegetation And Wave Climate In A Shallow Estuary, Ranjit S. Jadhav

LSU Doctoral Dissertations

This research investigates and quantifies the effectiveness of salt marsh vegetation in reducing storm-induced waves and surge, and the potential for wetland erosion due to wave action, using field measurements on the Louisiana coast. To quantify wave attenuation and wave energy dissipation by vegetation (Spartina alterniflora), wave data were measured along a transect using pressure transducers during two tropical storms. Measurements showed that incident waves attenuated exponentially over the vegetation. The linear spatial wave height reduction rate increased from 1.5% to 4% /m as incident wave height decreased. The bulk drag coefficient estimated from the field measurements decreased with increasing …


Growth Rate And Productivity Of A Louisiana Native Microalgae/Cyanobacteria Co-Culture: Feasibility For Use In Industrial Biotechnology Applications, Athens Gomes Silaban Jan 2012

Growth Rate And Productivity Of A Louisiana Native Microalgae/Cyanobacteria Co-Culture: Feasibility For Use In Industrial Biotechnology Applications, Athens Gomes Silaban

LSU Master's Theses

Interest in biofuels research has increased in the era of uncertainty of the current fossil fuel sustainability and global climate concerns. Microalgae offer advantages over terrestrial plants as a potential source of biomass-based fuel. In this study, a Louisiana native microalgae/cyanobacteria (Chlorella vulgaris/Leptolyngbya sp.) co-culture was examined to provide foundational information of its growth conditions. Batch studies were conducted to determine optimum nitrogen and irradiance level that yields maximum co-culture biomass growth and productivity under aerated and non-aerated conditions. The optimum nitrogen level was 2.94 mM N and the optimum initial scalar irradiance range was between 400 – 800 µmol …


Electric Elevator Drive With Position Control, Peter James Ford Jan 2012

Electric Elevator Drive With Position Control, Peter James Ford

LSU Master's Theses

This thesis is a study on the implementation of an elevator’s position-controlled electric drive. The information contained within this paper serves as a framework to expand the usefulness of electric drives through the addition of digital control systems and switching power supplies. The tangible example of an elevator driven by a permanent-magnet DC motor is used for this paper so that students may relate to the work and apply it to their future projects. The tasks to be accomplished in order to achieve an electric elevator drive with position control are: determining the parameters of the permanent-magnet DC motor, designing …


Low-Order Modeling Of Micro-Flier Impact With Thin Stationary Energetic Targets, Mark B. Fry Jan 2012

Low-Order Modeling Of Micro-Flier Impact With Thin Stationary Energetic Targets, Mark B. Fry

LSU Master's Theses

The impact of high-speed (500-1500 m/s), laser driven micro-fliers with thin energetic targets (10-100 &# 956;m) is being examined to characterize impact-induced heating and combustion of these materials. Aluminum fliers are propelled by a laser into a thin metallic target plate having a layer of energetic material deposited on its backside. Mass spectrometry is performed in vacuo on the energetic side to interrogate the shock-induced chemistry of the energetic material. It is important to ignite and possibly detonate the energetic material without perforation of the target plate avoiding contamination of the vacuum chamber. To guide development of these experiments, a …


Combinatorial Multi-Level Mold Inserts Using Micro Machining And X-Ray Lithography, Oblesh Jinka Jan 2012

Combinatorial Multi-Level Mold Inserts Using Micro Machining And X-Ray Lithography, Oblesh Jinka

LSU Master's Theses

The present technology advancement in biomedical, micro-electro-mechanical systems (MEMS) engineering, bio-MEMS, healthcare, etc. is driving the need to fabricate devices with multi-level, high aspect ratio and complex microstructures, which in turn requires high quality mold inserts with all these features. The present thesis is concentrated in fabricating a multi-level mold insert with complex quasi 3 dimensional micro structures with dimensions down to 10µm and aspect ratios greater than 30 using a process combination of micro milling with X-ray lithography. Therefore, in this study the main focus was to fabricate a high quality mold insert template, which can be electroplated to …


The Effect Of Elevated Water Content On Ethanol Combustion, Baine Bernard Breaux Jan 2012

The Effect Of Elevated Water Content On Ethanol Combustion, Baine Bernard Breaux

LSU Master's Theses

Ethanol is currently being considered as a potential alternative to traditional fuels. However, the fuel offers a low return in terms of energy output per dollar invested when compared to fossil fuels. More than 1/3 of the cost associated with bio-ethanol production is devoted to distillation and water removal. This study seeks to validate the use of hydrous ethanol as a practical fuel to be used in lieu of fossil fuels or anhydrous ethanol. Success would reduce the production cost associated with ethanol fuel. Hydrous ethanol was burned in a swirl-stabilized combustor, air is introduced at a constant flow rate …


Reductive Dechlorination Of High Concentrations Of 1,2-Dichloroethane, 1,2-Dichloropropane, And 1,1,2-Trichloroethane By Dehalogenimonas Sp., Andrew D. Maness Jan 2012

Reductive Dechlorination Of High Concentrations Of 1,2-Dichloroethane, 1,2-Dichloropropane, And 1,1,2-Trichloroethane By Dehalogenimonas Sp., Andrew D. Maness

LSU Master's Theses

The research goals presented here were to evaluate the solvent concentrations over which Dehalogenimonas lykanthroporepellens strain BL-DC-9T and Dehalogenimonas sp. IP3-3 are able to reductively dechlorinate 1,2-dichloroethane (1,2-DCA), 1,2-dichloropropane (1,2-DCP), and 1,1,2-trichloroethane (1,1,2-TCA). Both of these novel bacteria were isolated from contaminated groundwater at the PetroProcessors of Louisiana, Inc. Superfund site located near Baton Rouge. Both cluster in the phylum Chloroflexi, related to, but distinct from, the widely studied, reductively dechlorinating “Dehalococcoides” strains .

Although previous research demonstrated that strains BL-DC-9T and IP3-3 are able to reductively dechlorinate a variety of polyhalogenated alkanes, the solvent concentration at which the strains …


Frp Stiffener Efficiency Coefficient For Sbs Shear Strengthening Applications, Hamed Babaizadehroshanfekr Jan 2012

Frp Stiffener Efficiency Coefficient For Sbs Shear Strengthening Applications, Hamed Babaizadehroshanfekr

LSU Master's Theses

The use of composite materials such as Fiber Reinforced Polymer (FRP) to strengthen concrete structures has surged during the past two decades as an alternative for conventional methods of structural strengthening and repair. FRP materials are light and relatively easy to install. They are noncorrosive, durable and less vulnerable to environmental conditions in comparison to other construction and retrofitting materials. The knowledge and applications of composites for strengthening steel structures are relatively smaller when compared to concrete strengthening applications. Strengthening-By-Stiffening (SBS) is a new strengthening alternative that was developed at Louisiana State University. SBS has proven to be a practical …


Determining The Performance Of Breakwaters During High Energy Events: A Case Study Of The Holly Beach Breakwater System, Andrew Keane Woodroof Jan 2012

Determining The Performance Of Breakwaters During High Energy Events: A Case Study Of The Holly Beach Breakwater System, Andrew Keane Woodroof

LSU Master's Theses

Breakwaters have been constructed in many areas along Louisiana’s coastline to protect the shoreline from wave energy and erosion. During normal conditions, these breakwaters can typically be analyzed using traditional empirical methods for emergent breakwaters. However, Louisiana’s coastline is under constant threat from tropical storms and hurricanes, during which breakwaters can frequently become overtopped or submerged systems. Recent studies show that the type of shoreline response to a breakwater system may vary depending on the crest height of the breakwater in relation to the mean water level. Though emergent breakwaters typically induce sediment accretion along the shoreline, studies using laboratory …


Morphology Controlled Coating Of Catalytically Active Gold Structures Within Flow-Focused Millifluidic Reactor, Chelliah V. Navin Jan 2012

Morphology Controlled Coating Of Catalytically Active Gold Structures Within Flow-Focused Millifluidic Reactor, Chelliah V. Navin

LSU Master's Theses

Synthesis of micro/nanomaterials within confined flow-based systems such as microfluidics has always been a promising research. However, the inability to scale up reagent volumes due to geometric constraints and pressure development within the channels at higher flow rates has limited their usage. In recent times, millifluidics has emerged as a useful technique where, apart from the synthesis, the in situ characterization of materials becomes easier. In this study, formation of morphology-controlled gold structures at different time intervals (viz. 1, 5, and 9 h) within a millifluidic chip reactor was investigated using gold chloride and dimercaptosuccinic acid (DMSA) as precursor reagents …


Base-Caged Adenosine Triphosphate As A Model System For Photoactivatable Small Interfering Rna, Amanda Yoesting Hendrix Jan 2012

Base-Caged Adenosine Triphosphate As A Model System For Photoactivatable Small Interfering Rna, Amanda Yoesting Hendrix

LSU Master's Theses

Photocaged adenosine triphosphate (ATP) is one of the earliest examples of exerting spatial-temporal control over the activity of a substrate. The activity of ATP is blocked until near-ultraviolet light exposure photocleaves the cage moiety. Caged ATP has been used for a myriad of applications including kinetic studies of ATP-dependent enzymes. Traditional caging of ATP occurs at the gamma-phosphate, which has been found to competitively inhibit several enzymatic systems. It was hypothesized that blocking access to the adenosine N6 position via cage molecule would prevent the initial enzyme-substrate binding event from occurring prior to photolysis, effectively minimizing competitive inhibition. Utilizing a …


Rapid Microwave Drying Of Non-Food Agricultural Feedstock For Improved Biofuel Production, Laura A. Picou Jan 2012

Rapid Microwave Drying Of Non-Food Agricultural Feedstock For Improved Biofuel Production, Laura A. Picou

LSU Master's Theses

Due to limited supply of traditional fossil based fuels, and increased interest in air and water quality along with other environmental concerns, there has been a rise in the utilization of biomass based energy sources. Many agricultural materials can be used for the production of biofuels, including materials that are typically underutilized such as sweet sorghum bagasse and otherwise nuisance species such as Chinese tallow tree seeds. The goal of this project was to examine the relationship between the dielectric properties of sweet sorghum bagasse and Chinese tallow tree (CTT) seeds, respectively, and frequency and moisture content; to determine pertinent …


Stabilization Of Very Weak Subgrade Soil With Cementitious Stabilizers, Sanjay Kumar Dhakal Jan 2012

Stabilization Of Very Weak Subgrade Soil With Cementitious Stabilizers, Sanjay Kumar Dhakal

LSU Master's Theses

To evaluate the effect of high moisture content on the performance of weak subgrade soil and improve the engineering properties of weak subgrade soil through using cementitious materials, five different soils that represent range of subgrade soil in Louisiana (based on plasticity indices) were collected and considered in this research study. All tests on raw soils and treated/stabilized soils were performed on the soil laboratory at the Louisiana Transportation Research Center (LTRC). Ordinary Portland cement and hydrated lime were selected in this study to treat/stabilize the subgrade soils depending upon the soil type and plasticity index. The repeated load triaxial …


Factors Controlling Macondo Oil Biodegraqdation On A Rapidly Eroding Coastal Headlands Beach, Marilany G. Urbano Jan 2012

Factors Controlling Macondo Oil Biodegraqdation On A Rapidly Eroding Coastal Headlands Beach, Marilany G. Urbano

LSU Master's Theses

Fourchon Beach, located along the southeast Louisiana coast, was affected by the oil leaking from the British Petroleum’s Deepwater Horizon Oil rig explosion in 2010. The oil, labeled MC252 oil, came ashore in a stable emulsion form, contaminating the sand, salt pan, marsh and mangroves along the beach. A unique oil form, labeled SSRB (small surface residue ball) was formed from the MC252 oil and a combination of environmental factors. The SSRB is an aggregate of sand and emulsified oil, and forms a large portion of the oil still present on the supratidal zone of Fourchon Beach. SSRBs have not …


Advanced Ceramics And Composites Based On Rice Hulls, Peigen Zhang Jan 2012

Advanced Ceramics And Composites Based On Rice Hulls, Peigen Zhang

LSU Doctoral Dissertations

As a by-product of the agricultural industry, rice hulls are available at large volume across the world. The disposal of the rice hulls itself is a big problem for the rice millers where the rice paddies are peeled off and rice hulls are produced. There have been many disposal methods developed, but the true value of the rice hulls would be more appreciated when they are employed to produce high value-added advanced ceramics. In this dissertation, advanced ceramics, such as AlN nanowires, SiC whiskers, mullite and SiC/Al2O3 nano-sized composites, were developed and studied based on the rice hulls. The SiC …


Microfabrication Of Conductive Polymer Nanocomposite For Sensor Applications, Chaoxuan Liu Jan 2012

Microfabrication Of Conductive Polymer Nanocomposite For Sensor Applications, Chaoxuan Liu

LSU Doctoral Dissertations

This dissertation developed novel microfabrication techniques of conductive polymer nanocomposite and utilized this material as a functional element for various physical sensor applications. Microstructures of nanocomposite were realized through novel microcontact printing and laser ablation assisted micropatterning processes. Prototype devices including large-strain strain sensor and highly-sensitive pressure sensor were demonstrated showing distinct advantages over existing technologies. The polymer nanocomposite used in this work comprised elastomer poly(dimexylsiloxane) (PDMS) as polymer matrix and multi-walled carbon nananotubes (MWCNTs) as a conductive nanofiller. To achieve uniform distribution of carbon nanotubes within the polymer, an optimized dispersion process was developed, featuring a strong organic solvent—chloroform, …


Stability Problems In Constrained Pendulum Systems And Time-Delayed Systems, Prashanth Ramachandran Jan 2012

Stability Problems In Constrained Pendulum Systems And Time-Delayed Systems, Prashanth Ramachandran

LSU Doctoral Dissertations

In this dissertation, we study the boundary of stability of a class of linear mechanical systems as a function of a parameter. We consider two different systems under this class: a constrained double pendulum connected by a rigid rod and a state-feedback-controlled mechanical system with time delay. In the first system, the destabilizing parameter is the distance between the supports of the two pendulums. In the second system, the destabilizing parameter is the time delay. In the constrained double pendulum system, linear perturbation analysis is used to determine the natural frequency of the system. Our analysis reveals a zone of …


Global And Local Performance Of Prestressed Girder Bridges With Positive Moment Continuity Detail, Tanvir Hossain Jan 2012

Global And Local Performance Of Prestressed Girder Bridges With Positive Moment Continuity Detail, Tanvir Hossain

LSU Doctoral Dissertations

Global as well as local behavior of prestressed girder bridges made continuous by adding continuity diaphragms with a recently proposed positive moment continuity detail were investigated in this study. The focus of the investigation is on the positive moment caused by temperature gradients, time dependent effects such as creep and shrinkage, and some live load positions, and on the force transfer mechanisms through the diaphragm. The study utilized different approaches including analytical models for temperature evaluations and finite element models for structural assessments. Field data from a bridge using the new detail were used to validate the developed models. The …


Numerical Study Of Downhole Heat Exchanger Concept In Geothermal Energy Extraction From Saturated And Fractured Reservoirs, Yin Feng Jan 2012

Numerical Study Of Downhole Heat Exchanger Concept In Geothermal Energy Extraction From Saturated And Fractured Reservoirs, Yin Feng

LSU Doctoral Dissertations

Geothermal energy has gained a lot of attention recently due to several favorable aspects such as ubiquitously distributed, renewable, low emission resources while leveraging the advances in the associated technologies such as directional drilling and low enthalpy power generation plant. However, there are still many challenges such as the high initial capital cost of drilling and surface facilities, environmental risk of seismicity due to the induced disequilibrium in the formation, and sustainability of project over designed operational life. Traditional downhole heat exchangers (DHE) could potentially reduce the capital cost and the risk of seismicity, but they are unable to maintain …


Synthesis And Characterization Of Geopolymers For Infrastructural Applications, Jian He Jan 2012

Synthesis And Characterization Of Geopolymers For Infrastructural Applications, Jian He

LSU Doctoral Dissertations

In this study, the synthesis process, composition, and microstructure as well as mechanical properties of geopolymers generated by 3 different kinds of raw materials (i.e., metakaolin, mixture of red mud and fly ash, mixture of red mud and rice husk ash) was explored. For geopolymers from identical raw materials, variable parameters involved in the synthesis were examined to investigate the extent and degree of geopolymerization. Uniaxial compression testing was used to examine the mechanical properties (i.e. compressive strength, stiffness, and failure strain). Then the composition and microstructure were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM) as well …


An Experimental Investigation Of The Role Of Small Hydrocarbons And Combustion-Generated Nanoparticles On The Formation And Growth Reactions Of Polycyclic Aromatic Hydrocarbons During The Pyrolysis Of A Model-Fuel And Hydrocarbon Gases, Nimesh Bharat Poddar Jan 2012

An Experimental Investigation Of The Role Of Small Hydrocarbons And Combustion-Generated Nanoparticles On The Formation And Growth Reactions Of Polycyclic Aromatic Hydrocarbons During The Pyrolysis Of A Model-Fuel And Hydrocarbon Gases, Nimesh Bharat Poddar

LSU Doctoral Dissertations

Polycyclic aromatic hydrocarbons (PAH) are an important class of environmental pollutants formed during fuel combustion or pyrolysis. Therefore, an experimental study has been undertaken to better understand the formation and growth pathways of PAH.

To investigate the efficacy of C3 species as PAH growth agents in the context of solid fuels, pyrolysis experiments have been performed in an isothermal quartz flow reactor in the temperature range of 700–1000 °C and a fixed residence time of 0.3 s. Experiments are performed with the C3 hydrocarbon, propyne; with catechol (ortho-dihydroxybenzene), a model-fuel representative of aromatic moieties in coal …


Dynamic Characterization Of Vocal Fold Virbrations, Zhenyi Wei Jan 2012

Dynamic Characterization Of Vocal Fold Virbrations, Zhenyi Wei

LSU Doctoral Dissertations

An emerging trend among voice specialists is the use of quantitative protocols for the diagnosis and treatment of voice disorders. Vocal fold vibrations are directly related to voice quality. This research is devoted to providing an objective means of characterizing these vibrations. Our goal is to develop a dynamic model of vocal fold vibration, and map the parameter space of the model to a class of voice disorders; thus, furthering the assessment and diagnosis of voice disorder in clinical settings.

To this end, this dissertation introduces a new seven-mass biomechanical model for the vibration of vocal folds. The model is …


Evaluation Of The Thermal Performance And Cost Effectiveness Of Radiant Barrier Thermal Insulation Materials In Residential Construction, Somayeh Asadi Jan 2012

Evaluation Of The Thermal Performance And Cost Effectiveness Of Radiant Barrier Thermal Insulation Materials In Residential Construction, Somayeh Asadi

LSU Doctoral Dissertations

Reducing heating and cooling systems loads in buildings is a cost effective way to decrease energy consumption in residential houses. This reduction can be achieved in many ways including proper insulation of the building envelope. In recent years, considerable attention was given to the use of radiant reflective insulating barriers. Over the past years, reflective barrier insulation companies nationwide have experienced significant growth resulting in an industry average growth rate of 26.8%. This significant growth is expected to continue as a result of increased cooling demands and pressure from the energy sector and the economy. Growth is also predicted to …


Effect Of Surfactants And Brine Salinity And Composition On Spreading, Wettability And Flow Behavior In Gas-Condensate Reservoirs, Yu Zheng Jan 2012

Effect Of Surfactants And Brine Salinity And Composition On Spreading, Wettability And Flow Behavior In Gas-Condensate Reservoirs, Yu Zheng

LSU Doctoral Dissertations

The well-known condensate blockage problem causes severe impairment of gas productivity as the flowing bottom-hole pressure falls below the dew point in gas-condensate reservoirs. Hence, this study attempts to investigate the concept of modifying the spreading coefficient and wettability using low-cost surfactants in the near wellbore region, to prevent the gas flow problems associated with condensate buildup. This study also examines the effect of brine salinity and composition on wettability, spreading and adhesion in condensate buildup regions, to evaluate the ability of brine salinity/composition for enhanced gas productivity in gas-condensate reservoirs. In this study, experiments were performed at both ambient …


Plasmonic Devices For Manipulating Light At The Nanoscale: Slow-Light Waveguides And Compact Couplers, Yin Huang Jan 2012

Plasmonic Devices For Manipulating Light At The Nanoscale: Slow-Light Waveguides And Compact Couplers, Yin Huang

LSU Doctoral Dissertations

In this dissertation, I explore new plasmonic structures and devices for manipulating light at the nanoscale: slow-light waveguides and compact couplers. I first introduce a plasmonic waveguide system, based on a plasmonic analogue of electromagnetically induced transparency (EIT), which supports a subwavelength slow-light mode, and exhibits a small group velocity dispersion. The system consists of a periodic array of two metal-dielectric-metal (MDM) stub resonators side-coupled to a MDM waveguide. Decreasing the frequency spacing between the two resonances increases the slowdown factor and decreases the bandwidth of the slow-light band. I also show that there is a trade-off between the slowdown …


Lipid Production From A Louisiana Native Chlorella Vulgaris/Leptolyngbya Sp. Co-Culture For Biofuel Applications, Rong Bai Jan 2012

Lipid Production From A Louisiana Native Chlorella Vulgaris/Leptolyngbya Sp. Co-Culture For Biofuel Applications, Rong Bai

LSU Doctoral Dissertations

Over the last several decades, microalgae have garnered great interest for biofuel production mainly due to the high lipid productivity and minimum land competition with food crops. In this research, a Louisiana native Chlorella vulgaris/Leptolyngbya sp. co-culture was selected for lipid production. The goal of this work is to improve the lipid productivity and lipid composition of this co-culture via optimizing irradiance and nitrogen levels, lipid extraction method and modeling of pilot photobioreactor (HISTAR). Effects of irradiance and nitrate nitrogen levels on total lipid yield, neutral lipid portion, and fatty acid profile of non-aerated and aerated co-cultures were investigated in …