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Engineering

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Faculty Publications

1990

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In Situ Infrared Evidence For The Electrochemical Incorporation Of Hydrogen Into Si And Ge, K. C. Mandal, F. Ozanam, J.-N. Chazalviel Dec 1990

In Situ Infrared Evidence For The Electrochemical Incorporation Of Hydrogen Into Si And Ge, K. C. Mandal, F. Ozanam, J.-N. Chazalviel

Faculty Publications

No abstract provided.

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Predicted Secondary Current Distributions For Linear Kinetics In A Modified Three-Dimensional Hull Cell, F. A. Jagush, Ralph E. White, William E. Ryan Jan 1990

Predicted Secondary Current Distributions For Linear Kinetics In A Modified Three-Dimensional Hull Cell, F. A. Jagush, Ralph E. White, William E. Ryan

Faculty Publications

Current density distribution is an important consideration
for those involved in designing electrochemical systems
and electroplating systems in particular. Although it
is important, the common practice in industry is to use
trial and error to determine designs that optimize current
density distributions in electroplating. The purpose of this
paper is to illustrate the use of the finite element method
(FEM) to predict three-dimensional current density distributions.

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A Simple Model For A Zinc/Bromine Flow Cell And Associated Storage Tanks, G. D. Simpson, Ralph E. White Jan 1990

A Simple Model For A Zinc/Bromine Flow Cell And Associated Storage Tanks, G. D. Simpson, Ralph E. White

Faculty Publications

A simple model for a parallel plate, zinc/bromine flow cell and associated storage tanks is presented and used to make time-dependent predictions for various quantities in the system. The model is based on a previously published algebraic model of the cell at steady-state and time-dependent, first-order differential equations for the storage tanks. The Butler-Volmer equation is used for the electrochemical reactions, and the homogeneous reaction between bromine and bromide is included. The model predictions indicate that the charging operation of a zinc/bromine battery can be significantly improved by using a storage tank with a larger residence time for the bromine …

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Three-Dimensional Current Distributions In A Bipolar, Chlor-Alkali Membrane Cell, Ralph E. White, F. Jagush, H. S. Burney Jan 1990

Three-Dimensional Current Distributions In A Bipolar, Chlor-Alkali Membrane Cell, Ralph E. White, F. Jagush, H. S. Burney

Faculty Publications

The current distributions in a stack of bipolar, membrane
chlor-alkali cells are important design considerations
(1). The degree of nonuniformity of the current distribution
is important to know because highly nonuniform
current distributions could cause, among other things, severe
damage to the membrane in a cell stack (2).

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Electrochemical Behavior Of Graphite And Ni-Cr Electrodes In Sodium Polysulfide In The Absence And Presence Of Hydrogen Sulfide, Z. Mao, Ralph E. White, B. Dandapani, A. Anani, S. Srinivasan, A. J. Appleby Jan 1990

Electrochemical Behavior Of Graphite And Ni-Cr Electrodes In Sodium Polysulfide In The Absence And Presence Of Hydrogen Sulfide, Z. Mao, Ralph E. White, B. Dandapani, A. Anani, S. Srinivasan, A. J. Appleby

Faculty Publications

The electrochemical behavior of graphite and Ni-Cr electrodes in sodium tetrasulfide melt has been investigated using voltammetric, chronoamperometric, and chronopotentiometric techniques in the presence and absence of hydrogen sulfide. Two continuous phases, namely, Na2S2 and Na2S, are apparently formed at different potentials during the cathodic polarization. The blocking effect by these layers was much less significant on the Ni-Cr electrode than on graphite. The presence of H2S did not appear to influence the electrode reactions, but it significantly reduced the rate of formation of the continuous phases (Na2S2 or Na …

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Estimation Of The Diffusion Coefficient And Solubility For A Gas Diffusing Through A Membrane, Michael C. Kimble, Ralph E. White, Yu-Min Tsou, R. Neal Beaver Jan 1990

Estimation Of The Diffusion Coefficient And Solubility For A Gas Diffusing Through A Membrane, Michael C. Kimble, Ralph E. White, Yu-Min Tsou, R. Neal Beaver

Faculty Publications

Analysis of the data obtained by the electrochemical monitoring technique for diffusion of a gas through a membrane is considered. It is shown that combining a numerical method with a nonlinear parameter estimation technique provides a means to determine values for the diffusion coefficient and the solubility of the diffusing gas. It is shown that better accuracy can be obtained for the diffusion coefficient and solubility of this gas by using the method presented and all experimental data rather than only part of the data, as has often been done in the past.

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Discussion Of The Representation Of Intercrystalline Misorientation In Cubic Materials, Brent L. Adams, Hans Grimmer, Junwu Zhao Jan 1990

Discussion Of The Representation Of Intercrystalline Misorientation In Cubic Materials, Brent L. Adams, Hans Grimmer, Junwu Zhao

Faculty Publications

BLA and JZ acknowledge the support of the Office of Basic Energy Science of the US Department of Energy under grant No. DE-FG02-88ER45355. Help from Stuart Wright with the figures is gratefully acknowledged. Salient features of various parameterizations of cubic-cubic misorientation are discussed. It is proposed that the quaternion representation of rotations, as a pair of antipodal points on the surface of a four-dimensional sphere, encompasses the most desirable properties of other proposed representations, viz rectilinearity, a closed form for the composition of successive rotations, and an equivalence between the Euclidean measure on its parameter space and the invariant measure …

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