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Articles 1 - 30 of 109
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Electrochemical Oxidization Of Herring Sperm Dna And Its Interaction With Histone, Juan Xu, Gui-Ping Huang, Hong Li, Wei Zhu
Electrochemical Oxidization Of Herring Sperm Dna And Its Interaction With Histone, Juan Xu, Gui-Ping Huang, Hong Li, Wei Zhu
Journal of Electrochemistry
The voltammetric behavior of herring sperm DNA at glassy carbon electrode and its interaction with histone have been investigated by using cyclic voltammetry,differential pulse voltammetry,and fluorescence measurement.In the potential range of 0.20 V to 1.25 V,it is found that an irreversible oxidative peak is exhibited in acid solution,but in the neutral or alkaline solution two oxidative peaks are observed.Oxidative peak potential values show a negative shift with increasing pH via a slope of-57 mV·pH-1 and a linear relation with DNA concentration in the range of 0.45 to 8.20 mmol·L-1.In the presence of histone,the oxidative peak current of DNA and the …
Eiectro-Oxidation Of Methanol On Pdnio/C Catalyst In Alkaline Medium, Mei-Li Wang, Lin Sang, Cheng-De Huang
Eiectro-Oxidation Of Methanol On Pdnio/C Catalyst In Alkaline Medium, Mei-Li Wang, Lin Sang, Cheng-De Huang
Journal of Electrochemistry
The electro-oxidation of methanol in alkaline electrolyte at in-house synthesized PdNiO/C and Pd/C catalysts and the effect of heat treatment on the structure and performance of catalysts were studied by cyclic voltammetry,chronoamperometry,chronopotentiometry and X-ray diffraction methods.It is shown that when the reduction temperature is 70℃ and the ratio between Pd and Ni is 8∶2,The PdNiO/C catalyst presents a highest activity for methanol electrooxidation.Calcining can increase the particle size and crystallinity of catalysts,but decrease the dispersion and activity of catalysts, too.Besides,the NiO is disengaged from Pd lattice by heat-treatment.The optimal PdNiO/C catalyst shows higher catalytic activity and much better poisoning resistance …
Study On Electrochemical Impedance Spectroscopy Of Carbon Steel Eroded In Methyldiethanolamine Solution, Dong-Ping Wei, Rong-Zong Hu, Dan-Mei Pan, Wei-Xiong Huang, Rui Dong
Study On Electrochemical Impedance Spectroscopy Of Carbon Steel Eroded In Methyldiethanolamine Solution, Dong-Ping Wei, Rong-Zong Hu, Dan-Mei Pan, Wei-Xiong Huang, Rui Dong
Journal of Electrochemistry
Corrosion behavior of carbon steel in methyldiethanolamine(MDEA) solution was investigated by Electrochemical Impedance Spectroscopy(EIS).The results were showed that the corrosion rate of carbon steel in solution containing dissolved oxygen is higher than that in solution removed of dissolved oxygen before cathodic activation.They were reversed after cathodic activation.The corrosion rate is increased at first and then decreased when the concentration of MDEA is increased in the blank solutions.In the simulated solutions containing quantities of!heat-stable salts(HSS),the corrosion rate is decreased monotonously with increase of the MDEA concentration.As anodic polarization potential is increased,the EIS of carbon steel in HSS simulated solution showed characteristics …
Preparation And Properties Of High Capacity Lifepo_4, Jun Li, Gui-Tang Lai, Hui-Min Huang, Da-Guang Li, Xin-De Xia
Preparation And Properties Of High Capacity Lifepo_4, Jun Li, Gui-Tang Lai, Hui-Min Huang, Da-Guang Li, Xin-De Xia
Journal of Electrochemistry
Carbon-doped LiFePO4/C and pure phase LiFePO4 cathode materials were prepared by liquid-state precipitation reaction.The results of XRD,SEM,elemental analysis,FTIR and A.C.impedance tests show that the samples have had olivine structure and a 3.4V discharge platform.The tapped density of LiFePO4/C sample could reach 1.46g/cm3,the initiate discharge capacity is 144.6mAh/g at 0.1C,which remained capacity is 93.2% after 20 cycles.The first discharge capacity is 133.5mAh/g at 1C and the capacity decreased 8.76% after 20 cycles.
Electrochemical Behavior And Determination Of Luteolin At A Glassy Carbon Electrode, Ai-Lin Liu, Shao-Bo Zhang, Xiao-Sha Wu, Li-Ping Li, Yang-Yuan Cao, Li-Ying Huang, Xin-Hua Lin
Electrochemical Behavior And Determination Of Luteolin At A Glassy Carbon Electrode, Ai-Lin Liu, Shao-Bo Zhang, Xiao-Sha Wu, Li-Ping Li, Yang-Yuan Cao, Li-Ying Huang, Xin-Hua Lin
Journal of Electrochemistry
The electrochemical behavior of luteolin was studied by voltammetry at a glassy carbon electrode in phosphate buffer solution.The results exhibited that the well-defined redox peak of luteolin is observed and the electrode process is adsorption-controlled.The charge transfer coefficient(α) was calculated as 0.66 in phosphate buffer solution(pH 4.0).The relationships between oxidation peak current and the concentration of luteolin are linear in the range of 1.0×10-8 ～ 5.0×10-6 mol·L-1 by differential pulse voltammetric method.The detection limit had been estimated as 1.0×10-8 molL-1.This method can be used for the determination of luteolin with satisfactory results.
Selection Of Additions In The Process Of Electrochemical Synthesizing Of K_2feo_4, Wei-Hua Yang, Dong-Qin Bi, Yan Zhou, Hong-Hui Wang, Xin-Ren Lan
Selection Of Additions In The Process Of Electrochemical Synthesizing Of K_2feo_4, Wei-Hua Yang, Dong-Qin Bi, Yan Zhou, Hong-Hui Wang, Xin-Ren Lan
Journal of Electrochemistry
Some of different additions including KIO4 was added to the anodic electrolyte for electrochemical synthesizing of K2FeO4,the effects of these additions on current yield were investigated.XRD and SEM were used to characterize the structure and image of K2FeO4.The results show that KIO4 is a preferable addition.When the mass dosage of KIO4 is 0.02%,electrolysis time is 1 h,the current yield is enhanced by 31.6% and the corresponding purity of the product is improved by 3.85 %.
Ion-Implanting Modification Of Layered Manganese Dioxide And Its Electrochemical Performance, He-Ning Huang, Dong-Ping Lv, Xing-Kang Huang, Qi-Wei Zhang, Yong Yang
Ion-Implanting Modification Of Layered Manganese Dioxide And Its Electrochemical Performance, He-Ning Huang, Dong-Ping Lv, Xing-Kang Huang, Qi-Wei Zhang, Yong Yang
Journal of Electrochemistry
Layered MnO2(δ-MnO2) was prepared by thermal decomposition of potassium permanganate.Ti was ion-implanted into such δ-MnO2 by physical techniques,forming a composite(δ-MnO2-Ti).These materials were characterized by XRD,SEM,XPS techniques and their electrochemical proprieties were investigated.The results showed that the layered structure of δ-MnO2 did not been destroyed after Ti ion implantation,and the implanted Ti element was mainly Ti4+ as indicated by XPS.Both of the first and the highest discharge specific capacities of the ion-implanted layered MnO2(δ-MnO2-Ti),compared to those of δ-MnO2,were improved significantly.
Determination Of Malathion Based On Carbon Nanotubes Modified Electrode Incorporating Acetylcholinesterase, Lu Zhang, Yao-Dong Zhang, Hong-Lan Qi
Determination Of Malathion Based On Carbon Nanotubes Modified Electrode Incorporating Acetylcholinesterase, Lu Zhang, Yao-Dong Zhang, Hong-Lan Qi
Journal of Electrochemistry
A biosensor for determination of organophosphorus pesticide based on the acetylcholinesterase and multi-wall carbon nanotubes modified electrode is fabricated.Under the optimal conditions,the chronoamperometric current at +0.70V(vs.SCE) increased linearly with the concentration of malathion in the range from 6.0×10-10 to 6.0×10-9 mol·L-1 with a detection limit of 1.0×10-10 mol·L-1.The recoveries of malathion in lake water is 97% to 105% determinated by this method.
Analysis Of Three Phase Controlled Rectifier With The Same Distance Control As Compared To The Same Angle Control, Sudirman S., Sri Kurniati A.
Analysis Of Three Phase Controlled Rectifier With The Same Distance Control As Compared To The Same Angle Control, Sudirman S., Sri Kurniati A.
Makara Journal of Technology
Analysis of three phase controlled rectifier with the same distance control as compared to the same angle control. This research aim to compare the firing of the same distance and the same angle control at three phase controlled rectifier with seen generated harmonic at input (AC side). Then calculate of rectifier efficiency and power factor comparison from both the control type. The rectifier use passive filter with resistance 11 ohm and is analysed with program simulation using PSPICE version 7.1. Result of research indicate that use of the same distance control generates the 5th and 7th harmonics, while the same …
Trajectory Shaping Of Surface-To-Surface Missile With Terminal Impact Angle Constraint, S. Subchan
Trajectory Shaping Of Surface-To-Surface Missile With Terminal Impact Angle Constraint, S. Subchan
Makara Journal of Technology
This paper presents trajectory shaping of a surface-to-surface missile attacking a fixed with terminal impact angle constraint. The missile must hit the target from above, subject to the missile dynamics and path constraints. The problem is reinterpreted using optimal control theory resulting in the formulation of minimum integrated altitude. The formulation entails nonlinear, two-dimensional missile flight dynamics, boundary conditions and path constraints. The generic shape of optimal trajectory is: level flight, climbing, diving; this combination of the three flight phases is called the bunt manoeuvre. The numerical solution of optimal control problem is solved by a direct collocation method. The …
Effect Of Contact Time On Interface Reaction Between Aluminum Silicon (7% And 11%) Alloy And Steel Dies Skd 61, Bambang Suharno, Neni Octapiani Nurhayati, Bustanul Arifin, Sri Harjanto
Effect Of Contact Time On Interface Reaction Between Aluminum Silicon (7% And 11%) Alloy And Steel Dies Skd 61, Bambang Suharno, Neni Octapiani Nurhayati, Bustanul Arifin, Sri Harjanto
Makara Journal of Technology
Effect of Contact Time on Interface Reaction between Aluminum Silicon (7% and 11%) Alloy and Steel Dies SKD 61. Die soldering (die sticking) is a defect of metal casting in which molten metal “welds” to the metallic die mold surface during casting process. Die soldering is the result of an interface reaction between the molten aluminum and the die material. Aluminum alloy with 7 and 11% silicon and SKD 61 die steel are the most common melt and die material used in aluminum die casting. This research is done to study the morphology and the characteristics of the formed AlxFeySiz …
The Use Of Red Cabbage’S Anthocyanine Extract As A Photosensitizer On A Dye-Sensitized Nanocrystalline Tio2 Solar Cell, Akhiruddin Maddu, Mahfuddin Zuhri, Irmansyah Irmansyah
The Use Of Red Cabbage’S Anthocyanine Extract As A Photosensitizer On A Dye-Sensitized Nanocrystalline Tio2 Solar Cell, Akhiruddin Maddu, Mahfuddin Zuhri, Irmansyah Irmansyah
Makara Journal of Technology
The use of Red Cabbage’s anthocyanine extract as a photosensitizer on a Dye-Sensitized Nanocrystalline TiO2 Solar Cell. A solid-state dye-sensitized nanocrystalline TiO2 solar cell utilizing anthocyanin extract form red cabbage as photosensitizer was fabricated. The solar cell was formed in sandwich structure, which two electrodes sandwiching polymer electrolyte containing a redox couple (I-/I3 -). One of the electrodes, namely working electrode, TiO2 layer on TCO (transparent conducting oxide) coated glass substrate was sensitized with anthocyanin dye as electron donor in the system. Another electrode was a carbon sheet as a counter electrode. Gel electrolyte based on PEG (polyethylene glycol) containing …
Reverse Link Cdma System Capacity Evaluation For Stratospheric Platform Mobile Communications, Iskandar Iskandar
Reverse Link Cdma System Capacity Evaluation For Stratospheric Platform Mobile Communications, Iskandar Iskandar
Makara Journal of Technology
We propose an analysis of reverse link CDMA multispot beam stratospheric platforms (SPF) in this paper. The SPF is currently proposed as a novel wireless technology for the development of the next generation fixed and mobile communications. The geometry of this technology is different from that of the terrestrial but rather similar to the satellite based cellular system. However, evaluation on the CDMA system capacity of this technology has not been much reported. This paper addresses all possible multiple access interference analyses including the effects of channel fading and shadowing in order to evaluate the system capacity. Single SPF and …
The Potency Of Fire And Explosion Hazard On Premium Oil Storage Tank At Depot X 2007, Fatma Lestari, Warid Nurdiansyah
The Potency Of Fire And Explosion Hazard On Premium Oil Storage Tank At Depot X 2007, Fatma Lestari, Warid Nurdiansyah
Makara Journal of Technology
The Potency of Fire and Explosion Hazard on Premium Oil Storage Tank at Depot X 2007. Premium oil storage tanks have fire and explosion risk because Premium oil is flammable liquid. Because of that, fire and explosion risk assessment on Premium oil storage tank at Depot X is needed as foundation to fire and explosion risk management, and comply with regulations. Method of this research is Dow’s Fire and Explosion Index. This research indicate that F&EI value for Premium oil storage tank is 118,82. Based on that F&EI value, level of risk at Premium oil storage tank is intermediate risk.
Limiting Maximum Drag Reduction Asymptote For The Moment Coefficient Of An Enclosed Rotating Disk With Fine Spiral Grooves, Budiarso Budiarso, Keizo Watanabe, Satoshi Ogata
Limiting Maximum Drag Reduction Asymptote For The Moment Coefficient Of An Enclosed Rotating Disk With Fine Spiral Grooves, Budiarso Budiarso, Keizo Watanabe, Satoshi Ogata
Makara Journal of Technology
In this study, the limiting maximum drag reduction asymptote for the moment coefficient of an enclosed rotating disk with fine spiral grooves in turbulent flow region were obtained analytically. Analysis which were based on an assumption for a simple parabolic velocity distribution of turbulent pipe flow to represent relative tangential velocity, was carried out using momentum integral equations of the boundary layer. For a certain K- parameter the moment coefficient results agree well with experimental results for maximum drag reduction in an enclosed rotating disk with fine spiral grooves and drag reduction ratio approximately was 15 %. Additionally, the experimental …
Co2 Absorption From Its Mixture With Ch4 Or N2 Through Hollow Fiber Membrane Contactor Using Water As Solvent, Sutrasno Kartohardjono, Anggara Anggara, Subihi Subihi, Yuliusman Yuliusman
Co2 Absorption From Its Mixture With Ch4 Or N2 Through Hollow Fiber Membrane Contactor Using Water As Solvent, Sutrasno Kartohardjono, Anggara Anggara, Subihi Subihi, Yuliusman Yuliusman
Makara Journal of Technology
CO2 Absorption from Its Mixture with CH4 or N2 through Hollow Fiber Membrane Contactor using Water as Solvent. Hollow fiber membrane contactors have been widely used as gas-liquid contactors recently such as in the CO2 absorption process from gas stream. This research aims to evaluate the effectiveness of hollow fiber membrane contactor to absorb CO2 from its mixture with CH4 or N2 using water through mass transfer and hydrodynamic tests. There are 3 membrane modules used in this research with shell diameter of 1.9 cm, length of 40 cm, outer fiber diameter of 2.7 mm and fiber number in the …
The Syntheses And Electrochemical Performance Of Nano-Mno_2 For Supercapacitor, Jun Ma, Ming-Sen Zheng, Quan-Feng Dong
The Syntheses And Electrochemical Performance Of Nano-Mno_2 For Supercapacitor, Jun Ma, Ming-Sen Zheng, Quan-Feng Dong
Journal of Electrochemistry
Nano-manganese dioxide were prepared by two different methods which are low temperature solid reaction and chemical deposition.The products were characterized by XRD,SEM,BET and constant current charge-discharge tests.The result shows that there is a close relationship between specific capacitance and BET surface areas.Meanwhile the specific capacitance was impacted little by the structure of the nano-manganese dioxides.However,the product performance of high rates,was influenced by structure,the higher rate can be obtained with the more perfect crystal structure.
Prerapation And Supercapacitor Property Of Al Doped Co_3o_4, Xin Ge, Ye Chen, Chun-Xia Zhang, Chang Shu
Prerapation And Supercapacitor Property Of Al Doped Co_3o_4, Xin Ge, Ye Chen, Chun-Xia Zhang, Chang Shu
Journal of Electrochemistry
With KOH as precipitator to prepare Aluminum doped Co3O4,X-ray diffraction indicated that the doping Al did not change the crystal structure of Co3O4.Electrochemical properties of the sample were tested by cyclic voltammetry and constant-current charge/discharge.The results showed that the chemical doping improved the specific capacitance.When the mol ratio of Co(Ⅱ) with Al(Ⅲ)was 1∶0.05,the specific capacitance was up to 518.07 F/g within 0～400 mV potenitial at current density 5 mA/cm2.
Preparation,Structure,And Cv Study Of The Supported Ptruir/Tic Electrocatalysts For Oxygen Electrodes, Sheng Sui, Li-Rong Ma
Preparation,Structure,And Cv Study Of The Supported Ptruir/Tic Electrocatalysts For Oxygen Electrodes, Sheng Sui, Li-Rong Ma
Journal of Electrochemistry
The PtRuIr/TiC electrocatalysts were prepared by method of reduction and deposition on TiC powders as supports together with ultrasonic wave dispersion.The sampls were characterized by BET surface area,scanning electron microscope,X-ray diffraction,and cyclic voltammetry techniques.The active components of Pt,Ru,and Ir particles(2.6%Pt,1.3%Ru,16%Ir,and 80%TiC,by mass) were mainly dispersed on the outer surface of the TiC supports,which structures were in favor of fine variable crystallites.It was found that the electrochemical performance of the PtRuIr/TiC electrodes was about three times as that of the unsupported electrocatalysts with the same active compositions for oxygen evolution reaction.After 120 times of CV cycles,there was almost no PtRuIr/TiC dissolving …
Electro-Chemical Oxidation Kinetics Of The V(Iv) In The Sulfuric Acid Solution, Yong-Lian Qiao, Qian Xu, Jie Zhang, Yu-Chun Zhai
Electro-Chemical Oxidation Kinetics Of The V(Iv) In The Sulfuric Acid Solution, Yong-Lian Qiao, Qian Xu, Jie Zhang, Yu-Chun Zhai
Journal of Electrochemistry
The electro-chemical oxidation kinetics for V(IV) in the sulfuric acid solution were investigated by cyclic voltammetry and steady state polarization curves at a graphite,platinum or conducting polymer electrode.Some kinetics parameters for the electrochemical reaction of V(IV) were calculated according to the Tafel curves.The results showed that the exchange current density and reversibility of V(V)/V(IV) redox reaction at the graphite electrode is largest among the three electrodes.There is the broadest extent of water stability and large oxidgen evolution potential when the conducting polymer was used as a working electrode in the solution of VOSO4(0.5 mol/L) and H2SO4(2 mol/L),while it is easy …
Studies On Catalytic Mechanism Of Li/Socl_2 Batteries By Metal Phthalocyanine Complexes, Zhan-Wei Xu, Qing-Jin Sun, Bi-Yun Su, Tu-Lin Che, Yan-Hong Song, Yao-Min Li, Jian-She Zhao
Studies On Catalytic Mechanism Of Li/Socl_2 Batteries By Metal Phthalocyanine Complexes, Zhan-Wei Xu, Qing-Jin Sun, Bi-Yun Su, Tu-Lin Che, Yan-Hong Song, Yao-Min Li, Jian-She Zhao
Journal of Electrochemistry
Effects of metal phthalocyanine comlexes MPc(M= Mn(Ⅱ),Fe(Ⅱ),Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ)) as electrochemical catalysts on the performance of Li/SOCl2 batteries have been examined at constant resistance.And the reasons of MPc affecting the discharged voltage and discharged time of Li/SOCl2 batteries were also brought forward.A few new viewpoints on the catalytic mechanism of the reduction of thionyl chloride by phthalocyanine complexes were proposed.
Electrocatalytic Separation For Dopamine And Ascorbic Acid Using Poly-Evans Blue Modified Glassy Carbon Electrode And Simultaneous Determination, Li-Qing Lin, Xin-Hua Lin, Hong Yao, Jing-Hua Chen, Guang-Wen Li
Electrocatalytic Separation For Dopamine And Ascorbic Acid Using Poly-Evans Blue Modified Glassy Carbon Electrode And Simultaneous Determination, Li-Qing Lin, Xin-Hua Lin, Hong Yao, Jing-Hua Chen, Guang-Wen Li
Journal of Electrochemistry
Voltammetric behavior of the Dopamine(DA) and ascorbic acid(AA) at Poly-Evans Blue modified electrode were studied and a novel method for determination of the content of DA and AA is established.In pH 4.5 phosphate buffer solution,the modified electrode shows enhanced sensitivity and excellent electrochemical discrimination to DA and AA.The relationship between oxidation peak current and the concentration of DA or AA is linear in the range of 1.0 10-6 ～3.0×10-5mol/L and 5.0×10-6~1.05×10-4 mol/L,the detection limit has been estimated as 2.5(10-7 mol/L and 3.0 ×10-7 mol/ L,respectively.The oxidable potential difference of DA and AA was about 184 mV at Poly-Evans Blue modified …
Oxygen Enrichment Effect Of Mno_2-Pt/C Compound Catalyst To The Cathode Of Pemfc, Hong-Feng Xu, Mao-Feng Zhang, Quan-Quan Gan, Cai-Sheng Huang
Oxygen Enrichment Effect Of Mno_2-Pt/C Compound Catalyst To The Cathode Of Pemfc, Hong-Feng Xu, Mao-Feng Zhang, Quan-Quan Gan, Cai-Sheng Huang
Journal of Electrochemistry
TO study of the oxygen storage material of air cathode is crucial for increasing performance of proton exchange membrane fuel cell.Using the MnO2 as oxygen storage materials,a MnO2-Pt/C catalysts were prepared and is used to replace the conventional Pt/C in air cathode.The electrochemical performance of air cathode composed of MnO2 supported on Pt/C and the properties of fuel cell composed of MnO2-Pt/C were investigated by using the CV,galvanostatic dischange method and TEM.
Influence Of Chromium On The Semi-Conductive Property Of Passive Film Formed On Carbon Steel In Bicarbonate/Carbonate Buffer Solution, Jin-Bo Li, Jie-Wu Zhu, Mao-Sheng Zheng
Influence Of Chromium On The Semi-Conductive Property Of Passive Film Formed On Carbon Steel In Bicarbonate/Carbonate Buffer Solution, Jin-Bo Li, Jie-Wu Zhu, Mao-Sheng Zheng
Journal of Electrochemistry
The influence of chromium on the semi-conductive property of the passive film formed at carbon steel in bicarbonate/carbonate buffer solution,is investigated by using electrochemical impedance spectroscopy(EIS).The results showed that the passive film fomed at carbon steel appeared an n-type semi-conductive property,but if the passive film formed at carbon steel with 3% chromium content exhibited an a-p semi-conductive charatcer.The slopes of Mott-Schottky plot of two passive films increased with rising the formation potential,it indicating the defect density of the film decreasing,but for the passive film formed at carbon steel with chromium additive,its donor density was lower about one order of magnitude …
Fabrication And Charaterization Of Nitrogen-Doped Tio_2 Nanotube Array And Its Visible Light Activity, Hui-Fang Zhuang, Yue-Kun Lai, Jing Li, Lan Sun, Chang-Jian Lin
Fabrication And Charaterization Of Nitrogen-Doped Tio_2 Nanotube Array And Its Visible Light Activity, Hui-Fang Zhuang, Yue-Kun Lai, Jing Li, Lan Sun, Chang-Jian Lin
Journal of Electrochemistry
Nitrogen-doped TiO2 nanotube array was fabricated by an electrochemical anodic oxidation followed a wet process.XPS result indicates that the nitrogen atoms were doped into lattice of TiO2 nanotubes.The UV-Vis spectra show that the photoabsorption of N-doped TiO2 nanotube array film is enhanced in the visible light region.Compared with the TiO2 nanotube array film,the N-doped TiO2 nanotubes exhibite a higher photocatalytic activity which is evaluated by the decomposition rate of methyl orange using the tungsten-halogen lamp as light source.
Electrocatalytic Oxidation Of Methanol At The Nano Ni-B Amorphous Alloy Powdermicroelectrode, Yi-Xiong Zheng, Shi-Bing Yao, Shao-Min Zhou
Electrocatalytic Oxidation Of Methanol At The Nano Ni-B Amorphous Alloy Powdermicroelectrode, Yi-Xiong Zheng, Shi-Bing Yao, Shao-Min Zhou
Journal of Electrochemistry
Electrocatalytic oxidation of methanol at the nano Ni-B amorphous alloy powder-microelectrode in alkaline media was studied by using cyclic voltammetry.Compared to the highly preferred orientation(220) nickel electrode,The onset potential of methanol electrooxidation at the nano Ni-B microelectrode is negatively shifted about 0.04V,and the current density is increased approximately by 2 orders of magnitude.Thus,the nano Ni-B microelectrode has very strong electrocatalytic activity for the oxidation of methanol.The kinetic parameters were determined with the steady polarization curves.The results show that the rate constants for both the oxidation of Ni(Ⅱ) to Ni(Ⅲ) and the reduction of Ni(Ⅲ) to Ni(Ⅱ) at the nano Ni-B …
Preparation Of Manganese/Chromium Hexacyanoferrate Modified Glassy Carbon Electrode And Its Electrochemical Behavior, Sheng-Tao Zhang, Xiao-Yan Han, Ming-Yue Xue
Preparation Of Manganese/Chromium Hexacyanoferrate Modified Glassy Carbon Electrode And Its Electrochemical Behavior, Sheng-Tao Zhang, Xiao-Yan Han, Ming-Yue Xue
Journal of Electrochemistry
A film of poly(manganese/chromium hexacyanoferrate)(MnCrHCF)is formed on the glassy carbon electrode(GCE) by Cyclic Voltammetry scanning,and its electrochemical behavior was studied.Factors affecting the electro-deposition of the film such as pH values and sustaining electrolytes,were discussed.And mechanism of the reaction was investigated.
An Analytic Analysis Of W-Cdma Smart Antennas Beamforming Using Complex Conjugate And Doa Methods, Chi-Min Li, Jia-Chyi Wu, I-Tseng Tang
An Analytic Analysis Of W-Cdma Smart Antennas Beamforming Using Complex Conjugate And Doa Methods, Chi-Min Li, Jia-Chyi Wu, I-Tseng Tang
Journal of Marine Science and Technology
Wideband Code Division Multiple Access (W-CDMA) adopts the smart antenna techniques to increase the signal-to-interferencenoise ratio (SINR) and system capacity. In this paper, we statistically derive analytic results to prove the SINR performance for the two commonly used CC and DOA beamforming methods. Results show the both methods will have the same mean SINR performance and CC method will be more robust than the DOA method.
Optimization Of Perforated Doublelayer Absorbers Using Simulated Annealing, Min-Chie Chiu, Ying-Chun Chang, Long-Jyi Yeh, Tian-Syung Lan
Optimization Of Perforated Doublelayer Absorbers Using Simulated Annealing, Min-Chie Chiu, Ying-Chun Chang, Long-Jyi Yeh, Tian-Syung Lan
Journal of Marine Science and Technology
As noise is highly responsible for the psychological and physiological ills to workers, the noise control for enclosed manufacturing system with sound absorber becomes obligatory; besides, considering the maintenance and operation in a room, the minimal thickness of sound absorber is certainly requested, according. To meet these issues, the compromising design target, ratio of sound absorption coefficient to thickness of acoustic panel, is thus proposed and applied as a researched objective, accordingly. In this paper, the simulated annealing (SA) is utilized in the shape optimization of the double-layer sound absorption system. The paper tackles not only the theoretical derivation in …
Annealing Effects Of Semiconducting Barium-Titanate Thermister, Yeong-Chin Chen
Annealing Effects Of Semiconducting Barium-Titanate Thermister, Yeong-Chin Chen
Journal of Marine Science and Technology
Two Positive Temperature Coefficient of Resistivity (PTCR) ceramics with composition A, (Ba0.997Sb0.003)Ti1.005O3, and composition B, (Ba0.997Sb0.003)Ti1.005O3 + 0.1 mole% MnO2 were fabricated and examined herein. The ceramic grain size, oxygen pressure and annealing time need to be simultaneously controlled to obtain an optimum PTCR resistor. Additionally, the stoichiometric proportions of the constituent elements must be weighted carefully in order to produce good quality PTCR devices. This study thoroughly explores all the factors affecting the PTCR characteristics. Experiments were developed to verify that PTCR phenomena are strongly influenced by oxygen absorption. As the samples were annealed in Air atmosphere, the numbers …