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Improving The Efficiency Of Organic Solar Cells By Varying The Material Concentration In The Photoactive Layer, Kevin Anthony Latimer
Improving The Efficiency Of Organic Solar Cells By Varying The Material Concentration In The Photoactive Layer, Kevin Anthony Latimer
Electrical & Computer Engineering Theses & Dissertations
Polymer-fullerene bulk heterojunction solar cells have been a rapidly improving technology over the past decade. To further improve the relatively low energy conversion efficiencies of these solar cells, several modifications need to be made to the overall device structure. Emerging technologies include cells that are fabricated with interfacial layers to facilitate charge transport, and tandem structures are being introduced to harness the absorption spectrum of polymers with varying bandgap energies.
When new structures are implemented, each layer of the cell must be optimized in order for the entire device to function efficiently. The most volatile layer of these devices is …
Cyberknife Radiation Modeling: Effects Of Relaxed Translational And Rotational Constraints On Healthy Tissue Irradiation, Sudha Bhavaroop Potineni
Cyberknife Radiation Modeling: Effects Of Relaxed Translational And Rotational Constraints On Healthy Tissue Irradiation, Sudha Bhavaroop Potineni
Electrical & Computer Engineering Theses & Dissertations
The Cyberknife system is a robotic radio surgery instrument that is used to treat cancers in different parts of the human body. Because of its accuracy and precision, it has become one of the best radio surgery systems in the world. However, even with Cyberknife the treatment time for one session takes from 30 minutes up to 120 minutes depending on the size, shape, and position of the tumor in the human body. In this research, a solution is presented to aid in reducing this long treatment time. An algorithm is developed which simulates the amount of the healthy tissue …
Ultrafast Electron Diffraction Study Of The Dynamics Of Antimony Thin Films And Nanoparticles, Mahmoud Abdel-Fattah
Ultrafast Electron Diffraction Study Of The Dynamics Of Antimony Thin Films And Nanoparticles, Mahmoud Abdel-Fattah
Electrical & Computer Engineering Theses & Dissertations
The ultrafast fast phenomena that take place following the application of a 120 fs laser pulse on 20 nm antimony thin films and 40 nm nanoparticles were studied using time-resolved electron diffraction. Samples are prepared by thermal evaporation, at small thickness (< 10 nm) antimony nanoparticles form while at larger thicknesses we get continuous thin films.
The samples are annealed and studied by static heating to determine their Debye temperatures, which were considerably less than the standard value. The thermal expansion under static heating also yielded the expansion coefficient of the sample material. Nanoparticle samples gave a very accurate thermal expansion coefficient (11 × 10-6 K-1).
Ultrafast time resolved electron diffraction …
Improving The Efficiency Of Organic Solar Cells By Varying The Material Concentration In The Photoactive Layer, Kevin Anthony Latimer
Improving The Efficiency Of Organic Solar Cells By Varying The Material Concentration In The Photoactive Layer, Kevin Anthony Latimer
Electrical & Computer Engineering Theses & Dissertations
Polymer-fullerene bulk heterojunction solar cells have been a rapidly improving technology over the past decade. To further improve the relatively low energy conversion efficiencies of these solar cells, several modifications need to be made to the overall device structure. Emerging technologies include cells that are fabricated with interfacial layers to facilitate charge transport, and tandem structures are being introduced to harness the absorption spectrum of polymers with varying bandgap energies.
When new structures are implemented, each layer of the cell must be optimized in order for the entire device to function efficiently. The most volatile layer of these devices is …
The Tracking Performance Of Distributed Recoverable Flight Control Systems Subject To High Intensity Radiated Fields, Rui Wang
Electrical & Computer Engineering Theses & Dissertations
It is known that high intensity radiated fields (HIRF) can produce upsets in digital electronics, and thereby degrade the performance of digital flight control systems. Such upsets, either from natural or man-made sources, can change data values on digital buses and memory and affect CPU instruction execution. HIRF environments are also known to trigger common-mode faults, affecting nearly-simultaneously multiple fault containment regions, and hence reducing the benefits of n-modular redundancy and other fault-tolerant computing techniques. Thus, it is important to develop models which describe the integration of the embedded digital system, where the control law is implemented, as well …
Fusion Of Visual And Thermal Images Using Genetic Algorithms, Sertan Erkanli
Fusion Of Visual And Thermal Images Using Genetic Algorithms, Sertan Erkanli
Electrical & Computer Engineering Theses & Dissertations
Demands for reliable person identification systems have increased significantly due to highly security risks in our daily life. Recently, person identification systems are built upon the biometrics techniques such as face recognition. Although face recognition systems have reached a certain level of maturity, their accomplishments in practical applications are restricted by some challenges, such as illumination variations. Current visual face recognition systems perform relatively well under controlled illumination conditions while thermal face recognition systems are more advantageous for detecting disguised faces or when there is no illumination control. A hybrid system utilizing both visual and thermal images for face recognition …
A Study Of Diversity Techniques For Lte Wireless Systems, Ferhat Kaplan
A Study Of Diversity Techniques For Lte Wireless Systems, Ferhat Kaplan
Electrical & Computer Engineering Theses & Dissertations
The demand of attaining information and the wish to communicating anytime and anywhere has caused numerous innovations in the digital communication world. Today, approximately half of the people on earth somehow use wireless technology which is in every part of our lives. LTE (Long Term Evolution) and WIMAX (Worldwide Interoperability for Microwave Access) standards are the two leading wireless technologies, which support high data rates, multimedia applications, and voice video communications at very high speeds, also called 4G cellular systems in the global market.
These high expectations from wireless technology have revealed multiple antenna techniques which improve the performance and …
Investigation And Comparison Of Proportional Navigation Guidance And Beam Rider Guidance, Ertac Olgun
Investigation And Comparison Of Proportional Navigation Guidance And Beam Rider Guidance, Ertac Olgun
Electrical & Computer Engineering Theses & Dissertations
Air defense has an increasing importance in today's wars. To gain the advantage in air combat, pursuit interceptor aircraft, which use Air-to-Air Missiles (AAMs), have become more and more significant. However, these are not sufficient alone. The importance of Surface-to-Air Missiles (SAMs) also can not be ignored in air defense.
SAMs can use different tactical navigation guidance methods. Of these, two of the more important guidance methods are Proportional Navigation Guidance and Beam Rider Guidance, which are investigated in this thesis. To understand the idea better, a brief description and discussion of missiles are provided. Parts of the guided missiles …
Performance Analysis For Wimax Wireless Systems With Multiple Receive Antennas, Selcuk Taskin
Performance Analysis For Wimax Wireless Systems With Multiple Receive Antennas, Selcuk Taskin
Electrical & Computer Engineering Theses & Dissertations
Broadband wireless access has become the best way to meet the growing demand for fast Internet connections. WiMAX is one of the most promising broadband access technologies that allows fast deployment as well as low maintenance costs. WiMAX allows efficient use available bandwidth by using orthogonal frequency division multiplexing (OFDM) which is an efficient multi-carrier modulation technique. Diversity is a method for improving the reliability of a signal in fading environments by using two or more communication channels and is usually achieved by multiple antenna techniques.
In this thesis, receiver side diversity combining methods are studied and the performance of …
Video Stabilization Based On Speeded-Up Robust Features, Minqi Zhou
Video Stabilization Based On Speeded-Up Robust Features, Minqi Zhou
Electrical & Computer Engineering Theses & Dissertations
With the advancement of science and technology, portable devices using video cameras are becoming more popular. Videos captured by ordinary commercial cameras always suffer from undesired motion which results from human hand shaking and mobile platform vibration. The undesired motion would not only blur the image degrading the image quality leading to inaccurate results in automatic object recognition and tracking, but also make it difficult for people to focus on specific object regions. It is also a possibility that one may feel dizzy while watching shaky video for a long time. Many hardware and software methodologies have been developed by …
Characterizations Of Atmospheric Pressure Low Temperature Plasma Jets And Their Applications, Erdinc Karakas
Characterizations Of Atmospheric Pressure Low Temperature Plasma Jets And Their Applications, Erdinc Karakas
Electrical & Computer Engineering Theses & Dissertations
Atmospheric pressure low temperature plasma jets (APLTPJs) driven by short pulses have recently received great attention because of their potential in biomedical and environmental applications. This potential is due to their user-friendly features, such as low temperature, low risk of arcing, operation at atmospheric pressure, easy handheld operation, and low concentration of ozone generation. Recent experimental observations indicate that an ionization wave exists and propagates along the plasma jet. The plasma jet created by this ionization wave is not a continuous medium but rather consists of a bullet-like-structure known as "Plasma Bullet". More interestingly, these plasma bullets actually have a …
Learning Local Features Using Boosted Trees For Face Recognition, Rajkiran Gottumukkal
Learning Local Features Using Boosted Trees For Face Recognition, Rajkiran Gottumukkal
Electrical & Computer Engineering Theses & Dissertations
Face recognition is fundamental to a number of significant applications that include but not limited to video surveillance and content based image retrieval. Some of the challenges which make this task difficult are variations in faces due to changes in pose, illumination and deformation. This dissertation proposes a face recognition system to overcome these difficulties. We propose methods for different stages of face recognition which will make the system more robust to these variations. We propose a novel method to perform skin segmentation which is fast and able to perform well under different illumination conditions. We also propose a method …
Synthesis Of Ald Zinc Oxide And Thin Film Materials Optimization For Uv Photodetector Applications, Kandabara Nouhoum Tapily
Synthesis Of Ald Zinc Oxide And Thin Film Materials Optimization For Uv Photodetector Applications, Kandabara Nouhoum Tapily
Electrical & Computer Engineering Theses & Dissertations
Zinc oxide (ZnO) is a direct, wide bandgap semiconductor material. It is thermodynamically stable in the wurtzite structure at ambient temperature conditions. ZnO has very interesting optical and electrical properties and is a suitable candidate for numerous optoelectronic applications such as solar cells, LEDs and UV-photodetectors. ZnO is a naturally n-type semiconductor. Due to the lack of reproducible p-type ZnO, achieving good homojunction ZnO-based photodiodes such as UV-photodetectors remains a challenge. Meanwhile, heterojunction structures of ZnO with p-type substrates such as SiC, GaN, NiO, AlGaN, Si etc. are used; however, those heterojunction diodes suffer from low efficiencies. ZnO is an …
Growth Of Alkali Antimonide Photosensitive Thin Films, George Annobil
Growth Of Alkali Antimonide Photosensitive Thin Films, George Annobil
Electrical & Computer Engineering Theses & Dissertations
The experiment performed in this research addresses the growth of an alkali antimonide photosensitive film. Research was conducted to understand and develop a growth technique for a unique vapor deposition system in a vacuum environment. Specifically, the grown film will be utilized as a photocathode, and hence quantum efficiency (QE) and photocathode lifetime measurements are conducted. The research presents the successful growth of the binary compound cesium antimonide with achieved quantum efficiency of ~0.07% at ~240V anode bias. This experimental result demonstrated that the deposition technique was reliable in producing a feasible cathode. It further allowed the verification of theoretical …
Electronic Warfare By Using Unmanned Aerial Vehicles, Aydin Meric
Electronic Warfare By Using Unmanned Aerial Vehicles, Aydin Meric
Electrical & Computer Engineering Theses & Dissertations
Technology continues to evolve rapidly by the day. Developments in technology should be followed closely if a country wants to become more powerful. Nowadays nobody can afford to ignore the importance of Electronic Warfare and Unmanned Aerial Vehicles (UAV) in military applications. Both of them play a crucial role in military operations that they can change the course of a war.
There are different kinds of Electronic Warfare methods that can be applied according to the situations and any evolving circumstances. In the beginning Electronic Warfare was used mainly for defensive purposes, but these days Electronic Warfare is used for …
Solving The Vehicle Re-Identification Problem By Using Neural Networks, Tanweer Rashid
Solving The Vehicle Re-Identification Problem By Using Neural Networks, Tanweer Rashid
Computational Modeling & Simulation Engineering Theses & Dissertations
Vehicle re-identification is the process by which vehicle attributes measured at one point on a road network are compared to vehicle attributes measured at another point in an effort to match vehicles without using any unique identifiers such as license plate numbers. A match is made if the two measurements are estimated to belong to the same vehicle. Vehicle attributes can be sensor readings such as loop induction signatures, or they can also be actual vehicle characteristics such as length, weight, number of axles, etc. This research makes use of vehicle length, travel time, axle spacing and axle weights for …
A Framework For Incident Detection And Notification In Vehicular Ad-Hoc Networks, Mahmoud Abuelela
A Framework For Incident Detection And Notification In Vehicular Ad-Hoc Networks, Mahmoud Abuelela
Computer Science Theses & Dissertations
The US Department of Transportation (US-DOT) estimates that over half of all congestion events are caused by highway incidents rather than by rush-hour traffic in big cities. The US-DOT also notes that in a single year, congested highways due to traffic incidents cost over $75 billion in lost worker productivity and over 8.4 billion gallons of fuel. Further, the National Highway Traffic Safety Administration (NHTSA) indicates that congested roads are one of the leading causes of traffic accidents, and in 2005 an average of 119 persons died each day in motor vehicle accidents.
Recently, Vehicular Ad-hoc Networks (VANET) employing a …
Compensation Techniques In Accelerator Physics, Hisham Kamal Sayed
Compensation Techniques In Accelerator Physics, Hisham Kamal Sayed
Physics Theses & Dissertations
Accelerator physics is one of the most diverse multidisciplinary fields of physics, wherein the dynamics of particle beams is studied. It takes more than the understanding of basic electromagnetic interactions to be able to predict the beam dynamics, and to be able to develop new techniques to produce, maintain and deliver high quality beams for different applications. In this work, some basic theory regarding particle beam dynamics in accelerators will be presented. This basic theory, along with applying state of the art techniques in beam dynamics will be used in this dissertation to study and solve accelerator physics problems. Two …
Analysis Of Interband, Intraband, And Plasmon Polariton Transitions In Silver Nanoparticle Films Via In Situ Real-Time Spectroscopic Ellipsometry, S. A. Little, R. W. Collins, S. Marsillac
Analysis Of Interband, Intraband, And Plasmon Polariton Transitions In Silver Nanoparticle Films Via In Situ Real-Time Spectroscopic Ellipsometry, S. A. Little, R. W. Collins, S. Marsillac
Electrical & Computer Engineering Faculty Publications
The dielectric function of Ag nanoparticle films, deduced from an analysis of in situ real-time spectroscopic ellipsometry (RTSE) measurements, is found to evolve with time during deposition in close consistency with the film structure, deduced in the same RTSE analysis. In the nucleation regime, the intraband dielectric function component is absent and plasmon polariton behavior dominates. Only at nuclei contact, does the intraband amplitude appear, increasing above zero. Both intraband and plasmon amplitudes coexist during surface smoothening associated with coalescence. The intraband relaxation time increases rapidly after surface smoothening is complete, also in consistency with the thin film structural evolution.
An Apoptosis Targeted Stimulus With Nanosecond Pulsed Electric Fields (Nspefs) In E4 Squamous Cell Carcinoma, Wei Ren, Stephen J. Beebe
An Apoptosis Targeted Stimulus With Nanosecond Pulsed Electric Fields (Nspefs) In E4 Squamous Cell Carcinoma, Wei Ren, Stephen J. Beebe
Bioelectrics Publications
Stimuli directed towards activation of apoptosis mechanisms are an attractive approach to eliminate evasion of apoptosis, a ubiquitous cancer hallmark. In these in vitro studies, kinetics and electric field thresholds for several apoptosis characteristics are defined in E4 squamous carcinoma cells (SCC) exposed to ten 300 ns pulses with increasing electric fields. Cell death was [95% at the highest electric field and coincident with phosphatidylserine externalization, caspase and calpain activation in the presence and absence of cytochrome c release, decreases in Bid and mitochondria membrane potential (Δψm) without apparent changes reactive oxygen species levels or in Bcl2 and Bclxl levels. …
An Integrated Computer-Aided Robotic System For Dental Implantation, Xiaoyan Sun, Yongki Yoon, Jiang Li, Frederic D. Mckenzie
An Integrated Computer-Aided Robotic System For Dental Implantation, Xiaoyan Sun, Yongki Yoon, Jiang Li, Frederic D. Mckenzie
Electrical & Computer Engineering Faculty Publications
This paper describes an integrated system for dental implantation including both preoperative planning utilizing computer-aided technology and automatic robot operation during the intra-operative stage. A novel two-step registration procedure was applied for transforming the preoperative plan to the operation of the robot, with the help of a Coordinate Measurement Machine (CMM). Experiments with a patient-specific phantom were carried out to evaluate the registration error for both position and orientation. After adopting several improvements, registration accuracy of the system was significantly improved. Sub-millimeter accuracy with the Target Registration Errors (TREs) of 0.38±0.16 mm (N=5) was achieved. The target orientation errors after …
On The Visual Quality Enhancement Of Super-Resolution Images, Amr Hussein Yousef, Jiang Li, Mohammad Karim, Andrew G. Tescher (Ed.)
On The Visual Quality Enhancement Of Super-Resolution Images, Amr Hussein Yousef, Jiang Li, Mohammad Karim, Andrew G. Tescher (Ed.)
Electrical & Computer Engineering Faculty Publications
Super-resolution (SR) is the process of obtaining a higher resolution image from a set of lower resolution (LR) blurred and noisy images. One may, then, envision a scenario where a set of LR images is acquired with a sensor on a moving platform. In such a case, an SR image can be reconstructed in an area of sufficient overlap between the LR images which generally have a relative shift with respect to each other by subpixel amounts. The visual quality of the SR image is affected by many factors such as the optics blur, the inherent signalto- noise ratio of …
Bcc Skin Cancer Diagnosis Based On Texture Analysis Techniques, Shao-Hui Chuang, Xiaoyan Sun, Wen-Yu Chang, Gwo-Shing Chen, Adam Huang, Jiang Li, Frederic D. Mckenzie
Bcc Skin Cancer Diagnosis Based On Texture Analysis Techniques, Shao-Hui Chuang, Xiaoyan Sun, Wen-Yu Chang, Gwo-Shing Chen, Adam Huang, Jiang Li, Frederic D. Mckenzie
Electrical & Computer Engineering Faculty Publications
In this paper, we present a texture analysis based method for diagnosing the Basal Cell Carcinoma (BCC) skin cancer using optical images taken from the suspicious skin regions. We first extracted the Run Length Matrix and Haralick texture features from the images and used a feature selection algorithm to identify the most effective feature set for the diagnosis. We then utilized a Multi-Layer Perceptron (MLP) classifier to classify the images to BCC or normal cases. Experiments showed that detecting BCC cancer based on optical images is feasible. The best sensitivity and specificity we achieved on our data set were 94% …
3d Face Reconstruction From Limited Images Based On Differential Evolution, Qun Wang, Jiang Li, Vijayan K. Asari, Mohammad A. Karim, Andrew G. Tescher (Ed.)
3d Face Reconstruction From Limited Images Based On Differential Evolution, Qun Wang, Jiang Li, Vijayan K. Asari, Mohammad A. Karim, Andrew G. Tescher (Ed.)
Electrical & Computer Engineering Faculty Publications
3D face modeling has been one of the greatest challenges for researchers in computer graphics for many years. Various methods have been used to model the shape and texture of faces under varying illumination and pose conditions from a single given image. In this paper, we propose a novel method for the 3D face synthesis and reconstruction by using a simple and efficient global optimizer. A 3D-2D matching algorithm which employs the integration of the 3D morphable model (3DMM) and the differential evolution (DE) algorithm is addressed. In 3DMM, the estimation process of fitting shape and texture information into 2D …
Special Issue On Wireless Sensor And Actuator Networks, Jiming Chen, Karl H. Johanson, Stephan Olariu, Ioannis Ch. Paschalidis, Ivan Stojmenovic
Special Issue On Wireless Sensor And Actuator Networks, Jiming Chen, Karl H. Johanson, Stephan Olariu, Ioannis Ch. Paschalidis, Ivan Stojmenovic
Computer Science Faculty Publications
( First paragraph) WIRELESS Sensor Networks (WSNs), in their various shapes and forms, have greatly facilitated and enhanced the automated, remote, and intelligent monitoring of a large variety of physical systems. These networks consist of a large number of typically small devices, each incorporating sensing, processing, and wireless communications capabilities. Their use has penetrated a plethora of application domains from industrial and building automation, to environmental, wildlife, and health monitoring.
2d Face Database Diversification Based On 3d Face Modeling, Qun Wang, Jiang Li, Vijayan K. Asari, Mohammad A. Karim, Manuel Filipe Costa (Ed.)
2d Face Database Diversification Based On 3d Face Modeling, Qun Wang, Jiang Li, Vijayan K. Asari, Mohammad A. Karim, Manuel Filipe Costa (Ed.)
Electrical & Computer Engineering Faculty Publications
Pose and illumination are identified as major problems in 2D face recognition (FR). It has been theoretically proven that the more diversified instances in the training phase, the more accurate and adaptable the FR system appears to be. Based on this common awareness, researchers have developed a large number of photographic face databases to meet the demand for data training purposes. In this paper, we propose a novel scheme for 2D face database diversification based on 3D face modeling and computer graphics techniques, which supplies augmented variances of pose and illumination. Based on the existing samples from identical individuals of …
Coherent Phonons In Bismuth Film Observed By Ultrafast Electron Diffraction, A. Bugayev, A. Esmail, M. Abdel-Fattah, H. E. Elsayed-Ali
Coherent Phonons In Bismuth Film Observed By Ultrafast Electron Diffraction, A. Bugayev, A. Esmail, M. Abdel-Fattah, H. E. Elsayed-Ali
Applied Research Center Publications
The generation of coherent phonons in polycrystalline bismuth film excited with femtosecond laser pulse is observed by ultrafast time-resolved electron diffraction. The dynamics of the diffracted intensities from the (110), (202), and (024) lattice planes show pronounced oscillations at 130-150 GHz. The origin of these coherent acoustic phonons is discussed in view of optical phonon decay into two acoustic phonons. Different drop times in the intensity of the diffraction orders are observed and interpreted as anisotropy in the energy transfer rate of coherent optical phonons.
Low Temperature Epitaxial Growth Of Ge Quantum Dot On Si (100) - (2×1) By Femtosecond Laser Excitation, Ali Oguz Er, Wei Ren, Hani E. Elsayed-Ali
Low Temperature Epitaxial Growth Of Ge Quantum Dot On Si (100) - (2×1) By Femtosecond Laser Excitation, Ali Oguz Er, Wei Ren, Hani E. Elsayed-Ali
Electrical & Computer Engineering Faculty Publications
Low temperature epitaxy of Ge quantum dots on Si (100) - (2×1) by femtosecond pulsed laser deposition under femtosecond laser excitation was investigated. Reflection high-energy electron diffraction and atomic force microscopy were used to analyze the growth mode and morphology. Epitaxial growth was achieved at ∼70 °C by using femtosecond laser excitation of the substrate. A purely electronic mechanism of enhanced surface diffusion of the Ge adatoms is proposed. © 2011 American Institute of Physics. [doi:10.1063/1.3537813]
Precise Control Of Highly Ordered Arrays Of Nested Semiconductor/Metal Nanotubes, Diefeng Gu, Helmut Baumgart, Kandabara Tapily, Pragya Shrestha, Gon Namkoong, Xianyu Ao, Frank Müller
Precise Control Of Highly Ordered Arrays Of Nested Semiconductor/Metal Nanotubes, Diefeng Gu, Helmut Baumgart, Kandabara Tapily, Pragya Shrestha, Gon Namkoong, Xianyu Ao, Frank Müller
Electrical & Computer Engineering Faculty Publications
Lithographically defined microporous templates in conjunction with the atomic layer deposition (ALD) technique enable remarkable control of complex novel nested nanotube structures. So far three-dimensional control of physical process parameters has not been fully realized with high precision resolution, and requires optimization in order to achieve a wider range of potential applications. Furthermore, the combination of composite insulating oxide layers alternating with semiconducting layers and metals can provide various types of novel applications and eventually provide unique and advanced levels of multifunctional nanoscale devices. Semiconducting TiO2 nanotubes have potential applications in photovoltaic devices. The combination of nanostructured semiconducting materials …
Electronically Enhanced Surface Diffusion During Ge Growth On Si(100), Ali Orguz Er, Hani E. Elsayed-Ali
Electronically Enhanced Surface Diffusion During Ge Growth On Si(100), Ali Orguz Er, Hani E. Elsayed-Ali
Physics Faculty Publications
The effect of nanosecond pulsed laser excitation on surface diffusion during the growth of Ge on Si(100) at 250 °C was studied. In situ reflection high-energy electron diffraction was used to measure the surface diffusion coefficient while ex situ atomic force microscopy was used to probe the structure and morphology of the grown quantum dots. The results show that laser excitation of the substrate increases the surface diffusion during the growth of Ge on Si(100), changes the growth morphology, improves the crystalline structure of the grown quantum dots, and decreases their size distribution. A purely electronic mechanism of enhanced surface …