Digital Commons Network^™

Adsorption Of Lead On Single And Mixed Solid Systems, Soumya Das

Dissertations

Metal oxy-hydroxides and phyllosilicate minerals play a significant role in the fate and transport of heavy metals in the environment (Bertsch and Seaman, 1999). Chemical speciation of metals affects their bioavailability and chemical reactivity (Stumm and Morgan, 1996). Surface complexation models (SCMs) based on equilibrium thermodynamic principles have been successfully used to quantify adsorption of heavy metals on pure solid minerals, including phyllosilicates and oxy-hydroxides. For natural sediments with mixed mineralogy, Davis et al. (1998) suggested two different SCM approaches, namely, the component additivity and generalized composite models. In this study, adsorption of lead on pure HFO, silica and kaolinite …

Estimating Sea Level Due To Crustal Stretching In The Margin Of The Indian Ocean, Kisa Mwakanyamale

Masters Theses

Continental crust extension is a precursor to the formation of a new ocean. The overall crustal extension causes change in the volume of global oceans hence change in sea level. The break-up of Gondwana that began during Late Triassic to Early Jurassic time caused continental crustal extension prior to forming the Indian Ocean. Extension started 184 Ma with rifting between SE Africa, Madagascar and Antarctica. This was followed by rifting between Greater India, Australia and Antarctica beginning about 160 Ma. The most recent episode of extension occurred 34 Ma involving separation between Arabia and Horn of Africa. Gridded data sets …

Modified Fenton Oxidation Of Hydrocarbon Contaminated Soils With Cao2: Microbial Survival And Surfactant Production, Abraham Matthew Northup

Dissertations

The efficacy of CaO₂ for use in modified Fenton's (MF) reactions was investigated in this study, with the goal of developing a CaO₂-based MF oxidation technology for use in in situ chemical oxidation. Traditionally, liquid H₂O₂ (HP) is used, and is injected into the subsurface in excess to ensure a sufficient radius of influence. CaO₂ was investigated as an alternative source of H₂O₂ for MF reactions.

First, the rate of dissolution of powdered CaO₂ and the yield of HP was investigated. Our results showed that the rate of dissolution …

Some Applications Of Gaussian Quadrature And Neural Network Modeling In Earth Flows And Other Slow-Moving Landslides In Cohesive Slope Materials, Rennie Bwalya Kaunda

Dissertations

Geometrical changes and progressive displacements in earth flows and other slow moving landslides triggered by climatic changes may be addressed by digital modeling. Gaussian quadrature, a numerical integration technique though fixed points, is employed to compute geometrical areas defined by stratigraphic (soil or rock layering) units, vertical pole projections and a slip surface, based on kinematic admissibility. An example from the Lake Michigan coast shows that the total internal geometrical area is found to be preserved during the course of the progressive deformation. Displacement monitoring of the slope shows that it became less stable over a period of eleven years …

Towards A Better Understanding Of The Hydrology Of The Tigris- Euphrates System And Its Marshlands, Christopher K. Jones

Masters Theses

Rising demands for fresh water supplies are leading to water management practices that are altering natural flow systems world-wide. One of the most devastated of these natural systems is the Tigris-Euphrates watershed that over the past three decades has witnessed the construction of over 60 engineering projects that eliminated seasonal flooding, reduced natural flow and dramatically reduced the areal extent (1966: 11000 km² ; 2002: 750 km²) of the Mesopotamian Marshes downstream. We constructed a continuous (1964 to 1998) catchment-based rainfall runoff model for the entire Tigris-Euphrates watershed (area: one million km²) using the SWAT …

Laboratory Based Chemical And Isotopic Investigations On Biotic (Microbial) And Abiotic Reduction Of Iron And Oxidation Of Organic Compounds, Tsigabu Asmelash Gebrehiwet

Dissertations

Studies using chemical and isotopic techniques have been conducted to investigate experimental microbial (biotic) iron reduction and abiotic redox processes. In the microbially mediated study Fe(III) reduction and lactate oxidation at circum-neutral pH and anaerobic conditions were used to characterize the metabolic pathways followed by dissimilatory Fe⁺³ -reducing bacterium Shewanella putrefaciens strain 200R. Iron (II), Iron (III), dissolved inorganic carbon (DIC) and carbon isotope ratios were measured under bicarbonate and phosphate buffered conditions. Carbon isotope disproportionation among organic carbon substrate (lactate), biomass and respired carbon dioxide at the lag to stationary phase of the microbial growth curve showed …

Stratigraphy And Organic Carbon Contents Of Glacial Deposits In The City Of Portage, Michigan, U.S.A., Nathaniel A. Barnes

Masters Theses

The objectives of this study are to characterize the stratigraphy of the glacial drift in an area located in Portage, Michigan using four complete rotasonic cores, and to determine the variation of organic carbon content in the drift that may explain the high iron concentrations in the groundwater typically obtained in moderate to deep wells in southwestern Michigan. The four cores were characterized in detail in terms of lithology, textural and statistical analyses, gamma ray logging, S¹³C variation and organic carbon analyses. Clay minerals were characterized using X-ray diffraction analysis.

Results of this study identified two main diamicton …

Late Pleistocene Climate Variability And Chemical Weathering In The Goriganga, Higher Central Himalaya, North India, Steven Paul Beukema

Dissertations

Relict lacustrine deposits in the Higher Central Himalaya, India, provide a rich repository of paleoclimate information for the period 16 ka to 11 ka. Stable isotope analysis of deposits near the village of Burfu shows the hydrologic balance between glacial meltwater and monsoon precipitation as source waters for the lake. During the period from 15.5 ka to 14 ka the Burfu lake was largely fed by melting glaciers. A warming event correlated to glacial Meltwater Pulse 1a indicates a sudden increase in carbonate weathering in the region accompanied by a gradual decrease in the ratio of glacial meltwater/monsoon precipitation feeding …

Geophysical Monitoring Probes And Their Applications To Some Hydrogeological Problems, Laura Smart

Dissertations

Geophysical monitoring probes were constructed to monitor the vertical changes of water content and ion concentration in the subsurface. These devices contain electrodes for resistivity measurements and thermistors for temperature measurements. They are designed to monitor the resistivity and temperature of the saturated zone, the transition zone, and the vadose zone near a groundwater/surface water interface. Additional installations at the site include four monitoring wells and four Time Domain Reflectometry (TDR) access tubes, each paired with the geophysical probe installations. Pole-Pole resistivity measurements with an a-spacing of 5 cm are made using a CR1000 Campbell Scientific, Inc. datalogger. Automated data …