Digital Commons Network^™

The Vinylguaiacol/Indole Or Vgi ("Veggie") Ratio: A Novel Molecular Parameter To Evaluate The Relative Contributions Of Terrestrial And Aquatic Organic Matter To Sediments., Michael A. Kruge, Kevin K. Olsen, Jaroslaw W. Slusarczyk, Elaine Gomez

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The organic matter (OM) fraction of estuarine sediments is often distinctive and thus diagnostically useful in determinations of sedimentary provenance. Among the most fundamental distinctions to be made is that between terrestrial and aquatic OM. To supplement the parameters commonly used for this purpose (e.g., C/N and stable isotope ratios), we proposed the Vinylguaiacol/Indole or VGI ("Veggie") ratio, defined as [vinylguaiacol / (indole + vinylguaiacol)] using data produced by analytical pyrolysis-gas chromatography/mass spectrometry of dried, homogenized sediment samples. The ratio employs the peak areas of these two compounds on the mass chromatograms of their molecular ions (m/z 150 and 117). …

Simulation Of Contaminant Transport From Solid Domestic Waste Disposal Sites In The Warri Deltaic Plain Sands, Warri-Effurun, Nigeria, Charles Onoriode Usiaphre

Theses, Dissertations and Culminating Projects

Protecting the groundwater resource in the Warri Deltaic Plain sand from the impact of anthropogenic contamination requires an understanding and knowledge of groundwater flow paths, transport processes and the source of contamination. This study was carried out to find out contaminant transport from solid domestic waste sites to the groundwater. The U.S. Geological Survey three-dimensional finite-difference code, MODFLOW, was used to simulate the groundwater flow. The flow pattern reveals predominantly downward flow, with major horizontal motion towards towns around Ekurede Urhobo and Ekurede Itsekiri in Warri. Simulation of advective contaminant transport using MODPATE1 for particle tracking indicates local movement of …

Petrology And Geochemistry Of The Pompton Pink Granite, New Jersey Highlands, Ian Phillip Johnson

Theses, Dissertations and Culminating Projects

The Pompton Pink Granite is a small (~1 km²), post-orogenic granitoid body located in the New Jersey Highlands. It is a mildly peraluminous (ASI or aluminum saturation index, A/CNK = molar Al₂O₃ / (CaO + Na₂O + K₂O) > 1.0) pluton composed of microcline, microperthite, quartz, oligoclase, epidote, biotite, and magnetite and is classified as a granite based on its mineral and geochemical composition using standard IUGS classification schemes. The Pompton Pink Granite shows similar major-element geochemistry to other A-type granitoids found in the New Jersey Highlands, but its trace­ element geochemistry distinguishes it from these other …

Rock Magnetic And Remanence Properties Of Both Synthetic Martian Basaltic Intrusions And Dropstones Along The East Antarctic Margin, To Aid In The Understanding Of The Carriers Of Crustal Magnetic Anomalies, David Michael Cuomo Jr.

Theses, Dissertations and Culminating Projects

This thesis examines potential carriers of magnetic anomalies found in remote areas where direct sampling is impossible. The areas examined are the southern hemisphere of Mars and the East Antarctic Margin. We examine the rock magnetic and remanence properties of synthetic Mars basalts and Antarctic dropstones, to predict the type and intensity of anomaly they would produce.

The anomalies measured within the Martian crust are entirely remanent magnetization and are remarkably orders of magnitude stronger than the strongest terrestrial anomaly. Two basalt compositions denoted M-type and T-type, deemed relevant to the crust of Mars, were synthesized to examine contrasts in …

Ice Sheet Dynamics Of The Past 17 Myr In Southern Mcmurdo Sound, Antarctica: A Heavy Mineral Analysis, Daniel William Hauptvogel

Theses, Dissertations and Culminating Projects

The ANtarctic Geologie DRILLing program (ANDRILL) drilled a sediment core from a sea ice platform in the Ross Sea in southern McMurdo Sound (SMS), Antarctica, in late 2007. The core site is located just to the east of the Transantarctic Mountains (TAM) along the western margin of a half graben and is a site of heavy sedimentation from the TAM, the East Antarctic Ice Sheet (EAIS), the McMurdo Volcanic Group (MVG), and the West Antarctic Ice Sheet (WAIS) and Ross Ice Shelf. The upper 650 m of the core were analyzed for heavy minerals in order to interpret ice sheet …

Characterization Of Contaminant And Biomass-Derived Organic Matter In Sediments From The Lower Passaic River, New Jersey, Usa, Nicole Michelle Bujalski

Theses, Dissertations and Culminating Projects

The lower Passaic River has been heavily contaminated during the twentieth century due to the industrial activity within its watershed. The geochemistry of four deep cores was explored using an environmental forensics approach. Pyrolysis gaschromatography/ mass spectrometry (Py-GC/MS) and grain size analysis was performed in conjunction with radiometric analysis to understand the sediment and contaminant transport patterns. The distinctive molecular finger prints were identified by employing chromatogram fingerprints, polycyclic aromatic hydrocarbon distribution, principal component analysis, and chemostratigraphy. Radiometric analysis and observations of chlorinated contaminant patterns allowed for average sample depths to be correlated to approximate ages. Additionally three distinct zones …

Talus Slope Processes In The Appalachian : An Analysis Of Rock Size And Shape On The Shawangunk Ridge, Northwestern New Jersey, Muhammad Hamidul Haque

Theses, Dissertations and Culminating Projects

Sphericity, hardness, roundness, and size of talus boulders were analyzed to understand the mass wasting process on the Shawangunk Ridge in northwestern New Jersey. Similar studies have been conducted in other localities (e.g., Lassen Peak, California and Spitsbergen, Sweden) but few works were carried out in the eastern United States, particularly in the Appalachian region. During the Pleistocene, ice sheets advanced in North America, and glacial and periglacial (soil and rock affected by ice) environments existed throughout the Appalachians. Although the periglacial climate is not present in this region right now, rock falls are still active where weak joints are …

Role Of Dynamic Vegetation In Regional Climate Predictions Over Western Africa, Clement Alo, Guiling Wang

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

This study examines the role of vegetation dynamics in regional predictions of future climate change in western Africa using a dynamic vegetation model asynchronously coupled to a regional climate model. Two experiments, one for present day and one for future, are conducted with the linked regional climate-vegetation model, and the third with the regional climate model standing alone that predicts future climate based on present-day vegetation. These simulations are so designed in order to tease out the impact of structural vegetation feedback on simulated climate and hydrological processes. According to future predictions by the regional climatevegetation model, increase in LAI …

Geochemical Investigation Of An Offshore Sewage Sludge Deposit, Barcelona, Catalonia, Spain, Michael A. Kruge, Albert Permanyer, Jordi Serra, Danlin Yu

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

For 20 years ending in the 1990’s the city of Barcelona discharged the products from a large primary sewage treatment plant directly into the Mediterranean Sea via underwater conduits. About ca. 3 million m³ of relict sewage sludge, rich in organic matter and heavy metals, has spread over an elongated area offshore, due to successive ruptures of the conduits. The use of the discharge pipes ceased, but he sludge deposit remains in place for the time being.

To understand the history and present state of the sludge deposit in advance of future remediation, a program of geophysical mapping, sampling, …