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Triflic Acid Controlled Successive Annelation Of Aromatic Sulfonamides: An Efficient One-Pot Synthesis Of N-Sulfonyl Pyrroles, Indoles And Carbazoles, Abid Shaikh, Liliana Teixeira, Béla Török
Triflic Acid Controlled Successive Annelation Of Aromatic Sulfonamides: An Efficient One-Pot Synthesis Of N-Sulfonyl Pyrroles, Indoles And Carbazoles, Abid Shaikh, Liliana Teixeira, Béla Török
Abid Shaikh
A novel one-pot synthesis of N-substituted heterocycles via successive cyclization/annelation starting from primary sulfonamides is described. This process directly leads to N-sulfonyl pyrroles, indoles and carbazoles. The selection of an appropriate reactant/triflic acid ratio successfully controls the formation of the desired product.