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In Situ Studies Of Tic1−X N X Hard Coating Tribology, Marisa Rebelo De Figueiredo, Christopher Muratore, Robert Franz, Richard Chromik, Kathryn Wahl, Andrey Voevodin, Michel O'Sullivan, Markus Lechthaler, Christian Mitterer

Christopher Muratore

TiC1−x N x hard coatings present time-dependent tribological behavior with an initial running-in period (500–2000 cycles) marked by an elevated friction coefficient, followed by >10000 cycles with low-friction and wear at room temperature (RT) in ambient air. The mechanisms behind this behavior are not completely understood. Tribological tests performed at RT and at different relative humidity (RH) levels revealed that a minimum value between 15 and 25% RH is needed to trigger the low-friction regime at a sliding speed of 100 mm s−1. By in situ observations of transfer film growth, it could be observed that third body material …

Adaptive Nanocomposite Coatings With A Titanium Nitride Diffusion Barrier Mask For High-Temperature Tribological Applications, Christopher Muratore, Jianjun Hu, Andrey Voevodin

Christopher Muratore

Adaptive nanocomposite coatings that demonstrate low friction throughout broad ranges of temperature, wear, humidity and other environments are currently in development. One effective temperature adaptation mechanism at temperatures ≤ 500 °C is diffusion of noble metal to the coating surface, providing a low shear strength interface at the friction contact supported by a hard surface underneath. To prolong the wear lifetime of chameleon coatings relying upon this mechanism for low friction, a coating architecture incorporating a diffusion barrier mask to inhibit noble metal diffusion was employed. The diffusion barrier-capped coating provided lubrication at 500 °C over ten times longer than …

A Simultaneous Increase In The Thermal And Electrical Transport In Carbon Nanotube Yarns Induced By Inter-Tube Metallic Welding, Sabyasachi Ganguli, Amber Reed, Chaminda Jayasinghe, Joe Sprengard, Ajit Roy, Andrey Voevodin, Christopher Muratore

Christopher Muratore

Vertically aligned arrays of multiwall carbon nanotubes (MWCNT) were decorated with gold (Au) nanoparticles of different diameter and areal densities and spun into yarns. The melting point of Au nanoparticles determined by differential scanning calorimetry was approximately 260 °C, well below the oxidation temperature of carbon. A continuous yarn was formed while pulling out a bundle of CNTs from the metalized CNT array. Relatively low temperature (300 °C) thermal processing of the metalized yarn resulted in a 30% improvement in thermal conductivity, 40% increase in electrical conductivity and a 4× increase in elastic modulus. Cross-sections of the yarn were examined …

Temporally And Spatially Resolved Plasma Spectroscopy In Pulsed Laser Deposition Of Ultra-Thin Boron Nitride Films, Nicholas Glavin, Christopher Muratore, Michael Jespersen, Jianjun Hu, Timothy Fisher, Andrey Voevodin

Christopher Muratore

Physical vapor deposition (PVD) has recently been investigated as a viable, alternative growth technique for two-dimensional materials with multiple benefits over other vapor deposition synthesis methods. The high kinetic energies and chemical reactivities of the condensing species formed from PVD processes can facilitate growth over large areas and at reduced substrate temperatures. In this study, chemistry, kinetic energies, time of flight data, and spatial distributions within a PVD plasma plume ablated from aboron nitride (BN) target by a KrF laser at different pressures of nitrogen gas were investigated. Time resolved spectroscopy and wavelength specific imaging were used to identify and …

Cross-Plane Thermal Properties Of Transition Metal Dichalcogenides, Christopher Muratore, Vikas Varshney, Jaime Gengler, Jianjun Hu, John Bultman, Timothy Smith, Patrick Shamberger, Bo Qiu, Xiulin Ruan, Ajit Roy, Andrey Voevodin

Christopher Muratore

In this work, we explore the thermal properties of hexagonal transition metal dichalcogenide compounds with different average atomic masses but equivalent microstructures. Thermal conductivity values of sputtered thin films were compared to bulk crystals. The comparison revealed a >10 fold reduction in thin film thermal conductivity. Structural analysis of the films revealed a turbostratic structure with domain sizes on the order of 5–10 nm. Estimates of phonon scattering lengths at domain boundaries based on computationally derived group velocities were consistent with the observed film microstructure, and accounted for the reduction in thermal conductivity compared to values for bulk crystals.

Fabrication Of Micro-Meltblown Filtration Media Using Parallel Plate Die Design, Mohammad A. Hassan

Mohammad Abouelreesh Hassan

Meltblown fibers are typically produced using a die technology based on the slot concept, an extension of the sheet die technology with a series of holes substituting the center rectangular slot of the sheet die. While this prevalent technology has met with considerable success, an economical, facile design would be desirable. In this study a new parallel plate die concept to fabricate micro-meltblown fibers that offers simplicity, ease of use, and low cost was examined. The new die concept had parallel plates forming channels for polymer melt to flow through with a set of air holes surrounding them. This die …

Procesy Cieplne I Aparaty (Lab), Wojciech M. Budzianowski

Wojciech Budzianowski

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Design Analysis Of Fixed-Bed Synergic Adsorption Of Heavy Metals And Acid Blue 25 On Activated Carbon, M.T. Hernandez-Eudave, Adrian Bonilla-Petriciolet, M.R. Moreno-Virgen, C.K. Rojas-Mayorga, R. Tovar-Gomez

Adrian Bonilla-Petriciolet

This study reports the multicomponent adsorption of dye AB25, nickel (Ni2+) and zinc (Zn2+) ions on an activated carbon using binary mixtures of metal and dye, and packed bed columns at different operating conditions. Design parameters of packed bed adsorption columns have been calculated using the breakthrough curves and Thomas model, and an analysis has been performed to determine the effect and magnitude of the synergistic adsorption on the design parameters and adsorbent performance. Results showed that there is a strong synergistic adsorption of heavy metals on activated carbon caused by the presence of dye AB25 in binary mixtures. The …

Inżynieria Chemiczna Lab., Wojciech M. Budzianowski

Wojciech Budzianowski

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Getting To The Root Of Bacterial Hairs: What Is “S”?, Rebecca Gaddis, Samantha O'Conner, Evan Anderson, Terri Camesano, Nancy Burnham

Nancy A. Burnham

An atomic force microscope (AFM) was used to measure the steric forces of lipopolysaccharides (LPS) on the biofilm-forming bacteria, Pseudomonas aeruginosa. It is well known that LPS play a vital role in biofilm formation. These forces were characterized with a modified version of the Alexander and de Gennes (AdG) model for polymers, which is a function of equilibrium brush length, L, probe radius, R, temperature, T, separation distance, D, and an indefinite density variable, s. This last parameter was originally distinguished by de Gennes as the root spacing or mesh spacing depending upon the type of polymer adhesion; however since …

Secondary Current Distributions Using Topaz2d And Linear Kinetics, E. C. Dimpault-Darcy, Ralph E. White

Ralph E. White

Secondary current density distributions are of interest
to cell designers. The purpose of this note is to illustrate
how to use an existing numerical method to determine
these distributions for cells that contain conducting and
nonconducting bodies between the main anode and cathode.

Secondary Current Distributions Using Topaz2d And Linear Kinetics, E. C. Dimpault-Darcy, Ralph E. White

Ralph E. White

Secondary current density distributions are of interestto cell designers. The purpose of this note is to illustratehow to use an existing numerical method to determinethese distributions for cells that contain conducting andnonconducting bodies between the main anode and cathode.

Controlling Microbial Contamination During Hydrolysis Of Afex-Pretreated Corn Stover And Switchgrass: Effects On Hydrolysate Composition, Microbial Response And Fermentation, Jose Serate, Dan Xie, Edward Pohlmann, Charles Donald Jr., Mahboubeh Shabani, Li Hinchman, Alan Higbee, Mick Mcgee, Alex La Reau, Grace E. Klinger, Sheena Li, Chad L. Myers, Charles Boone, Donna M. Bates, Dave Cavalier, Dustin Eilert, Lawrence G. Oates, Gregg Sanford, Trey K. Sato, Bruce Dale, Robert Landrick, Jeff Piotrowski, Rebecca G. Gong, Yaoping Zhang

Rebecca Ong

Unraveling The Mystery Of Natural Rubber Biosynthesis. Part Ii: Composition And Growth Of In Vitro Natural Rubber Using High-Resolution Size Exclusion Chromatography, Cheng Ching Chiang, Balaka Barkakaty, Judit Puskas, Wenshuang Xie, Katrina Cornish, Federic Peruch, Alain Deffieux

Balaka Barkakaty

The superior properties of natural rubber (cis-1,4-polyisoprene [NR]) are a function of its structure and composition, properties that still remain a mystery and that are irreplaceable by any synthetic rubber. NR from guayule (Parthenium argentatum) has been gaining special interest for its hypoallergenic properties while maintaining superior mechanical properties that are commonly associated with the Brazilian rubber tree (Hevea brasiliensis), the most common source of NR. Techniques exist to isolate washed rubber particles (WRPs) that contain enzymatically active rubber transferase, to study NR biosynthesis, and previous work on the in vitro NR growth in Hevea has demonstrated the presence of …

Evaluation Of Effective Operational Cycle Time And Bioprocess Parameters In A Sequential Batch Reactor For Efficient Organic And Nutrient Removal From Domestic Sewage, Sandip S. Magdum, Siva Kumar Varigala, Yogesh N. Patil, Gauri P. Minde, Janardhan B. Bornare, V. Kalyanraman

Sandip S. Magdum

Anaerobic, anoxic and aerobic environment can be simulated in the single stage sequential batch reactor (SBR) . Various design conditions viz., combinations of different phase time and different cycle time, hydraulic residence time (HRT), substrate loading rate, sludge age (SRT) and aeration time were analyzed for optimum biological treatment. The pilot runs were evaluated with the design conditions of food/microbe ratio (F/M) 0.2 per day and MLSS of 4950 mg/L. For the given design conditions 4, 5 and 6 hours cycle lengths were analyzed for their efficient performance with 30-33% of decant volume for sewage containing C:N:P of 100:8:2. Studies …

Catalytic Deoxygenation Of Guaiacol Using Methane, Yang Xiao

Yang Xiao

Chapter 2 - Thermoplastic-Thermoset Nanostructured Polymer Blends.Pdf, Amos Adeniyi, Oluranti Agboola, Emmanuel R. Sadiku, M. O. Durowoju, P. A. Olubambi, A. B. Reddy, I. D. Ibrahim, W. K. Kupolati

Chongwen Huang

One-Dimensional Approach To Modeling Damage Evolution In Galvanic Corrosion, Aaron Stenta, S. Basco, A. Smith, Curtis Clemons, Dimitry Golovaty, Kevin Kreider, Joseph Wilder, Gerald Young, Robert Lillard

Gerald W Young

A one-dimensional mathematical model is developed to describe time-dependent damage evolution in well-mixed (spatially uniform species concentrations) galvanic systems using an IR drop approach. An asymptotic procedure taking advantage of disparity in length scales (thin film approximation for the electrolyte thickness) is used to derive the model. Limitations that result from the reduction of dimension are described, along with an analysis demonstrating the ability of the 1D model to capture physical phenomena, such as area ratio effects. Computed potential, current density, and corrosion damage profiles are compared and verified with experimental data available in the literature and 2D galvanic corrosion …

One-Dimensional Approach To Modeling Damage Evolution In Galvanic Corrosion, Aaron Stenta, S. Basco, A. Smith, Curtis Clemons, Dimitry Golovaty, Kevin Kreider, Joseph Wilder, Gerald Young, Robert Lillard

Kevin L. Kreider

A one-dimensional mathematical model is developed to describe time-dependent damage evolution in well-mixed (spatially uniform species concentrations) galvanic systems using an IR drop approach. An asymptotic procedure taking advantage of disparity in length scales (thin film approximation for the electrolyte thickness) is used to derive the model. Limitations that result from the reduction of dimension are described, along with an analysis demonstrating the ability of the 1D model to capture physical phenomena, such as area ratio effects. Computed potential, current density, and corrosion damage profiles are compared and verified with experimental data available in the literature and 2D galvanic corrosion …

One-Dimensional Approach To Modeling Damage Evolution In Galvanic Corrosion, Aaron Stenta, S. Basco, A. Smith, Curtis Clemons, Dimitry Golovaty, Kevin Kreider, Joseph Wilder, Gerald Young, Robert Lillard

Dimitry Golovaty

A one-dimensional mathematical model is developed to describe time-dependent damage evolution in well-mixed (spatially uniform species concentrations) galvanic systems using an IR drop approach. An asymptotic procedure taking advantage of disparity in length scales (thin film approximation for the electrolyte thickness) is used to derive the model. Limitations that result from the reduction of dimension are described, along with an analysis demonstrating the ability of the 1D model to capture physical phenomena, such as area ratio effects. Computed potential, current density, and corrosion damage profiles are compared and verified with experimental data available in the literature and 2D galvanic corrosion …

One-Dimensional Approach To Modeling Damage Evolution In Galvanic Corrosion, Aaron Stenta, S. Basco, A. Smith, Curtis Clemons, Dimitry Golovaty, Kevin Kreider, Joseph Wilder, Gerald Young, Robert Lillard

Curtis B. Clemons

A one-dimensional mathematical model is developed to describe time-dependent damage evolution in well-mixed (spatially uniform species concentrations) galvanic systems using an IR drop approach. An asymptotic procedure taking advantage of disparity in length scales (thin film approximation for the electrolyte thickness) is used to derive the model. Limitations that result from the reduction of dimension are described, along with an analysis demonstrating the ability of the 1D model to capture physical phenomena, such as area ratio effects. Computed potential, current density, and corrosion damage profiles are compared and verified with experimental data available in the literature and 2D galvanic corrosion …

Silver (I)-Imidazole Cyclophane Gem-Diol Complexes Encapsulated By Electrospun Tecophilic Nanofibers: Formation Of Nanosilver Particles And Antimicrobial Activity, Abdulkareem Melaiye, Zhaohui Sun, Khadijah Hindi, Amy Milsted, Daniel Ely, Darrell Reneker, Claire Tessier, Wiley Youngs

Wiley J. Youngs

Silver(I)-imidazole cyclophane gem-diol complex, 3 [Ag2C36 N10(O)4](2+)2(x)-, where x = OH- or CO3(2-), was synthesized and well characterized. The minimum inhibition concentration tests showed that the aqueous form of 3 is 2 times less effective as an antibiotic than 0.5% AgNO3, with about the same amount of silver. The antimicrobial activity of 3 was enhanced when encapsulated into Tecophilic polymer by electrospinning to obtain mats made of nano-fibers. The fiber mats released nanosilver particles, which in turn sustained the antimicrobial activity of the mats over a long period of time. The rate of bactericidal activity of 3 was greatly improved …

Silver (I)-Imidazole Cyclophane Gem-Diol Complexes Encapsulated By Electrospun Tecophilic Nanofibers: Formation Of Nanosilver Particles And Antimicrobial Activity, Abdulkareem Melaiye, Zhaohui Sun, Khadijah Hindi, Amy Milsted, Daniel Ely, Darrell Reneker, Claire Tessier, Wiley Youngs

Claire A. Tessier

Silver(I)-imidazole cyclophane gem-diol complex, 3 [Ag2C36 N10(O)4](2+)2(x)-, where x = OH- or CO3(2-), was synthesized and well characterized. The minimum inhibition concentration tests showed that the aqueous form of 3 is 2 times less effective as an antibiotic than 0.5% AgNO3, with about the same amount of silver. The antimicrobial activity of 3 was enhanced when encapsulated into Tecophilic polymer by electrospinning to obtain mats made of nano-fibers. The fiber mats released nanosilver particles, which in turn sustained the antimicrobial activity of the mats over a long period of time. The rate of bactericidal activity of 3 was greatly improved …

A Ga3+Self-Assembled Fluorescent Probe For Atp Imaging In Vivo, Liangliang Xiao, Shiguo Sun, Zhichao Pei, Yuxin Pei, Yi Pang, Yongqian Xu

Yi Pang

Adenosine 5′-triphosphate (ATP) is a functional molecule associated with many important biological processes. Fluorescent detection methods for ATP with facile performance and high selectivity are in demand. One of the possible multi-membered arrays assembled between DHBO and Ga3+ ions was conducted in aqueous solution, which can selectively recognize ATP with fluorescence enhancement from ADP, AMP and other structurally similar nucleoside triphosphates in vitro and in vivo. ATP facilitates the interaction between DHBO and Ga3+ ions, resulting in the fluorescence increase. The detection limit for ATP was calculated to be 5.49×10−7 M, which is much lower than that of intracellular concentrations …

Synthesis And Electrochemical Properties Of A New Class Of Boron-Containing N-Type Conjugated Polymers, Jianfang Chai, Chao Wang, Li Jia, Yi Pang, Matthew Graham, Stephen Cheng

Yi Pang

Several electron-deficient polymers containing the 9,10-diboroanthracene unit have been synthesized and characterized. Electrochemical study shows that they have high electron affinities. Photoluminescence of rr-P3HT is quenched in the presence of one of the polymers in the solid state, demonstrating the potential utility of this class of polymer as powerful n-type materials in organic photovoltaic devices.

Biocompatible Flavone-Based Fluorogenic Probes For Quick Wash-Free Mitochondria! Imaging In Living Cells, Bin Liu, Mickey Shah, Ge Zhang, Qin Liu, Yi Pang

Yi Pang

Mitochondria, vital organelles existing in almost all eukaryotic cells, play a crucial role in energy metabolism and apoptosis of aerobic organisms. In this work, we report two new flavone-based fluorescent probes, MC-Mito1 and MC-Mito2, for monitoring mitochondria in living cells. These two probes exhibit remarkably low toxicity, good cell permeability, and high specificity; these probes complement the existing library of mitochondrial imaging agents. The new dyes give nearly no background fluorescence, and their application does not require tedious postwashing after cell staining. The appreciable tolerance of MC-Mito2 encourages a broader range of biological applications for understanding the cell degeneration and …

Uv-Absorption And Silica/Titania Colloids Using A Core--Shell Approach, Liang Zhou, Hendrik Heinz, Mark Soucek, Elvin Aleman, David Modarelli

David A. Modarelli

Metal-oxo-colloids have been prepared using tetraethoxysilane (TEOS) oligomers with titanium tetra-i-propoxide (TIP) or titanium (di-i-propoxide) bis(acetylacetonate) (TIA) precursors. Transmission electron microscopy (TEM), FTIR, UV-Vis, and photoluminescence spectroscopy were used to investigate the composition, the size, and optical properties of the Si/Ti core–shell colloids. The presence of hetero-bonded silicate structure (Si–O–Ti) was indicated by FTIR spectroscopy. The size of Si/TIP system ranged from 55 to 120 nm and Si/TIA system ranged from 220 to 250 nm. The TEM data indicated that the size of colloids can be controlled by the TIP or TIA content. The Si/Ti system …

Improvement Of Mechanical Properties And Water Stability Of Vegetable Protein Based Plastics, Gowrishankar Srinivasan

Gowrishankar Srinivasan

Bio-renewable bio-degradable plastics are a potential solution to the growing problems of pollution caused by petroleum plastics and dependency on foreign nations for petroleum resources. One possible feed stock for these materials are vegetable proteins, especially from soy bean and corn. These proteins have relatively high molecular weights and have the potential of being processed with standard polymer processing technologies. But some issues that need to be addressed are their water instability (soy protein) and inferior mechanical properties as compared to petroleum derived plastics. In this study, soy protein isolates (SPI) and zein protein was processed with various additives and …

Identification Of A Highly Specific Hydroxyapatite-Binding Peptide Using Phage Display, Marc Roy, Scott Stanley, Eric Amis, Matthew Becker

Eric J. Amis

A peptide sequence SVSVGMKPSPRP that selectively recognizes hydroxyapatite (HA) is identified by using a phage display approach. The engineered sequence exhibits chemical and structural specificity for HA over calcium carbonate and HA's amorphous calcium phosphate precursor. In situ binding to HA in a tooth cross section further demonstrates the sequence specificity and utility in nondestructive imaging applications.

Biocompatible Flavone-Based Fluorogenic Probes For Quick Wash-Free Mitochondria! Imaging In Living Cells, Bin Liu, Mickey Shah, Ge Zhang, Qin Liu, Yi Pang

Ge Zhang

Mitochondria, vital organelles existing in almost all eukaryotic cells, play a crucial role in energy metabolism and apoptosis of aerobic organisms. In this work, we report two new flavone-based fluorescent probes, MC-Mito1 and MC-Mito2, for monitoring mitochondria in living cells. These two probes exhibit remarkably low toxicity, good cell permeability, and high specificity; these probes complement the existing library of mitochondrial imaging agents. The new dyes give nearly no background fluorescence, and their application does not require tedious postwashing after cell staining. The appreciable tolerance of MC-Mito2 encourages a broader range of biological applications for understanding the cell degeneration and …