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Thermocapillary Effects In Driven Dewetting And Self-Assembly Of Pulsed Laser-Irradiated Metallic Films, Mikhail Khenner

Mikhail Khenner

A mathematical model for the evolution of pulsed laser-irradiated, molten metallic films has been developed using the lubrication theory. The heat transfer problem that incorporates the absorbed heat from a single laser beam or the interfering laser beams is solved analytically. Using this temperature field, we derive the 3D long-wave evolution PDE for the film height. To get insights into dynamics of dewetting, we study the 2D version of the evolution equation by means of a linear stability analysis and by numerical simulations. The stabilizing and destabilizing effects of various system parameters, such as the reflectivity, the peak laser beam …

Absolute Nitrogen Atom Density Measurements By Two-Photon Laser-Induced Fluorescence Spectroscopy In Atmospheric Pressure Dielectric Barrier Discharges Of Pure Nitrogen, Et-Touhami Es-Sebbar, Christian Sarra-Bournet, Nicolas Naudé, Françoise Massines, Nicolas Gherardi

Dr. Et-touhami Es-sebbar

In this paper, two-photon absorption laser induced fluorescence spectroscopy is used to follow the nitrogen atom density in flowing dielectric barrier discharges fed with pure nitrogen and operating at atmospheric pressure. Two different dielectric barrier discharge regimes are investigated: the Townsend regime, which is homogeneous although operating at atmospheric pressure, and the more common filamentary regime. In both regimes, densities as high as 3x1014 /cm3 are detected. However, the N atoms kinetic formation depends on the discharge regime. The saturation level is reached more rapidly with a filamentary discharge. For a given discharge regime, the N atom density depends strongly …

Contributions To The Development Of The S.E.T.U.P. (Experimental And Theoretical Simulations Useful For Planetology) Project, E. Arzoumanian, C. Romanzin, M-C. Gazeau, Et. Es-Sebbar, A. Jolly, S. Perrier, Y. Benilan

Dr. Et-touhami Es-sebbar

No abstract provided.

Multiwavelength Studies For Titan's Atmospheric Composition Analysis, Y. Benilan, Et. Es-Sebbar, N. Fray, M-C. Gazeau, A. Jolly, M. Schwell, J. Guillemin

Dr. Et-touhami Es-sebbar

Titan's atmosphere mainly made of nitrogen and methane is rich in organic molecules. Hydrocarbons are formed from the photolytic dissociation of CH4 and nitriles are created by dissociation of N2 followed by reactions with hydrocarbons. In order to understand the physicochemical mechanisms responsible for the evolution of Titan's atmosphere, photochemical models are built. The latter need constrains for vertical profiles of organic compounds from the high thermosphere down to the low stratosphere as well as photodissociation rates. Those profiles over the entire atmosphere can be retrieved from Cassini observations, in particular by limb sounding, coupling infrared and ultraviolet spectroscopy. However, …

Polymer , Yu Zhu

Yu Zhu

No abstract provided.

Chemistry Of Materials , Yu Zhu

Yu Zhu

No abstract provided.

Vuv Photostability Of Prebiotic Species, M. Schwell, Y. Bénilan, M.-C. Gazeau, N. Fray, A. Jolly, Et. Es-Sebbar, N. Champion, S. Leach, H. W Jochims, H. Baumgärtel, E. Rühl

Dr. Et-touhami Es-sebbar

No abstract provided.

S.E.T.U.P. Experimental And Theoretical Simulations Useful For Planetology- Related Studies In The Frame Of A Program Of Titan’S Atmosphere Laboratory Simulations, M.-C. Gazeau, Et. Es-Sebbar, E. Arzoumanian, C. Romanzin, A. Jolly, S. Perrier, Y. Bénilan

Dr. Et-touhami Es-sebbar

No abstract provided.

Novel Catalytic Process For Flue Gas Conditioning In Electrostatic Precipitators Of Coal-Fired Power Plants, Andrey N. Zagoruiko, Bair S. Balzhinimaev, Sergey V. Vanag, Sergey A. Lopatin, Alexander M. Zykov, Sergey N. Anichkov, Nick D. Hutson

Andrey N Zagoruiko

The presentation is devoted to the development of the new catalytic process for oxidation of SO2 to SO3 on the base of the novel Pt-containing catalyst with Zr-Si fiber-glass support. It was demonstrated that such catalyst reveals excellent low-temperature activity and unique long-term operation stability. The process may be applied for production of SO3 for conditioning of flue gases from coal-fired powerplants.

New Generation Of Catalytic Technologies For Environmental Protection On The Base Of Fiber-Glass Catalysts, Bair S. Balzhinimaev, Andrey N. Zagoruiko

Andrey N Zagoruiko

Novel glass-fiber based catalysts containing extra-low amounts of noble metals (0.01-0.02% mass of Pt or Pd) demonstrate unique performance in many catalytic reactions, resulted from the ability of the glass fibers to stabilize the transient metals in the glass bulk in a highly-dispersed form. Moreover, specific heat/mass transfer properties, original geometry, high flexibility and high mechanical strength of such catalysts give the way to develop really new catalytic processes and novel reactor designs. The paper is dedicated to the successful research and development (from fundamental research issues to pilot and semi-industrial tests) of different catalytic oxidation processes based on application …

Understanding Adsorption And Desorption Processes In Mesoporous Materials With Independent Disordered Channels, Peter A. Monson, Sergej Naumov, Rustem Valiullin, Jörg Kärger

Peter A. Monson

Using a lattice-gas model in mean-field theory, we discuss the problem of how adsorption and desorption of fluids in independent cylinderlike pores is influenced by variations in the pore diameter along the length of the pore, surface roughness of the pore walls, and chemical heterogeneity. We also consider the impact of contact with the bulk phase via the pore opening and the possibility of interactions between neighboring pores via a liquid film on the external surface of the material. We find that a combination of pore size variation along the length of the pore and surface roughness yields sorption hysteresis …

Electrospinning Route For The Fabrication Of Pn Junction Using Nanofiber Yarns, Darrell Reneker

Darrell Hyson Reneker

Electrospinning is a simple, versatile, and cost effective method for generating nanoscale fibers, wires, and tubes. Nanowires and nanotubes could be important building blocks for nanoscale electronics, optoelectronics, and sensors as they can function as miniaturized devices as well as electrical interconnects. We report on a simple method to fabricate free standing ceramic nanofiber heterostructures, which exhibit rectifying behavior of a p-n junction

Characterization Of An N2 Flowing Microwave Post-Discharge By Oes Spectroscopy And Determination Of Absolute Ground-State Nitrogen Atom Densities By Talif, Et. Es-Sebbar, Y. Benilan, A. Jolly, M-C. Gazeau

Dr. Et-touhami Es-sebbar

A flowing microwave post-discharge source sustained at 2.45 GHz in pure nitrogen has been investigated by optical emission spectroscopy (OES) and two-photon absorption laser-induced fluorescence (TALIF) spectroscopy. Variations of the optical emission along the post-discharge (near, pink and late afterglow) have been studied and the gas temperature has been determined. TALIF spectroscopy has been used in the late afterglow to determine the absolute ground-state nitrogen atomic densities using krypton as a reference gas. Measurements show that the microwave flowing post-discharge is an efficient source of N (4S) atoms in late afterglow. In our experimental conditions, the maximum N (4S) density …

Comparison Between Direct Quadrature Method Of Moments And The Method Of Classes For Bubbly Flow, Brahim Selma, Rachid Bannari, Pierre Proulx

Rachid BANNARI

No abstract provided.

Design And Cfd Analysis Of Mass Transfer And Shear Stresses Distributions In Airlift Reactor, Rachid Bannari, Brahim Selma, Abdelfettah Bannari, Pierre Proulx

Rachid BANNARI

The design, scale-up and performance evaluation of biological reactors require accurate information about the gas-liquid flow dynamics. In this study, we use CFD techniques to investigate important parameters of the multiphase flow dynamics on an initial airlift bioreactor in order to improve its design. Such parameters are distributions of shear stresses and mass transfer. Our initial proposed design of the airlift bioreactor was used for biomass growing. Specifically to produce cellulase enzyme using the fungus Trichoderma Reesei. However, the morphology of the microorganism obtained in this bioreactor was not appropriated to produce cellulase. Since the microorganism morphology presented a small …

Small-World Network Models Of Intercellular Coupling Predict Enhanced Synchronization In The Suprachiasmatic Nucleus, Christina Vasalou, Erik D. Herzog, Michael A. Henson

Michael A Henson

The suprachiasmatic nucleus (SCN) of the hypothalamus is a multioscillator system that drives daily rhythms in mammalian behavior and physiology. Based on recent data implicating vasoactive intestinal polypeptide (VIP) as the key intercellular synchronizing agent, we developed a multicellular SCN model to investigate the effects of cellular heterogeneity and intercellular connectivity on circadian behavior. A 2-dimensional grid was populated with 400 model cells that were heterogeneous with respect to their uncoupled rhythmic behavior (intrinsic and damped pacemakers with a range of oscillation periods) and VIP release characteristics (VIP producers and nonproducers). We constructed small-world network architectures in which local connections …

Proceedings Of The Scientific Conference On Energy And It At Alvsjo Fair, Stockholm March 11-12, 2009 In Connection With The “Energitinget 2009, Dr. Erik Dahlquist, Dr. Jenny Palm

Dr. Erik Dahlquist

This book contains the proceedings from the Energy and IT conference at Alvsjo Energy conference "Energitinget" arranged by Swedish Energy Agency, with approximately 2500 visitors. The papers contain both technical and social science papers, relating to both energy efficiency in buildings and in industry.

An Immune Self-Adaptive Differential Evolution Algorithm With Application To Estimate Kinetic Parameters For Homogeneous Mercury Oxidation, Chunping Hu, Xuefeng Yan

Chunping Hu

A new version of differential evolution (DE) algorithm, in which immune concepts and methods are applied to determine the parameter setting, named immune self-adaptive differential evolution (ISDE), is proposed to improve the performance of the DE algorithm. During the actual operation, ISDE seeks the optimal parameters arising from the evolutionary process, which enable ISDE to alter the algorithm for different optimization problems and improve the performance of ISDE by the control parameters’ self-adaptation. The performance of the proposed method is studied with the use of nine benchmark problems and compared with original DE algorithm and other well-known self-adaptive DE algorithms. …

A Coupled Cfd-Kinetic Models For Cellulase Production In Airlift Reactor, Rachid Bannari, Abdelfettah Bannari, Brahim Selma, Pierre Proulx

Rachid BANNARI

Cellulase production provides a catalyst for cellulose hydrolysis to glucose, to be used for eventual production of ethanol. The transport of reactants may influence the reaction rate remarkably, for the biological reaction, especially the enzymatic reaction, The transport behavior of the components in a biological system should be considered in the model. In this work, we propose a coupled model between hydrodynamics (twoPhaseEuler- Foam) and a kinetic model for batch and fed-batch cellulase enzyme production by T. reesei from cellulose/lactose substrate which is constructed from literature concepts and laboratory data. Good agreement is obtained between the results and experimental data.

Density Of Jatropha Curcas Seed Oil And Its Methyl Esters: Measurement And Estimations, Abdul Aziz Abdul Raman

Abdul Aziz Abdul Raman

Density data as a function of temperature have been measured for Jatropha curcas seed oil, as well as biodiesel jatropha methyl esters at temperatures from above their melting points to 90 ° C. The data obtained were used to validate the method proposed by Spencer and Danner using a modified Rackett equation. The experimental and estimated density values using the modified Rackett equation gave almost identical values with average absolute percent deviations less than 0.03% for the jatropha oil and 0.04% for the jatropha methyl esters. The Janarthanan empirical equation was also employed to predict jatropha biodiesel densities. This equation …

Kpca-Rvm Modeling Method And Its Application For Soft Sensor, Xuefeng Yan, Jia Chen, Chunping Hu, Feng Qian

Chunping Hu

A novel modeling method integrated KPCA with RVM is proposed. Firstly, kernel primary component analysis (KPCA) is employed to identify the principal components from the nonlinear transform data of independent variables, which are regarded as character variables. Then, regression between character variables and dependent variables is done based on RVM, and the optimal number of the character variables is adaptively determined according to the generalization performance of the regression model. Thus, KPCA-RVM method can eliminate the disturbance of redundant information and achieve the best nonlinear model with good generalization performance. Finally, the method of KPCA-RVM is demonstrated by a 4-CBA's …

Researches On Copper. History & Metallurgy, Fathi Habashi

Fathi Habashi

Gold. History, Metallurgy, Culture, Fathi Habashi

Fathi Habashi

The Natural Transparency And Piezoelectric Response Of The Greta Oto Butterfly Wing, Valerie R. Binetti, Jessica D. Schiffman, Oren D. Leaffer, Jonathan E. Spanier, Caroline L. Schauer

Jessica D. Schiffman

The Greta oto, or the ‘‘glasswing butterfly’’, is a member of the Ithomiini tribe. Although rare among lepidopteran, the G. oto’s wings are naturally transparent. To understand the material properties of natural transparency, the various structures on the surface of the wings, both the transparent and brown ‘‘veins’’ and wing parameter regions were studied using scanning electron microscopy (SEM), transmission electron microscopy (TEM), reflectance spectrometry, transmission spectrometry and scanning probe microscopy (SPM) in order to investigate their local structure, periodic character, and electromechanical response. Nanosized protuberances in a highly ordered array were found on the surface of the transparent part …

Macroporous Silica Using A “Sticky” Stöber Process, Rebecca Cademartiri, Michael A. Brook, Robert Pelton, John D. Brennan

Rebecca Cademartiri

The generation of macroporous silica structures using a sol–gel process generally requires the presence of high molecular weight, water-soluble polymers. We demonstrate that significantly lower molecular weight poly(ethylene glycol) (PEG) polymers can drive a particle aggregation process to generate macroporous silica. Compared to unfunctionalized PEGs (HO–PEG–HO, molecular weight > 10 000 g mol−1), PEG polymers with allyl (A–PEG–A) or silyl end groups (CH2)3Si(OEt)3 (Si–PEG–Si), with molecular weights of 2000 g mol−1 or greater, lead to monolithic macroporous structures derived from aggregates of nearly monodisperse particles. Lower molecular weight (less than 1000 g mol−1) allyl or silyl PEG, or hydroxy-terminated PEG–OH, lead …

Exploring The Transition From Wall Slip To Bulk Shearing Banding In Well-Entangled Dna Solutions, Shi-Qing Wang, Pouyan Boukany

Shi-Qing Wang

In this study we have carried out a combination of rheometric and particle-tracking velocimetric (PTV) measurements to investigate nonlinear rheological behavior of three entangled DNA solutions (with ca. 150 entanglements per chain) and, in particular, to explore a transformation from slip-dominated steady-state flow to bulk shear inhomogeneity. In the stress plateau regime, an elastic recoil-like response occurs transiently at either interfaces or sample interior after stress overshoot during a startup shear. In both startup shear and creep mode, wall slip, bulk shear banding or a combination of both have been observed in both transient and steady states. The water-based solution …

Computation Of Jump Coefficients For Momentum Transfer Between A Porous Medium And A Fluid Using A Closed Generalized Transfer Equation, Francisco J. Valdes-Parada, José Alvarez-Ramirez, Benoît Goyeau, J. Alberto Ochoa-Tapia

Francisco J. Valdes-Parada

The momentum transfer between a homogeneous fluid and a porous medium in a system analogous to the one used by Beavers and Joseph (J Fluid Mech 30:197–207, 1967) is studied using volume averaging techniques. In this article, we present a closed generalized momentum transport equation (GTE) that is valid everywhere and is expressed in terms of position-dependent effective transport coefficients, which are computed from the solution of associated closure problems previously reported. A combination of the velocity profiles from the GTE in the definition of the excess terms that define the jump coefficients allows their computation using numerical techniques. The …

Jump Condition For Diffusive And Convective Mass Transfer Between A Porous Medium And A Fluid Involving Adsorption And Chemical Reaction, Francisco J. Valdes-Parada, Jose Alvarez-Ramirez, Benoît Goyeau, J. Alberto Ochoa-Tapia

Francisco J. Valdes-Parada

In this paper, mass transfer at the fluid–porous medium boundaries is studied.The problem considers both diffusive and convective transport, along with adsorption and reaction effects in the porous medium. The result is a mass flux jump condition that is expressed in terms of effective transport coefficients. Such coefficients (a total dispersion tensor and effective reaction and adsorption coefficients) may be computed from the solution of the corresponding closure problem here stated and solved as a function of the Péclet number (Pe), the porosity and a local Thiele modulus. For the case of negligible convective transport (i.e., Pe << 1), the closure problem reduces to the one recently solved by the authors for diffusion and reaction between a fluid and a microporous medium.

Multiobjective Optimization Of An Industrial Lpg Thermal Cracker Using A First Principles Model, Reza Nabavi, G.P Rangaiah, Ali Niaei, Dariush Salari

Seyed Reza nabavi

Thermal cracking of hydrocarbons in the presence of steam is the most important process for the production of ethylene and propylene, which are the raw materials for many petrochemicals. In this work, multiobjective optimization (MOO) of an industrial LPG (liquefied petroleum gas containing mainly propane and butane) thermal cracker is studied using the elitist nondominated sorting genetic algorithm adapted with the jumping gene operator, NSGA-II-aJG. A first principles model based on free radical mechanism for LPG thermal cracking is employed for optimization. Several bi- and triobjective optimization problems are solved; these problems involved maximization of annual ethylene/propylene production, selectivity and …

پاسخهای تشریحی سوالات کنکور کارشناسی ارشد رشته شیمی کاربردی-چاپ دوم-ویرایش جدید, A. Khataee, M. H. Rasoulifard, Mir Saeed Seyed Dorraji, V. Vatanpoor

Mir saeed Seyed Dorraji

No abstract provided.