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Articles 1 - 27 of 27
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Data Management And Visualization Of X-Ray Diffraction Spectra From Thin Film Ternary Composition Spreads, I. Takeuchi, C. Long, O. Famodu, M. Murakami, Jason Hattrick-Simpers, G. Rubloff, M. Stukowski, K. Rajan
Data Management And Visualization Of X-Ray Diffraction Spectra From Thin Film Ternary Composition Spreads, I. Takeuchi, C. Long, O. Famodu, M. Murakami, Jason Hattrick-Simpers, G. Rubloff, M. Stukowski, K. Rajan
Jason R. Hattrick-Simpers
We discuss techniques for managing and visualizing x-ray diffraction spectrum data for thin film composition spreads which map large fractions of ternary compositional phase diagrams. An in-house x-ray microdiffractometer is used to obtain spectra from over 500 different compositions on an individual spread. The MATLAB software is used to quickly organize the data and create various plots from which one can quickly grasp different information regarding structural and phase changes across the composition spreads. Such exercises are valuable in rapidly assessing the “overall” picture of the structural evolution across phase diagrams before focusing in on specific composition regions for detailed …
High-Throughput Screening Of Magnetic Properties Of Quench Metallic-Alloy Thin-Film Composition Spreads, Jason Hattrick-Simpers, Cui Jun, Makoto Murakami, Antonio Orozco, Lee Knauss, Robert Booth, Edward Greve, Samuel Lofland, Manfred Wuttig, Ichiro Takeuchi
High-Throughput Screening Of Magnetic Properties Of Quench Metallic-Alloy Thin-Film Composition Spreads, Jason Hattrick-Simpers, Cui Jun, Makoto Murakami, Antonio Orozco, Lee Knauss, Robert Booth, Edward Greve, Samuel Lofland, Manfred Wuttig, Ichiro Takeuchi
Jason R. Hattrick-Simpers
No abstract provided.
Applications Of High Throughput (Combinatorial) Methodologies To Electronic, Magnetic, Optical, And Energy-Related Materials, Martin L. Green, Ichiro Takeuchi, Jason R. Hattrick-Simpers
Applications Of High Throughput (Combinatorial) Methodologies To Electronic, Magnetic, Optical, And Energy-Related Materials, Martin L. Green, Ichiro Takeuchi, Jason R. Hattrick-Simpers
Jason R. Hattrick-Simpers
High throughput (combinatorial) materials science methodology is a relatively new research paradigm that offers the promise of rapid and efficient materials screening, optimization, and discovery. The paradigm started in the pharmaceutical industry but was rapidly adopted to accelerate materials research in a wide variety of areas. High throughput experiments are characterized by synthesis of a “library” sample that contains the materials variation of interest (typically composition), and rapid and localized measurement schemes that result in massive data sets. Because the data are collected at the same time on the same “library” sample, they can be highly uniform with respect to …
Phase Transformation In An Yttrium-Hydrogen System Studied By Tem, K. Wang, Jason Hattrick-Simpers, L. Bendersky
Phase Transformation In An Yttrium-Hydrogen System Studied By Tem, K. Wang, Jason Hattrick-Simpers, L. Bendersky
Jason R. Hattrick-Simpers
No abstract provided.
Rapid Structural Mapping Of Ternary Metallic Alloy Systems Using The Combinatorial Approach And Cluster Analysis, C. Long, Jason Hattrick-Simpers, M. Murakami, R. Srivastava, I. Takeuchi, V. Karen, X. Li
Rapid Structural Mapping Of Ternary Metallic Alloy Systems Using The Combinatorial Approach And Cluster Analysis, C. Long, Jason Hattrick-Simpers, M. Murakami, R. Srivastava, I. Takeuchi, V. Karen, X. Li
Jason R. Hattrick-Simpers
We are developing a procedure for the quick identification of structural phases in thin film composition spread experiments which map large fractions of compositional phase diagrams of ternary metallic alloy systems. An in-house scanning x-ray microdiffractometer is used to obtain x-ray spectra from 273 different compositions on a single composition spread library. A cluster analysissoftware is then used to sort the spectra into groups in order to rapidly discover the distribution of phases on the ternary diagram. The most representative pattern of each group is then compared to a database of known structures to identify known phases. Using this method, …
Fabrication And Characterization Of In-Situ Grown Epitaxial Ba1-XSrXTio3 Composition Spreads, K. Chang, M. Aronova, O. Famodu, Jason Hattrick-Simpers, S. Lofland, I. Takeuchi, C. Lu, L. Bendersky, H. Chang
Fabrication And Characterization Of In-Situ Grown Epitaxial Ba1-XSrXTio3 Composition Spreads, K. Chang, M. Aronova, O. Famodu, Jason Hattrick-Simpers, S. Lofland, I. Takeuchi, C. Lu, L. Bendersky, H. Chang
Jason R. Hattrick-Simpers
No abstract provided.
Raman Spectroscopic Observation Of Dehydration In Ball-Milled Linh2-Libh4-Mgh2 Nanoparticles, Jason Hattrick-Simpers, James Maslar, Michael Niemann, Chun Chiu, Sesha Srinivasan, Elias Stefanakos, Leonid Bendersky
Raman Spectroscopic Observation Of Dehydration In Ball-Milled Linh2-Libh4-Mgh2 Nanoparticles, Jason Hattrick-Simpers, James Maslar, Michael Niemann, Chun Chiu, Sesha Srinivasan, Elias Stefanakos, Leonid Bendersky
Jason R. Hattrick-Simpers
No abstract provided.
Phase Formation And Hydrogen Ordering In Yttrium-Hydrogen System, Ke Wang, Jason Hattrick-Simpers, Leonid Bendersky
Phase Formation And Hydrogen Ordering In Yttrium-Hydrogen System, Ke Wang, Jason Hattrick-Simpers, Leonid Bendersky
Jason R. Hattrick-Simpers
No abstract provided.
Combinatorial Study Of Ni-Ti-Pt Ternary Metal Gate Electrodes On Hfo2 For The Advanced Gate Stack, K.-S. Chang, M. Green, J. Suehle, E. Vogel, H. Xiong, Jason Hattrick-Simpers, I. Takeuchi, O. Famodu, K. Ohmori, P. Ahmet, T. Chikyow, P. Majhi, B.-H. Lee, M. Gardner
Combinatorial Study Of Ni-Ti-Pt Ternary Metal Gate Electrodes On Hfo2 For The Advanced Gate Stack, K.-S. Chang, M. Green, J. Suehle, E. Vogel, H. Xiong, Jason Hattrick-Simpers, I. Takeuchi, O. Famodu, K. Ohmori, P. Ahmet, T. Chikyow, P. Majhi, B.-H. Lee, M. Gardner
Jason R. Hattrick-Simpers
The authors have fabricated combinatorial Ni–Ti–Pt ternary metal gate thin film libraries on HfO2 using magnetron co-sputtering to investigate flatband voltage shift (ΔVfb) , work function (Φm) , and leakage current density (JL) variations. A more negative ΔVfb is observed close to the Ti-rich corner than at the Ni- and Pt-rich corners, implying smaller Φm near the Ti-rich corners and higher Φm near the Ni- and Pt-rich corners. In addition, measured JL values can be explained consistently with the observed Φm variations. Combinatorial methodologies prove to be useful in surveying the large compositional space of ternary alloymetal gate electrode systems.
Interphase Exchange Coupling In Fe/Sm-Co Bilayers With Gradient Fe Thickness, Ming-Hui Yu, Jason Hattrick-Simpers, Ichiro Takeuchi, Jing Li, Z. Wang, J. Liu, S. Lofland, Somdev Tyagi, J. Freeland, D. Giubertoni, M. Bersani, M. Anderle
Interphase Exchange Coupling In Fe/Sm-Co Bilayers With Gradient Fe Thickness, Ming-Hui Yu, Jason Hattrick-Simpers, Ichiro Takeuchi, Jing Li, Z. Wang, J. Liu, S. Lofland, Somdev Tyagi, J. Freeland, D. Giubertoni, M. Bersani, M. Anderle
Jason R. Hattrick-Simpers
We have fabricated Fe∕Sm–Co bilayers with gradient Fe thicknesses in order to systematically study the dependence of exchange coupling on the thickness of the Fe layer. The Fe layer was deposited at two different temperatures (150 and 300°C) to study the effect of deposition temperature on the exchange coupling. Magneto-optical Kerr effect and x-ray magnetic circular dichroism (XMCD) have been employed as nondestructive rapid characterization tools to map the magnetic properties of the gradient samples. Systematic enhancement in exchange coupling between the soft layer and the hard layer is observed as the soft layer thickness is decreased. Separate exchange couplings …
High-Throughput Characterization Of Shape Memory Thin Films Using Automated Temperature-Dependent Resistance Measurements, Sigurd Thienhaus, Christiane Zamponi, Holger Rumpf, Jason Hattrick-Simpers, Ichiro Takeuchi, Alfred Ludwig
High-Throughput Characterization Of Shape Memory Thin Films Using Automated Temperature-Dependent Resistance Measurements, Sigurd Thienhaus, Christiane Zamponi, Holger Rumpf, Jason Hattrick-Simpers, Ichiro Takeuchi, Alfred Ludwig
Jason R. Hattrick-Simpers
No abstract provided.
High-Throughput Screening Of Shape Memory Alloy Thin-Film Spreads Using Nanoindentation, Arpit Dwivedi, Thomas Wyrobek, Oden Warren, Jason Hattrick-Simpers, Olubenga Famodu, Ichiro Takeuchi
High-Throughput Screening Of Shape Memory Alloy Thin-Film Spreads Using Nanoindentation, Arpit Dwivedi, Thomas Wyrobek, Oden Warren, Jason Hattrick-Simpers, Olubenga Famodu, Ichiro Takeuchi
Jason R. Hattrick-Simpers
We have demonstrated the utility of nanoindentation as a rapid characterization tool for mapping shape memoryalloy compositions in combinatorial thin-film libraries. Nanoindentation was performed on Ni–Mn–Al ternary composition spreads. The indentation hardness and the reduced elastic modulus were mapped across a large fraction of the ternary phase diagram. The large shape memoryalloy composition region, located around the Heusler composition (Ni2MnAl), was found to display significant departure in these mechanical properties from the rest of the composition spread. In particular, the modulus and the hardness values are lower for the martensite region than those of the rest of the phase diagram.
A Semi-Empirical Model For Tilted-Gun Planar Magnetron Sputtering Accounting For Chimney Shadowing, Johnathan Bunn, C. Metting, Jason Hattrick-Simpers
A Semi-Empirical Model For Tilted-Gun Planar Magnetron Sputtering Accounting For Chimney Shadowing, Johnathan Bunn, C. Metting, Jason Hattrick-Simpers
Jason R. Hattrick-Simpers
No abstract provided.
Note: A Simple Thermal Gradient Annealing Unit For The Treatment Of Thin Films, C. Metting, Johnathan Bunn, Ellen Underwood, Yihao Zhu, G. Koley, T. Crawford, Jason Hattrick-Simpers
Note: A Simple Thermal Gradient Annealing Unit For The Treatment Of Thin Films, C. Metting, Johnathan Bunn, Ellen Underwood, Yihao Zhu, G. Koley, T. Crawford, Jason Hattrick-Simpers
Jason R. Hattrick-Simpers
A gradient annealing cell has been developed for the high-throughput study of thermalannealing effects on thin-film libraries in different environments. The inexpensive gradientannealing unit permits temperature gradients as large as 28 °C/mm and can accommodate samples ranging in length from 13 mm to 51 mm. The system was validated by investigating the effects of annealing temperature on the crystallinity, resistivity, and transparency of tin-doped indium oxide deposited on a glass substrate by magnetron sputtering. The unit developed in this work will permit the rapid optimization of materials properties such as crystallinity, homogeneity, and conductivity across a variety of applications.
Combinatorial Investigation Of Magnetostriction In Fe-Fa And Fe-Ga-Al, Jason R. Hattrick-Simpers, Dwight Hunter, Corneliu M. Craciunescu, Kyu Sung Jang, Makoto Murakami, James Cullen, Manfred Wuttig, Ichiro Takeuchi, Samuel E. Lofland, Leonid Bendersky, Noble Woo, Robert Bruce Vandover, Toshiya Takahashi, Yasubumi Furuya
Combinatorial Investigation Of Magnetostriction In Fe-Fa And Fe-Ga-Al, Jason R. Hattrick-Simpers, Dwight Hunter, Corneliu M. Craciunescu, Kyu Sung Jang, Makoto Murakami, James Cullen, Manfred Wuttig, Ichiro Takeuchi, Samuel E. Lofland, Leonid Bendersky, Noble Woo, Robert Bruce Vandover, Toshiya Takahashi, Yasubumi Furuya
Jason R. Hattrick-Simpers
A high-throughput high-sensitivity optical technique for measuringmagnetostriction of thin-film composition-spread samples has been developed. It determines the magnetostriction by measuring the induced deflection of micromachined cantilever unimorph samples. Magnetostrictionmeasurements have been performed on as-deposited Fe–Ga and Fe–Ga–Al thin-film composition spreads. The thin-film Fe–Ga spreads display a similar compositional variation of magnetostriction as bulk. A previously undiscovered peak in magnetostriction at low Ga content was also observed and attributed to a maximum in the magnetocrystalline anisotropy. Magnetostrictive mapping of the Fe–Ga–Al ternary system reveals the possibility of substituting up to 8at.%Al in Fe70Ga30 without significant degradation of magnetostriction.
Recent Developments In Thermoelectric Metrology At Nist, W. Wong-Ng, J. Martin, E. Thomas, M. Otani, N. Lowhorn, M. Green, G. Liu, Y. Yan, Jason Hattrick-Simpers, T. Tran
Recent Developments In Thermoelectric Metrology At Nist, W. Wong-Ng, J. Martin, E. Thomas, M. Otani, N. Lowhorn, M. Green, G. Liu, Y. Yan, Jason Hattrick-Simpers, T. Tran
Jason R. Hattrick-Simpers
No abstract provided.
Giant Magnetostriction In Annealed Co1-XFeX Thin-Films, Dwight Hunter, Will Osborn, Ke Wang, Nataliya Kazantseva, Jason R. Hattrick-Simpers, Richard Suchoski, Ryota Takahashi, Marcus L. Young, Apurva Mehta, Leonid A. Bendersky, Same E. Lofland, Manfred Wuttig, Ichiro Takeuchi
Giant Magnetostriction In Annealed Co1-XFeX Thin-Films, Dwight Hunter, Will Osborn, Ke Wang, Nataliya Kazantseva, Jason R. Hattrick-Simpers, Richard Suchoski, Ryota Takahashi, Marcus L. Young, Apurva Mehta, Leonid A. Bendersky, Same E. Lofland, Manfred Wuttig, Ichiro Takeuchi
Jason R. Hattrick-Simpers
Chemical and structural heterogeneity and the resulting interaction of coexisting phases can lead to extraordinary behaviours in oxides, as observed in piezoelectric materials at morphotropic phase boundaries and relaxor ferroelectrics. However, such phenomena are rare in metallic alloys. Here we show that, by tuning the presence of structural heterogeneity in textured Co1−xFex thin films, effective magnetostriction λeff as large as 260 p.p.m. can be achieved at low-saturation field of ~10 mT. Assuming λ100 is the dominant component, this number translates to an upper limit of magnetostriction ofλ100≈5λeff >1,000 p.p.m. Microstructural analyses …
Characterization Of Magnetic Degradation Mechanism In A High Neutron-Flux Environment, Adib Samin, Jie Qiu, Jason Hattrick-Simpers, Liyang Dai-Hattrick, Yuan Zheng, Lei Cao
Characterization Of Magnetic Degradation Mechanism In A High Neutron-Flux Environment, Adib Samin, Jie Qiu, Jason Hattrick-Simpers, Liyang Dai-Hattrick, Yuan Zheng, Lei Cao
Jason R. Hattrick-Simpers
No abstract provided.
Observation Of Phase Transitions In Hydrogenated Yttrium Films Via Normalized Infrared Emissivity, Jason Hattrick-Simpers, Ke Wang, Lei Cao, Chun Chiu, Edwin Heilweil, Robert Downing, Leonid Bendersky
Observation Of Phase Transitions In Hydrogenated Yttrium Films Via Normalized Infrared Emissivity, Jason Hattrick-Simpers, Ke Wang, Lei Cao, Chun Chiu, Edwin Heilweil, Robert Downing, Leonid Bendersky
Jason R. Hattrick-Simpers
No abstract provided.
Enhanced Dielectric Properties In Single Crystal-Like Bifeo3 Thin Films Grown By Flux-Mediated Epitaxy, S.-H. Lim, M. Murakami, J. Yang, S.-Y. Young, Jason Hattrick-Simpers, M. Wuttig, L. Salamanca-Riba, I. Takeuchi
Enhanced Dielectric Properties In Single Crystal-Like Bifeo3 Thin Films Grown By Flux-Mediated Epitaxy, S.-H. Lim, M. Murakami, J. Yang, S.-Y. Young, Jason Hattrick-Simpers, M. Wuttig, L. Salamanca-Riba, I. Takeuchi
Jason R. Hattrick-Simpers
We have fabricated single crystal-like BiFeO3 (BFO) thin films by flux-mediated epitaxy using pulsed laser deposition(PLD). The Bi–Cu–O flux composition and its thickness were optimized using composition spread, thickness gradient, and temperature gradient libraries. The optimized BFO thin films grown with this technique showed larger grain size of ∼2μm and higher dielectric constant in the range of 260–340 than those for standard PLD grown films. In addition, the leakage current density of the films was reduced by two orders of magnitude compared to that of standard PLD grown films.
Optical Cell For Combinatorial In Situ Raman Spectroscopic Measurements Of Hydrogen Storage Materials At High Pressures And Temperatures, Jason Hattrick-Simpers, Wilbur Hurst, Sesha Srinivasan, James Maslar
Optical Cell For Combinatorial In Situ Raman Spectroscopic Measurements Of Hydrogen Storage Materials At High Pressures And Temperatures, Jason Hattrick-Simpers, Wilbur Hurst, Sesha Srinivasan, James Maslar
Jason R. Hattrick-Simpers
An optical cell is described for high-throughput backscattering Raman spectroscopic measurements of hydrogen storagematerials at pressures up to 10 MPa and temperatures up to 823 K. High throughput is obtained by employing a 60 mm diameter × 9 mm thick sapphire window, with a corresponding 50 mm diameter unobstructed optical aperture. To reproducibly seal this relatively large window to the cell body at elevated temperatures and pressures, a gold o-ring is employed. The sample holder-to-window distance is adjustable, making this cell design compatible with optical measurement systems incorporating lenses of significantly different focal lengths, e.g., microscope objectives and single element …
Tunable Multiferroic Properties In Nanocomposite Pbtio3-Cofe2O4 Epitaxial Thin Films, M. Murakami, K.-S. Chang, M. Aronova, C.-L. Lin, Ming Yu, Jason Hattrick-Simpers, M. Wuttig, I. Takeuchi, C. Gao, B. Hu, S. Lofland, L. Knauss, L. Bendersky
Tunable Multiferroic Properties In Nanocomposite Pbtio3-Cofe2O4 Epitaxial Thin Films, M. Murakami, K.-S. Chang, M. Aronova, C.-L. Lin, Ming Yu, Jason Hattrick-Simpers, M. Wuttig, I. Takeuchi, C. Gao, B. Hu, S. Lofland, L. Knauss, L. Bendersky
Jason R. Hattrick-Simpers
We report on the synthesis of PbTiO3–CoFe2O4 multiferroic nanocomposites and continuous tuning of their ferroelectric and magnetic properties as a function of the average composition on thin-film composition spreads. The highest dielectric constant and nonlinear dielectric signal was observed at (PbTiO3)85–(CoFe2O4)15, where robust magnetism was also observed. Transmission electron microscopy revealed a pancake-shaped epitaxial nanostructure of PbTiO3 on the order of 30 nm embedded in the matrix of CoFe2O4 at this composition. Composition dependent ferroics properties observed here indicate that there is considerable interdiffusion of cations into each other.
Demonstration Of Magnetoelectric Scanning Probe Microscopy, Jason R. Hattrick-Simpers, Liyang Dai, Manfred Wuttig, Ichiro Takeuchi, Eckhard Quandt
Demonstration Of Magnetoelectric Scanning Probe Microscopy, Jason R. Hattrick-Simpers, Liyang Dai, Manfred Wuttig, Ichiro Takeuchi, Eckhard Quandt
Jason R. Hattrick-Simpers
A near-field room temperature scanning magnetic probe microscope has been developed using a laminated magnetoelectric sensor. The simple trilayer longitudinal-transverse mode sensor, fabricated using Metglas as the magnetostrictive layer and polyvinylidene fluoride as the piezoelectric layer, shows an ac field sensitivity of 467±3μV∕Oe in the measured frequency range of 200Hz–8kHz. The microscope was used to image a 2mm diameter ring carrying an ac current as low as 10−5A. ac fields as small as 3×10−10T have been detected.
Exploration Of Artificial Multiferroic Thin-Film Heterostructures Using Composition Spreads, K.-S. Chang, M. A. Aronova, C.-L. Lin, M. Murakami, M.-H. Yu, Jason R. Hattrick-Simpers, O. O. Famodu, S. Y. Lee, R. Ramesh, M. Wuttig, I. Takeuchi, C. Gao, L. A. Bendersky
Exploration Of Artificial Multiferroic Thin-Film Heterostructures Using Composition Spreads, K.-S. Chang, M. A. Aronova, C.-L. Lin, M. Murakami, M.-H. Yu, Jason R. Hattrick-Simpers, O. O. Famodu, S. Y. Lee, R. Ramesh, M. Wuttig, I. Takeuchi, C. Gao, L. A. Bendersky
Jason R. Hattrick-Simpers
We have fabricated a series of composition spreads consisting of ferroelectric BaTiO3 and piezomagnetic CoFe2O4 layers of varying thicknesses modulated at nanometer level in order to explore artificial magnetoelectricthin-film heterostructures. Scanning microwavemicroscopy and scanning superconducting quantum interference device microscopy were used to map the dielectric and magnetic properties as a function of continuously changing average composition across the spreads, respectively. Compositions in the middle of the spreads were found to exhibit ferromagnetism while displaying a dielectric constant as high as ≈120.
An Infrared Imaging Method For High-Throughput Combinatorial Investigation Of Hydrogenation-Dehydrogenation And New Phase Formation Of Thin Films, H. Oguchi, Jason Hattrick-Simpers, I. Takeuchi, E. Heilweil, L. Bendersky
An Infrared Imaging Method For High-Throughput Combinatorial Investigation Of Hydrogenation-Dehydrogenation And New Phase Formation Of Thin Films, H. Oguchi, Jason Hattrick-Simpers, I. Takeuchi, E. Heilweil, L. Bendersky
Jason R. Hattrick-Simpers
We have developed an infrared imaging setup enabling in situ infrared images to be acquired, and expanded on capabilities of an infrared imaging as a high-throughput screening technique, determination of a critical thickness of a Pd capping layer which significantly blocks infrared emission from below, enhancement of sensitivity to hydrogenation and dehydrogenation by normalizing raw infrared intensity of a Mg thin film to an inert reference, rapid and systematic screening of hydrogenation and dehydrogenation properties of a Mg–Ni composition spread covered by a thickness gradient Pd capping layer, and detection of formation of a Mg2Si phase in a Mg thin …
Multimode Quantitative Scanning Microwave Microscopy Of In Situ Grown Epitaxial Ba1-XSrXTio3 Composition Spreads, K. Chang, M. Aronova, O. Famodu, I. Takeuchi, S. Lofland, Jason Hattrick-Simpers, H. Chang
Multimode Quantitative Scanning Microwave Microscopy Of In Situ Grown Epitaxial Ba1-XSrXTio3 Composition Spreads, K. Chang, M. Aronova, O. Famodu, I. Takeuchi, S. Lofland, Jason Hattrick-Simpers, H. Chang
Jason R. Hattrick-Simpers
We have performed variable-temperature multimode quantitative microwavemicroscopy of in situepitaxial Ba1−xSrxTiO3 thin-film composition spreads fabricated on (100) LaA1O3 substrates. Dielectric properties were mapped as a function of continuously varying composition from BaTiO3 to SrTiO3. We have demonstrated nondestructive temperature-dependent dielectric characterization of local thin-film regions. Measurements are simultaneously taken at multiple resonant frequencies of the microscope cavity. The multimode measurements allow frequency dispersion studies. We observe strong composition-dependent dielectric relaxation in Ba1−xSrxTiO3 at microwave frequencies.
One-Step Production Of Long-Chain Hydrocarbons From Waste-Biomass-Derived Chemicals Using Bi-Functional Heterogeneous Catalysts, Cun Wen, Elizabeth Barrow, Jason Hattrick-Simpers, Jochen Lauterbach
One-Step Production Of Long-Chain Hydrocarbons From Waste-Biomass-Derived Chemicals Using Bi-Functional Heterogeneous Catalysts, Cun Wen, Elizabeth Barrow, Jason Hattrick-Simpers, Jochen Lauterbach
Jason R. Hattrick-Simpers
n this study, we demonstrate the production of long-chain hydrocarbons (C8+) from 2-methylfuran (2MF) and butanal in a single step reactive process by utilizing a bi-functional catalyst with both acid and metallic sites. Our approach utilizes a solid acid for the hydroalkylation function and as a support as well as a transition metal as hydrodeoxygenation catalyst. A series of solid acids was screened, among which MCM-41 demonstrated the best combination of activity and stability. Platinum nanoparticles were then incorporated into the MCM-41. The Pt/MCM-41 catalyst showed 96% yield for C8+ hydrocarbons and the catalytic performance was stable over four reaction …