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The Use Of Pure Cultures As A Means Of Understanding The Performance Of A Mixed Culture In The Biodegradation Of Phenol, Chirasakdi Varuntanya

Dissertations

In an effort to gain a more fundamental understanding of the performance of mixed microbial cultures in the biodegradation of toxic organic chemicals, studies have been conducted using three phenol degrading species isolated from a municipal treatment plant. The rate of phenol degradation was investigated for each of the three pure phenol degrading species, and various combinations of the three species. A simple competitive model was used to predict the behavior of the mixed cultures by using the pure culture Monod rate constants. The model fit the growth data for total biomass very well, although (as with the pure culture …

Fluid Flow And Gas Absorption In An Ejector Venturi Scrubber, Iclal Atay

Dissertations

Empirical models were developed to describe the fluid flow characteristics and gas absorption efficiency of an ejector venturi scrubber. The empirical constants were determined experimentally using stop action photographs of the spray, static pressure measurements, and sulfur dioxide absorption efficiencies.

To take photographs of the spray, a 2 foot high, clear plastic ejector venturi scrubber was used, with a 4 inch diameter gas entrance port. Photographic equipment included a Hasselblad camera, Xenon flash lamp, and Polaroid 667 ASA 3000 film. Exposure duration was about 1 microsecond, resulting in complete stop-action of the spray droplets at liquid rates up to 6 …

Reactions Of Chlorocarbon Species With Hydrogen Over Palladium On Alumina Catalyst And Zeolite Catalyst-Development Of Deactivation Models, Yuh-Der Yang

Dissertations

Four catalytic dechlorination reactions were studied experimentally using a fixed-bed reactor at atmosphere pressure. Reaction mechanisms were proposed, and the kinetics modelled.

The first reaction is 1,2-dichloroethane with hydrogen over zeolite catalyst. Catalyst deactivation models were examined.

The second reaction was between 1,2-dichloroethane and hydrogen over palladium catalyst on alumina support. Formation of two intermediates on the catalyst surface is proposed, which then produced ethane, ethylene, and ethyl chloride. Higher conversion to ethane and ethylene was observed at temperatures above 218°C while conversion to chloroethane is higher at temperatures below 218°C. The activation energy was found to be 15 Kcal/gm-mole. …