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Chemical Engineering

Louisiana State University

2011

CO2 pathways to fuels

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Electrochemical Reduction Of Co2 To Methanol, Minh Tuyen Hoang Le Jan 2011

Electrochemical Reduction Of Co2 To Methanol, Minh Tuyen Hoang Le

LSU Master's Theses

An efficient method to convert CO2 to fuels using renewable energy could displace crude oil without increasing CO2 emission and provide high-density energy storage reservoirs similar to liquid fuels or batteries. Although photoelectrochemical conversion of CO2 is possible, solar-to-fuel efficiencies are lower than the combination of conventional photovoltaics (up to 40% efficiency) and electrochemical cells (up to 80% Faradaic efficiency). In the electrochemical case, electrical energy from renewable sources may be converted to hydrocarbons or alcohols using electrocatalysts. The direct reduction of CO2 to CH3OH is known to occur at several types of electrocatalysts including oxidized Cu electrodes. In this …