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- <p>Soluble glass -- Analysis<br />Hydroxyl group<br />Glass -- Analysis<br />Thermal stresses<br />Gases -- Separation<br />Absorption</p> (1)
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Phase Equilibria And Thermodynamic Studies In The System Cao-Feo-Fe2o3-Sio2, M. Timucin, Arthur E. Morris
Phase Equilibria And Thermodynamic Studies In The System Cao-Feo-Fe2o3-Sio2, M. Timucin, Arthur E. Morris
Materials Science and Engineering Faculty Research & Creative Works
Phase equilibria and thermodynamic properties of the system CaO-FeO-Fe2O3-SiO2 were studied at 1450° and 1550°C, over a range of pO2 from 1 to about 10-11 atm. Isothermal phase diagrams and activity-composition diagrams were constructed for 0, 5, 10, 20, and 30 wt pct SiO2 sections. The data are applicable to further understanding the behavior of simple BOF steelmaking slags. © 1970 The Minerals, Metals & Materials Society - ASM International - The Materials Information Society.
Fracture Surface Energy Determinations Of High Density Polycrystalline Ceramics, Gene Arthur Pahlmann
Fracture Surface Energy Determinations Of High Density Polycrystalline Ceramics, Gene Arthur Pahlmann
Masters Theses
"Values of fracture surface energy were measured for steatite, zircon, mullite and four densities of alumina. Rods of these high density materials were cut into thin rectangular specimens which were notched and broken in three-point loading. The resulting load necessary for fracture of the specimens was used to calculate the fracture surface energy of the materials. The value for the steatite was around 20,000 ergs/cm². The values for the zircon and mullite were on the order of 13,000 ergs/cm², and the values for the aluminas ranged from 17,000 to 24,000 ergs/cm²"--Abstract, page ii.
Thermal Expansion Of Orthorhombic Pbo, Charles A. Sorrell
Thermal Expansion Of Orthorhombic Pbo, Charles A. Sorrell
Materials Science and Engineering Faculty Research & Creative Works
Thermal expansion of orthorhombic PbO was investigated by high‐temperature X‐ray diffraction. The coefficients in the a0, and c0 directions are equal and Pb–O chains extended in the a0 direction and bonded into layers in the b0 direction; appreciable Pb–Pb bonding is indicated. Coordination and bond distances observed in PbSiO3 and lead silicate glasses, which are similar to those of massicot, and PbnOn polymeric units reported in PbO vapor are interpreted as additional evidence of the importance of PbO chains as structural entities. Copyright © 1970, Wiley Blackwell. All rights reserved
Diffusion And Internal Friction In Sodium-Rubidium Silicate Glasses, Gary L. Mcvay
Diffusion And Internal Friction In Sodium-Rubidium Silicate Glasses, Gary L. Mcvay
Doctoral Dissertations
"The internal friction and self diffusion coefficients of sodium and rubidium ions for (1 - X) Na₂O·X Rb₂O·3 SiO₂ glasses have been measured. The diffusion measurements employed radioactive isotopes and a thin sectioning technique and extended from 350 to 500°C. Internal friction measurements were made from -150 to 500°C and at frequencies of 0.05 to 6000 Hz. The maximum height for the mixed alkali internal friction peak occurs at the composition where the sodium and rubidium diffusion coefficients are equal. It is concluded that the mechanism responsible for the mixed alkali peak is a cooperative rearrangement of sodium-rubidium ions and …
Some Effects Of Oh Groups On Sodium Silicate Glasses, Mokhtar Sayed Maklad
Some Effects Of Oh Groups On Sodium Silicate Glasses, Mokhtar Sayed Maklad
Doctoral Dissertations
"Glasses of various compositions in the Na₂O-SiO₂ system were prepared with different levels of OH concentration. Phase separation kinetics, thermal expansion, radiation induced optical absorption, and internal friction of these glasses were studied. The increase in OH content in these glasses was found to (a) enhance the rate of phase separation; (b) increase thermal expansion above the glass temperature and change the dilatometric softening temperature in a way that depends on microstructure; (c) increase the radiation induced optical absorption bands associated with positive hole centers and decrease those associated with electron trap centers; and, (d) decrease the low temperature alkali …
Temperature Variation In Distribution Of Relaxation Times In Aluminosilicate Glasses, David Wayne Moore
Temperature Variation In Distribution Of Relaxation Times In Aluminosilicate Glasses, David Wayne Moore
Doctoral Dissertations
"The distribution of relaxation times for the alkali peak in a Li₂ O·A1₂O₃ ·2.0SiO₂ glass and for the mixed alkali peak in a 0.5Li₂O·0.5Na₂O·A1₂O₃·2.OSiO₂ glass was studied using the internal friction technique. A lognormal distribution of relaxation times provided the best agreement with the experimental data. The ß parameter of the lognormal distribution function, which is related to the half-height peak width, varied with temperature, indicating that the distribution of relaxation times is dependent upon the activation energy and the activation entropy of the relaxation mechanism. The major contributor to the distribution of relaxation times is a wide distribution in …
Thermal Expansion Of Tetragonal Pbo, Charles A. Sorrell
Thermal Expansion Of Tetragonal Pbo, Charles A. Sorrell
Materials Science and Engineering Faculty Research & Creative Works
Thermal expansion of tetragonal PbO, investigated by high‐temperature X‐ray diffraction in vacuum, is nearly isotropic, with the coefficient in the c0 direction only slightly greater than that in the a0 direction. Volume thermal expansion is only slightly greater than in massicot. Retardation of the litharge‐massicot transformation is tentatively interpreted as the result of very low oxygen partial pressures caused by catastrophic oxidation of the stainless‐steel sample holder and resulting oxygen scavenging by lead vapor. Copyright © 1970, Wiley Blackwell. All rights reserved
Carburization Of Type 316l Stainless Steel In Static Sodium, F. B. Litton, Arthur E. Morris
Carburization Of Type 316l Stainless Steel In Static Sodium, F. B. Litton, Arthur E. Morris
Materials Science and Engineering Faculty Research & Creative Works
The transport of carbon from an iron-87 wt.% carbon alloy through static sodium to Type 316L stainless steel was investigated at temperatures of interest to the liquid-metal fast-breeder reactor (LMFBR) program. The rate-controlling step for the experimental geometry employed was the diffusion of carbon in the source. © 1970.
Investigation Of The System Al₂O₃-Teo₂-O₂, Vera Zelenkova Sestak
Investigation Of The System Al₂O₃-Teo₂-O₂, Vera Zelenkova Sestak
Masters Theses
"The system Al₂O₃-TeO₂-O₂ has been investigated by X-ray diffraction and differential thermal analysis in air and in sealed silica ampoules. The tellurate, Al₂TeO₆, with tellurium in the +6 valence state, forms in air but not in vacuum at 1 mm pressure. A second phase, a tellurite, possibly Al₂Te₂O₇, forms in air or vacuum by devitrification. The glass-forming region is wider than previously stated and is more extensive in vacuum--from 50% to 98% TeO₂. Tentative phase boundaries have been placed for the system in air and vacuum"--Abstract, page ii.