Physics Commons^™

Hydrolysis Of P-Nitrophenyl Esters Promoted By Semi-Fluorinated Quaternary Ammonium Polymer Latexes And Films, Baljinder Kaur, Sean P. Mcbride, Warren T. Ford

Physics Faculty Research

Semifluorinated polymer latexes were prepared by emulsion polymerization of 2.5-25% of a fluoroalkyl methacrylate, 25% chloromethylstyrene, 1% styrylmethyl(trimethyl)ammonium chloride, and the remainder 2-ethylhexyl methacrylate under surfactant-free conditions. The chloromethylstyrene units were converted to quaternary ammonium ions with trimethylamine. In aqueous dispersions at particle concentrations of less than 1 mg mL^-1 the quaternary ammonium ion latexes promoted hydrolyses of p-nitrophenyl hexanoate (PNPH) in pH 9.4 borate buffer and of diethyl p-nitrophenyl phosphate (Paraoxon) in 0.1 M NaOH at 30 ^oC with half-lives of less than 10 minutes. Thin 0.7-2 μm films of the latexes on glass promoted fast …

Fast Response Dual Frequency Liquid Crystal Materials, Qiong Song

Electronic Theses and Dissertations

Dual frequency liquid crystal (DFLC) exhibits a positive dielectric anisotropy at low frequencies and negative dielectric anisotropy at high frequencies. The frequency where dielectric anisotropy is zero is called crossover frequency. DFLC can achieve fast rise time and fast decay time with the assistance of applied voltage. However, one drawback of DFLC is that it has dielectric heating effect when driven at a high frequency. Thus, the first part of this dissertation is to develop low crossover frequency DFLC materials. The dielectric relaxation and physical properties of some single- and double-ester compounds were investigated. Experimental results indicate that the double-ester …

Closed Time-Like Curves And Inertial Frame Dragging: How To Time Travel Via Spacetime Rotation, Conrad Wilson Moore

Honors Theses

As the number of solutions to the Einstein equations with realistic matter sources that admit closed time-like curves (CTC's) has grown drastically, it has provoked some authors [10] to call for a physical interpretation of these seemingly exotic curves that could possibly allow for causality violations. A first step in drafting a physical interpretation would be to understand how CTC's are created because the recent work of [16] has suggested that, to follow a CTC, observers must counter-rotate with the rotating matter, contrary to the currently accepted explanation that it is due to inertial frame dragging that CTC's are created. …

Vibrational Spectroscopic Monitoring Of Co2-O Energy Transfer: Cooling Processes In Atmospheres Of Venus & Mars, Jakob Aaron Schaeffer

Honors Theses

The vibrational excitation of CO2 by a fast-moving O atom followed by infrared emission from the vibrationally excited CO2 has been shown to be an important cooling mechanism in the upper atmospheresof Venus, Earth and Mars. We are trying to determine more precisely the efficiency (rate coefficient) of the CO2-O vibrational energy transfer. For experimental ease the reverse reaction is used, i.e. collision of a vibrationally excited CO2 with atomic O, where we are able to convert to the atmospherically relevant reaction via a known equilibrium constant. The goal of this experiment was to measure the magnitudes of rate coefficients …

Classical Phases And Quantum Angles In The Description Of Interfering Bose-Einstein Condensates, Wj Mullin, F Laloe

Physics Department Faculty Publication Series

The interference of two Bose-Einstein condensates, initially in Fock states, can be described in terms of their relative phase, treated as a random unknown variable. This phase can be understood either as emerging from the measurements or pre-existing to them; in the latter case, the originating states could be phase states with unknown phases, so an average over all their possible values is taken. Both points of view lead to a description of probabilities of results of experiments in terms of a phase angle, which plays the role of a classical variable. Nevertheless, in some situations, this description is not …

Type-1.5 Superconductivity In Multiband Systems: The Eects Of Interband Couplings, Johan Carlstrom, Egor Babaev, Martin Speight

Physics Department Faculty Publication Series

In contrast to single-component superconductors, which are described at the level of Ginzburg- Landau theory by a single parameter and are divided in type-I < 1= p 2 and type-II > 1= p 2 classes, two-component systems in general possesses three fundamental length scales and have been shown to possess a separate \type-1.5" superconducting state1,2. In that state, as a consequence of the extra fundamental length scale, vortices attract one another at long range but repel at shorter ranges, and therefore should form clusters in low magnetic elds. In such clusters one can dene a negative interface energy inside a cluster and at the same there one …

The Beliaev Technique For A Weakly Interacting Bose Gas, B Capogrosso-Sansone, S Giorgini, S Pilati, L. Pollet, N Prokof'ev, B Svistunov, M Troyer

Physics Department Faculty Publication Series

Aiming at simplicity of explicit equations and, at the same time, controllable accuracy of the theory, we present our results for all the thermodynamic quantities and correlation functions for a weakly interacting Bose gas at short-to-intermediate distances obtained within an improved version of Beliaev's diagrammatic technique. With a controllably small (but essentially finite) Bogoliubov's symmetry-breaking term, Beliaev's diagrammatic technique becomes regular in the infrared limit. Up to higher-order terms (for which we present parametric order-of-magnitude estimates), the partition function and entropy of the system formally correspond to those of a non-interacting bosonic (pseudo-)Hamiltonian with a temperature-dependent Bogoliubov-type dispersion relation. Away …

Spectroscopic Analysis Of Tungsten Oxide Thin Films For Sensor Applications, Jose Luis Enriquez Carrejo

Open Access Theses & Dissertations

The objective of this study is targeted toward improving the quality of pure tungsten oxide (WO3) for application to the detection of poisoning gases, especially of H2S. While pure WO3 is a recognized candidate for gas sensing, its characteristics are strongly dependent on the conditions and methods used in its deposition.

Samples of WO3 thin films analyzed in this work were grown on silicon and sapphire substrates using RF magnetron sputtering at a number of different substrate temperatures and Ar:O2 pressure ratios. The properties of the samples were investigated spectroscopically with the goal of determining how variations in the above …

Search For Gravitational-Wave Inspiral Signals Associated With Short Gamma-Ray Bursts During Ligo's Fifth And Virgo's First Science Run, J. Abadie, B. P. Abbott, R. Abbott, T. Accadia, F. Acernese, R. Adhikari, P. Ajith, B. Allen, G. Allen, Shaon Ghosh

Department of Physics and Astronomy Faculty Scholarship and Creative Works

Progenitor scenarios for short gamma-ray bursts (short GRBs) include coalescenses of two neutron stars or a neutron star and black hole, which would necessarily be accompanied by the emission of strong gravitational waves. We present a search for these known gravitational-wave signatures in temporal and directional coincidence with 22 GRBs that had sufficient gravitational-wave data available in multiple instruments during LIGO's fifth science run, S5, and Virgo's first science run, VSR1. We find no statistically significant gravitational-wave candidates within a [ - 5, + 1)s window around the trigger time of any GRB. Using the Wilcoxon-Mann-Whitney U-test, we find no …

Search For Gravitational-Wave Bursts Associated With Gamma-Ray Bursts Using Data From Ligo Science Run 5 And Virgo Science Run 1, B. P. Abbott, R. Abbott, F. Acernese, R. Adhikari, P. Ajith, B. Allen, G. Allen, M. Alshourbagy, R. S. Amin, S. B. Anderson, Rodica Martin

Department of Physics and Astronomy Faculty Scholarship and Creative Works

We present the results of a search for gravitational-wave bursts (GWBs) associated with 137 gamma-ray bursts (GRBs) that were detected by satellite-based gamma-ray experiments during the fifth LIGO science run and first Virgo science run. The data used in this analysis were collected from 2005 November 4 to 2007 October 1, and most of the GRB triggers were from the Swift satellite. The search uses a coherent network analysis method that takes into account the different locations and orientations of the interferometers at the three LIGO-Virgo sites. We find no evidence for GWB signals associated with this sample of GRBs. …

Searches For Gravitational Waves From Known Pulsars With Science Run 5 Ligo Data, B. P. Abbott, R. Abbott, F. Acernese, R. Adhikari, P. Ajith, B. Allen, G. Allen, M. Alshourbagy, R. S. Amin, Rodica Martin

Department of Physics and Astronomy Faculty Scholarship and Creative Works

We present a search for gravitational waves from 116 known millisecond and young pulsars using data from the fifth science run of the LIGO detectors. For this search, ephemerides overlapping the run period were obtained for all pulsars using radio and X-ray observations. We demonstrate an updated search method that allows for small uncertainties in the pulsar phase parameters to be included in the search. We report no signal detection from any of the targets and therefore interpret our results as upper limits on the gravitational wave signal strength. The most interesting limits are those for young pulsars. We present …

Super-Resolution Using Adaptive Wiener Filters, Russell C. Hardie

Electrical and Computer Engineering Faculty Publications

The spatial sampling rate of an imaging system is determined by the spacing of the detectors in the focal plane array (FPA). The spatial frequencies present in the image on the focal plane are band-limited by the optics. This is due to diffraction through a finite aperture. To guarantee that there will be no aliasing during image acquisiton, the Nyquist criterion dictates that the sampling rate must be greater than twice the cut-off frequency of the optics. However, optical designs involve a number of trade-offs and typical imaging systems are designed with some level of aliasing. We will refer to …

Harvesting Single Ferroelectric Domain Stressed Nanoparticles For Optical And Ferroic Applications, Gary Cook, J. L. Barnes, S. A. Basun, Dean R. Evans, Ron F. Ziolo, Arturo Ponce, Victor Yu. Reshetnyak, Anatoliy Glushchenko, Partha P. Banerjee

Electrical and Computer Engineering Faculty Publications

We describe techniques to selectively harvest single ferroelectric domain nanoparticles of BaTiO3 as small as 9 nm from a plethora of nanoparticles produced by mechanical grinding. High resolution transmission electron microscopy imaging shows the unidomain atomic structure of the nanoparticles and reveals compressive and tensile surface strains which are attributed to the preservation of ferroelectric behavior in these particles.

We demonstrate the positive benefits of using harvested nanoparticles in disparate liquid crystal systems.

Phase Transitions In A Three Dimensional U(1)×U(1) Lattice London Superconductor: Metallic Superfluid And Charge-4e Superconducting States, Egil V. Herland, Egor Babaev, Asle Sudbø

Physics Department Faculty Publication Series

We consider a three dimensional lattice U(1)×U(1) and [U(1)]N superconductors in the London limit with individually conserved condensates. The U(1)×U(1) problem, generically, has two types of intercomponent interactions of different characters. First, the condensates are interacting via a minimal coupling to the same fluctuating gauge field. A second type of coupling is the direct dissipationless drag represented by a local intercomponent current-current coupling term in the free-energy functional. In this work, we present a study of the phase diagram of a U(1)×U(1) superconductor which includes both of these interactions. We study phase transitions and two types of competing paired phases …

A Simple Radionuclide-Driven Single-Ion Source, M Montero Diez, K Twelker, W Fairbank Jr, G Gratta, P Barbeau, K Barry, R Devoe, M Dolinski, M Green, F Leport, A Muller, R Neilson, K O'Sullivan, N Ackerman, B Aharmin, M Auger, C Benitez-Medina, M Breidenbach, A Burenkov, S Cook, T Daniels, K Donato, J Farine, G Giroux, R Gornea, K Graham, C Hagemann, C Hall, K Hall, D Hallman, C Hargrove, S Herrin, A Karelin, L. Kaufman, A Kuchenkov, K Kumar, J Lacey, D Leonard, D Mackay, R Maclellan, B Mong, E Niner, A Odian, A Piepke, A Pocar, C Prescott, K Pushkin, E Rollin, P Rowson, D Sinclair, S Slutsky, V Stekhanov, J Vuilleumier, U Wichoski, J Wodin, L Yang, Y Yen

Physics Department Faculty Publication Series

We describe a source capable of producing single barium ions through nuclear recoils in radioactive decay. The source is fabricated by electroplating 148Gd onto a silicon α-particle detector and vapor depositing a layer of BaF2 over it. 144Sm recoils from the alpha decay of 148Gd are used to dislodge Ba+ ions from the BaF2 layer and emit them in the surrounding environment. The simultaneous detection of an α particle in the substrate detector allows for tagging of the nuclear decay and of the Ba+ emission. The source is simple, durable, and can be manipulated and used in different environments. We …

Gauge Non-Invariance As Tests Of Emergent Gauge Symmetry, John Donoghue, Mohamed M. Anber, Ufuk Aydemir

Physics Department Faculty Publication Series

We motivate the concept of emergent gauge symmetry and discuss ways that this concept can be tested. The key idea is that if a symmetry is emergent, one should look for small violations of this symmetry because the underlying fundamental theory does not contain the symmetry. We describe our recent work implementing this idea in the gravity sector. We also describe the reasons why violations of gauge symmetry may well be linked to violations of Lorentz invariance.

Topological Multicritical Point In The Phase Diagram Of The Toric Code Model And Three-Dimensional Lattice Gauge Higgs Model, I Tupitsyn, A Kitaev, Nikolai Prokof'ev, P.C.E Stamp

Physics Department Faculty Publication Series

We construct a mapping between the two-dimensional toric code model in external magnetic fields, hz and hx, and the three-dimensional classical Ising system with plaquette interactions, which is equivalent to the three-dimensional Z2 gauge Higgs model with anisotropy between the imaginary time and spatial directions. The isotropic limit of the latter model was studied using Monte Carlo simulations on large (up to 603) lattices in order to determine the stability of the topological phase against generic magnetic field perturbations and to resolve fine details of the phase diagram. We find that the topological phase is bounded by second-order transition lines, …

The 17/5 Spectrum Of The Kelvin-Wave Cascade, E Kozik, Boris Svistunov

Physics Department Faculty Publication Series

Direct numeric simulation of the Biot-Savart equation readily resolves the 17/5 spectrum of the Kelvin-wave cascade from the 11/3 spectrum of the non-local (in the wavenumber space) cascade scenario by L’vov and Nazarenko. This result is a clear-cut visualisation of the unphysical nature of the 11/3 solution, which was established earlier on the grounds of symmetry.

Field-Induced Quantum Phase Transitions In The Spin-1/2 Triangular-Lattice Antiferromagnet Cs2cubr4, Nathanael Alexander Fortune, Scott T. Hannahs, Y. Takano, Y. Yoshida, T. Sherline, A. A. Wilson-Muenchow, T. Ono, H. Tanaka

Physics: Faculty Publications

In classical magnetic spin systems, geometric frustration leads to a large number of states of identical energy. We report here evidence from magnetocaloric and related measurements that in Cs2CuBr4 — a geometrically frustrated Heisenberg S= 1/2 triangular antiferromagnet — quantum fluctuations stabilize a series of gapped collinear spin states bounded by first-order transitions at simple increasing fractions of the saturation magnetization for fields directed along the c axis. Only the first of these quantum phase transitions has been theoretically predicted, suggesting that quantum effects continue to dominate at fields much higher than previously considered.

Structural, Electronic, Vibrational And Thermodynamical Properties Of Surfaces And Nanoparticles, Handan Yildirim

Electronic Theses and Dissertations

The main focus of the thesis is to have better understanding of the atomic and electronic structures, vibrational dynamics and thermodynamics of metallic surfaces and bi-metallic nanoparticles (NPs) via a multi-scale simulational approach. The research presented here involves the study of the physical and chemical properties of metallic surfaces and NPs that are useful to determine their functionality in building novel materials. The study follows the 'bottom-up' approach for which the knowledge gathered at the scale of atoms and NPs serves as a base to build, at the macroscopic scale, materials with desired physical and chemical properties. We use a …