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Colloidal Plasmonic Titanium Nitride Nanoparticles: Properties And Applications, Urcan Guler, Sergey Suslov, Alexander V. Kildishev, Alexandra Boltasseva, Vladimir M. Shalaev 2014 Birck Nanotechnology Center, School of ECE

Colloidal Plasmonic Titanium Nitride Nanoparticles: Properties And Applications, Urcan Guler, Sergey Suslov, Alexander V. Kildishev, Alexandra Boltasseva, Vladimir M. Shalaev

U. Guler

Optical properties of colloidal plasmonic titanium nitride nanoparticles are examined with an eye on their photothermal and photocatalytic applications via transmission electron microscopy and optical transmittance measurements. Single crystal titanium nitride cubic nanoparticles with an average size of 50 nm, which was found to be the optimum size for cellular uptake with gold nanoparticles [1], exhibit plasmon resonance in the biological transparency window and demonstrate a high absorption efficiency. A self-passivating native oxide at the surface of the nanoparticles provides an additional degree of freedom for surface functionalization. The titanium oxide shell surrounding the plasmonic core can create new opportunities …


Ferroelectric Polarization Dependent Interface Effects, Xiaohui Liu 2014 University of Nebraska-Lincoln

Ferroelectric Polarization Dependent Interface Effects, Xiaohui Liu

Department of Physics and Astronomy: Dissertations, Theses, and Student Research

Utilization of the switchable spontaneous polarization of nanometer scale ferroelectric materials offers a promising avenue for future nanoelectronic devices. In this dissertation, we use density-functional calculations and phenomenological modeling to explore the effects of interface termination on thin-film heterostructures, the effects of electron doping in bulk ferroelectric materials on ferroelectric stability, and the effects of ferroelectric polarization switching on the electronic and transport properties of interfaces.

For SrRuO3/BaTiO3/SrRuO3 epitaxial heterostructures grown on SrTiO3, we find that the built-in dipole at the BaO/RuO2 terminated interface leads to a strong preference for one polarization. …


C-Metrics In Gauged Stu Supergravity And Beyond, H. Lu, Justin F. Vázquez-Poritz 2014 Beijing Normal University

C-Metrics In Gauged Stu Supergravity And Beyond, H. Lu, Justin F. Vázquez-Poritz

Publications and Research

We construct charged generalizations of the dilaton C-metric in various fourdimensional theories, including STU gauged supergravity as well as a one-parameter family of Einstein-Maxwell-dilaton theories whose scalar potential can be expressed in terms of a superpotential. In addition, we present time-dependent generalizations of the dilaton C-metric and dilaton Ernst solutions, for which the time evolution is driven by the dilaton. These C-metric solutions provide holographic descriptions of a strongly-coupled three-dimensional field theory on the background of a black hole, a gravitational soliton, and a black hole undergoing time evolution.


Vibrational And Structural Signatures Of The Crossover Between Dense Glassy And Sparse Gel-Like Attractive Colloidal Packings, Matthew A. Lohr, Tim Still, Raman Ganti, Matthew D. Gratale, Zoey S. Davidson, Kevin B. Aptowicz, Carl P. Goodrich, Daniel M. Sussman, A. G. Yodh 2014 University of Pennsylvania

Vibrational And Structural Signatures Of The Crossover Between Dense Glassy And Sparse Gel-Like Attractive Colloidal Packings, Matthew A. Lohr, Tim Still, Raman Ganti, Matthew D. Gratale, Zoey S. Davidson, Kevin B. Aptowicz, Carl P. Goodrich, Daniel M. Sussman, A. G. Yodh

Physics & Engineering Faculty Publications

We investigate the vibrational modes of quasi-two-dimensional disordered colloidal packings of hard colloidal spheres with short-range attractions as a function of packing fraction. Certain properties of the vibrational density of states (vDOS) are shown to correlate with the density and structure of the samples (i.e., in sparsely versus densely packed samples). Specifically, a crossover from dense glassy to sparse gel-like states is suggested by an excess of phonon modes at low frequency and by a variation in the slope of the vDOS with frequency at low frequency. This change in phonon mode distribution is demonstrated to arise largely from localized …


Organic Solar Cells: Electrodes, Performance Enhancement And Degradation Mechanisms, Reginald J. Bauld 2014 The University of Western Ontario

Organic Solar Cells: Electrodes, Performance Enhancement And Degradation Mechanisms, Reginald J. Bauld

Electronic Thesis and Dissertation Repository

In this thesis I focus on a number of aspects associated with the fabrication and characterization of organic photovoltaics. Specifically, my work focuses on evaluating solution processed graphene electrodes for use in organic photovoltaics, improving the performance of indium tin oxide transparent contacts by coating them with Au nanoparticles, and understanding the degradation pathways of Poly(3-hexylthiophene-2,5-diyl): Phenyl-C61-butyric acid methyl ester (P3HT:PCBM) organic solar cells. In my work on graphene electrodes for organic solar cells I worked out a relationship between the sheet resistance and the film transmittance that is useful to optimize such electrodes. Investigation of organic solar cell degradation …


Neutron Scattering Studies Of Phosphate Proton Conductors, Amal Bajes Al-Wahish 2014 University of Tennessee - Knoxville

Neutron Scattering Studies Of Phosphate Proton Conductors, Amal Bajes Al-Wahish

Doctoral Dissertations

Proton ceramic fuel cells operating in the intermediate temperature range of 300-500 °C offer potentially revolutionary advantages over existing fuel cells because expensive noble metal catalysts would not be needed, and in situ reforming of liquid bio-fuels such as ethanol or methanol would be possible.The chief obstacle facing intermediate fuel cells is the lack of a suitable electrolyte in the operating temperature range. A good electrolyte is thermally and chemically stable, inexpensive, environmentally friendly, and has a proton conductivity on the order of 10-2 S cm-1 [Siemens per centimeter] at 400 °C. Acceptor-doped lanthanum orthophosphate is an …


Ferroelectric Tunnel Junctions With Graphene Electrodes, Haidong Lu, Alexey Lipatov, Sangjin Ryu, D. J. Kim, H. Lee, M. Ye. Zhuravlev, Chang-Beom Eom, Evgeny Y. Tsymbal, Alexander Sinitskii, Alexei Gruverman 2014 University of Nebraska-Lincoln

Ferroelectric Tunnel Junctions With Graphene Electrodes, Haidong Lu, Alexey Lipatov, Sangjin Ryu, D. J. Kim, H. Lee, M. Ye. Zhuravlev, Chang-Beom Eom, Evgeny Y. Tsymbal, Alexander Sinitskii, Alexei Gruverman

Evgeny Tsymbal Publications

Polarization-driven resistive switching in ferroelectric tunnel junctions (FTJs)—structures composed of two electrodes separated by an ultrathin ferroelectric barrier—offers new physics and materials functionalities, as well as exciting opportunities for the next generation of non-volatile memories and logic devices. Performance of FTJs is highly sensitive to the electrical boundary conditions, which can be controlled by electrode material and/or interface engineering. Here, we demonstrate the use of graphene as electrodes in FTJs that allows control of interface properties for significant enhancement of device performance. Ferroelectric polarization stability and resistive switching are strongly affected by a molecular layer at the graphene/BaTiO3 interface. …


Electrostatic Breakdown Analysis, Sam Hansen 2014 Utah State University

Electrostatic Breakdown Analysis, Sam Hansen

Senior Theses and Projects

Materials potentially suitable for spacecraft construction were exposed to electrostatic discharge in the USU Materials Physics Group lab, with hopes of identifying samples that possess greater resistance to breakdown. Breakdown shape and size may be important to determining material suitability for spacecraft construction [1]. The discharge damage sites of tested samples were examined, measured and logged into a matrix file for data analysis. Once logged, data was sorted within the matrix and compared graphically to identify trends.


Electrostatic Breakdown Analysis, Sam Hansen, JR Dennison, Allen Andersen 2014 Utah State University

Electrostatic Breakdown Analysis, Sam Hansen, Jr Dennison, Allen Andersen

Senior Theses and Projects

Materials potentially suitable for spacecraft construction were exposed to electrostatic discharge in the USU Materials Physics Group lab, with hopes of identifying samples that possess greater resistance to breakdown. Breakdown shape and size may be important to determining material suitability for spacecraft construction [1]. The discharge damage sites of tested samples were examined, measured and logged into a matrix file for data analysis. Once logged, data was sorted within the matrix and compared graphically to identify trends.


Studies On The Wrinkling Of Thin Polymer Films Floating On Liquid, Kamil B. Toga 2014 University of Massachusetts Amherst

Studies On The Wrinkling Of Thin Polymer Films Floating On Liquid, Kamil B. Toga

Doctoral Dissertations

This dissertation aims to broaden our understanding on wrinkling instabilities occurring on floating polymeric sheets, and tries to establish innovative methods that exploit these patterns in studies on material behavior and interfacial phenomena. We will address three major topics in this thesis including, i) characterization of the conditions required to buckle an annular disc, ii) characterization of wrinkles occurring around a droplet/bubble placed on a membrane that is kept taut at the liquid-air interface, and iii) using wrinkling patterns as a probe to understand the interfacial behavior and dynamics of ultrathin films. The first project in this thesis is about …


Nonlinear Optimal Filter Technique For Analyzing Energy Depositions In Tes Sensors Driven Into Saturation, Benjamin Shank, Jeffrey Yen, Blas Cabrera, John Mark Kreikebaum, Robert Moffatt, Peter Redl, Betty Young, Paul Brink, Matthew Cherry, Astrid Tomada 2014 Hope College

Nonlinear Optimal Filter Technique For Analyzing Energy Depositions In Tes Sensors Driven Into Saturation, Benjamin Shank, Jeffrey Yen, Blas Cabrera, John Mark Kreikebaum, Robert Moffatt, Peter Redl, Betty Young, Paul Brink, Matthew Cherry, Astrid Tomada

Faculty Publications

We present a detailed thermal and electrical model of superconducting transition edge sensors(TESs) connected to quasiparticle (qp) traps, such as the W TESs connected to Al qp traps used for CDMS (Cryogenic Dark Matter Search) Ge and Si detectors. We show that this improvedmodel, together with a straightforward time-domain optimal filter, can be used to analyze pulses well into the nonlinear saturation region and reconstruct absorbed energies with optimal energyresolution.


Control Of Majorana Edge Modes By A G-Factor Engineered Nanowire Spin Transistor, Amrit De, Alexey Kovalev 2014 University of California, Riverside

Control Of Majorana Edge Modes By A G-Factor Engineered Nanowire Spin Transistor, Amrit De, Alexey Kovalev

Department of Physics and Astronomy: Faculty Publications

We propose the manipulation of Majorana edge states via hybridization and spin currents in a nanowire spin transistor. The spin transistor is based on a heterostructure nanowire comprising of semiconductors with large and small g-factors that form the topological and non-topological regions respectively. The hybridization of bound edge states results in spin currents and 4π-periodic torques, as a function of the relative magnetic field angle – an effect which is dual to the fractional Josephson effect. We establish relation between torques and spin-currents in the non-topological region where the magnetic field is almost zero and spin is …


Fate Of The Bose Insulator In The Limit Of Strong Localization And Low Cooper-Pair Density In Ultrathin Films, Shawna M. Hollen, G. E. Fernandes, J. M. Xu, J M. Valles Jr. 2014 University of New Hampshire - Main Campus

Fate Of The Bose Insulator In The Limit Of Strong Localization And Low Cooper-Pair Density In Ultrathin Films, Shawna M. Hollen, G. E. Fernandes, J. M. Xu, J M. Valles Jr.

Physics & Astronomy

A Bose insulator composed of a low density of strongly localized Cooper pairs develops at the two-dimensional superconductor to insulator transition (SIT) in a number of thin film systems. Investigations of ultrathin amorphous PbBi films far from the SIT described here provide evidence that the Bose insulator gives way to a second insulating phase with decreasing film thickness. At a critical film thickness dc the magnetoresistance changes sign from positive, as expected for boson transport, to negative, as expected for fermion transport, signs of local Cooper-pair phase coherence effects on transport vanish, and the transport activation energy exhibits a kink. …


Pre-Breakdown Arcing And Electrostatic Discharge In Dielectrics Under High Dc Electric Field Stress, Allen Andersen, JR Dennison 2014 Utah State University

Pre-Breakdown Arcing And Electrostatic Discharge In Dielectrics Under High Dc Electric Field Stress, Allen Andersen, Jr Dennison

Journal Articles

Highly disordered insulating materials exposed to high electric fields will, over time, degrade and fail, potentially causing catastrophic damage to devices. Step-up to electrostatic discharge (ESD) tests were performed for two common polymer dielectrics, low density polyethylene and polyimide. Pre-breakdown transient current spikes or arcs were observed, using both slow and high speed detection. These pre-ESD discharge phenomena are explained in terms of breakdown modes and defect generation on a microscopic scale. The field at which pre-breakdown arcing begins was compared to the onset field for electrostatic discharge at which complete breakdown occurs for each material studied. We present evidence …


Pre-Breakdown Arcing And Electrostatic Discharge In Dielectrics Under High Dc Electric Field Stress, Allen Andersen, JR Dennison 2014 Utah State University

Pre-Breakdown Arcing And Electrostatic Discharge In Dielectrics Under High Dc Electric Field Stress, Allen Andersen, Jr Dennison

Conference Proceedings

Highly disordered insulating materials exposed to high electric fields will, over time, degrade and fail, potentially causing catastrophic damage to devices. Step-up electrostatic discharge (ESD) tests were performed for two common polymer dielectrics, low density polyethylene and polyimide. Prebreakdown transient current spikes or pre-arcs were observed, using both slow and high speed detection. These pre-ESD discharge phenomena are explained in terms of breakdown modes and defect generation on a microscopic scale. The field at which pre-breakdown arcing begins was compared to the onset field for electrostatic discharge at which complete breakdown begins to occur for each material. We present evidence …


Cathodolumiescence Studies Of The Density Of States Of Disordered Silicon Dioxide, JR Dennison, Amberly Evans Jensen 2014 Utah State Univesity

Cathodolumiescence Studies Of The Density Of States Of Disordered Silicon Dioxide, Jr Dennison, Amberly Evans Jensen

Presentations

Electron bombardment measurements have shown that disordered SiO2 exhibits cathodoluminescence, with an overall intensity that varies with incident electron beam energy and current density, sample temperature, exposure time, and wavelength. A simple model based on the defect density of states—used to explain electron transport in highly disordered insulating materials—has been extended to predict the relative cathodoluminescent intensity and spectral radiance for disordered SiO 2 as a function of these variables. The spectral radiance exhibited four distinct bands, corresponding to four distinct energy distributions of defect states within the band gap; each showed different temperature dependence. These localized defect or “trap” …


Cathodoluminescence Events Coincident With Muon Detection, Kenneth Zia, Justin Dekany, JR Dennison 2014 Utah State University

Cathodoluminescence Events Coincident With Muon Detection, Kenneth Zia, Justin Dekany, Jr Dennison

Presentations

Samples of highly disordered insulating material have been irradiated with keV electron beams, resulting in three forms of electron induced light emission with differing duration: arcs (duration), “flares” (~100 s), and cathodoluminescence (as long as beam is on) [Dennison, 2013]. The arc and cathodoluminescence phenomena are well understood, while the flares’ origins are not. Flares were observed at intervals of ~2 per hr. This is within a factor of 2 for the expected muon cross section at an altitude of Logan, UT (1370 m) caused by high altitude cosmic rays; those high energy particles could have deposited sufficient energy throughout …


Discharge Breakdown Analyses, Sam Hansen, JR Dennison, Allen Andersen 2014 Utah State University

Discharge Breakdown Analyses, Sam Hansen, Jr Dennison, Allen Andersen

Presentations

Material breakdown due to Electrostatic discharge (ESD) is the primary cause of spacecraft damage due to environment interactions in space. This occurs when the space plasma fluxes charge a craft to high voltages where insulating craft materials then break down. This failure allows current to flow freely through the material, this can damage or destroy onboard electrical systems. My project focuses on the effects of these breakdowns on suspect materials commonly used for electrical insulation in space. The USU Material Physics Group has performed ESD tests on hundreds of samples to date. The ESD damage sites of these samples have …


Lifetimes Of Polymeric Dielectrics: A Dual-Defect Model, Allen Andersen, JR Dennison 2014 Utah State University

Lifetimes Of Polymeric Dielectrics: A Dual-Defect Model, Allen Andersen, Jr Dennison

Presentations

Electrostatic discharge (ESD) can cause catastrophic failures in electronic devices. Estimating the lifetime of dielectrics under prolonged high field exposure is a major design concern for applications including spacecraft, high voltage DC power transmission, and semiconductor electronics. Dielectric strengths listed in engineering handbooks are primarily based on cursory measurements with poor repeatability and tend to overestimate ESD fields in real applications. Standard measurements subject test samples to ~500 V/s ramp rates until breakdown. We present the results of ESD studies in two prototypical polymer dielectrics using a ramp rate of ~20 V/4s until breakdown together with tests applying a static …


Modeling The Energy Dependent Cathodoluminescent Intensity Of A Carbon Composite Material, Justin Christensen, Kelby T. Peterson, Justin Dekany, JR Dennison 2014 Utah State University

Modeling The Energy Dependent Cathodoluminescent Intensity Of A Carbon Composite Material, Justin Christensen, Kelby T. Peterson, Justin Dekany, Jr Dennison

Presentations

When highly disordered insulating materials are subjected to energetic electron bombardment they can emit photons. This process is termed “cathodoluminescence.” This occurs in the space plasma environment and is an important phenomenon to understand when designing any object to be put into space. Light emitted from spacecraft materials can affect optical detection, and can cause stray-light contamination in space-based observatories. The Materials Physics Group at Utah State University uses an ultra-high vacuum chamber equipped with electron guns and a cryostat to control the sample temperature to simulate the space environment and to observe its affects on sample materials. Previous studies …


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