Open Access. Powered by Scholars. Published by Universities.®

Radiochemistry Commons

Open Access. Powered by Scholars. Published by Universities.®

247 Full-Text Articles 276 Authors 40,864 Downloads 29 Institutions

All Articles in Radiochemistry

Faceted Search

247 full-text articles. Page 7 of 8.

Recycling And Reuse Of Radioactive Materials, Thomas Joseph O'dou 2012 University of Nevada, Las Vegas

Recycling And Reuse Of Radioactive Materials, Thomas Joseph O'Dou

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Radiochemistry Program at the University of Nevada, Las Vegas (UNLV) has a Radiation Protection Program that was designed to provide students with the ability to safely work with radioactive materials in quantities that are not available in other academic environments. Requirements for continuous training and supervision make this unique program capable of turning out graduates that have an understanding of contamination and dose control techniques that complement their knowledge of the elements that they work with. The Program has also adopted a radionuclide recovery and reuse program that has provided materials from other universities, government agencies, and private companies ...


Mußestudien Und Radiochemie: Eine Fruchtpfolle Synthese, Winfried S. Peters 2012 Selected Works

Mußestudien Und Radiochemie: Eine Fruchtpfolle Synthese, Winfried S. Peters

Winfried S. Peters

This makes no sense at all!


Evaluating Actinide Sorption To Graphite With Regards To Triso Repository Performance, Corey Christopher Keith 2012 University of Nevada, Las Vegas

Evaluating Actinide Sorption To Graphite With Regards To Triso Repository Performance, Corey Christopher Keith

UNLV Theses, Dissertations, Professional Papers, and Capstones

Graphite has the potential for inclusion in nuclear waste for disposal in waste repository settings. Implementation of High Temperature Gas-cooled Reactors contributes to this potential through use of TRISO fuel, if direct disposal of the graphite matrix surrounding the fuel is employed. The inclusion of the large mass and volume in the TRISO fuel waste form differs significantly from used light water reactor fuel waste forms, requiring new performance models to describe the behavior in a repository setting. The purpose of this study is to evaluate the potential for the graphite to improve actinide, specifically uranium and neptunium, retardation from ...


Hrc Enews — 2012 Summer, Megan M. Iudice 2012 University of Nevada, Las Vegas

Hrc Enews — 2012 Summer, Megan M. Iudice

Publications (HRC)

This issue contains staff accomplishments and announcements, event listings, and a "new faces" listing for new staff, affiliates, and researchers.


Hrc Enews — 2012 Spring, Megan M. Iudice 2012 University of Nevada, Las Vegas

Hrc Enews — 2012 Spring, Megan M. Iudice

Publications (HRC)

This issue contains staff accomplishments and announcements, event listings, and a "new faces" listing for new staff, affiliates, and researchers.


National Center For Nuclear Security, Veraun Chipman, Amanda Klingensmith, Cathy Snelson 2012 Nevada National Security Site

National Center For Nuclear Security, Veraun Chipman, Amanda Klingensmith, Cathy Snelson

NSTec UNLV Symposium

National Center for Nuclear Security (NCNS) Mission

•Chartered mission is to enhance the Nation’s verification and detection capabilities in support of nuclear arms control and nonproliferation through R&D activities at the NNSS
•Three focus areas
–Treaty Verification Technologies
–Nonproliferation Technologies
–Technical Nuclear Forensics


Toward A Regional Radiocarbon Model For The East Texas Woodland Period, Robert Z. Selden Jr., Timothy K. Perttula 2012 Archeological & Environmental Consultants, LLC

Toward A Regional Radiocarbon Model For The East Texas Woodland Period, Robert Z. Selden Jr., Timothy K. Perttula

CRHR: Archaeology

The East Texas Radiocarbon Database contributes to an analysis of tempo and place for Woodland era (ca. 500 B.C. - A.D. 800) archaeological sites within the region. The temporal and spatial distributions of calibrated radiocarbon (14C) ages (n=127) with a standard deviation (ΔT) of 61 from archaeological sites with Woodland components (n=51) are useful in exploring the development and geographical continuity of the peoples in East Texas, and lead to a refinement of our current chronological understanding of the period. While the analysis of the dates produces less than significant findings due to sample size, they ...


The East Texas Caddo: Modeling Tempo And Place, Robert Z. Selden Jr., Timothy K. Perttula 2012 Archeological & Environmental Consultants, LLC

The East Texas Caddo: Modeling Tempo And Place, Robert Z. Selden Jr., Timothy K. Perttula

CRHR: Archaeology

Analysis of the Caddo sample (n=889 dates) from the East Texas radiocarbon database is used to establish the tempo and place of Caddo era (ca. A.D. 800-1680) archaeological sites, site clusters, and communities across the region. The temporal and spatial distribution of radiocarbon ages from settlements, mound centers, and cemeteries across the region have utility in exploring the development and geographical continuity of the Caddo peoples; establishing the specific times when areas were abandoned or population sizes diminished; and defining times and areas illustrating an intensification in mound center construction and large cemeteries became a focus of community ...


Hrc Enews — 2012 Winter, Megan M. Iudice 2012 University of Nevada, Las Vegas

Hrc Enews — 2012 Winter, Megan M. Iudice

Publications (HRC)

This issue contains staff accomplishments and announcements, event listings, and a "new faces" listing for new staff, affiliates, and researchers.


Spectroscopic Methods Of Process Monitoring For Safeguards Of Used Nuclear Fuel Separations, Jamie Lee Warburton 2011 University of Nevada, Las Vegas

Spectroscopic Methods Of Process Monitoring For Safeguards Of Used Nuclear Fuel Separations, Jamie Lee Warburton

UNLV Theses, Dissertations, Professional Papers, and Capstones

To support the demonstration of a more proliferation-resistant nuclear fuel processing plant, techniques and instrumentation to allow the real-time, online determination of special nuclear material concentrations in-process must be developed. An ideal materials accountability technique for proliferation resistance should provide nondestructive, realtime, on-line information of metal and ligand concentrations in separations streams without perturbing the process. UV-Visible spectroscopy can be adapted for this precise purpose in solvent extraction-based separations.

The primary goal of this project is to understand fundamental URanium EXtraction (UREX) and Plutonium-URanium EXtraction (PUREX) reprocessing chemistry and corresponding UV-Visible spectroscopy for application in process monitoring for safeguards. By ...


Intragroup Separation Of Trivalent Lanthanides And Actinides For Neutron Capture Experiments In Stockpile Stewardship Sciences, Narek Gharibyan 2011 University of Nevada, Las Vegas

Intragroup Separation Of Trivalent Lanthanides And Actinides For Neutron Capture Experiments In Stockpile Stewardship Sciences, Narek Gharibyan

UNLV Theses, Dissertations, Professional Papers, and Capstones

Knowledge of low-energy cross sections for stable and unstable nuclei in neutron-, γ- and ion induced reactions is important in both the simulation and radiochemistry diagnosis of nuclear device performance. This dissertation explores extraction chromatography and ion chromatography methods for the intragroup separation of trivalent actinides and lanthanides in support of cross section measurements for isotopes of interest. For trivalent actinides, americium (Am(III)) and curium (Cm(III)), separation is necessary to assist in experiments related to the measurement of neutron capture cross section for 241 Am and the production of 242 m Am/242g Am isomeric ratio. Extraction ...


Undergraduate Research Opportunities Program 2011, Nicholle Booker, University of Nevada, Las Vegas 2011 Graduate Affairs Coordinator, College of Sciences, University of Nevada, Las Vegas

Undergraduate Research Opportunities Program 2011, Nicholle Booker, University Of Nevada, Las Vegas

Undergraduate Research Opportunities Program (UROP)

Undergraduate Research Opportunities Program

On August 9, 2011 the UNLV College of Sciences will celebrate the accomplishments of undergraduate students participating in the Summer 2011 Undergraduate Research Opportunities Program (UROP) and the Research Experience For Undergraduates (REU) Program.

The public is invited to attend, beginning at 10:00 a.m.

Please join us to view student research posters. Student research topics include: biomedicine and human health, Nevada's fragile environment and ecosystems, climate change, stem cell research, microbiology, astrophysics, and many others.

Over 25 UNLV undergraduates and a cohort of 25 undergraduates selected from colleges and universities across the nation ...


Equilibrium Speciation Of Select Lanthanides In The Presence Of Acidic Ligands In Homo- And Heterogeneous Solutions, Troy Robinson 2011 University of Nevada, Las Vegas

Equilibrium Speciation Of Select Lanthanides In The Presence Of Acidic Ligands In Homo- And Heterogeneous Solutions, Troy Robinson

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation explores lanthanide speciation in liquid solution systems related to separation schemes involving the acidic ligands: bis(2-ethylhexyl) phosphoric acid (HDEHP), lactate, and 8-hydroxyquinoline. Equilibrium speciation of neodymium (Nd3+ ), sodium (Na+ ), HDEHP, water, and lactate in the TALSPEAK liquid-liquid extraction system was explored under varied Nd3+ loading of HDEHP in the organic phase and through extraction from aqueous HCl and lactate media. System speciation was probed through vapor pressure osmometry, visible and Fourier Transform Infrared (FTIR) spectroscopy, 22 Na and 13 C labeled lactate radiotracer distribution measurements, Karl Fischer titrations, and equilibrium pH measurements. Distribution of Nd ...


Synthesis, Extraction, Dissolution, And Voltammetry Of F-Species In A Room Temperature Ionic Liquid Solvent, Wendy Jacqueline Pemberton 2011 University of Nevada, Las Vegas

Synthesis, Extraction, Dissolution, And Voltammetry Of F-Species In A Room Temperature Ionic Liquid Solvent, Wendy Jacqueline Pemberton

UNLV Theses, Dissertations, Professional Papers, and Capstones

Room temperature ionic liquids (RTILs) are salts that are liquids from as low as -96 °C to up to 100 °C. RTILs are of high interest in many fields of study because of their negligible vapor pressure, high electrochemical stability, high conductivity, and wide electrochemical windows. These diverse solvents have recently been used in organic synthesis, as extraction solvents, and as electrochemical solvents. It is as a direct result of the multifunctional capabilities of these RTIL solvents that they are examined in this work. The ability to probe the chemistry of lanthanides and actinides is based on the unique properties ...


Unlv Stars Unabridged Report, University of Nevada, Las Vegas 2011 University of Nevada, Las Vegas

Unlv Stars Unabridged Report, University Of Nevada, Las Vegas

Reports (USI)

University of Nevada, Las Vegas, by earning a 2011 Silver Rating in the Sustainability Tracking, Assessment & Ratings System (STARS), is ahead of the curve among public universities – and improving.

STARS is a voluntary, self–reporting framework developed by the Association for the Advancement of Sustainability in Higher Education (AASHE) to help measure sustainability performance over time and among colleges and universities nationwide. The UNLV Sustainability Council oversaw STARS, which by measuring sustainability can help UNLV to reduce energy consumption and waste, improve education, attract research, and generate jobs.

A rating of Silver puts UNLV in great company – with Yale, University ...


Electrochemistry Of Technetium Analogues Rhenium And Molybdenum In Room Temperature Ionic Liquid, Pauline Nancy Serrano 2011 University of Nevada, Las Vegas

Electrochemistry Of Technetium Analogues Rhenium And Molybdenum In Room Temperature Ionic Liquid, Pauline Nancy Serrano

UNLV Theses, Dissertations, Professional Papers, and Capstones

Rhenium was used as an analog for Technetium to study the electrochemical redox properties because the two elements share the same stable oxidation states in aqueous solutions. However, Tc-99 is radioactive and is not readily available for experimentation purposes. Molybdenum is also of interest because when Mo-99 is irradiated, the decay products are Tc-99m and Tc-99. Approximately 30% Tc-99m is eluted from the Mo columns for radiopharmaceutical use with the remaining Mo-99 source decaying to Tc-99 which is discarded as radioactive hospital waste. Currently there are no viable procedures for the reclamation of the radioactive Tc-99 from either fission streams ...


Extraction Chromatographic Studies Of Rutherfordium And Dubnium Homologs, Megan E. Bennett 2011 University of Nevada, Las Vegas

Extraction Chromatographic Studies Of Rutherfordium And Dubnium Homologs, Megan E. Bennett

UNLV Theses, Dissertations, Professional Papers, and Capstones

Studying the chemistry of transactinide elements does not only allow for these elements to be properly placed in the Periodic Table, but it also permits for the extrapolation of the electronic structure based upon the position of the element in the Periodic Table. In addition it enable for the assessment of the role that relativistic effects play in the chemical behavior of the heaviest elements. An improved understanding of the role of relativistic effects in chemistry of the heaviest elements allows for a better understanding of the fundamentals principles that govern the Periodic Table. In order to investigate the chemistry ...


Speciation And Spectroscopy Of The Uranyl And Tetravalent Plutonium Nitrate Systems: Fundamental Studies And Applications To Used Fuel Reprocessing, Nicholas A. Smith 2010 University of Nevada, Las Vegas

Speciation And Spectroscopy Of The Uranyl And Tetravalent Plutonium Nitrate Systems: Fundamental Studies And Applications To Used Fuel Reprocessing, Nicholas A. Smith

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation explores the use of UV-Visible spectroscopy and Time Resolved Laser Induced Fluorescence spectroscopy as near real time process monitors of uranium and plutonium concentrations in aqueous reprocessing trains. The molar absorptivities and linear ranges of these metals were investigated under total nitrate and acid concentrations similar to those found in current reprocessing systems. Concurrent to this, a new multiple wavelength monitor was derived that is capable of determining the total nitrate concentration spectroscopically. This method uses the uranium absorbance spectrum to calculate the nitrate concentration in solution. When used as part of an Advanced Safeguard suite, this technique ...


Hrc Enews — 2010 Fall, Megan K. Svarz 2010 University of Nevada, Las Vegas

Hrc Enews — 2010 Fall, Megan K. Svarz

Publications (HRC)

This issue contains staff accomplishments and announcements, event listings, and a "new faces" listing for new staff, affiliates, and researchers.


Undergraduate Research Opportunities Program 2010, University of Nevada, Las Vegas 2010 University of Nevada, Las Vegas

Undergraduate Research Opportunities Program 2010, University Of Nevada, Las Vegas

Undergraduate Research Opportunities Program (UROP)

The Undergraduate Research Opportunities Program (UROP) cultivates and supports research partnerships and invites undergraduates to work as the junior colleagues of faculty. The program offers the opportunity to work on cutting edge research—whether you join established research projects or pursue your own ideas. As participants, undergraduates engage in each phase of standard research activity: developing research plans, writing proposals, conducting research, analyzing data. and presenting research results in oral and written form. The projects take place over the summer, and research can be done in any academic department or interdisciplinary laboratory. Projects can last for an entire semester, and ...


Digital Commons powered by bepress