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Articles 1 - 30 of 118
Full-Text Articles in Social and Behavioral Sciences
Satellite Evidence For A Large Source Of Formic Acid From Boreal And Tropical Forests, T Stavrakou, J F. Muller, J Peeters, A Razavi, L Clarisse, C Clerbaux, P Coheur, D Hurtmans, M De Maziere, C Vigouroux, Nicholas Deutscher, David Griffith, Nicholas Jones, Clare Paton-Walsh
Satellite Evidence For A Large Source Of Formic Acid From Boreal And Tropical Forests, T Stavrakou, J F. Muller, J Peeters, A Razavi, L Clarisse, C Clerbaux, P Coheur, D Hurtmans, M De Maziere, C Vigouroux, Nicholas Deutscher, David Griffith, Nicholas Jones, Clare Paton-Walsh
Faculty of Science - Papers (Archive)
Formic acid contributes significantly to acid rain in remote environments1, 2. Direct sources of formic acid include human activities, biomass burning and plant leaves. Aside from these direct sources, sunlight-induced oxidation of non-methane hydrocarbons (largely of biogenic origin) is probably the largest source3, 4. However, model simulations substantially underpredict atmospheric formic acid levels5, 6, 7, indicating that not all sources have been included in the models. Here, we use satellite measurements of formic acid concentrations to constrain model simulations of the global formic acid budget. According to our simulations, 100–120 Tg of formic acid is produced annually, which is two …
Synthesis Of 3-Halo-2,5-Disubstituted Furans Via Cux Mediated Cyclization-Halogenation Reactions, Arife Yazici, Stephen G. Pyne
Synthesis Of 3-Halo-2,5-Disubstituted Furans Via Cux Mediated Cyclization-Halogenation Reactions, Arife Yazici, Stephen G. Pyne
Faculty of Science - Papers (Archive)
The Cu(I) halide (X = I, Br, Cl) mediated reactions of Cbz-protected cis-2-phenylethenyl-3-hydroxypyrrolidine gave novel 3-halo-2,5-trisubstituted furans in good yields, via a cyclization-halogenation, ring-opening reaction sequence. In contrast, the reactions with CuCN gave mainly the corresponding 3-cyanofuro[3,2-b]pyrrole formed from a cyclization-cyanation reaction.
Negotiating Change: Working With Children And Their Employers To Transform Child Domestic Work In Iringa, Tanzania, Natascha Klocker
Negotiating Change: Working With Children And Their Employers To Transform Child Domestic Work In Iringa, Tanzania, Natascha Klocker
Faculty of Science - Papers (Archive)
This paper documents the practical and action-oriented findings of an investigation into child domestic work undertaken in Iringa, Tanzania from 2005 to 2007. It provides an overview of the experiences of both child domestic workers and their employers, before discussing their suggestions for how child domestic working arrangements may be improved. The latter sections of the paper relate the attempts to regulate child domestic work that emerged from such dialogue. In providing detailed information on that process, the paper is positioned within the field of action research and resists the boundary frequently applied between academia and activism. It also moves …
Preliminary Validation Of Column-Averaged Volume Mixing Ratios Of Carbon Dioxide And Methane Retrieved From Gosat Short-Wavelength Infrared Spectra, David W. Griffith, G C. Toon, B Connor, R Sussmann, Thorsten Warneke, Nicholas M. Deutscher, Paul O. Wennberg, Justus Notholt, V Sherlock, J Robinson, O Uchino, C M. Roehl, I Morino, Debra Wunch, Janina Messerschmidt, Y Yoshida, M Inoue, M Rettinger
Preliminary Validation Of Column-Averaged Volume Mixing Ratios Of Carbon Dioxide And Methane Retrieved From Gosat Short-Wavelength Infrared Spectra, David W. Griffith, G C. Toon, B Connor, R Sussmann, Thorsten Warneke, Nicholas M. Deutscher, Paul O. Wennberg, Justus Notholt, V Sherlock, J Robinson, O Uchino, C M. Roehl, I Morino, Debra Wunch, Janina Messerschmidt, Y Yoshida, M Inoue, M Rettinger
Faculty of Science - Papers (Archive)
Column-averaged volume mixing ratios of carbon dioxide and methane retrieved from the Greenhouse gases Observing SATellite (GOSAT) Short-Wavelength InfraRed observation (GOSAT SWIR XCO2 and XCH4 ) were compared with the reference calibrated data obtained by ground-based high-resolution Fourier Transform Spectrometers (g-b FTSs) participating in the Total Carbon Column Observing Network (TCCON). Preliminary results are as follows: the GOSAT SWIR XCO2 and XCH4 (Version 01.xx) are biased low by 8.85 ±4.75 ppm (2.3±1.2 %) and 20.4±18.9 ppb (1.2±1.1 %), respectively. The standard deviation of the GOSAT SWIR XCO2 and XCH4 is about 1% after correcting the negative biases of XCO2 and …
An Unusually Flexible Expanded Hexaamine Cage And Its Cuii Complexes: Variable Coordination Modes And Incomplete Encapsulation, C-J Qin, Lloyd James, Jy D. Chartres, Leighton J. Alcock, Kimberley J. Davis, Anthony C. Willis, Alan M. Sargeson, Paul V. Bernhardt, Stephen F. Ralph
An Unusually Flexible Expanded Hexaamine Cage And Its Cuii Complexes: Variable Coordination Modes And Incomplete Encapsulation, C-J Qin, Lloyd James, Jy D. Chartres, Leighton J. Alcock, Kimberley J. Davis, Anthony C. Willis, Alan M. Sargeson, Paul V. Bernhardt, Stephen F. Ralph
Faculty of Science - Papers (Archive)
The bicyclic hexaamine "cage" ligand Me 8tricosaneN 6 (1,5,5,9,13,13,20,20-octamethyl-3,7,11,15,18, 22-hexaazabicyclo[7.7.7]tricosane) is capable of encapsulating octahedral metal ions, yet its expanded cavity allows the complexed metal to adopt a variety of geometries comprising either hexadentate or pentadentate coordination of the ligand. When complexed to Cu II the lability of the metal results in a dynamic equilibrium in solution between hexadentate- and pentadentate- coordinated complexes of Me 8tricosaneN 6. Both [Cu(Me 8tricosaneN 6)](ClO 4) 2 (6-coordinate) and [Cu(Me 8tricosaneN 6)](S 2O 6) (5-coordinate) have been characterized structurally. In weak acid (pH 1) a singly protonated complex [Cu(HMe 8tricosaneN 6)] 3+ has been …
Extensional And Colisional Magmatic Records In The Apiai Terrane, South-Southeastern Brazil: Integration Of Geochronological U-Pb Zircon Ages, Oswaldo Siga Junior, Miguel Angelo Stipp Basei, Allen P. Nutman, Kei Sato, Ian Mcreath, Claudia Regina Passarelli, Dunyi Liu
Extensional And Colisional Magmatic Records In The Apiai Terrane, South-Southeastern Brazil: Integration Of Geochronological U-Pb Zircon Ages, Oswaldo Siga Junior, Miguel Angelo Stipp Basei, Allen P. Nutman, Kei Sato, Ian Mcreath, Claudia Regina Passarelli, Dunyi Liu
Faculty of Science - Papers (Archive)
The aim of this work is the presentation of a synthesis of available geochronological data for the basement inliers and metavolcano-sedimentary sequences which occur in the southern part of the Apiai Terrane, south-southeastern Brazil. These data, especially those obtained during the last decade, have made substantial modifi cations to the tectonic scenario of south-southeastern Brazil with the recognition of the presence of extensional basins (continental rifts) with magmatism and sedimentation at the late Paleoproterozoic (1790 - 1750 Ma) and of the Mesoproterozoic (1600 - 1450 Ma). These processes started at the late Paleoproterozoic in the Betara, Perau and Apiai Mirim …
An Automated Land Subdivision Tool For Urban And Regional Planning: Concepts, Implementation And Testing, Rohan Wickramasuriya, Laurie A. Chisholm, Marjetta Puotinen, Nicholas Gill, Peter Klepeis
An Automated Land Subdivision Tool For Urban And Regional Planning: Concepts, Implementation And Testing, Rohan Wickramasuriya, Laurie A. Chisholm, Marjetta Puotinen, Nicholas Gill, Peter Klepeis
Faculty of Science - Papers (Archive)
Simulation of the land subdivision process is useful in many applied and research areas. Planners use such tools to understand potential impacts of planning regulations prior to their implementation. While the credibility of both land-use change and urban growth models would be enhanced by integrating capabilities to simulate land subdivision, such research is lacking in the published literature. Of the few subdivision tools that exist, most are either not fully-automated or are unable to generate realistic subdivision layouts. This limits their applicability, particularly for high resolution land-use change models. In this paper, we present a fully-automated land subdivision tool that …
Synthesis And Structural Characterization Of 1-[2-(5-Nitro-1h-Indol-2-Yl)Phenyl]Methylpyridinium Chloride, John B. Bremner, Siritron Samosorn, Brian W. Skelton, Allan White
Synthesis And Structural Characterization Of 1-[2-(5-Nitro-1h-Indol-2-Yl)Phenyl]Methylpyridinium Chloride, John B. Bremner, Siritron Samosorn, Brian W. Skelton, Allan White
Faculty of Science - Papers (Archive)
In the course of studies on hybrid antibacterials incorporating 2-aryl-5-nitro-1Hindolemoieties as potential bacterial NorA efflux pump inhibitors, the compound 1-[2-(5-nitro-1H-indol-2-yl)phenyl]methylpyridinium chloride (2) was synthesized and structurallycharacterized. This pyridinium chloride salt crystallized in the monoclinic space groupP21/c with the following unit cell dimensions: a 10.274(3) A, b 13.101(4) A, c 13.439(4)A, B 107.702(7)deg, V 1723.2(9) A3, Z (f.u.) = 4; R1 = 0.048, and wR2 = 0.13. Of interest inthe single crystal X-ray structure is the (intramolecular) disposition of the pyridinium planeover the indole heterocyclic residue [interplanar dihedral angle 17.91(4)deg].
Toward Accurate Co2 And Ch4 Observations From Gosat, A Butz, S Guerlet, O Hasekamp, D Schepers, A Galli, Ilse Aben, C Frankenberg, J-M Hartmann, H Tran, A Kuze, Gretchen Keppel-Aleks, G C. Toon, Debra Wunch, P Wennberg, Nicholas M. Deutscher, David W. Griffith, Ronald Macatangay, Janina Messerschmidt, Justus Notholt, Thorsten Warneke
Toward Accurate Co2 And Ch4 Observations From Gosat, A Butz, S Guerlet, O Hasekamp, D Schepers, A Galli, Ilse Aben, C Frankenberg, J-M Hartmann, H Tran, A Kuze, Gretchen Keppel-Aleks, G C. Toon, Debra Wunch, P Wennberg, Nicholas M. Deutscher, David W. Griffith, Ronald Macatangay, Janina Messerschmidt, Justus Notholt, Thorsten Warneke
Faculty of Science - Papers (Archive)
The column-average dry air mole fractions of atmospheric carbon dioxide and methane (XCO2 and XCH4) are inferred from observations of backscattered sunlight conducted by the Greenhouse gases Observing SATellite (GOSAT). Comparing the first year of GOSAT retrievals over land with colocated ground-based observations of the Total Carbon Column Observing Network (TCCON), we find an average difference (bias) of-0.05% and-0.30% for XCO2 and XCH4 with a station-to-station variability (standard deviation of the bias) of 0.37% and 0.26% among the 6 considered TCCON sites. The root-mean square deviation of the bias-corrected satellite retrievals from colocated TCCON observations amounts to 2.8 ppm for …
Nanoesi Mass Spectrometry Of Rubisco And Rubisco Activase Structures And Their Interactions With Nucleotides And Sugar Phosphates, Michelle Blayney, Spencer M. Whitney, Jennifer L. Beck
Nanoesi Mass Spectrometry Of Rubisco And Rubisco Activase Structures And Their Interactions With Nucleotides And Sugar Phosphates, Michelle Blayney, Spencer M. Whitney, Jennifer L. Beck
Faculty of Science - Papers (Archive)
Ribulose bisphosphate carboxylase/oxygenase (Rubisco) is the protein that is responsible for the fixation of carbon dioxide in photosynthesis. Inhibitory sugar phosphate molecules, which can include its substrate ribulose-1,5- bisphosphate (RuBP), can bind to Rubisco catalytic sites and inhibit catalysis. These are removed by interaction with Rubisco activase (RA) via an ATP hydrolytic reaction. Here we show the first nanoESI mass spectra of the hexadecameric Rubisco and of RA from a higher plant (tobacco). The spectra of recombinant, purified RA revealed polydispersity in its oligomeric forms (up to hexamer) and that ADP was bound. ADP was removed by dialysis against a …
The Long Life Of Birds: The Rat-Pigeon Comparison Revisited, William A. Buttemer, Anthony J. Hulbert, M K. Montgomery
The Long Life Of Birds: The Rat-Pigeon Comparison Revisited, William A. Buttemer, Anthony J. Hulbert, M K. Montgomery
Faculty of Science - Papers (Archive)
The most studied comparison of aging and maximum lifespan potential (MLSP) among endotherms involves the 7-fold longevity difference between rats (MLSP 5y) and pigeons (MLSP 35y). A widely accepted theory explaining MLSP differences between species is the oxidative stress theory, which purports that reactive oxygen species (ROS) produced during mitochondrial respiration damage bio-molecules and eventually lead to the breakdown of regulatory systems and consequent death. Previous rat-pigeon studies compared only aspects of the oxidative stress theory and most concluded that the lower mitochondrial superoxide production of pigeons compared to rats was responsible for their much greater longevity. This conclusion is …
Daily And 3-Hourly Variability In Global Fire Emissions And Consequences For Atmospheric Model Predictions Of Carbon Monoxide, M Mu, James Randerson, G R. Van Der Werf, L Giglio, Prasad Kasibhatla, D Morton, G J. Collatz, R S. Defries, E J. Hyer, E M. Prins, David W. Griffith, Debra Wunch, G C. Toon, V Sherlock, Paul O. Wennberg
Daily And 3-Hourly Variability In Global Fire Emissions And Consequences For Atmospheric Model Predictions Of Carbon Monoxide, M Mu, James Randerson, G R. Van Der Werf, L Giglio, Prasad Kasibhatla, D Morton, G J. Collatz, R S. Defries, E J. Hyer, E M. Prins, David W. Griffith, Debra Wunch, G C. Toon, V Sherlock, Paul O. Wennberg
Faculty of Science - Papers (Archive)
"Attribution of the causes of atmospheric trace gas and aerosol variability often requires the use of high resolution time series of anthropogenic and natural emissions inventories. Here we developed an approach for representing synoptic-and diurnal-scale temporal variability in fire emissions for the Global Fire Emissions Database version 3 (GFED3). We disaggregated monthly GFED3 emissions during 2003-2009 to a daily time step using Moderate Resolution Imaging Spectroradiometer (MODIS)-derived measurements of active fires from Terra and Aqua satellites. In parallel, mean diurnal cycles were constructed from Geostationary Operational Environmental Satellite (GOES) Wildfire Automated Biomass Burning Algorithm (WF_ABBA) active fire observations. Daily variability …
Methane Observations From The Greenhouse Gases Observing Satellite: Comparison To Ground-Based Tccon Data And Model Calculations, Robert Parker, Hartmut Boesch, Austin Cogan, Annemarie Fraser, Liang Feng, Paul Palmer, Janina Messerschmidt, Nicholas M. Deutscher, David W. Griffith, Justus Notholt, Paul O. Wennberg, Debra Wunch
Methane Observations From The Greenhouse Gases Observing Satellite: Comparison To Ground-Based Tccon Data And Model Calculations, Robert Parker, Hartmut Boesch, Austin Cogan, Annemarie Fraser, Liang Feng, Paul Palmer, Janina Messerschmidt, Nicholas M. Deutscher, David W. Griffith, Justus Notholt, Paul O. Wennberg, Debra Wunch
Faculty of Science - Papers (Archive)
We report new short-wave infrared (SWIR) column retrievals of atmospheric methane (X CH4) from the Japanese Greenhouse Gases Observing SATellite (GOSAT) and compare observed spatial and temporal variations with correlative ground-based measurements from the Total Carbon Column Observing Network (TCCON) and with the global 3-D GEOS-Chem chemistry transport model. GOSAT X CH4 retrievals are compared with daily TCCON observations at six sites between April 2009 and July 2010 (Bialystok, Park Falls, Lamont, Orleans, Darwin and Wollongong). GOSAT reproduces the site-dependent seasonal cycles as observed by TCCON with correlations typically between 0.5 and 0.7 with an estimated single-sounding precision between 0.4-0.8%. …
Retrieval Of Atmospheric Co2 With Enhanced Accuracy And Precision From Sciamachy: Validation With Fts Measurements And Comparison With Model Results, M Reuter, H Bovensmann, M Buchwitz, Jp Burrows, B Connor, Nicholas M. Deutscher, David W. Griffith, J Heymann, Gretchen Keppel-Aleks, Janina Messerschmidt, Justus Notholt, Christof Petri, J Robinson, O Schneising, V Sherlock, Voltaire A. Velazco, Thorsten Warneke, Paul O. Wennberg, Debra Wunch
Retrieval Of Atmospheric Co2 With Enhanced Accuracy And Precision From Sciamachy: Validation With Fts Measurements And Comparison With Model Results, M Reuter, H Bovensmann, M Buchwitz, Jp Burrows, B Connor, Nicholas M. Deutscher, David W. Griffith, J Heymann, Gretchen Keppel-Aleks, Janina Messerschmidt, Justus Notholt, Christof Petri, J Robinson, O Schneising, V Sherlock, Voltaire A. Velazco, Thorsten Warneke, Paul O. Wennberg, Debra Wunch
Faculty of Science - Papers (Archive)
The Bremen Optimal Estimation differential optical absorption spectroscopy (DOAS) (BESD) algorithm for satellite based retrievals of XCO 2 (the column-average dry-air mole fraction of atmospheric CO 2) has been applied to Scanning Imaging Absorption Spectrometer for Atmospheric Cartography (SCIAMACHY) data. It uses measurements in the O 2-A absorption band to correct for scattering of undetected clouds and aerosols. Comparisons with precise and accurate ground-based Fourier transform spectrometer (FTS) measurements at four Total Carbon Column Observing Network (TCCON) sites have been used to quantify the quality of the new SCIAMACHY XCO 2 data set. Additionally, the results have been compared to …
A Novel Bath Lily-Like Graphene Sheet-Wrapped Nano-Si Composite As A High Performance Anode Material For Li-Ion Batteries, Jun Chen, Jun Yang, Zi-Feng Ma, Pengfei Gao, Yu-Shi He, Xiao Zhen Liao, Xiaowei Yang
A Novel Bath Lily-Like Graphene Sheet-Wrapped Nano-Si Composite As A High Performance Anode Material For Li-Ion Batteries, Jun Chen, Jun Yang, Zi-Feng Ma, Pengfei Gao, Yu-Shi He, Xiao Zhen Liao, Xiaowei Yang
Faculty of Science - Papers (Archive)
"A novel bath lily-like graphene sheet-wrapped nano-Si composite synthesized via a simple spray drying process exhibits a high reversible capacity of 1525 mAh g(-1) and superior cycling stability, which could be attributed to a synergistic effect between highly conductive graphene sheets and active nanoparticles in the open nano/micro-structure."
The Dirt On Assessing Post-Fire Erosion In The Mount Lofty Ranges: Comparing Methods, Rowena H. Morris, Solomon Buckman, Paul Connelly, Deirdre Dragovich, Bertram Ostendorf, Ross A. Bradstock
The Dirt On Assessing Post-Fire Erosion In The Mount Lofty Ranges: Comparing Methods, Rowena H. Morris, Solomon Buckman, Paul Connelly, Deirdre Dragovich, Bertram Ostendorf, Ross A. Bradstock
Faculty of Science - Papers (Archive)
Land managers are required to assess a range of environmental attributes prior to and after prescribed burning. Current environmental assessments vary depending on the organisation involved and the existing information about localised soil erosion. Auditing successful environmental assessments requires ongoing field monitoring to evaluate whether the magnitude and extent of predicted post-fire impacts are comparable. The impacts of post-fire erosion were assessed by the authors using the techniques of water sampling, sediment traps, erosion pins, laser scanning, photogrammetry and visual field assessment. Each data collecting method varies in its spatial and temporal reach in terms of monitoring landscape changes in …
The Age Of The 20 Meter Solo River Terrace, Java, Indonesia And The Survival Of Homo Erectus In Asia, Etty Indriati, Carl C. Swisher, Christopher Lepre, Rhonda L. Quinn, Rusyad A. Suriyanto, Agus T. Hascaryo, Rainer Grun, Craig S. Feibel, Briana L. Pobiner, Maxime Aubert, Wendy Lees, Susan C. Anton
The Age Of The 20 Meter Solo River Terrace, Java, Indonesia And The Survival Of Homo Erectus In Asia, Etty Indriati, Carl C. Swisher, Christopher Lepre, Rhonda L. Quinn, Rusyad A. Suriyanto, Agus T. Hascaryo, Rainer Grun, Craig S. Feibel, Briana L. Pobiner, Maxime Aubert, Wendy Lees, Susan C. Anton
Faculty of Science - Papers (Archive)
Homo erectus was the first human lineage to disperse widely throughout the Old World, the only hominin in Asia through much of the Pleistocene, and was likely ancestral to H. sapiens. The demise of this taxon remains obscure because of uncertainties regarding the geological age of its youngest populations. In 1996, some of us co-published electron spin resonance (ESR) and uranium series (U-series) results indicating an age as young as 35-50 ka for the late H. erectus sites of Ngandong and Sambungmacan and the faunal site of Jigar (Indonesia). If correct, these ages favor an African origin for recent humans …
Remarkable Synergistic Effects In A Mixed Porphyrin Dye-Sensitized Tio2 Film, Attila J. Mozer, Gordon G. Wallace, David L. Officer, Matthew Griffith, Pawel W. Wagner, Klaudia K. Wagner, George Tsekouras, Shogo Mori, Ying Dong
Remarkable Synergistic Effects In A Mixed Porphyrin Dye-Sensitized Tio2 Film, Attila J. Mozer, Gordon G. Wallace, David L. Officer, Matthew Griffith, Pawel W. Wagner, Klaudia K. Wagner, George Tsekouras, Shogo Mori, Ying Dong
Faculty of Science - Papers (Archive)
A remarkable 300% efficiency enhancement driven by a matching increase in the short circuit current was observed in a mixed porphyrin dye-sensitized solar cell constructed from two dyes in a 3:1 ratio. Absorbed photon-to-current conversion efficiency measurements indicate an improved charge injection yield for both dyes in the mixture. Several possible origins for the observed performance enhancement are discussed.
Clusterin Facilitates In Vivo Clearance Of Extracellular Misfolded Proteins, Amy R. Wyatt, Justin J. Yerbury, Paula Berghofer, I Greguric, Andrew Katsifis, Christopher Dobson, Mark R. Wilson
Clusterin Facilitates In Vivo Clearance Of Extracellular Misfolded Proteins, Amy R. Wyatt, Justin J. Yerbury, Paula Berghofer, I Greguric, Andrew Katsifis, Christopher Dobson, Mark R. Wilson
Faculty of Science - Papers (Archive)
The extracellular deposition of misfolded proteins is a characteristic of many debilitating age-related disorders. However, little is known about the specific mechanisms that act to suppress this process in vivo. Clusterin (CLU) is an extracellular chaperone that forms stable and soluble complexes with misfolded client proteins. Here we explore the fate of complexes formed between CLU and misfolded proteins both in vitro and in a living organism. We show that proteins injected into rats are cleared more rapidly from circulation when complexed with CLU as a result of their more efficient localisation to the liver and that this clearance …
The Later Stone Age Calvaria From Iwo Eleru, Nigeria: Morphology And Chronology, Katerina Harvati, Chris Stringer, Rainer Grun, Maxime Aubert, Philip Allsworth-Jones, Caleb Adebayo Folorunso
The Later Stone Age Calvaria From Iwo Eleru, Nigeria: Morphology And Chronology, Katerina Harvati, Chris Stringer, Rainer Grun, Maxime Aubert, Philip Allsworth-Jones, Caleb Adebayo Folorunso
Faculty of Science - Papers (Archive)
Background: In recent years the Later Stone Age has been redated to a much deeper time depth than previously thought. At the same time, human remains from this time period are scarce in Africa, and even rarer in West Africa. The Iwo Eleru burial is one of the few human skeletal remains associated with Later Stone Age artifacts in that region with a proposed Pleistocene date. We undertook a morphometric reanalysis of this cranium in order to better assess its affinities. We also conducted Uranium-series dating to re-evaluate its chronology. Methodology/Principal Findings: A 3-D geometric morphometric analysis of cranial landmarks …
1-(3-Chlorophenyl)-2-Methyl-4-Nitro-1h-Imidazole-5-Carboxamide, Pawel W. Wagner, Maciej Kubicki, A Korzanski
1-(3-Chlorophenyl)-2-Methyl-4-Nitro-1h-Imidazole-5-Carboxamide, Pawel W. Wagner, Maciej Kubicki, A Korzanski
Faculty of Science - Papers (Archive)
In the crystal structure of the title compound, C11H9ClN4O3,pairs of NH N(imidazole) hydrogen bonds connect themolecules into centrosymmetric dimers, which are furtherconnected by NH O(carbamoyl) hydrogen bonds intoC(4) chains along [010]. Interplay of these two kinds ofhydrogen bonds connect the molecules into layers perpendicularto [101]. The imidazole [maximum deviation0.0069 (9) A ] and phenyl rings are inclined at a dihedral angleof 58.44 (6); the nitro group is almost coplanar [dihedralangle 5.8 (2)] with the imidazole ring while the carbamoylgroup is almost perpendicular [70.15 (13)] to it.
Recruitment Limitation Of Native Species In Invaded Coastal Dune Communities, Kristine O. French, Natalie A. Sullivan, Tanya J. Mason
Recruitment Limitation Of Native Species In Invaded Coastal Dune Communities, Kristine O. French, Natalie A. Sullivan, Tanya J. Mason
Faculty of Science - Papers (Archive)
"Recruitment limitation may limit the ability of sites to regenerate after disturbances such as weed invasion and weed management. We investigated seed bank constraints and dispersal limitation in coastal dune communities on the east coast of Australia. The ability of sites to regenerate naturally following weed removal was assessed in coastal dune communities invaded by the invasive alien, bitou bush (Chrysanthemoides monilifera subsp. rotundata). To investigate recruitment limitation, seed banks and vegetation of invaded, native, intensively managed (selective application of herbicide and some re-vegetation) and extensively managed (large-scale, non-selective herbicide application) sites were compared. We investigated the dispersal mechanisms of …
Antimalarial, Anticancer, Antimicrobial Activities And Chemical Constituents Of Essential Oil From The Aerial Parts Of Cyperus Kyllingia Endl, Stephen G. Pyne, Boonsom Liawruangrath, Saisunee Liawruangrath, M Garson, S Khamsan, A Teerawutkulrag
Antimalarial, Anticancer, Antimicrobial Activities And Chemical Constituents Of Essential Oil From The Aerial Parts Of Cyperus Kyllingia Endl, Stephen G. Pyne, Boonsom Liawruangrath, Saisunee Liawruangrath, M Garson, S Khamsan, A Teerawutkulrag
Faculty of Science - Papers (Archive)
The chemical constituents of the essential oil from Cyperus kyllingia Endl. were analyzed by a GC, GC-MS. Twenty-three compounds were identified, accounting for 93.75% of the total oil that consisted mainly of oxygenated sesquiterpenes (53.52%), particularly sesquiterpene hydrocarbons (38.97%), and carboxylic acid (1.26%). The most representative compounds were -cadinol (19.32%), caryophyllene oxide (12.17%), -muurolol (11.58%), -humulene (9.85%), and -atlantone (6.07%). The oil showed significant activities against Plasmodium falcipalum (K1, multi drug resistant strain) and NCI-H187 (Small Cell Lung Cancer) with the IC50 values of 7.52 and 7.72 g/mL, respectively. The oil exhibited highly active against Staphylococcus aureus ATCC25923 and moderately …
Remote Real-Time Monitoring Of Subsurface Landfill Gas Migration, Cormac Fay, Aiden R. Doherty, Stephen T. Beirne, F Collins, C Foley, John Healy, Breda M. Kiernan, Hyowon Lee, Damien Maher, D Orpen, Thomas Phelan, Zhengwei Qiu, Kirk Zhang, Cathal Gurrin, Brian Corcoran, Noel E. O'Connor, A F Smeaton, D Diamond
Remote Real-Time Monitoring Of Subsurface Landfill Gas Migration, Cormac Fay, Aiden R. Doherty, Stephen T. Beirne, F Collins, C Foley, John Healy, Breda M. Kiernan, Hyowon Lee, Damien Maher, D Orpen, Thomas Phelan, Zhengwei Qiu, Kirk Zhang, Cathal Gurrin, Brian Corcoran, Noel E. O'Connor, A F Smeaton, D Diamond
Faculty of Science - Papers (Archive)
The cost of monitoring greenhouse gas emissions from landfill sites is of major concern for regulatory authorities. The current monitoring procedure is recognised as labour intensive, requiring agency inspectors to physically travel to perimeter borehole wells in rough terrain and manually measure gas concentration levels with expensive hand-held instrumentation. In this article we present a cost-effective and efficient system for remotely monitoring landfill subsurface migration of methane and carbon dioxide concentration levels. Based purely on an autonomous sensing architecture, the proposed sensing platform was capable of performing complex analytical measurements in situ and successfully communicating the data remotely to a …
The Australian Methane Budget: Interpreting Surface And Train-Borne Measurements Using A Chemistry Transport Model, A Fraser, C C. Miller, Paul Palmer, Nicholas M. Deutscher, Nicholas B. Jones, David W. Griffith
The Australian Methane Budget: Interpreting Surface And Train-Borne Measurements Using A Chemistry Transport Model, A Fraser, C C. Miller, Paul Palmer, Nicholas M. Deutscher, Nicholas B. Jones, David W. Griffith
Faculty of Science - Papers (Archive)
We investigate the Australian methane budget from 2005-2008 using the GEOS-Chem 3D chemistry transport model, focusing on the relative contribution of emissions from different sectors and the influence of long-range transport. To evaluate the model, we use in situ surface measurements of methane, methane dry air column average (XCH 4) from ground-based Fourier transform spectrometers (FTSs), and train-borne surface concentration measurements from an in situ FTS along the north-south continental transect. We use gravity anomaly data from Gravity Recovery and Climate Experiment to describe the spatial and temporal distribution of wetland emissions and scale it to a prior emission estimate, …
Transport Of Nox Emissions From Sugarcane Fertilisation Into The Great Barrier Reef Lagoon, Clare Paton-Walsh, Stephen R. Wilson, Travis A. Naylor, David W. T Griffith, O Tom Denmead
Transport Of Nox Emissions From Sugarcane Fertilisation Into The Great Barrier Reef Lagoon, Clare Paton-Walsh, Stephen R. Wilson, Travis A. Naylor, David W. T Griffith, O Tom Denmead
Faculty of Science - Papers (Archive)
The Great Barrier Reef World Heritage Area contains highly sensitive ecosystems that are threatened by the effects of anthropogenic activity including eutrophication. The nearby sugarcane plantations of tropical north Queensland are fertilised annually and there has been ongoing concern about the magnitude of the loss of applied nitrogen to the environment. Previous studies have considered the potential of rainwater run-off to deposit reactive nitrogen species into rivers and ultimately into the Great Barrier Reef Lagoon, but have neglected the possibility of transport via the atmosphere. This paper reports the results of a modelling study commissioned by Australia’s National Heritage Trust …
Synthesis And Preliminary Evaluation Of Amiloride Analogs As Inhibitors Of The Urokinase-Type Plasminogen Activator (Upa), Hayden Matthews, Marie Ranson, Joel Tyndall, Michael J. Kelso
Synthesis And Preliminary Evaluation Of Amiloride Analogs As Inhibitors Of The Urokinase-Type Plasminogen Activator (Upa), Hayden Matthews, Marie Ranson, Joel Tyndall, Michael J. Kelso
Faculty of Science - Papers (Archive)
A known side-activity of the oral potassium-sparing diuretic drug amiloride is inhibition of the enzyme urokinase-type plasminogen activator (uPA, Ki = 7 mu M), a promising anticancer target. Several studies have demonstrated significant antitumor/metastasis properties for amiloride in animal cancer models and it would appear that these arise, at least in part, through inhibition of uPA. Selective optimization of amiloride’s structure for more potent inhibition of uPA and loss of diuretic effects would thus appear as an attractive strategy towards novel anticancer agents. The following report is a preliminary structure-activity exploration of amiloride analogs as inhibitors of uPA. A …
Climate-Induced Reaction Norms For Life-History Traits In Pythons, Beata Ujvari, Richard Shine, L Luiselli, Thomas R. Madsen
Climate-Induced Reaction Norms For Life-History Traits In Pythons, Beata Ujvari, Richard Shine, L Luiselli, Thomas R. Madsen
Faculty of Science - Papers (Archive)
Climate change modelers predict increasingly frequent ''extreme events,'' so it is critical to quantify whether organismal responses (such as reproductive output) measured over the range of usual climatic conditions can predict responses under more extreme conditions. In a 20-year field study on water pythons (Liasis fuscus), we quantified the effects of climatically driven annual variation in food supply on demographic traits of female pythons (feeding rate, body size, body mass, and reproductive output). Reaction norms linking food supply to feeding rates and residual body mass were broadly linear, whereas norms linking food supply to female body size became curvilinear when …
Trial By Fire: Natural Hazards, Mixed-Methods And Cultural Research, Christine Eriksen, Nicholas J. Gill, Ross A. Bradstock
Trial By Fire: Natural Hazards, Mixed-Methods And Cultural Research, Christine Eriksen, Nicholas J. Gill, Ross A. Bradstock
Faculty of Science - Papers (Archive)
This paper considers the issues of research 'relevance' and 'use' to reflect upon a cultural geography research project on bushfire that did not begin with any specific aim of being useful to policy makers but which has garnered considerable and ongoing interest from a broad audience. It provides an example of how the integration of quantitative and qualitative research methods and data can enhance research into cultural aspects of natural hazards whilst simultaneously playing a key role in ensuring that the research results are of interest to a wide range of groups. Using a mixed-methods research approach was found to …
The Potential Demise Of A Population Of Adders (Vipera Berus) In Smygehuk, Sweden, Thomas Madsen, Beata Ujvari
The Potential Demise Of A Population Of Adders (Vipera Berus) In Smygehuk, Sweden, Thomas Madsen, Beata Ujvari
Faculty of Science - Papers (Archive)
In 1999 and 2004, we published reports on how the introduction of 20 males into a severely inbred and isolated population of Adders (Vipera berus) halted its decline towards extinction. The introduction significantly enhanced the population's genetic variability, which resulted in a dramatic increase in offspring viability and a rapid increase in numbers. Unfortunately, recently a new and unprecedented development is threatening the population's future survival. In 2004 permission was granted by the Swedish Nature Conservation Agency of the County Administrative Board to build a house and an adjacent 1 m tall brick wall, right across the habitat occupied by …