Social and Behavioral Sciences Commons^™

Cosmogenic 3he And 21ne Surface Exposure Dating Of Young Basalts From Southern Mendoza, Argentina, Venera R. Espanon, Masahiko Honda, Allan R. Chivas

Faculty of Science, Medicine and Health - Papers: part A

Southern Mendoza, Argentina, is characterised by abundant Pleistocene to Holocene volcanism associated with back-arc magmatism, influenced by the subducting Nazca plate. Age determinations in this volcanic area have been improved during the last 5 years. However, there are some volcanic features especially in the Payunia Volcanic Field (PVF) which suggest fairly recent eruptions and which have not been chronologically determined. Recent studies on the Llancanelo Volcanic Field (LLVF) and PVF have determined volcanic activity mainly using K-Ar and 40Ar/39Ar as well as cosmogenic 3He. However, K-Ar and 40Ar/39Ar fail to produce reliable ages in Holocene basaltic flows. To better constrain …

Earth Is (Mostly) Flat: Apportionment Of The Flux Of Continental Sediment Over Millennial Time Scales: Reply, J K. Willenbring, Alexandru T. Codilean, B Mcelroy

Faculty of Science, Medicine and Health - Papers: part A

We thank Warrick et al. (2014) for the Comment on our recent synthesis of 10Be-derived denudation rates (Willenbring et al., 2013), in which we suggested that gently sloping areas, representing ∼90% of the Earth’s land surface, have sufficiently high rates of denudation to produce a majority of mass fluxes to the world’s ocean.

First, Warrick et al. take issue with labeling our global cosmogenic nuclide denudation fluxes “sediment” and with the inferred comparisons to other sediment yield apportionment studies. We apologize for instances of unclear wording related to the terms: sediment production, sediment to the oceans, and mass flux. Unlike …

Late-Holocene Climatic Variability Indicated By Three Natural Archives In Arid Southern Australia, Luke A. Gliganic, Timothy J. Cohen, Jan-Hendrik May, John D. Jansen, Gerald C. Nanson, Anthony Dosseto, Joshua R. Larsen, Maxime Aubert

Faculty of Science, Medicine and Health - Papers: part A

Three terrestrial climate proxies are used to investigate the evolution of Holocene palaeoenvironments in southern central Australia, all of which present a coherent record of palaeohydrology. Single-grain optically stimulated luminescence from sediments supplemented by 14C from charcoal and lacustrine shells was obtained to date shoreline deposits (Lake Callabonna) and the adjacent Mt Chambers Creek alluvial fan. Our findings are complemented by a U/Th-based record of speleothem growth in the Mt Chambers Creek catchment, which we interpret to reflect increased precipitation. Together, these archives shed light on the timing of, and possible sources of water for, Holocene pluvial intervals. We identified …

Distributed Leadership: Building Capacity For Interdisciplinary Climate Change Teaching At Four Universities, Aidan Davison, Paul Brown, Emma Pharo, Kristin Warr, Helen Mcgregor, Sarah Terkes, Davina Boyd, Pamela Abuodha

Faculty of Science, Medicine and Health - Papers: part A

Purpose - Interdisciplinary approaches to climate change teaching are well justified and arise from the complexity of climate change challenges and the integrated problem-solving responses they demand. These approaches require academic teachers to collaborate across disciplines. Yet, the fragmentation typical of universities impedes collaborative teaching practice. This paper aims to report on the outcomes of a distributed leadership project in four Australian universities aimed at enhancing interdisciplinary climate change teaching. Design/methodology/approach - Communities of teaching practice were established at four Australian universities with participants drawn from a wide range of disciplines. The establishment and operation of these communities relied on …

Factors Governing The Rejection Of Trace Organic Contaminants By Nanofiltration And Reverse Osmosis Membranes, Hai Q. Dang, Long D. Nghiem, William E. Price

Faculty of Science, Medicine and Health - Papers: part A

This study aimed to elucidate key factors governing the rejection of trace organic contaminants (TrOCs) by nanofiltration (NF) and reverse osmosis (RO) membranes. The rejection of 16 selected hydrophilic and hydrophobic TrOCs by an NF and an RO membranes was evaluated at different solution pH values using a cross-flow NF/RO filtration system. An analytical technique consisting of solid phase extraction followed by gas chromatography and mass spectrometry detection was used for the analysis of the TrOCs. In general, rejection increased in the order of decreasing membrane permeability, increasing molecular weight (or equivalent molecular width) of the TrOCs, and increasing hydrophilicity. …

Environmental Character And History Of The Lake Eyre Basin, One Seventh Of The Australian Continent, Anna Habeck-Fardy, Gerald C. Nanson

Faculty of Science, Medicine and Health - Papers: part A

One of the world's largest internally drained (endorheic) basins, the 1.14 million km2 Lake Eyre (hydrological) Basin (LEB), covers nearly 15% of the Australian continent. Palaeoclimatic and associated flow regime variations are recorded in an archive of fluvial, aeolian and lacustrine sediments that are particularly accessible for deposits from the past ~ 300 ka, and are especially relevant for the past ~ 50 ka during which humans have inhabited Australia. Due to its great size, economic resources and diverse latitudinal extent, it has for over six decades been the focus of environmental, scientific and resource-based studies across numerous disciplines. With …

Critical Cartography And The Use Of New Technologies For Conserving The Australian Coastline: A Case Study From Lord Howe Island, Sarah Hamylton

Faculty of Science, Medicine and Health - Papers: part A

Maps exert power. In this paper I explore the power of maps in relation to the technical methods employed and the political context of their production. The internal power of maps is realised in the actions taken by cartographers themselves when making maps, while the external power of maps is both realised by the patrons of cartography and wielded through the use of cartographic products as agents for natural resource management, in particular for defining conservation strategies. An Australian case study of coastal mapping is used to examine the methods employed and motivation behind map production through a series of …

Synthesis, Properties, Water And Solute Permeability Of Mwnt Buckypapers, Md. Harun-Or Rashid, Son Q. T Pham, Luke J. Sweetman, Leighton J. Alcock, Anthony Wise, Long D. Nghiem, Gerry Triani, Marc In Het Panhuis, Stephen F. Ralph

Faculty of Science, Medicine and Health - Papers: part A

High power tip sonication was used to prepare dispersions containing multi-walled carbon nanotubes (MWNTs), or multi-walled carbon nanotubes functionalised with carboxylic acid groups (MWNT-COOH) or amine groups (MWNT-NH2). The dispersion of carbon nanotubes was facilitated by the presence of a surfactant (Triton X-100) or various macrocyclic ligands (derivatised porphyrin, phthalocyanine or calixarene) in the solution. Vacuum filtration of the dispersions afforded self-supporting membranes known as buckypapers. Microanalysis provided evidence for retention of the surfactant or macrocyclic ligands in the buckypapers, which were also characterised by measurement of their electrical conductivities (24±16 to 58±11 S/cm), contact angles (28±1° to 55±10°) and …

Discordance Between Cosmogenic Nuclide Concentrations In Amalgamated Sands And Individual Fluvial Pebbles In An Arid Zone Catchment, Alexandru T. Codilean, Cassandra R. Fenton, Derek Fabel, Paul Bishop, Sheng Xu

Faculty of Science, Medicine and Health - Papers: part A

Based on cosmogenic 10Be and 26Al analyses in 15 individual detrital quartz pebbles (16–21 mm) and cosmogenic 10Be in amalgamated medium sand (0.25–0.50 mm), all collected from the outlet of the upper Gaub River catchment in Namibia, quartz pebbles yield a substantially lower average denudation rate than those yielded by the amalgamated sand sample. 10Be and 26Al concentrations in the 15 individual pebbles span nearly two orders of magnitude (0.22 ± 0.01 to 20.74 ± 0.52 × 10610Be atoms g−1 and 1.35 ± 0.09 to 72.76 ± 2.04 × 10626Al atoms g−1, respectively) and yield average denudation rates of ∼0.7 …

Using Communities Of Practice To Enhance Interdisciplinary Teaching: Lessons From Four Australian Institutions, Emma Pharo, Aidan Davison, Helen Mcgregor, Kristin Warr, Paul Brown

Faculty of Science, Medicine and Health - Papers: part A

We report on the establishment of communities of practice at four Australian institutions and evaluate their effectiveness and durability as a means of building staff and institutional capacity for interdisciplinary teaching. A community of practice approach is a potentially valuable methodology for overcoming dynamics of fragmentation, isolation and competition within universities. The communities we established were anchored by a shared focus on the topic of climate change and they worked collaboratively to build relationships of trust and reciprocity between teachers in a wide range of disciplines. The aim of each community was to improve the teaching of climate change through …

Rapid Profiling Of Laser-Induced Photochemistry In Single Microdroplets Using Mass Spectrometry, Phillip J. Tracey, Bartholomew S. Vaughn, Brendon J. Roberts, Berwyck L. J Poad, Adam J. Trevitt

Faculty of Science, Medicine and Health - Papers: part A

Rapid assessment of laser-induced photochemistry in single microdroplets is afforded by on-demand microdroplet generation coupled to a commercial ion-trap mass spectrometer. Single microdroplets (diameter 50 μm, 65 pL) fall on a steel needle held at +2 kV where they subsequently form a spray that is directed toward the inlet of an ion-trap mass spectrometer. It is demonstrated that single microdroplet mass spectra are recordable, one at a time, for methanol droplets containing 100 μM 4-iodoaniline. Extending on this, to probe laser-initiated photochemistry in single picoliter volumes, a UV laser pulse is timed to intercept the droplet before hitting the needle. …

Will Coral Islands Maintain Their Growth Over The Next Century? A Deterministic Model Of Sediment Availability At Lady Elliot Island, Great Barrier Reef, Sarah Hamylton

Faculty of Science, Medicine and Health - Papers: part A

A geomorphic assessment of reef system calcification is conducted for past (3200 Ka to present), present and future (2010-2100) time periods. Reef platform sediment production is estimated at 569 m3 yr−1 using rate laws that express gross community carbonate production as a function of seawater aragonite saturation, community composition and rugosity and incorporating estimates of carbonate removal from the reef system. Key carbonate producers including hard coral, crustose coralline algae and Halimeda are mapped accurately (mean R2 = 0.81). Community net production estimates correspond closely to independent census-based estimates made in-situ (R2 = 0.86). Reef-scale outputs are compared with historic …

Annual Distributions And Sources Of Arctic Aerosol Components, Aerosol Optical Depth, And Aerosol Absorption, Thomas J. Breider, Loretta J. Mickley, Daniel Jacob, Qiaoqiao Wang, Jenny A. Fisher, Rachel Y.-W Chang, Becky Alexander

Faculty of Science, Medicine and Health - Papers: part A

Radiative forcing by aerosols and tropospheric ozone could play a significant role in recent Arctic warming. These species are in general poorly accounted for in climate models. We use the GEOS-Chem global chemical transport model to construct a 3-D representation of Arctic aerosols and ozone that is consistent with observations and can be used in climate simulations. We focus on 2008, when extensive observations were made from different platforms as part of the International Polar Year. Comparison to aircraft, surface, and ship cruise observations suggests that GEOS-Chem provides in general a successful year-round simulation of Arctic black carbon (BC), organic …

The Impact Of Spectral Resolution On Satellite Retrieval Accuracy Of Co2 And Ch4, A Galli, Sandrine Guerlet, Andre Butz, Ilse Aben, H Suto, A Kuze, Nicholas Deutscher, Justus Notholt, Debra Wunch, Paul Wennberg, D W. T Griffith, Otto Hasekamp, J Landgraf

Faculty of Science, Medicine and Health - Papers: part A

The Fourier-transform spectrometer on board the Japanese GOSAT (Greenhouse gases Observing SATellite) satellite offers an excellent opportunity to study the impact of instrument resolution on retrieval accuracy of CO2 and CH4. This is relevant to further improve retrieval accuracy and to optimize the cost-benefit ratio of future satellite missions for the remote sensing of greenhouse gases. To address this question, we degrade GOSAT measurements with a spectral resolution of ≈ 0.24 cm−1 step by step to a resolution of 1.5 cm−1. We examine the results by comparing relative differences at various resolutions, by referring the results to reference values from …

Isomer-Specific Product Detection Of Gas-Phase Xylyl Radical Rearrangement And Decomposition Using Vuv Synchrotron Photoionization, Patrick Hemberger, Adam J. Trevitt, Thomas Gerber, Edward Ross, Gabriel Da Silva

Faculty of Science, Medicine and Health - Papers: part A

Xylyl radicals are intermediates in combustion processes since their parent molecules, xylenes, are present as fuel additives. In this study we report on the photoelectron spectra of the three isomeric xylyl radicals and the subsequent decomposition reactions of the o-xylyl radical, generated in a tubular reactor and probed by mass selected threshold photoelectron spectroscopy and VUV synchrotron radiation. Franck-Condon simulations are applied to augment the assignment of elusive species. Below 1000 K, o-xylyl radicals decompose by hydrogen atom loss to form closed-shell o-xylylene, which equilibrates with benzocyclobutene. At higher temperatures relevant to combustion engines, o-xylylene generates styrene in a multistep …

Simultaneous Nitrification/Denitrification And Trace Organic Contaminant (Troc) Removal By An Anoxic-Aerobic Membrane Bioreactor (Mbr), Hop Phan, Faisal Ibney Hai, Jinguo Kang, Hoa Dam, Ren Zhang, William Price, Andreas Broeckmann, Long Nghiem

Faculty of Science, Medicine and Health - Papers: part A

Simultaneous nitrification/denitrification and trace organic contaminant (TrOC) removal during wastewater treatment by an integrated anoxic-aerobic MBR was examined. A set of 30 compounds was selected to represent TrOCs that occur ubiquitously in domestic wastewater. The system achieved over 95% total organic carbon (TOC) and over 80% total nitrogen (TN) removal. In addition, 21 of the 30 TrOCs investigated here were removed by over 90%. Low oxidation reduction potential (i.e., anoxic/anaerobic) regimes were conducive to moderate to high (50% to 90%) removal of nine TrOCs. These included four pharmaceuticals and personal care products (primidone, metronidazole, triclosan, and amitriptyline), one steroid hormone …

Late Pleistocene Glaciation Of The Kodar Mountains, South-Central Siberia, Constrained By Be-10 Exposure Dating, Martin Margold, John Jansen, Artem L. Gurinov, Natalya V. Reznichenko, Alexandru T. Codilean, David Fink

Faculty of Science, Medicine and Health - Papers: part A

Geophysical Research Abstracts of EGU General Assembly 2014, held 27 April - 2 May, 2014 in Vienna, Austria.

Constraining The Timescales Of Sediment Transport In Lowland Regions Using U-Series Isotopes And Morphometric Analysis, Ashley Martin, Anthony Dosseto, Allan Chivas, Jan-Hendrik May

Faculty of Science, Medicine and Health - Papers: part A

Geophysical Research Abstracts of EGU General Assembly 2014, held 27 April - 2 May, 2014 in Vienna, Austria.

Tectono-Stratigraphy And Structure Of The Northwestern Zagros Collision Zone Across The Iraq-Iran Border, Sarmad A. Ali, Mohammad Mohajjel, Khalid Aswad, Sabah Ismail, Solomon Buckman, Brian Jones

Faculty of Science, Medicine and Health - Papers: part A

Tectono-stratigraphic units within the Zagros Orogen in northeast Iraq (foreland) and northwest Iran (hinterland) are correlated to provide an integrated map along the collision zone. Access to this part of Iraq during the past four decades has been limited due to geopolitical situation. Structural cross-sections across the Zagros Suture Zone in this area reveal the relationships between the tectonic terranes of various ages and different origins. Terranes of oceanic affinity have accreted onto the Arabian plate during collision-accretion events that started in the Late Cretaceous. The collision resulted in closure of the Neotethys Ocean and the construction of a structurally …

Trace Elements And Metal Pollution In Aerosols At An Alpine Site, New Zealand: Sources, Concentrations And Implications, Samuel K. Marx, Karen S. Lavin, Kimberly J. Hageman, Balz S. Kamber, Tadhg O'Loingsigh, Grant H. Mctainsh

Faculty of Science, Medicine and Health - Papers: part A

Atmospheric aerosol samples were collected at a remote site in New Zealand's Southern Alps. Collected samples were found to be a mixture of New Zealand and Australian sourced sediment, using their trace element signatures. Aerosol concentrations and the relative contribution of different sources was found to be a function of specific air-mass trajectories influencing the study site, dust entrainment rates in source areas and rainfall. Results show that Australian dust is a major source of particulate matter in New Zealand, particularly in remote alpine locations; however, locally derived dust is also important. Metal pollutants, including Pb, Cu and Sn, were …

Photodissociation Of Tempo-Modified Peptides: New Approaches To Radical-Directed Dissociation Of Biomolecules, David L. Marshall, Christopher S. Hansen, Adam J. Trevitt, Han Bin Oh, Stephen J. Blanksby

Faculty of Science, Medicine and Health - Papers: part A

Radical-directed dissociation of gas phase ions is emerging as a powerful and complementary alternative to traditional tandem mass spectrometric techniques for biomolecular structural analysis. Previous studies have identified that coupling of 2-[(2,2,6,6-tetramethylpiperidin-1-oxyl)methyl]benzoic acid (TEMPO-Bz) to the N-terminus of a peptide introduces a labile oxygen–carbon bond that can be selectively activated upon collisional activation to produce a radical ion. Here we demonstrate that structurally-defined peptide radical ions can also be generated upon UV laser photodissociation of the same TEMPO-Bz derivatives in a linear ion-trap mass spectrometer. When subjected to further mass spectrometric analyses, the radical ions formed by a single laser …

Unprecedented Wind Erosion And Perturbation Of Surface Geochemistry Marks The Anthropocene In Australia, Samuel Marx, Hamish Mcgowan, Balz Kamber, Jon M. Knight, John Denholm, Atun Zawadzki

Faculty of Science, Medicine and Health - Papers: part A

[1] Australia, the last continent to undergo industrial development, is an ideal environment in which to quantify the magnitude of human-induced environmental change during the Anthropocene because its entire agricultural and industrial history has occurred within this period. Analysis of an alpine peat mire showed that rapid industrial and agricultural development (both pastoral and cropping) over the past 200 years has resulted in significant environmental change in Australia. Beginning in the 1880s, rates of wind erosion and metal enrichment were up to 10 and 30 times that of background natural conditions, respectively. Increased dust deposition and an expansion in dust …

Response To Sheppard, C. Atoll Rim Expansion Or Erosion In Diego Garcia Atoll, Indian Ocean? Comment On Hamylton, S.; East, H. A Geospatial Appraisal Of Ecological And Geomorphic Change On Diego Garcia Atoll, Chagos Islands (British Indian Ocean Territory). Remote Sens. 2012, 4, 3444-3461, Sarah Hamylton, Holly East

Faculty of Science, Medicine and Health - Papers: part A

We welcome Sheppard's comments on our recent assessment of both ecological and geomorphic change at Diego Garcia Atoll in the central Indian Ocean [1]. Whilst our assessment incorporated numerous aspects of change, including movements of the lagoon rim shorelines, changes in the terrestrial vegetation on the lagoon rim and amendments to the bathymetry of the lagoon basin through dredging activities [2], this comment solely addresses the estimates of shoreline change. Here we make some brief remarks relating to this shoreline assessment of Diego Garcia and elaborate on some of the complexities of the geomorphic processes that underpin shoreline dynamics. These …

Interdependency Of Tropical Marine Ecosystems In Response To Climate Change, Megan I. Saunders, Javier X. Leon, David P. Callaghan, Chris M. Roelfsema, Sarah Hamylton, Christopher J. Brown, Tom Baldock, Aliasghar Golshani, Stuart R. Phinn, Catherine E. Lovelock, Ove Hoegh-Guldberg, Colin Woodroffe, Peter J. Mumby

Faculty of Science, Medicine and Health - Papers: part A

Ecosystems are linked within landscapes by the physical and biological processes they mediate. In such connected landscapes, the response of one ecosystem to climate change could have profound consequences for neighbouring systems. Here, we report the first quantitative predictions of interdependencies between ecosystems in response to climate change. In shallow tropical marine ecosystems, coral reefs shelter lagoons from incoming waves, allowing seagrass meadows to thrive. Deepening water over coral reefs from sea-level rise results in larger, more energetic waves traversing the reef into the lagoon1, 2, potentially generating hostile conditions for seagrass. However, growth of coral reef such that the …

Inner Gorges Cut By Subglacial Meltwater During Fennoscandian Ice Sheet Decay, John Jansen, Alexandru T. Codilean, Arjen P. Stroeven, Derek Fabel, C Hattestrand, Johan Kleman, J M. Harbor, J Heymann, Peter Kubik, S Xu

Faculty of Science, Medicine and Health - Papers: part A

The century-long debate over the origins of inner gorges that were repeatedly covered by Quaternary glaciers hinges upon whether the gorges are fluvial forms eroded by subaerial rivers, or subglacial forms cut beneath ice. Here we apply cosmogenic nuclide exposure dating to seven inner gorges along ~500 km of the former Fennoscandian ice sheet margin in combination with a new deglaciation map. We show that the timing of exposure matches the advent of ice-free conditions, strongly suggesting that gorges were cut by channelized subglacial meltwater while simultaneously being shielded from cosmic rays by overlying ice. Given the exceptional hydraulic efficiency …

Preliminary Results Of Dietary And Environmental Reconstructions Of Early To Middle Pleistocene Stegodons From The So'a Basin Of Flores, Indonesia, Based On Enamel Stable Isotope Records, Mika Puspaningrum, Gerrit Van Den Bergh, Allan Chivas, Erick Setiabudi, Iwan Kurniawan, Adam Brumm, Thomas Sutikna

Faculty of Science, Medicine and Health - Papers: part A

Abstract of a paper that was presented at the VIth International Conference on Mammoths and their Relatives, Greece, 5-12 May 2014.

Himalayan Denudation: Noise Vs. Time, Oliver Korup, Henry Munack, Alexandru T. Codilean, Jan-Henrik Blothe, Peter Kubik

Faculty of Science, Medicine and Health - Papers: part A

Geophysical Research Abstracts of EGU General Assembly 2014, held 27 April - 2 May, 2014 in Vienna, Austria.