Social and Behavioral Sciences Commons^™

Spatial Queries In The Presence Of Obstacles, Jun Zhang, Dimitris Papadias, Kyriakos Mouratidis, Manli Zhu

Kyriakos MOURATIDIS

Despite the existence of obstacles in many database applications, traditional spatial query processing utilizes the Euclidean distance metric assuming that points in space are directly reachable. In this paper, we study spatial queries in the presence of obstacles, where the obstructed distance between two points is defined as the length of the shortest path that connects them without crossing any obstacles. We propose efficient algorithms for the most important query types, namely, range search, nearest neighbors, e-distance joins and closest pairs, considering that both data objects and obstacles are indexed by R-trees. The effectiveness of the proposed solutions is verified …

Continuous Medoid Queries Over Moving Objects, Stavros Papadopoulos, Dimitris Sacharidis, Kyriakos Mouratidis

Kyriakos MOURATIDIS

In the k-medoid problem, given a dataset P, we are asked to choose kpoints in P as the medoids. The optimal medoid set minimizes the average Euclidean distance between the points in P and their closest medoid. Finding the optimal k medoids is NP hard, and existing algorithms aim at approximate answers, i.e., they compute medoids that achieve a small, yet not minimal, average distance. Similarly in this paper, we also aim at approximate solutions. We consider, however, the continuous version of the problem, where the points in P move and our task is to maintain the medoid set on-the-fly …

Spatial Cloaking Revisited: Distinguishing Information Leakage From Anonymity, Kar Way Tan, Yimin Lin, Kyriakos Mouratidis

Kyriakos MOURATIDIS

Location-based services (LBS) are receiving increasing popularity as they provide convenience to mobile users with on-demand information. The use of these services, however, poses privacy issues as the user locations and queries are exposed to untrusted LBSs. Spatial cloaking techniques provide privacy in the form of k-anonymity; i.e., they guarantee that the (location of the) querying user u is indistinguishable from at least k-1 others, where k is a parameter specified by u at query time. To achieve this, they form a group of k users, including u, and forward their minimum bounding rectangle (termed anonymzing spatial region, ASR) to …

Medoid Queries In Large Spatial Databases, Kyriakos Mouratidis, Dimitris Papadias, Spiros Papadimitriou

Kyriakos MOURATIDIS

Assume that a franchise plans to open k branches in a city, so that the average distance from each residential block to the closest branch is minimized. This is an instance of the k-medoids problem, where residential blocks constitute the input dataset and the k branch locations correspond to the medoids. Since the problem is NP-hard, research has focused on approximate solutions. Despite an avalanche of methods for small and moderate size datasets, currently there exists no technique applicable to very large databases. In this paper, we provide efficient algorithms that utilize an existing data-partition index to achieve low CPU …

Mind Mapping As An Interactive Tool For Engaging Complex Geographical Issues, David Lloyd, William Boyd, Kristin Den Exter

Dr Kristin den Exter

Students and communities engaging with complex geographical issues require tools to assist them structure and contextualise data. This paper examines the use of mind mapping as a tool in geographical education. Case studies are presented from a sample of undergraduate and cross-cultural educational settings demonstrating the use of mind mapping in communication, analysis and problem solving. In critiquing this educational tool, we conclude that mind mapping is particularly effective with communities whose cultures are strong on visual communication but weaker on written communication and in cross-cultural situations where use of written English would disadvantage learners.

Proyecto De Investigación: La Primera Agencia Espacial Mexicana: La Comisión Nacional Del Espacio Exterior (1962-1977), J. R. Joel Flores-Mariscal

J. R. Joel Flores-Mariscal

No abstract provided.

Proyecto De Investigación: Los Mexicanos En Las Operaciones De La Segunda Guerra Mundial, J. R. Joel Flores-Mariscal

J. R. Joel Flores-Mariscal

No abstract provided.

Beyond Technology Readiness Levels For Software: U.S. Army Workshop Report, Stephen Blanchette Jr., Cecilia Albert, Suzanne Garcia-Miller

Stephen Blanchette Jr.

No abstract provided.

Leaching Mechanism Of Semiconducting Minerals, Fathi Habashi

Fathi Habashi

The mechanism of leaching of semiconducting minerals such as PbS, ZnS, UO2, etc., has been the subject of intensive speculation by hydrometallurgists in the early 1950s. The electrochemical mechanism proposed in 1970 by the author in volume 2 of his Principles of Extractive Metallurgy avoids the assumption of forming intermediate complexes that cannot be isolated or identified.

Changing Mutual Perception Of Television News Viewers And Program Makers In India- A Case Study Of Cnn-Ibn And Its Unique Initiative Of Citizen Journalism, Ratnesh Dwivedi Mr

Ratnesh Dwivedi

The Indian television system is one of the most extensive systems in the world. Terrestrial broadcasting, which has been the sole preserve of the government, provides television coverage to over 90% of India's 900 million people. By the end of 1996 nearly 50 million households had television sets. International satellite broadcasting, introduced in 1991, has swept across the country because of the rapid proliferation of small scale cable systems. By the end of 1996, Indians could view dozens of foreign and local channels and the competition for audiences and advertising revenues was one of the hottest in the world. In …

Closing The Gap Between The Industry And Higher Education Institutions- Case Examples From East African Region, Deogratias Harorimana Mr

Dr Deogratias Harorimana

Much complained about is the quality of graduates Universities put on the labour market. Less talked about however is why knowledge institutions seems to be bad knowledge managers. In this presentation I argue that DIRECT collaborative relationship between Industry,Governments and Higher Education Institutions is a per-requisite.Good relationship is key to building such a successful knowledge transfer strategies between Industries and Educational and Research Institutions. This paper explores what makes a good Knowledge Transfer Partnership Strategy and highlights some key lessons for businesses, Universities and Government bodies. This paper was a Key note presentation to the Annual International Conference on Building …

Is Necessity The Mother Of Innovation? The Adoption And Use Of Web Technologies Among Congressional Offices, Kevin Esterling, David Lazer, Michael Neblo

David Lazer

From first paragraph: Communication between legislator and constituents is fundamental to effective democratic representation, and devising the institutional means for citizen/legislator communication stands as one of the core and persistent problems in the practice of democracy. A legislator needs information about the preferences, ideals, norms, and beliefs of her constituents in order to do her job well. Similarly, citizens need information about the actions and decisions of their representative in order to maintain appropriate accountability. But as national problems become more complex, and as the political process grows more and more dominated by experts and organized groups, it is becoming …

Morphogrammatics Of Reflection, Rudolf Kaehr

Rudolf Kaehr

Turning back from the studies of morphogrammatics to some open questions of reflectional programming, the recountered problematics might be put into a different light and new methods of handling formal aspects of reflection and reflectionality shall be introduced. Albeit the use of light-metaphors, morphogrammatic reflection is not sketched along the paradigm of optical metaphors. Morphograms are presenting neither propositions nor perceptions able for mirroring (representation). Exercises in defining morphogrammatic retro-grade recursion and reflection schemata are continued from the paper “Sketches to Morphogrammatic Programming”.

Management Of Land Use Land Cover Through The Application Of Remote Sensing, Geographic Information Systems And Simulation, Praveen Jha

Praveen Jha Dr

Deforestation and degradation of forest areas, including those in the Protected Areas (PAs), are major concerns in India. There were 2 broad objectives of the study: the technological objective pertained to the development of state-of-art programs that could serve as Decision Support Systems while finalizing plans and policy interventions, while the other objective aimed at generating geo-spatial data in 2 PAs. A part of the Eastern Himalaya biodiversity hotspot, Manas Tiger Reserve (MTR), Assam, India having an area of 2837.12 sq km and an important part of Rajaji-Corbett Tiger Conservation Unit, Rajaji National Park (RNP), Uttarakhand, India, having an area …

A New Approach To Community Flood Education, Neil Dufty

Neil Dufty

No abstract provided.

The Metadata Challenge: Promoting Discovery, Access, And Usability For Online Books, John Mark Ockerbloom

John Mark Ockerbloom

With millions of books, serials, and other documents now digitized, rich troves of information and culture can now be made available to anyone in the world with an Internet connection. But these riches are worthless if they cannot be found, accessed, and effectively used by the readers who need them. The key to unlock these treasures is metadata. Networked computing enables techniques for making metadata more effective than ever; yet in practice, online collections all too often either do not have or do not take full advantage of the best metadata they could use.

There is much ongoing work harnessing …

Men In Black: The Impact Of New Contracts On Football Referees’ Performances, Babatunde Buraimo, Alex Bryson, Rob Simmons

Dr Babatunde Buraimo

No abstract provided.

Community Radio:History,Growth,Challenges And Current Status Of It With Special Reference To India, Ratnesh Dwivedi Mr

Ratnesh Dwivedi

Community radio is a type of radio service that caters to the interests of a certain area, broadcasting content that is popular to a local audience but which may often be overlooked by commercial or mass-media broadcasters. Modern-day community radio stations often serve their listeners by offering a variety of content that is not necessarily provided by the larger commercial radio stations. Community radio outlets may carry news and information programming geared toward the local area, particularly immigrant or minority groups that are poorly served by other major media outlets. Philosophically two distinct approaches to community radio can be discerned, …

Superoxide Does React With Peroxides: Direct Observation Of The Haber-Weiss Reaction In The Gas Phase, Stephen J. Blanksby, G. B. Ellison, V. M. Bierbaum, S. Kato

Stephen Blanksby

Reactions of superoxide with hydrogen peroxide and organic hydroperoxides are observed as efficient processes in the gas phase and yield products – including the ozonide anion – that are consistent with the one-electron reduction of the peroxide.

Investigation Of The Gas Phase Reactivity Of The 1-Adamantyl Radical Using A Distonic Radical Anion Approach, D. G. Harman, Stephen J. Blanksby

Stephen Blanksby

The gas phase reactions of the bridgehead 3-carboxylato-1-adamantyl radical anion were observed with a series of neutral reagents using a modified electrospray ionisation linear ion trap mass spectrometer. This distonic radical anion was observed to undergo processes suggestive of radical reactivity including radical-radical combination reactions, substitution reactions and addition to carbon-carbon double bonds. The rate constants for reactions of the 3-carboxylato-1-adamantyl radical anion with the following reagents were measured (in units 10 12 cm3 molecule 1 s 1): 18O2 (85±4), NO (38.4±0.4), I2 (50±50), Br2 (8±2), CH3SSCH3 (12±2), styrene (1.20±0.03), CHCl3 (H abstraction 0.41±0.06, Cl abstraction 0.65±0.1), CDCl3 (D abstraction …

The Lowest Singlet And Triplet States Of The Oxylallyl Diradical, David A. Hrovat, Stephen J. Blanksby, W C. Lineberger, Andrei Sanov, Luis Verlarde, Weston T. Borden, Daniel J. Goebbert, Adam J. Gianola, Xin Zhou, Stephanie M. Villano, Takatoshi Ichino

Stephen Blanksby

Photodetachment of the oxyallyl radical anion leads to formation of the oxyallyl diradical, an elusive transient molecule involved in many organic reactions. As described by W. C. Lineberger et al. in their Communication on page 8509 ff., the photoelectron spectrum reveals that the oxyallyl ground state is singlet and the lowest triplet state is only 55 meV higher in energy. The spectral profile indicates that the planar singlet state is the transition state for ringopening of cyclopropanone, whilst the CCC bending motion is activated upon photodetachment to the triplet state.

Online Ozonolysis Methods For The Determination Of Double Bond Position In Unsaturated Lipids, Michael Thomas, Todd W. Mitchell, Stephen J. Blanksby

Stephen Blanksby

Modern lipidomics relies heavily on mass spectrometry for the structural characterization and quantification of lipids of biological origins. Structural information is gained by tandem mass spectrometry (MS/MS) whereby lipid ions are fragmented to elucidate lipid class, fatty acid chain length, and degree of unsaturation. Unfortunately, however, in most cases double bond position cannot be assigned based on MS/MS data alone and thus significant structural diversity is hidden from such analyses. For this reason, we have developed two online methods for determining double bond position within unsaturated lipids; ozone electrospray ionization mass spectrometry (OzESI-MS) and ozone-induced dissociation (OzID). Both techniques utilize …

Prenylated Alkylbisphenols From Grevillea Whiteana, Stephen J. Blanksby, Hao Wang, Paul I. Forster, David N. Leach, Peter G. Waterman, Michael C. Thomas

Stephen Blanksby

Eleven new bisresorcinols including four mixtures each of two isomers and one resorcinol/phloroglucinol derivative, together with five known resorcinols have been isolated from the ethyl acetate extract of sterns of Grevillea whiteana. The new Compounds were identified as 4-(3-hydroxy-3-methylbutyl)grebustol-B (10a), 4'-(3-hydroxy-3-methylbutyl)grebustol-B (10b), 4-(4-hydroxy-3-methylbutyl)grebustol-B (2a) and 4'-(4-hydroxy-3-methylbutyl) rebustol-B (2b), 2,2-dimethyldihydropyrano grebustol-B (11a) and iso-2,2-dimethyldihydropyranogrebustol-B (11b), 2,2-dimethyl-3 xi-hydroxydihydropyranogrebustol-B (7a) and iso-2,2-dimethyl-3 xi-hydroxydihydropyranogrebustol-B (7b), 15-(2-(4-hydroxy-3-methylbutyl)-resorcinol-5-yl)-1-(phloroglucinolyl )-9(Z)pentadecen-one (whiteanone) (4), 5,5'-(hexadecan-diyl)bisresorcinol (12) and 2-methyl-5,5'-(8(Z)hexadecen-1,16-diyl)bisresorcinol (9). This is the first record of pyranobisresorcinols in the genus and the first report of a phloroglucinol terminal Phenolic unit in any Grevillea species.

Identification Of Abundant Alkyl Ether Glycerophospholipids In The Human Lens By Tandem Mass Spectrometry Techniques, Roger J. Truscott, Jane Deeley, Todd W. Mitchell, Michael Thomas, Stephen J. Blanksby

Stephen Blanksby

Previous studies have shown that the human lens contains glycerophospholipids with ether linkages. These lipids differ from conventional glycerophospholipids in that the sn-1 substituent is attached to the glycerol backbone via an 1-O-alkyl or an 1-O-alk-1'-enyl ether rather than an ester bond. The present investigation employed a combination of collision-induced dissociation (CID) and ozone-induced dissociation (OzID) to unambiguously distinguish such 1-O-alkyl and 1-O-alk-1'-enyl ethers. Using these methodologies the human lens was found to contain several abundant 1-O-alkyl glycerophos-phoethanolamines, including GPEtn(16:0e/9Z-18:1), GPEtn(11Z-18:1e/9Z-18:1), and GPEtn(18:0e/9Z-18:1), as well as a related series of unusual 1-O-alkyl glycerophosphoserines, including GPSer(16:0e/9Z-18:1), GPSer(11Z-18:1e/9Z-18:1), GPSer(18:0e/9Z-18:1) that to our …

Trapping Of A Tert-Adamantyl Peroxyl Radical In The Gas Phase, D. G. Harman, Stephen J. Blanksby

Stephen Blanksby

A bridgehead adamantyl peroxyl radical has been prepared and isolated in the gas phase by the reaction of a distonic radical anion with dioxygen in a quadrupole ion-trap mass spectrometer.

Fragmentation Pathways Of 2,3-Dimethyl-2,3-Dinitrobutane Cations In The Gas Phase, Martin Paine, Benjamin Kirk, Simon Ellis-Steinborner, Stephen J. Blanksby

Stephen Blanksby

2,3-Dimethyl-2,3-dinitrobutane (DMNB) is an explosive taggant added to plastic explosives during manufacture making them more susceptible to vapour-phase detection systems. In this study, the formation and detection of gas-phase [M+H](+), [M+Li](+), [M+NH4](+) and [M+Na](+) adducts of DMNB was achieved using electrospray ionisation on a triple quadrupole mass spectrometer. The [M+H](+) ion abundance was found to have a strong dependence on ion source temperature, decreasing markedly at source temperatures above 50 degrees C. In contrast, the [M+Na](+) ion demonstrated increasing ion abundance at source temperatures up to 105 degrees C. The relative susceptibility of DMNB adduct ions toward dissociation was investigated …

Ion-Molecule Reactions Of O,S-Dimethyl Methylphosphonothioate: Evidence For Intramolecular Sulfur Oxidation During Vx Perhydrolysis, Jilliarne Williams, Martin Paine, Stephen J. Blanksby, Michael L. Rogers, Andrew M. Mcanoy

Stephen Blanksby

The alkaline perhydrolysis of the nerve agent O-ethyl S-[2-(diisopropylamino)ethyl] methylphosphonothioate (VX) was investigated by studying the ion-molecule reactions of HOO- with O,S-dimethyl methylphosphonothioate in a modified linear ion-trap mass spectrometer. In addition to simple proton transfer, two other abundant product ions are observed at m/z 125 and 109 corresponding to the S-methyl methylphosphonothioate and methyl methylphosphonate anions, respectively. The structure of these product ions is demonstrated by a combination of collision-induced dissociation and isotope-labeling experiments that also provide evidence for their formation by nucleophilic reaction pathways, namely, (i) S(N)2 at carbon to yield the S-methyl methylphosphonothioate anion and (ii) nucleophilic …

Tandem Mass Spectrometry Of Deprotonated Iodothyronines, A. M. Couldwell, M. C. Thomas, Todd Mitchell, A. Hulbert, Stephen J. Blanksby

Stephen Blanksby

In order to assist with the development of more selective and sensitive methods for thyroid hormone analysis the [M-H]– anions of the iodothyronines; T4, T3, rT3, (3,5)-T2 and the non-iodinated thyronine (T0) have been generated by negative ion electrospray mass spectrometry. Tandem mass spectra of these ions were recorded on a triple quadrupole mass spectrometer and show a strong analogy with the fragmentation pathways of the parent compound, tyrosine. All iodothyronines also show significant abundances of the iodide anion in their tandem mass spectra, which represents an attractive target for MRM analysis, given that iodothyronines are the only iodine bearing …

A Comparison Of The Gas Phase Acidities Of Phospholipid Headgroups:Experimental And Computational Studies, M. C. Thomas, Todd Mitchell, Stephen J. Blanksby

Stephen Blanksby

Proton-bound dimers consisting of two glycerophospholipids with different headgroups were prepared using negative ion electrospray ionization and dissociated in a triple quadrupole mass spectrometer. Analysis of the tandem mass spectra of the dimers using the kinetic method provides, for the first time, an order of acidity for the phospholipid classes in the gas phase of PE < PA << PG < PS < PI. Hybrid density functional calculations on model phospholipids were used to predict the absolute deprotonation enthalpies of the phospholipid classes from isodesmic proton transfer reactions with phosphoric acid. The computational data largely support the experimental acidity trend, with the exception of …

Ion-Molecule Reactions Reveal Facile Radical Migration In Peptides, Stephen J. Blanksby, Benjamin N. Moore, Ryan R. Julian

Stephen Blanksby

Ion-molecule reactions between molecular oxygen and peptide radicals in the gas phase demonstrate that radical migration occurs easily within large biomolecules without addition of collisional activation energy.