Biological and Chemical Physics Commons^™

A Model For Orientation Effects In Electron‐Transfer Reactions, Paul Siders, Robert J. Cave, R.A. Marcus

All HMC Faculty Publications and Research

A method for solving the single‐particle Schrödinger equation with an oblate spheroidal potential of finite depth is presented. The wave functions are then used to calculate the matrix element T_BA which appears in theories of nonadiabatic electron transfer. The results illustrate the effects of mutual orientation and separation of the two centers on T_BA. Trends in these results are discussed in terms of geometrical and nodal structure effects. Analytical expressions related to T_BA for states of spherical wells are presented and used to analyze the nodal structure effects for T_BA for the spheroidal wells.

Alternating Current Studies And Kinetic Analysis Of Valinomycin Mediated Charge-Transport Through Lipid Bilayer Membranes, Kenneth Lee Cox

Dissertations and Theses

In this study we have investigated the frequency dependence of bilayer lipid membranes for a series of glycerylmonoolein/n-decane bilayers in various aqueous ionic solutions containing the ionophore valinomycin. Reliable values of membrane capacitance and conductance were obtained over the frequency range 0.2 - 200 KHz using an automatic balancing bridge under the control of a microprocessor unit. The admittance data was then normalized and curve-fitted to produce relaxation times and amplitudes from which the kinetic rate parameters, as deduced from a single slab dielectric membrane model, were calculated. These ac experimental rate constants were then compared with those obtained from …

The Effects On Plant Growth, W M. Porter, J. S. Yeates

Journal of the Department of Agriculture, Western Australia, Series 4

The level of acidity of a soil reflects its chemical and sometimes its biological condition. Changes in acidity mean changes in the availability to plants of some soil elements, and modifications to the biological processes in the soil.

Some elements become more available to plants in acis soils, and in some soils particular elements can reach toxic levels. Other elements can be effected in the opposite way: deficiencies can develop in acid conditions.

It is important to realise, however, that the chemical nature of all soils varies. Beccause of these variations, acidity can affect each soil differently and thus influence …

Atlas Of High Resolution Infrared Spectra Of Carbon Dioxide: February 1984 Edition, D. Chris Benner

Arts & Sciences Articles

Long-path, low-pressure laboratory absorption spectra of carbon dioxide i are presented in an atlas format for the spectral regions 1830 to 2100 cm" , 2395 to 2680 cm-I i , and 3140 to 3235 cm- . The data were recorded at 0.01 cm"I resolution and room temperature with the Fourier transform spectrometer in the McMath solar telescope complex of the National Solar Observatory at Kitt Peak. A list of positions and assignments is given for the 3336 lines observed. A total of 52 bands of 12C1602, 13C1602, 12C160180, 12C160170, and 13C160180 have been identified.