Atomic, Molecular and Optical Physics Commons^™

Speciation And Spectroscopy Of The Uranyl And Tetravalent Plutonium Nitrate Systems: Fundamental Studies And Applications To Used Fuel Reprocessing, Nicholas A. Smith

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation explores the use of UV-Visible spectroscopy and Time Resolved Laser Induced Fluorescence spectroscopy as near real time process monitors of uranium and plutonium concentrations in aqueous reprocessing trains. The molar absorptivities and linear ranges of these metals were investigated under total nitrate and acid concentrations similar to those found in current reprocessing systems. Concurrent to this, a new multiple wavelength monitor was derived that is capable of determining the total nitrate concentration spectroscopically. This method uses the uranium absorbance spectrum to calculate the nitrate concentration in solution. When used as part of an Advanced Safeguard suite, this technique …

Doppler-Broadening Of Light Nuclei Gamma-Ray Spectra, Melinda D. Whitfield

Masters Theses & Specialist Projects

Non-destructive methods of material interrogation are used to locate hidden explosives and thwart terrorism attempts. In one such method materials are bombarded with neutrons which react with the nuclei of the atoms within causing a de-excitation process emitting a gamma-ray. The spectrum displayed by the collection of these gamma-rays gives valuable information regarding the material’s elemental make-up. It has been hypothesized that gamma-rays from neutron-induced gamma-ray reactions on light elements with atomic numbers less than 20, including most of the gamma-rays of interest in explosives detection, are Doppler-broadened. This thesis focuses on the gamma ray spectra from the 4438 keV …

Color Changes In Stochastic Light Fields Propagating In Non-Kolmogorov Turbulence, Olga Korotkova, Elena Shchepakina

Physics Articles and Papers

The dependence of spectral shifts and switches in optical stochastic beams propagating through nonclassic turbulent medium on the slope of the power spectrum of fluctuations in the refractive index is revealed.

Time Dilation In Relativistic Two-Particle Interactions, B T. Shields, Rainer Grobe, E V. Stefanovich, M R. Ware, Qichang Su, M C. Morris

Faculty publications – Physics

We study the orbits of two interacting particles described by a fully relativistic classical mechanical Hamiltonian. We use two sets of initial conditions. In the first set (dynamics 1) the system's center of mass is at rest. In the second set (dynamics 2) the center of mass evolves with velocity V. If dynamics 1 is observed from a reference frame moving with velocity-V, the principle of relativity requires that all observables must be identical to those of dynamics 2 seen from the laboratory frame. Our numerical simulations demonstrate that kinematic Lorentz space-time transformations fail to transform particle observables between the …

Determination Of The Axial-Vector Weak Coupling Constant With Ultracold Neutrons., J. Liu, Michael P. Mendenhall, Anthony T. Holley, Henning O. Back, Thomas J. Bowles, Leah J. Broussard, Richard Carr, Stephen Clayton, Scott Currie, Bradley W. Filippone, A. Garcı́A, Peter Geltenbort, Kevin P. Hickerson, J. Todd Hoagland, Gary E. Hogan, B. Hona, Takeyasu M. Ito, Chenyu Liu, Mark Makela, Russell R. Mammei, J.W. Martin, Daneil Melconian, Charles L. Morris, Robert W. Pattie, A. Pérez Galván, Margaret L. Pitt, Bradley Plaster, John C. Ramsey, R. Rios, R. Russell, Andy Saunders, Susan J. Seestrom, Walter E. Sondheim, E. Tatar, Robert B. Vogelaar, Brittany Vorndick, Christopher Wrede, H. Yan, Albert R. Young

Robert W. Pattie Jr.

Spatio-Temporal Coupling Of Random Electromagnetic Pulses Interacting With Reflecting Gratings, Min Yao, Yangjian Cai, Olga Korotkova, Qiang Lin, Zhaoying Wang

Physics Articles and Papers

Matrix optics is applied to a class of random, in time and space, electromagnetic pulsed beam-like (REMPB) radiation interacting with linear optical elements. A 66 order matrix describing transformation of a six-dimensional state vector including four spatial and two temporal positions within the field is used to derive conditions for spatio-temporal coupling. An example is included which deals with a spatio-temporal coupling in a typical REMPB on reflection from a reflecting grating. Electromagnetic nature of such interaction is explored via considering dependence of the degree of polarization of the reflected REMPB on its source and on the structure of the …

Measurement And Modeling Of Infrared Nonlinear Absorption Coefficients And Laser-Induced Damage Thresholds In Ge And Gasb, Torrey J. Wagner, Matthew J. Bohn, Ronald A. Coutu Jr., L. P. Gonzales, J. M. Murray, K. L. Schepler, S. Guha

Faculty Publications

Using a simultaneous fitting technique to extract nonlinear absorption coefficients from data at two pulse widths, we measure two-photon and free-carrier absorption coefficients for Ge and GaSb at 2.05 and 2.5 µm for the first time, to our knowledge. Results agreed well with published theory. Single-shot damage thresholds were also measured at 2.5 µm and agreed well with modeled thresholds using experimentally determined parameters including nonlinear absorption coefficients and temperature dependent linear absorption. The damage threshold for a single-layer Al₂O₃ anti-reflective coating on Ge was 55% or 35% lower than the uncoated threshold for picosecond or nanosecond …

Two-Loop Soft Anomalous Dimensions For Single Top Quark Associated Production With A W- Or H-, Nikolaos Kidonakis

Faculty and Research Publications

I present results for the two-loop soft anomalous dimensions for associated production of a single top quark with a W boson or a charged Higgs boson. The calculation uses expressions for the massive cusp anomalous dimension, which are presented in different forms, and it allows soft-gluon resummation at next-to-next-to-leading-logarithm (NNLL) accuracy. From the NNLL resummed cross section I derive approximate NNLO cross sections for bg→tW- and bg→tH- at LHC energies of 7, 10, and 14 TeV.

Site-Specific Photocatalytic Splitting Of Methanol On Tio2(110), Chuanyao Zhou, Zefeng Ren, Shijing Tan, Zhibo Ma, Xinchun Mao, Dongxu Dai, Hongjun Fan, Xueming Yang, Jerry L. Larue, Russell Cooper, Alec M. Wodtke, Zhou Wang, Zhenyu Li, Bing Wang, Jinlong Yang, Jianguo Hou

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Clean hydrogen production is highly desirable for future energy needs, making the understanding of molecular-level phenomena underlying photocatalytic hydrogen production both fundamentally and practically important. Water splitting on pure TiO₂ is inefficient, however, adding sacrificial methanol could significantly enhance the photocatalyzed H₂ production. Therefore, understanding the photochemistry of methanol on TiO₂ at the molecular level could provide important insights to its photocatalytic activity. Here, we report the first clear evidence of photocatalyzed splitting of methanol on TiO₂ derived from time-dependent two-photon photoemission (TD-2PPE) results in combination with scanning tunneling microscopy (STM). STM tip induced molecular manipulation …

Space-Time Properties Of A Boson-Dressed Fermion For The Yukawa Model, R E. Wagner, M R. Ware, Q Su, Rainer Grobe

Faculty publications – Physics

We analyze the interaction of fermions and bosons through a one-dimensional Yukawa model. We numerically compute the energy eigenstates that represent a physical fermion, which is a superposition of bare fermionic and bosonic eigenstates of the uncoupled Hamiltonian. It turns out that even fast bare fermions require only low-momentum dressing bosons, which attach themselves to the fast fermion through quantum correlations. We compare the space-time evolution of a physical fermion with that of its bare counterpart and show the importance of using dressed observables. The time evolution of the center of mass as well as the wave packet's spatial width …

Frequency Dependence In The Initiation Of Laser-Induced Damage, Jeremy Gulley

Jeremy R. Gulley

Numerous studies have investigated the role of photoionization in ultrafast laser-induced damage of bulk dielectrics. This study examines the role of spectral width and instantaneous laser frequency in laser-induced damage using a frequency dependent multiphoton ionization model and numerical simulation of an 800 nm laser pulse propagating through fused silica. When the individual photon wavelengths are greater than 827 nm, an additional photon is required for photoionization, reducing the probability of the event by many orders of magnitude. Simulation results suggest that this frequency dependence may significantly affect the processes of laser-induced damage and filamentation.

Full Multiple Scattering Analysis Of Xanes At The Cd L 3- And O K- Edges In Cdo Films Combined With A Soft-X-Ray Emission Investigation, I. N. Demchenko, J. D. Denlinger, M. Chernyshova, K. M. Yu, D. T. Speaks, P. Olalde-Velasco, Oliver Hemmers, W. Walukiewicz, A. Derkachova, K. Lawniczak-Jablonska

Environmental Studies Faculty Publications

X-ray absorption near edge structure (XANES) at the cadmium L3 and oxygen K edges for CdO thin films grown by pulsed laser deposition method, is interpreted within the real-space multiple scattering formalism, FEFF code. The features in the experimental spectra are well reproduced by calculations for a cluster of about six and ten coordination shells around the absorber for L3 edge of Cd and K edge of O, respectively. The calculated projected electronic density of states is found to be in good agreement with unoccupied electronic states in experimental data and allows to conclude that the orbital character of the …

Absolute Ground-State Nitrogen Atom Density In A N2/Ch4 Late Afterglow: Talif Experiments And Modelling Studies, Et. Es-Sebbar, M.-C. Gazeau, Y. Benilan, A. Jolly, C D. Pintassilgo

Dr. Et-touhami Es-sebbar

Following a first study on a late afterglow in flowing pure nitrogen post discharge, we report new two-photon absorption laser-induced fluorescence (TALIF) measurements of the absolute ground-state atomic nitrogen density N(4S) and investigate the influence of methane introduced downstream from the discharge by varying the CH4 mixing ratio from 0% up to 50%. The N (4S) maximum density is about 2.2 × 1015 cm−3 in pure N2 for a residence time of 22 ms and does not change significantly for methane mixing ratio up to ~15%, while above, a drastic decrease is observed. The influence of the residence time has …

Vibrational Spectroscopic Study Of The 1,3,5,7-Cyclooctatetraene At High Static Pressures, Edward Romano

UNLV Theses, Dissertations, Professional Papers, and Capstones

1,3,5,7-cyclooctatetraene (COT) is a single-ringed hydrocarbon that has not been studied extensively under high static pressures. It was the intent of this study to reveal its high-pressure behavior through its vibrational spectra. To this end, its infrared spectra as a function of pressure were collected at the National Synchrotron Light Source (NSLS) U2A beamline, as well as its Raman spectra over pressure using a micro-Raman spectrometer.

The spectra show the typical stiffening of force constants with increasing pressure for most peaks, particularly those which would theoretically exhibit a mode-softening behavior under hypotheses of molecular planarization and aromatization. Additionally, the data …

Testing Quantum Randomness In Single-Photon Polarization Measurements With The Nist Test Suite, David Branning, Matthew Bermudez

Faculty Scholarship

A binary sequence was constructed from 1.7×10⁷ polarization measurements of single photons from a spontaneous parametric downconversion source, under pumping conditions similar to those used in optical quantum cryptography. To search for correlations in the polarization measurement outcomes, we subjected the sequence to a suite of tests developed at the National Institute of Standards and Technology (NIST) for the assessment of algorithmic random-number generators. The bias of the sequence was low enough to allow all fifteen tests to be applied directly to the polarization outcomes without using any numerical unbiasing procedures. No statistically significant deviations from randomness were observed, …

Time-Resolved Compton Scattering For A Model Fermion-Boson System, R E. Wagner, Rainer Grobe, Q Su

Faculty publications – Physics

We study the scattering of a boson with a fermion with full spatial and temporal resolution based on the one-dimensional Yukawa Hamiltonian. In quantum field theory this interaction is described by the annihilation and creation of bosons with intermediate virtual particle states. We show that this process can be modeled in the center-of-mass frame by a scattering potential, permitting us to interpret the absorption and re-emission processes in quantum mechanical terms of a characteristic force. This Compton force between the fermion and boson is repulsive for large distances and attractive for shorter spacings. We also examine the periodic dynamics of …

Effect Of Particle Properties And Light Polarization On The Plasmonic Resonances In Metallic Nanoparticles, U. Guler, R. Turan

U. Guler

The resonance behavior of localized surface plasmons in silver and gold nanoparticles was studied in the visible and near-infrared regions of the electromagnetic spectrum. Arrays of nano-sized gold (Au) and silver (Ag) particles with different properties were produced with electron-beam lithography technique over glass substrates. The effect of the particle size, shape variations, period, thickness, metal type, substrate type and sulfidation were studied via transmission and reflectance measurements. The results are compared with the theoretical calculations based on the DDA simulations performed by software developed in this study. We propose a new intensity modulation technique based on localized surface plasmons …

Experimental And Theoretical Studies On Nitrogen Plasma And Methane Photolysis: Implications For Laboratory Simulations Of Titan’S Atmosphere, M-C. Gazeau, Y. Benilan, E. Arzoumanian, Et. Es-Sebbar, A. Jolly

Dr. Et-touhami Es-sebbar

No abstract provided.

Spectroscopic Studies Applied To Uvis Observations Of Titan, Y. Benilan, F. Capalbo, Et. Es-Sebbar, N. Fray, A. Jolly, M-C. Gazeau, J-C. Guillemin, M. Schwell

Dr. Et-touhami Es-sebbar

No abstract provided.

Talif Investigation And Modelling Of The Absolute N(4s) Density In A N2-Ch4 Late Afterglow, C.D. Pintassilgo, Et. Es-Sebbar, Y. Benilan, M-C. Gazeau, A. Jolly

Dr. Et-touhami Es-sebbar

The purpose of the present work is the experimental and numerical study of the absolute ground-state nitrogen atoms density N(4S) in the late afterglow of a pure N2 flowing microwave discharge in which different amounts of CH4 have been injected at 25 cm downstream from the nitrogen discharge. The absolute N(4S) concentrations have been measured using Two-photon Absorption Laser-Induced Fluorescence (TALIF), while a detailed kinetic model has been developed to simulate both the discharge and the post-discharge regions. Theoretical predictions are then compared to experimental measurements.

Combined Experimental And Theoretical Studies On Methane Photolysis At 121.6 Nm And 248 Nm- Implications On A Program Of Laboratory Simulations Of Titan’S Atmosphere, C. Romanzin, E. Arzoumanian, Et. Es-Sebbar, A. Jolly, S. Perrier, M.-C. Gazeau, Y. Bénilan

Dr. Et-touhami Es-sebbar

Methane is, together with N2, the main precursor of Titan’s atmospheric chemistry. In our laboratory, we are currently developing a program of laboratory simulations of Titan’s atmosphere, where methane is intended to be dissociated by multiphotonic photolysis at 248 nm. A preliminary study has shown that multiphotonic absorption of methane at 248 nm is efficient and leads to the production of hydrocarbons such as C2H2 (Romanzin et al., 2008). Yet, at this wavelength, little is known about the branching ratios of the hydrocarbon radicals (CH3, CH2 and CH) and their following photochemistry. This paper thus aims at investigating methane photochemistry …

Spectroscopic Study Of Ultracold Rubidium Atoms In An Optical Dipole Force Trap, Eman Mohammed Ahmed

Physics Theses & Dissertations

The interaction of light with atoms and molecules is of fundamental interest in many branches of science. In atomic physics, this interaction can be used to cool and spatially confine (trap) atoms. These traps can be used as the starting point for other experiments, but the dynamics of the cooling and trapping processes is itself of interest. In order to better understand the physics of trapping atoms in an optical dipole force trap, we have conducted a series of spectroscopic measurements of ultracold rubidium atoms in such a trap. The trap was created at the focus of a Nd:YAG laser …

Communications: Chain And Double-Ring Polymeric Structures: Observation Of Alnh3n+1 − (N=4–8) And Al4h14 −, Xiang Li, Andrej Grubisic, Kit H. Bowen, Anil K. Kandalam, Boggavarapu Kiran, Gerd F. Gantefoer, Puru Jena

Physics & Engineering Faculty Publications

No abstract provided.

Temperature-Dependent Photoabsorption Cross-Section Of Cyano-Diacetylene In The Vacuum Uv, N. Fray, Y. Bénilan, M.-C. Gazeau, A. Jolly, M. Schwell, E. Arzoumanian, Et. Es-Sebbar, T. Ferradaz, J.- C. Guillemin

Dr. Et-touhami Es-sebbar

Using synchrotron radiation as a tunable VUV light source, we have measured, for the first time, the absolute photoabsorption cross sections of HC5N with a spectral resolution of 0.05 nm in the region between 80 and 205 nm from 233 to 298 K. The measured cross sections are used to predict the HC5N photodestruction rate in the solar system and to model a transmission spectrum in Titan's atmosphere. Comparing the latter with that acquired by the Ultraviolet Imaging Spectrograph on board the Cassini spacecraft, we have determined an upper limit of 2.7 × 10−5 on the HC5N abundance at 1100 …

Design And Construction Of A Thermal Diffusion Cloud Chamber, Alexander Donoghue

Physics

This paper will cover the theory behind a thermal diffusion cloud chamber. In addition to that it will cover the process, thought and material used to construct two different cloud chambers. It will also discuss the effects of materials used in each chamber on the working of the chamber.

Optical Coherence: Recreation Of The Experiment Of Thompson And Wolf, David Collins

Physics

The purpose of our experiment is to recreate the experiment done by Thompson and Wolf in 1957 on the measurement of optical coherence. What is novel about our approach is that it allows one to view the effects of source size on optical spatial coherence in real time.

Collisional Transfer Of Population And Orientation In Nak, Seth T. Ashman, C. M. Wolfe, J. Huennekens, B. Beser, J. Bai, A. M. Lyyra

Engineering & Physics Faculty Publications

We report current work to study transfer of population and orientation in collisions of NaK molecules with argon and potassium atoms using polarization labeling (PL) and laser- induced fluorescence (LIF) spectroscopy. In the PL experiment, a circularly polarized pump laser excites a specific NaK A1Σ +(v 0=16, J 0 ) ← X1Σ +(v 00=0, J 0 ± 1) transition, creating an orientation (non-uniform MJ0 level distribution) in both levels. The linearly polarized probe laser is scanned over various 31Π(v, J 0±1) ← A1Σ +(v 0=16, J 0 ) transitions. The probe laser passes through a crossed linear polarizer before detection, …

Experimental Studies Of The Nacs 53Π0 And 1(A)3Σ+ States, Seth T. Ashman, Brett Mcgeehan, Christopher Wolfe, Carl Faust, John Huennekens

Engineering & Physics Faculty Publications

We present experimental studies of the NaCs molecule that are currently underway in our laboratory. The opticaloptical double resonance method is used to obtain Doppler-free excitation spectra for several excited states. Selected data from the 53Π0 electronic state are used to obtain Rydberg-Klein-Rees (RKR) and Inverse Perturbation Approach (IPA) potential curves. We are also mapping the repulsive wall of the 1(a) 3Σ +potential using many resolved bound-free fluorescence spectra from individual ro-vibrational levels of the 53Π0 electronic state to the 1(a) 3Σ + state. Using the determined 53Π0 state potential we fit the repulsive wall of the 1(a) 3Σ + …

Partial Phonon Density Of States Of 57-Iron And 161-Dysprosium In Dyfe3 By Nuclear Resonant Inelastic X-Ray Scattering Under High Pressure, Elizabeth Anne Tanis

UNLV Theses, Dissertations, Professional Papers, and Capstones

The dual partial phonon density of states (DOS) from two different Mossbauer isotopes (161Dy and 57Fe) in the same material (DyFe3) was successfully measured using the nuclear resonant inelastic x-ray scattering (NRIXS) technique at high pressure. Nuclear inelastic scattering measurements yield an in-depth understanding of the element-specific dynamic properties. The Debye temperatures , the Lamb-Mossbauer factor, and the vibrational contributions to the Helmholtz free energy, specific heat , entropy and internal energy are calculated directly from the phonon density of states.

Exponential Enhancement Of Field-Induced Pair Creation From The Bosonic Vacuum, R E. Wagner, M R. Ware, Q Su, Rainer Grobe

Faculty publications – Physics

Using numerical solutions to quantum field theory, the creation of boson-antiboson pairs from the vacuum under a very strong localized external electric field is explored. The simulations reveal that the initial linear increase of the number of particles turns into an exponential growth. This self-amplification can be understood as the result of the interaction of the previously generated particles with the creation process. While the number of particles keeps increasing, the spatial shape of the (normalized) charge density of the created particles reaches a universal form that can be related to the bound states of the supercritical potential well. We …