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Synthesis, Characterization, And Magnetic Properties Of Nanosizedzn0.5co0.5erxfe2-Xo4 Prepared By Coprecipitation Method, Zouheir Bitar, Doaa El-Said Bakeer, Ramadan Awad

Turkish Journal of Physics

In the present work, the effect of doping zinc cobalt ferrite by different concentrations of Er3+ on structural, optical, and magnetic properties was studied. Nanosized Zn0.5Co0.5ErxFe2-xO4 (0 ≤ x ≤ 0.2) was synthesized by the coprecipitation method. XRD analysis confirmed the formation of one phase face FCC spinel structure belonging to the Fd3m space group. TEM exhibited that the particle size decreased with the increase of Er3+ content, which is in agreement with XRD results. Two significant absorption bands from FTIR spectra were observed between 400 and 600 cm-1. The band gap energy value obtained from UV-Vis increased with the …

Theoretical Studies Of Structural And Electronic Properties In Transition Metal Oxides, Tsezar F. Seman

Dissertations

The following studies are presented: theory of K-edge resonant inelastic x-ray scattering and its application for La_0.5Sr_1.5MnO₄, effects of rare earth ion size on the stability of the coherent Jahn-Teller distortions in undoped perovskite manganites, and symmetry-mode-based classical and quantum mechanical formalism of lattice dynamics.

The formula based on tight-binding approach for the calculation of K-edge resonant inelastic x-ray scattering (RIXS) spectrum for transition metal oxides is presented first, by extending the previous existing result to include explicit momentum dependence and a basis with multiple core-hole sites. This formula is applied to layered charge, …

Rare-Earth-Doped Materials With Application To Optical Signal Processing, Quantum Information Science, And Medical Imaging Technology, R L. Cone, C W. Thiel, Y Sun, Thomas Böttger, R M. Macfarlane

Physics and Astronomy

Unique spectroscopic properties of isolated rare earth ions in solids offer optical linewidths rivaling those of trapped single atoms and enable a variety of recent applications. We design rare-earth-doped crystals, ceramics, and fibers with persistent or transient “spectral hole” recording properties for applications including high-bandwidth optical signal processing where light and our solids replace the high-bandwidth portion of the electronics; quantum cryptography and information science including the goal of storage and recall of single photons; and medical imaging technology for the 700-900 nm therapeutic window. Ease of optically manipulating rare-earth ions in solids enables capturing complex spectral information in 105 …