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2005

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Articles 811 - 839 of 839

Full-Text Articles in Physics

Kinetic Structure Simulations Of Nematic Polymers In Plane Couette Cells. Ii: In-Plane Structure Transitions, M. Gregory Forest, Ruhai Zhou, Qi Wang Jan 2005

Kinetic Structure Simulations Of Nematic Polymers In Plane Couette Cells. Ii: In-Plane Structure Transitions, M. Gregory Forest, Ruhai Zhou, Qi Wang

Mathematics & Statistics Faculty Publications

Nematic, or liquid crystalline, polymer (LCP) composites are composed of large aspect ratio rod-like or platelet macromolecules. This class of nanocomposites exhibits tremendous potential for high performance material applications, ranging across mechanical, electrical, piezoelectric, thermal, and barrier properties. Fibers made from nematic polymers have set synthetic materials performance standards for decades. The current target is to engineer multifunctional films and molded parts, for which processing flows are shear-dominated. Nematic polymer films inherit anisotropy from collective orientational distributions of the molecular constituents and develop heterogeneity on length scales that are, as yet, not well understood and thereby uncontrollable. Rigid LCPs in …


Vortex-Phonon Interaction, E Kozik, Boris Svistunov Jan 2005

Vortex-Phonon Interaction, E Kozik, Boris Svistunov

Physics Department Faculty Publication Series

Kelvin waves—helical waves on quantized vortex lines—are the normal modes of vortices in a superfluid. At zero temperature, the only dissipative channel of vortex dynamics is phonon emission. Starting with the hydrodynamic action, we derive the Hamiltonian of vortex-phonon interaction, thereby reducing the problem of the interaction of Kelvin waves with sound to inelastic elementary excitation scattering. On the basis of this formalism, we calculate the rate of sound radiation by superfluid turbulence at zero temperature and estimate the value of short-wavelength cutoff of the turbulence spectrum.


Absence Of Fragmentation In Two-Dimensional Bose-Einstein Condensation, Jp Fernandez, Wj Mullin Jan 2005

Absence Of Fragmentation In Two-Dimensional Bose-Einstein Condensation, Jp Fernandez, Wj Mullin

Physics Department Faculty Publication Series

We investigate the possibility that the BEC-like phenomena recently detected on two-dimensional finite trapped systems consist of fragmented condensates. We derive and diagonalize the one-body density matrix of a two-dimensional isotropically trapped Bose gas at finite temperature. For the ideal gas, the procedure reproduces the exact harmonic-oscillator eigenfunctions and the Bose distribution. We use a new collocation-minimization method to study the interacting gas in the Hartree-Fock approximation and obtain a ground-state wavefunction and condensate fraction consistent with those obtained by other methods. The populations of the next few eigenstates increase at the expense of the ground state but continue to …


Thorium-Based Thin Films As Highly Reflective Mirrors In The Euv, David D. Allred, William R. Evans, Jed E. Johnson, Richard L. Sandberg, R. Steven Turley Jan 2005

Thorium-Based Thin Films As Highly Reflective Mirrors In The Euv, David D. Allred, William R. Evans, Jed E. Johnson, Richard L. Sandberg, R. Steven Turley

Faculty Publications

As applications for extreme ultraviolet (EUV) radiation have been identified, the demand for better optics has also increased. Thorium and thorium oxide thin films (19 to 61 nm thick) were RF-sputtered and characterized using atomic force microscopy (AFM), spectroscopic ellipsometry, low-angle x-ray diffraction (LAXRD), x-ray photoelectron spectroscopy (XPS), and x-ray absorption near edge structure (XANES) in order to assess their capability as EUV reflectors. Their reflectance and absorption at different energies were also measured and analyzed at the Advanced Light Source in Berkeley. The reflectance of oxidized thorium is reported between 2 and 32 nm at 5, 10, and 15 …


Levitation Using Microwave-Induced Plasmas, R. J. Exton, S. Popovic, G. C. Herring, M. Cooper Jan 2005

Levitation Using Microwave-Induced Plasmas, R. J. Exton, S. Popovic, G. C. Herring, M. Cooper

Physics Faculty Publications

The levitation of objects above a microwave horn is demonstrated. High-power microwave pulses generate a low-temperature, diffuse plasma on the surface of the horn window. The thermal effect of the surface plasma brings about a localized increase in the pressure and results in a vertical flow of air, thus levitating the object.


Long Distance Effects And Strangeness In The Nucleon, John Donoghue, Barry Holstein, Tobias Huber, Andreas Ross Jan 2005

Long Distance Effects And Strangeness In The Nucleon, John Donoghue, Barry Holstein, Tobias Huber, Andreas Ross

Physics Department Faculty Publication Series

We discuss the calculation of the strange magnetic radius of the proton in chiral perturbation theory. In particular, we investigate the low-energy component of the loop integrals involving kaons. We separate the chiral calculation into a low-energy part and a high-energy component through use of a momentum space separation scale. This separation shows that most of the chiral calculation comes from high energies where the effective field theory treatment is not valid. The resulting low-energy prediction is in better agreement with dispersive treatments. Finally, we briefly discuss magnetic moments and show how our techniques can help resolve an old puzzle …


Quantum Quasi-Paradoxes And Quantum Sorites Paradoxes, Florentin Smarandache Jan 2005

Quantum Quasi-Paradoxes And Quantum Sorites Paradoxes, Florentin Smarandache

Branch Mathematics and Statistics Faculty and Staff Publications

There can be generated many paradoxes or quasi-paradoxes that may occur from the combination of quantum and non-quantum worlds in physics. Even the passage from the micro-cosmos to the macro-cosmos, and reciprocally, can generate unsolved questions or counter-intuitive ideas. We define a quasi-paradox as a statement which has a prima facie self-contradictory support or an explicit contradiction, but which is not completely proven as a paradox. We present herein four elementary quantum quasi-paradoxes and their corresponding quantum Sorites paradoxes, which form a class of quantum quasi-paradoxes.


Upper Limits From The Ligo And Tama Detectors On The Rate Of Gravitational-Wave Bursts, B. P. Abbott, R. Abbott, W. G. Anderson, Mario C. Diaz, Wm. R. Johnston, Soumya Mohanty, Cristina V. Torres Jan 2005

Upper Limits From The Ligo And Tama Detectors On The Rate Of Gravitational-Wave Bursts, B. P. Abbott, R. Abbott, W. G. Anderson, Mario C. Diaz, Wm. R. Johnston, Soumya Mohanty, Cristina V. Torres

Physics and Astronomy Faculty Publications and Presentations

We report on the first joint search for gravitational waves by the TAMA and LIGO collaborations. We looked for millisecond-duration unmodeled gravitational-wave bursts in 473 hr of coincident data collected during early 2003. No candidate signals were found. We set an upper limit of 0.12 events per day on the rate of detectable gravitational-wave bursts, at 90% confidence level. From software simulations, we estimate that our detector network was sensitive to bursts with root-sum-square strain amplitude above approximately 1–3×10−19  Hz−1/2 in the frequency band 700-2000 Hz. We describe the details of this collaborative search, with particular emphasis on its advantages …


Phase Effects In The Diffraction Of Light: Beyond The Grating Equation, Stacy Wise, V. Quetschke, A. J. Deshpande, G. Mueller, D. H. Reitze, D. B. Tanner, B. F. Whiting, Y. Chen Jan 2005

Phase Effects In The Diffraction Of Light: Beyond The Grating Equation, Stacy Wise, V. Quetschke, A. J. Deshpande, G. Mueller, D. H. Reitze, D. B. Tanner, B. F. Whiting, Y. Chen

Physics and Astronomy Faculty Publications and Presentations

Diffraction gratings affect the absolute phase of light in a way that is not obvious from the usual derivation of optical paths using the grating equation. For example, consider light which encounters first one and then the second of two parallel gratings. If one grating is moved parallel to its surface, the phase of the light diffracted from the grating pair is shifted by 2π each time the grating is moved by one grating constant, even though the geometric path length is not altered by the motion. This additional phase shift must be included when incorporating diffraction gratings in interferometers.


Electric-Field Generated By The Combustion Of Titanium In Nitrogen, Karen S. Martirosyan, Mona Setoodeh, Dan Luss Jan 2005

Electric-Field Generated By The Combustion Of Titanium In Nitrogen, Karen S. Martirosyan, Mona Setoodeh, Dan Luss

Physics and Astronomy Faculty Publications and Presentations

A short temporal electrical impulse (duration of 30–150ms) was generated during the nitridation of mixtures of titanium and titanium nitride by a high temperature moving reaction front. The maximum voltage and current were generated in the combustion front region, in which the conversion of Ti to TiN was incomplete. The electric field (voltage up to 2V and current up to 60mA) decayed and vanished before the maximum combustion temperature was attained. The generation of an electric field during a rapid high-temperature nitridation is most probably due to the different diffusion velocities of charge carriers through the growing titanium nitride shell …


Coupled Electrical And Magnetic Properties In (La,Sr)Feo3-Δ, X.-D. Zhou, Qingsheng Cai, Jinbo Yang, M. S. Kim, William B. Yelon, William Joseph James, Y.-W. Shin, B. J. Scarfino, Harlan U. Anderson Jan 2005

Coupled Electrical And Magnetic Properties In (La,Sr)Feo3-Δ, X.-D. Zhou, Qingsheng Cai, Jinbo Yang, M. S. Kim, William B. Yelon, William Joseph James, Y.-W. Shin, B. J. Scarfino, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

This article is aimed at studying the temperature dependence oxygen nonstoichiometry, magnetic moments, Fe3+ fraction, Néel temperature and conductivity of (La,Sr)FeO3-δ. It is found that the magnetic properties in La0.60 Sr0.40 Fe3-δ is determined by Fe3+ and its concentration, and the conductance is resulted from Fe4+ ions, which act as electron holes. Both of magnetic and electrical properties were directly governed by oxygen nonstoichiometry (δ). when δ=0.2, the compound has maximum Fe3+, the saturation magnetic moments and Néel temperature are 3.8 µB and 410 °C, both at the highest level, …


Phase Transition In Single Crystal Cs2nb4o11, Jianjun Liu, E. P. Kharitonova, Chun-Gang Duan, Wai-Ning Mei, Robert W. Smith, John R. Hardy Jan 2005

Phase Transition In Single Crystal Cs2nb4o11, Jianjun Liu, E. P. Kharitonova, Chun-Gang Duan, Wai-Ning Mei, Robert W. Smith, John R. Hardy

Physics Faculty Publications

We studied temperature dependence of complex capacitance, impedance, and polarized Raman spectra of single crystal Cs2Nb4O11. First, we observed a sharp λ-shaped peak at 165 °C in the complex capacitance, then found drastic changes in the Raman spectra in the same temperature range. Utilizing the pseudosymmetry search of structure space group, we attributed the observed anomalies to a structural change from the room temperature orthorhombic Pnn2 to another orthorhombic Imm2. We also measured room temperature polarized Raman spectra in different symmetries of normal vibrations and assigned high wavenumber Raman bands to the …


How Generic Scale Invariance Influences Quantum And Classical Phase Transitions, D. Belitz, T. Kirkpatrick, Thomas Vojta Jan 2005

How Generic Scale Invariance Influences Quantum And Classical Phase Transitions, D. Belitz, T. Kirkpatrick, Thomas Vojta

Physics Faculty Research & Creative Works

This review discusses a paradigm that has become of increasing importance in the theory of quantum phase transitions, namely, the coupling of the order-parameter fluctuations to other soft modes and the resulting impossibility of constructing a simple Landau-Ginzburg-Wilson theory in terms of the order parameter only. The soft modes in question are manifestations of generic scale invariance, i.e., the appearance of long-range order in whole regions in the phase diagram. The concept of generic scale invariance and its influence on critical behavior is explained using various examples, both classical and quantum mechanical. The peculiarities of quantum phase transitions are discussed, …


Near-Field Intensity Correlations In Semicontinuous Metal Films, K. Seal, H. Noh, Alexey Yamilov, A. K. Sarchev, D. A. Genov, V. M. Shalaev, Z. C. Ying, Hui Cao Jan 2005

Near-Field Intensity Correlations In Semicontinuous Metal Films, K. Seal, H. Noh, Alexey Yamilov, A. K. Sarchev, D. A. Genov, V. M. Shalaev, Z. C. Ying, Hui Cao

Physics Faculty Research & Creative Works

Spatial intensity correlation functions of semicontinuous metal-dielectric films of varying metal concentration, p, were obtained from near-field microscopy. The data shows a transition from propagation to localization and back to propagation of optical excitations with increase in p.


Static Pairwise Annihilation In Complex Networks, M. F. Laguna, M. Aldana, H. Larralde, V. M. Kenkre, Paul Ernest Parris Jan 2005

Static Pairwise Annihilation In Complex Networks, M. F. Laguna, M. Aldana, H. Larralde, V. M. Kenkre, Paul Ernest Parris

Physics Faculty Research & Creative Works

We study static annihilation on complex networks, in which pairs of connected particles annihilate at a constant rate during time. Through a mean-field formalism, we compute the temporal evolution of the distribution of surviving sites with an arbitrary number of connections. This general formalism, which is exact for disordered networks, is applied to Kronecker, Erdös-Rényi (i.e., Poisson), and scale-free networks. We compare our theoretical results with extensive numerical simulations obtaining excellent agreement. Although the mean-field approach applies in an exact way neither to ordered lattices nor to small-world networks, it qualitatively describes the annihilation dynamics in such structures. Our results …


Photonic Band Structure Of Zno Photonic Crystal Slab Laser, Alexey Yamilov, X. Wu, Hui Cao Jan 2005

Photonic Band Structure Of Zno Photonic Crystal Slab Laser, Alexey Yamilov, X. Wu, Hui Cao

Physics Faculty Research & Creative Works

We recently reported on the realization of ultraviolet photonic crystal laser based on zinc oxide [Appl. Phys. Lett. 85, 3657 (2004)]. Here we present the details of structural design and its optimization. We develop a computational supercell technique that allows a straightforward calculation of the photonic band structure of ZnO photonic crystal slab on sapphire substrate. We find that despite the small index contrast between the substrate and the photonic layer, the low-order eigenmodes have predominantly transverse-electric (TE) or transverse-magnetic polarization. Because emission from ZnO thin film shows a strong TE preference, we are able to limit our consideration to …


Analysis Of High-Quality Modes In Open Chaotic Microcavities, W. Fang, Alexey Yamilov, Hui Cao Jan 2005

Analysis Of High-Quality Modes In Open Chaotic Microcavities, W. Fang, Alexey Yamilov, Hui Cao

Physics Faculty Research & Creative Works

We present a numerical study of the high-quality modes in two-dimensional dielectric stadium microcavities. Although the classical ray mechanics is fully chaotic in a stadium billiard, all of the high-quality modes show a ``strong scar'' around unstable periodic orbits. when the deformation (ratio of the length of the straight segments over the diameter of the half circles) is small, the high-quality modes correspond to whispering-gallery-type trajectories and their quality factors decrease monotonically with increasing deformation. At large deformation, each high-quality mode is associated with multiple unstable periodic orbits. Its quality factor changes nonmonotonically with the deformation, and there exists an …


Limits On Gravitational-Wave Emission From Selected Pulsars Using Ligo Data, B. P. Abbott, R. Abbott, Mario C. Diaz, Wm. R. Johnston, Soumya Mohanty, Soma Mukherjee, Cristina V. Torres Jan 2005

Limits On Gravitational-Wave Emission From Selected Pulsars Using Ligo Data, B. P. Abbott, R. Abbott, Mario C. Diaz, Wm. R. Johnston, Soumya Mohanty, Soma Mukherjee, Cristina V. Torres

Physics and Astronomy Faculty Publications and Presentations

We place direct upper limits on the amplitude of gravitational waves from 28 isolated radio pulsars by a coherent multidetector analysis of the data collected during the second science run of the LIGO interferometric detectors. These are the first direct upper limits for 26 of the 28 pulsars. We use coordinated radio observations for the first time to build radio-guided phase templates for the expected gravitational-wave signals. The unprecedented sensitivity of the detectors allows us to set strain upper limits as low as a few times 10−24. These strain limits translate into limits on the equatorial ellipticities of the pulsars, …


Measurement Of Charm Fragmentation Ratios And Fractions In Photoproduction At Hera, S. Chekanov, M. Derrick, S. Magill, S. Miglioranzi, B. Musgrave, J. Repond, R. Yoshida, Margarita C. K. Mattingly, N. Pavel, A. G. Yagües Molina, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, P. Giusti, G. Iacobucci, A. Margotti, A. Montanari, R. Nania, F. Palmonari, A. Pesci, A. Polini Jan 2005

Measurement Of Charm Fragmentation Ratios And Fractions In Photoproduction At Hera, S. Chekanov, M. Derrick, S. Magill, S. Miglioranzi, B. Musgrave, J. Repond, R. Yoshida, Margarita C. K. Mattingly, N. Pavel, A. G. Yagües Molina, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, P. Giusti, G. Iacobucci, A. Margotti, A. Montanari, R. Nania, F. Palmonari, A. Pesci, A. Polini

Faculty Publications

© 2005, Springer New York LLC. All rights reserved. The production of D∗+, D0, D+, D+s and Λ+c charm hadrons and their antiparticles in ep scattering at HERA was measured with the ZEUS detector using an integrated luminosity of 79 pb−1. The measurement has been performed in the photoproduction regime with the exchanged-photon virtuality Q2 < 1GeV2 and for photon-proton centre-of-mass energies in the range 130 3.8GeV and pseudorapidity |η(D,Λc)| < 1.6. The production cross sections were used to determine the ratio of neutral and charged D-meson production rates, Ru/d, the strangeness-suppression factor, γs, and the fraction of charged D mesons produced in a vector state, Pdv. The measured Ru/d and γs values agree with those obtained in deep inelastic scattering and in e+e- annihilations. The measured Pdv value is smaller than, but consistent with, the previous measurements. The fractions of c quarks hadronising as a particular charm hadron, f(c → D, Λc), were derived in the given kinematic range. The measured open-charm fragmentation fractions are consistent with previous results, although the measured f(c → D*+) is smaller and f(c → Λ+c) is larger than those obtained in e+e- annihilations. These results generally support the hypothesis that fragmentation proceeds independently of the hard sub-process.


A New Form Of Matter — Unmatter, Composed Of Particles And Anti-Particles, Florentin Smarandache Jan 2005

A New Form Of Matter — Unmatter, Composed Of Particles And Anti-Particles, Florentin Smarandache

Branch Mathematics and Statistics Faculty and Staff Publications

Besides matter and antimatter there must exist unmatter (as a new form of matter) in accordance with the neutrosophy theory that between an entity (a) and its opposite there exist intermediate entities . Unmatter is neither matter nor antimatter, but something in between. An atom of unmatter is formed either by (1): electrons, protons, and antineutrons, or by (2): antielectrons, antiprotons, and neutrons. At CERN it will be possible to test the production of unmatter. The existence of unmatter in the universe has a similar chance to that of the antimatter, and its production also difficult for present technologies.


Inclusive And Exclusive Compton Processes In Quantum Chromodynamics, A. Psaker Jan 2005

Inclusive And Exclusive Compton Processes In Quantum Chromodynamics, A. Psaker

Physics Theses & Dissertations

In our work, we describe two types of Compton processes. As an example of an inclusive process, we consider the high-energy photoproduction of massive muon pairs off the nucleon. We analyze the process in the framework of the QCD parton model, in which the usual parton distributions emerge as a tool to describe the nucleon in terms of quark and gluonic degrees of freedom. To study its exclusive version, a new class of phenomenological functions is required, namely, generalized parton distributions. They can be considered as a generalization of the usual parton distributions measured in deeply inelastic lepton-nucleon scattering. Generalized …


Thermal And Conductivity Studies Of Chitosan Acetate-Based Polymer Electrolytes, Zurina Osman Dec 2004

Thermal And Conductivity Studies Of Chitosan Acetate-Based Polymer Electrolytes, Zurina Osman

Zurina Osman

Thermogravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC) have been employed to study the thermal stability of the chitosan acetate-based polymer electrolyte films. The glass transition temperature, T-g measurements confirm the conductivity enhancement effect by adding the plasticizer and salt in the chitosan acetate films


Gaas–Polymer Hybrids Formed By Surface-Initiated Atom-Transfer Radical Polymerization Of Methyl Methacrylate, Qj Cai, Df Guo, F.R. Zhu, Et Kang, Kg Neoh Dec 2004

Gaas–Polymer Hybrids Formed By Surface-Initiated Atom-Transfer Radical Polymerization Of Methyl Methacrylate, Qj Cai, Df Guo, F.R. Zhu, Et Kang, Kg Neoh

Professor ZHU, Fu Rong

No abstract provided.


Flexible Top-Emitting Electroluminescent Devices On Polyethylene Terephthalate Substrates, Yq Li, Lw Tan, Xt Hao, Ks Ong, F.R. Zhu, Ls Hung Dec 2004

Flexible Top-Emitting Electroluminescent Devices On Polyethylene Terephthalate Substrates, Yq Li, Lw Tan, Xt Hao, Ks Ong, F.R. Zhu, Ls Hung

Professor ZHU, Fu Rong

No abstract provided.


A General Low-Temperature Route For Large-Scale Fabrication Of Highly Oriented Zno Nanorod/Nanotube Arrays, Hd Yu, Zp Zhang, My Han, Xt Hao, F.R. Zhu Dec 2004

A General Low-Temperature Route For Large-Scale Fabrication Of Highly Oriented Zno Nanorod/Nanotube Arrays, Hd Yu, Zp Zhang, My Han, Xt Hao, F.R. Zhu

Professor ZHU, Fu Rong

No abstract provided.


Effects Of Electron Irradiation On The Ferroelectric Properties Of Langmuir-Blodgett Copolymer Films, Christina Othon, Fred Bateman, Stephen Ducharme Dec 2004

Effects Of Electron Irradiation On The Ferroelectric Properties Of Langmuir-Blodgett Copolymer Films, Christina Othon, Fred Bateman, Stephen Ducharme

Christina M Othon

The effect of irradiation on the ferroelectric properties of Langmuir-Blodgett films of the copolymer poly(vinylidene fluoride-trifluoroethylene) was investigated using 1‐MeV electrons for doses from 0.16 to 1.10 MGy, where 1 Gray (Gy) = 100 rad. Irradiation causes a systematic decrease in the phase-transition temperature, crystallinity, and spontaneous polarization of the films. The crystallinity and spontaneous polarization of the films decreased by amounts proportional to the dose, both tending toward zero near a dose of 1.30 MGy. The ferroelectric-paraelectric phase-transition temperature, however, was only reduced by about 12%, indicating that the primary effect of irradiation was to convert a crystalline ferroelectric …


Approximate Solutions For Magmon Propagation From A Reservoir, Tim Marchant Dec 2004

Approximate Solutions For Magmon Propagation From A Reservoir, Tim Marchant

Tim Marchant

A 1D partial differential equation (pde) describing the flow of magma in the Earth's mantle is considered, this equation allowing for compaction and distension of the surrounding matrix due to the magma. The equation has periodic travelling wave solutions, one limit of which is a solitary wave, called a magmon. Modulation equations for the magma equation are derived and are found to be either hyperbolic or of mixed hyperbolic/elliptic type, depending on the specific values of the wave number, mean height and amplitude of the underlying modulated wave. The periodic wave train is stable in the hyperbolic case and unstable …


Spatially Heterogeneous Dynamics And The Adam-Gibbs Relation In The Dzugutov Liquid, Yeshitela Gebremichael, M Vogel, M Bergroth, Francis W. Starr, Sharon C. Glotzer Dec 2004

Spatially Heterogeneous Dynamics And The Adam-Gibbs Relation In The Dzugutov Liquid, Yeshitela Gebremichael, M Vogel, M Bergroth, Francis W. Starr, Sharon C. Glotzer

Francis Starr

No abstract provided.


Interactions Between Xenon And Phospholipid Bicelles Studied By 2h/129xe/131xe Nmr And Optical Pumping Of Nuclear Spins, Xiaoxia Li, Caitlin Newberry, Indrajit Saha, Panayiotis Nikolaou, Nicholas Whiting, Boyd M. Goodson Dec 2004

Interactions Between Xenon And Phospholipid Bicelles Studied By 2h/129xe/131xe Nmr And Optical Pumping Of Nuclear Spins, Xiaoxia Li, Caitlin Newberry, Indrajit Saha, Panayiotis Nikolaou, Nicholas Whiting, Boyd M. Goodson

Nicholas Whiting

The interactions between xenon and DMPC/DHPC bicelles (q = 3.5%,7.5% w/v) were studied via 2H, 129Xe, 131Xe, and optically enhanced 129Xe NMR. The chemical shifts, linewidths, and quadrupolar couplings of the xenon/bicelle NMR signals were correlated with different regions of the bicellar phase diagram. The addition of xenon (<70 mM) was observed to reduce the temperature-onset of bicelle alignment by several degrees, in quantitative agreement with effects previously observed with chloroform; however, the stable liquid-crystalline range was not significantly reduced. Preliminary laser-polarized xenon/bicelle studies yielded 129Xe T1 values of ~120 s, long enough to permit a variety of planned experiments.