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Full-Text Articles in Physics

Si Doping Of High-Al-Mole Fraction Alxga1-Xn Alloys With Rf Plasma-Induced Molecular-Beam-Epitaxy, Jeonghyun Hwang, William J. Schaff, Lester F. Eastman, Shawn T. Bradley, Leonard J. Brillson, David C. Look, J. Wu, Wladek Walukiewicz, Madalina Furis, Alexander N. Cartwright Dec 2002

Si Doping Of High-Al-Mole Fraction Alxga1-Xn Alloys With Rf Plasma-Induced Molecular-Beam-Epitaxy, Jeonghyun Hwang, William J. Schaff, Lester F. Eastman, Shawn T. Bradley, Leonard J. Brillson, David C. Look, J. Wu, Wladek Walukiewicz, Madalina Furis, Alexander N. Cartwright

Physics Faculty Publications

Very high levels of n-type doping of AlxGa1−xN alloys were recently achieved by rf plasma-induced molecular-beam epitaxy on sapphire substrates and Si as a dopant. Electron concentrations were obtained up to 1.25×1020 cm−3 when the Al mole fraction was 50%, and 8.5×1019 cm−3 electrons were measured even when the Al mole fraction was 80%. Other material properties were determined by optical absorption, photoluminescence, cathodoluminescence, x-ray diffraction, and atomic force microscopy measurements and high optical and morphological qualities were shown.


Recombination Of Excitons Bound To Oxygen And Silicon Donors In Freestanding Gan, A. Wysmolek, K. P. Korona, R. Stepniewski, J. M. Baranowsky, J. Bloniarz, M. Potemski, R. L. Jones, David C. Look, J. Kuhl, S. S. Park, S. K. Lee Dec 2002

Recombination Of Excitons Bound To Oxygen And Silicon Donors In Freestanding Gan, A. Wysmolek, K. P. Korona, R. Stepniewski, J. M. Baranowsky, J. Bloniarz, M. Potemski, R. L. Jones, David C. Look, J. Kuhl, S. S. Park, S. K. Lee

Physics Faculty Publications

The neutral donor bound exciton recombination processes in freestanding GaN have been studied. The photoluminescence spectrum shows emission lines related to silicon and oxygen donors. Time-resolved luminescence allows us to correlate the principal donor bound exciton lines with their two-electron satellites. The magnetic field splitting of the two-electron lines is well described by the theory of the hydrogen atom in a magnetic field. For the oxygen donor a 1.5 meV chemical shift and a 30.8 meV effective Rydberg have been evaluated. Two-electron satellites involving excitations to the 2p and 2s donor states are separated by an energy of 1.0 and …


Microcathodoluminescence And Electron Beam Induced Current Observation Of Dislocations In Freestanding Thick N-Gan Sample Grown By Hydride Vapor Phase Epitaxy, A. Y. Polyakov, A. V. Govorkov, N. B. Smirnov, Z-Q. Fang, David C. Look, Seong-Ju S. Park, J. H. Han Nov 2002

Microcathodoluminescence And Electron Beam Induced Current Observation Of Dislocations In Freestanding Thick N-Gan Sample Grown By Hydride Vapor Phase Epitaxy, A. Y. Polyakov, A. V. Govorkov, N. B. Smirnov, Z-Q. Fang, David C. Look, Seong-Ju S. Park, J. H. Han

Physics Faculty Publications

Microcathodolumunescence (MCL) spectra measurements, MCL and electron beam induced current (EBIC) imaging of the freestanding n-GaN samples grown by hydride vapor phase epitaxy were made. Dark-spot defects in plan-view EBIC and MCL images and dark line defects in MCL images taken on the cleaved surface of the samples could be associated with dislocations. MCL spectra measurements in the vicinity of dislocations and in the matrix do not reveal specific luminescence bands that could be attributed to dislocations but rather suggest that dislocation regions have higher density of deep nonradiative traps.


Deep Electron And Hole Traps In Freestanding N-Gan Grown By Hydride Vapor Phase Epitaxy, A. Y. Polyakov, N. B. Smirnov, A. V. Govorkov, Z-Q. Fang, David C. Look, Seong-Ju S. Park, J. H. Han Nov 2002

Deep Electron And Hole Traps In Freestanding N-Gan Grown By Hydride Vapor Phase Epitaxy, A. Y. Polyakov, N. B. Smirnov, A. V. Govorkov, Z-Q. Fang, David C. Look, Seong-Ju S. Park, J. H. Han

Physics Faculty Publications

Deep level electron and hole traps were studied by means of deep level transient spectroscopy with electrical and optical injection on a freestanding thick n-GaN sample with low dislocation density. It is shown that at both the upper and the lower surface of the sample there exists a thin, ∼0.5 μm layer of damaged material with lowered concentration of electrons and enhanced density of deep centers. Deep in the bulk of the film the densities of the majority of the electron and hole traps are shown to be very low, but measurably higher on the lower face (N face), …


Thermoelectric Effect Spectroscopy Of Deep Levels In Semi-Insulating Gan, U. V. Desnica, M. Pavlovic, Z-Q. Fang, David C. Look Oct 2002

Thermoelectric Effect Spectroscopy Of Deep Levels In Semi-Insulating Gan, U. V. Desnica, M. Pavlovic, Z-Q. Fang, David C. Look

Physics Faculty Publications

The report of thermoelectric effect spectroscopy (TEES) applied on semi-insulating GaN was presented. The type of TEES setup, especially suitable for film-on-substrate samples, was devised. TEES enabled determination of sign of observed deep traps. Using TEES and thermally stimulated current spectroscopy measurements in combination with the simultaneous multiple peak analysis formalism all important trap parameters were determined. The shallowest identified electron and hole traps had activation energies Ec−0.09 eV and Ev+0.167 eV, respectively. Results indicate that both these traps, oppositely charged are present in the studied material in relatively high concentrations causing the electrical compensation and …


Representation Of A Quantum Ensemble As A Minimal Set Of Pure States, Thomas E. Skinner, Steffen J. Glaser Sep 2002

Representation Of A Quantum Ensemble As A Minimal Set Of Pure States, Thomas E. Skinner, Steffen J. Glaser

Physics Faculty Publications

The density matrix ρ for an n-level system is decomposed into the minimum number of pure states necessary to calculate physical observables. The corresponding physical system is first represented by a set B of n pure states |βi〉, together with their statistical weights. The time evolution of the system is therefore calculated as B(t)=UB(t0), with the propagator U operating on each member of the set, in contrast to the more laborious ρ(t)=Uρ(t0)U. At least one of the states can be eliminated from the set by reducing its weight to zero via a …


Characterization Of Homoepitaxial P-Type Zno Grown By Molecular Beam Epitaxy, David C. Look, D. C. Reynolds, C. W. Litton, R. L. Jones, D. B. Eason, G. Cantwell Sep 2002

Characterization Of Homoepitaxial P-Type Zno Grown By Molecular Beam Epitaxy, David C. Look, D. C. Reynolds, C. W. Litton, R. L. Jones, D. B. Eason, G. Cantwell

Physics Faculty Publications

An N-doped, p-type ZnO layer has been grown by molecular beam epitaxy on an Li-diffused, bulk, semi-insulating ZnO substrate. Hall-effect and conductivity measurements on the layer give: resistivity = 4×101 Ω cm; hole mobility = 2 cm2/V s; and hole concentration = 9×1016 cm−3. Photoluminescence measurements in this N-doped layer show a much stronger peak near 3.32 eV (probably due to neutral acceptor bound excitons), than at 3.36 eV (neutral donor bound excitons), whereas the opposite is true in undoped ZnO. Calibrated, secondary-ion mass spectroscopy measurements show an N surface concentration of about …


Deep Hole Traps In N-Gan Films Grown By Hydride Vapor Phase Epitaxy, A. Y. Polyakov, N. B. Smirnov, A. V. Govorkov, Z-Q. Fang, David C. Look, Richard J. Molnar, A. V. Osinsky May 2002

Deep Hole Traps In N-Gan Films Grown By Hydride Vapor Phase Epitaxy, A. Y. Polyakov, N. B. Smirnov, A. V. Govorkov, Z-Q. Fang, David C. Look, Richard J. Molnar, A. V. Osinsky

Physics Faculty Publications

Concentrations of deep hole traps were measured in a set of hydride vapor phase epitaxy grown samples with thicknesses varying from 2.6 to 68 μm. Results were obtained from low temperature capacitance–voltage measurements before and after illumination and from deep level transient spectroscopy measurements with optical injection (ODLTS). The former revealed the presence of high densities (∼1015 to 1016 cm−3) of hole traps whose concentration decreased with sample thickness in a manner similar to that found for the dislocation density. Capacitance versus temperature measurements in the dark and after illumination suggested that these traps form a …


Depth-Dependent Investigation Of Defects And Impurity Doping In Gan/Sapphire Using Scanning Electron Microscopy And Cathodoluminescence Spectroscopy, X. L. Sun, S. H. Goss, L. J. Brillson, David C. Look, Richard J. Molnar May 2002

Depth-Dependent Investigation Of Defects And Impurity Doping In Gan/Sapphire Using Scanning Electron Microscopy And Cathodoluminescence Spectroscopy, X. L. Sun, S. H. Goss, L. J. Brillson, David C. Look, Richard J. Molnar

Physics Faculty Publications

Cathodoluminescence (CL) imaging and temperature-dependent cathodoluminescence spectroscopy (CLS) have been used to probe the spatial distribution and energies of electronic defects near GaN/Al2O3 interfaces grown by hydride vapor phase epitaxy (HVPE). Cross sectional secondary electron microscopy imaging, CLS, and CL imaging show systematic variations in defect emissions with a wide range of HVPE GaN/sapphire electronic properties. These data, along with electrochemical capacitance–voltage profiling and secondary ion mass spectrometry provide a consistent picture of near-interface doping by O out-diffusion from Al2O3 into GaN over hundreds of nanometers. Low-temperature CL spectra exhibit a new donor level …


Production Of Nitrogen Acceptors In Zno By Thermal Annealing, N. Y. Garces, N. C. Giles, L. E. Halliburton, G. Cantwell, D. B. Eason, D. C. Reynolds, David C. Look Feb 2002

Production Of Nitrogen Acceptors In Zno By Thermal Annealing, N. Y. Garces, N. C. Giles, L. E. Halliburton, G. Cantwell, D. B. Eason, D. C. Reynolds, David C. Look

Physics Faculty Publications

Nitrogen acceptors are formed when undoped single crystals of zinc oxide (ZnO) grown by the chemical-vapor transport method are annealed in air or nitrogen atmosphere at temperatures between 600 and 900 °C. After an anneal, an induced near-edge absorption band causes the crystals to appear yellow. Also, the concentration of neutral shallow donors, as monitored by electron paramagnetic resonance (EPR), is significantly reduced. A photoinduced EPR signal due to neutral nitrogen acceptors is observed when the annealed crystals are exposed to laser light (e.g., 364, 442, 458, or 514 nm) at low temperature. The nitrogens are initially in the nonparamagnetic …


Electrical Characterization Of Vapor-Phase-Grown Single-Crystal Zno, F. D. Auret, S. A. Goodman, M. J. Legodi, W. E. Meyer, David C. Look Feb 2002

Electrical Characterization Of Vapor-Phase-Grown Single-Crystal Zno, F. D. Auret, S. A. Goodman, M. J. Legodi, W. E. Meyer, David C. Look

Physics Faculty Publications

Gold Schottky-barrier diodes (SBDs) were fabricated on vapor-phase-grown single-crystal ZnO. Deep-level transient spectroscopy, using these SBDs, revealed the presence of four electron traps, the major two having levels at 0.12 eV and 0.57 below the conduction band. Comparison with temperature-dependent Hall measurements suggests that the 0.12 eV level has a temperature activated capture cross section with a capture barrier of about 0.06 eV and that it may significantly contribute to the free-carrier density. Based on the concentrations of defects other than this shallow donor, we conclude that the quality of the vapor-phase-grown ZnO studied here supercedes that of other single-crystal …


Donor And Acceptor Concentrations In Degenerate Inn, David C. Look, H. Lu, William J. Schaff, J. Jasinski, Z. Liliental-Weber Jan 2002

Donor And Acceptor Concentrations In Degenerate Inn, David C. Look, H. Lu, William J. Schaff, J. Jasinski, Z. Liliental-Weber

Physics Faculty Publications

A formalism is presented to determine donor (ND) and acceptor (NA) concentrations in wurtzitic InN characterized by degenerate carrier concentration (n) and mobility (μ). The theory includes scattering not only by charged point defects and impurities, but also by charged threading dislocations, of concentration Ndis. For a 0.45-μm-thick InN layer grown on Al2O3 by molecular beam epitaxy, having Ndis = 5×1010 cm−2, determined by transmission electron microscopy, n(20 K) = 3.5×1018 cm−3 and μ(20 K) = 1055 cm2 …


High Spatial Resolution Thermal Conductivity Of Bulk Zno (0001), Diana I. Florescu, L. G. Mourokh, Fred H. Pollak, David C. Look, G. Cantwell, X. Li Jan 2002

High Spatial Resolution Thermal Conductivity Of Bulk Zno (0001), Diana I. Florescu, L. G. Mourokh, Fred H. Pollak, David C. Look, G. Cantwell, X. Li

Physics Faculty Publications

We measured high spatial/depth resolution 300 K thermal conductivity κ of the Zn and O surfaces of two bulk n-type ZnO (0001) samples, grown by a vapor-phase transport method, using scanning thermal microscopy (SThM). The thermal investigation was performed in both point-by-point (∼2 μm resolution) and area-scan modes. On the first sample κ=1.16±0.08 (Zn face)/1.10±0.09 (O face) W/cm K while for the second material κ=1.02±0.07 (Zn face)/0.98±0.08 (O face) W/cm K. These are the highest κ values reported on ZnO. A correlation between SThM area-scan readings and surface topography was established by simultaneously performing atomic force microscopy scans. The …