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Articles 1 - 8 of 8
Full-Text Articles in Physics
Electronic Origins Of Ordering In Multicomponent Metallic Alloys: Application To The Cu-Ni-Zn System, J. D. Althoff, Duane D. Johnson, F. J. Pinski, J. B. Staunton
Electronic Origins Of Ordering In Multicomponent Metallic Alloys: Application To The Cu-Ni-Zn System, J. D. Althoff, Duane D. Johnson, F. J. Pinski, J. B. Staunton
Duane D. Johnson
We investigate the ordering tendencies of the fcc Cu-Ni-Zn system using a recently developed first-principles, density-functional-based theory of atomic short-range order (ASRO) in disordered substitutional alloys of an arbitrary number of components. We find for the binary alloys a variety of effects which should lead to competition in the ternaries: commensurate ordering (Ni-Zn), long-period ordering (Cu-rich Cu-Zn), and clustering (Cu-Ni), in agreement with experiment. We calculate the ASRO of various disordered ternary alloys (as described by the Warren-Cowley pair-correlation function) and discuss its relationship to the electronic structure of the binary and ternary disordered alloys. We find [100]-type ASRO over …
Gaussian Phase Approximation For Evaluating The Decay Of Nmr Spin Echoes, Charles Recchia, K Gorny, C Pennington
Gaussian Phase Approximation For Evaluating The Decay Of Nmr Spin Echoes, Charles Recchia, K Gorny, C Pennington
Charles H Recchia
No abstract provided.
Effects Of Local Non-Equilibrium Solute Diffusion On Rapid Solidification Of Alloys, Sergey Sobolev
Effects Of Local Non-Equilibrium Solute Diffusion On Rapid Solidification Of Alloys, Sergey Sobolev
Sergey Sobolev
A conceptual foundation for the study of local non-equilibrium solute diffusion under rapid solidifica- tion conditions is proposed. The model takes into account the relaxation to local equilibrium of the solute flux and incorporates two diffusion speeds, VDb, the bulk liquid diffusion speed, and VDi, the interface diffusive speed, as the most important parameters governing the solute concentration in the liquid phase and solute partitioning. The analysis of the model predicts complete solute trapping and the transition to a purely thermally controlled solidification, which occur abruptly when the interface velocity V equals the bulk liquid diffusion speed VDb. The abrupt …
The Local-Nonequilibrium Temperature Field Around The Melting And Crystallization Front Induced By Picosecond Pulsed Laser Irradiation, Sergey Sobolev
The Local-Nonequilibrium Temperature Field Around The Melting And Crystallization Front Induced By Picosecond Pulsed Laser Irradiation, Sergey Sobolev
Sergey Sobolev
The local-nonequilibrium model for heat transport around melting and crystallization zone induced by ultrafast laser irradiation is considered. The model predicts strong overheating during melting of the material near the interface. Moreover, the local-nonequilibrium effects lead to an interface temperature gradient steeper than expected from the classical heat flow calculations. Possible modification of the kinetics of melting to include the relaxation effects is also discussed.
Raman Spectroscopy Of Carbon Materials, Jr Dennison, Mark Holtz, Greg Swain
Raman Spectroscopy Of Carbon Materials, Jr Dennison, Mark Holtz, Greg Swain
Journal Articles
Use of carbon materials is no longer limited to diamond jewelry or graphite pencils and lubricants. The last decade has witnessed an explosion of technological applications driven by the development of fabrication methods and the discovery of several new classes of pure carbon. Structural diversity exhibited by the carbon atoms, from local chemical order to long-range crystalline order, is key to understanding their physical and chemical properties and in future materials development. This article summarizes the use of Raman spectroscopy as a principal tool to investigate the vibrational dynamics of carbon materials and to provide indirect structural characterization of their …
Application Of (E,2e) Spectroscopy To The Electronic Structure Of Valence Electrons In Crystalline And Amorphous Solids, Jr Dennison, A. L. Ritter
Application Of (E,2e) Spectroscopy To The Electronic Structure Of Valence Electrons In Crystalline And Amorphous Solids, Jr Dennison, A. L. Ritter
Journal Articles
This review presents theoretical and experimental aspects of (e,2e) spectroscopy specific to the study of crystalline and amorphous solids. The cross section for (e,2e) scattering is proportional to the spectral momentum density of the ejected electron under certain approximations. The theoretical framework for interpreting (e,2e) measurements is summarized here and general properties of the spectral momentum density of solids are discussed. Different designs of the (e,2e) spectrometer are described and sample preparation techniques are briefly reviewed. A summary of recent (e,2e) experiments on the electronic structure of valence electrons in graphite, ion sputtered and evaporated amorphous carbon, and aluminum-aluminum oxide …
Selective Inversion In Solid-State Deuteron Nmr, Marco J. Brown
Selective Inversion In Solid-State Deuteron Nmr, Marco J. Brown
Dissertations, Theses, and Masters Projects
Deuteron NMR selective inversion (SI) is developed to study slow molecular motions in solids. Theoretical and practical aspects of selective inversion of spin-1 nuclei in solids are presented. Differences between powdered solids and liquids are considered. Double sideband modulated (DSBM) shaped pulses are shown to improve the performance of SI pulses. DSBM and DANTE selective pulses are compared for off-resonance SI applications. Common spin-{dollar}{lcub}1{rcub}\over{lcub}2{rcub}{dollar} shaped pulses are tested for suitability to solid state deuteron NMR. Simple, short pulses are shown to be most effective due to fast spin-spin relaxation and large underlying homogeneous linewidths in solids.;The power and utility of …
The Projector Basis Method For Electronic Band Structure Calculations, Christopher Haas
The Projector Basis Method For Electronic Band Structure Calculations, Christopher Haas
Dissertations, Theses, and Masters Projects
Over the last several decades, two methods have emerged as the standard tools for the calculation of electronic band structures. These methods, the Car-Parinello plane wave method and the linear augmented plane wave method (LAPW), each have strengths and weaknesses in different regimes of physical problems. The Car-Parinello algorithm is ideal for calculations with soft pseudopotentials and large numbers of atoms. The LAPW method, on the other hand, easily handles all-electron and hard-core pseudopotential calculations with a small number of atoms. The projector basis method, presented here, is a hybrid mixed basis method which allows the calculation of moderately large …